Solution Is A Homogeneous Mixture of Two or More Substances. Ex. Sugar + Water Sugar Solution Salt in Water Salt Solution

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CHAPTER 2

SOLUTION

Is a homogeneous mixture of
two or more substances.

Ex. sugar + water= sugar solution


salt in water= salt solution
Components of a solution:

1. Solute – the substance that is being


dissolved
- component in a smaller amount
Ex. Sugar

2. Solvent- the substance that does the


dissolving
- component in greater amount.
Ex. water
Types of solution based on the phases
of the solute & solvent:
Solute Solvent Example
1. solid solid Cu in Au
2. liquid solid Hg in Cu
3. gas solid H in Pt
4. solid liquid sugar in water
5. liquid liquid alcohol in water
6. gas liquid oxygen in water
7. gas gas carbon dioxide in air
Identify the solute and the
solvent:
a. 10 g KCl dissolved in 100g of water

b. Soda water: CO2 (g) dissolved in water


c. An alloy composed of 80% Zn and 20% Cu
d. A mixture of O2 ( 200 mm Hg) and He
(500 mm Hg)

e. A solution of 40 ml CCl4 and 2 ml Br2


Type of solution based on its capacity to
dissolve a solute:
1. Unsaturated- contains the minimum amount of
solute present in a given amount of solvent at
room temperature.

2. Saturated- contains the maximum amount of solute


that can dissolve in a given amount of solvent at
room temperature.

3. Supersaturated- contains the maximum amount of


solute than present in a given amount of solvent
at an elevated temperature.
Identify each of the following as a
saturated or unsaturated solution
1. A sugar cube dissolves when added to a cup of
coffee.
2. A KCl crystal added to a KCl solution does not
change in size.
3. A layer of sugar forms in the bottom of a glass of
ice tea.
4. The rate of crystal formation equals the rate of
solution.
5. Upon heating, all the sugar dissolves
Factors which affect solubility:

1. Nature of solute and solvent


2. Temperature
3. Agitation
4. Surface Area
5. Particle Size
6. Concentration
Water is polar and hexane is non-polar.
In which solvent is each of the
following soluble?

1. Bromine Br2 , non-polar ___________


2. HCl, polar ___________
3. Cholesterol, non-polar __________
4. Vit. D, non-polar __________
5. Ascorbic acid, polar ______________
Type of solution based on the degree
of ionization
1. Electrolyte
substance that break up into ions
when it goes into a solution.
a. strong electrolyte - (completely ionized)
Ex. NaOH
b. weak electrolyte - (partially ionized)
Ex. HCN
2. Non- electrolyte
substance that does not break up into
ions when it goes into solution.
Ex. Organic compound such as C12H22O11
Quantitative ways of expressing the
concentration of solution:
1. Percent by mass

mass of solute
% by mass = -------------------- x 100
mass of solution

Ex. Find the percentage by mass of K 2CO3 in a solution made


by dissolving 25.0 g of K 2CO3 in 100.0 g of water.
2. Percent by volume

volume of solute
% by volume = ----------------------- x100
volume of solution

Ex. Calculate the volume of pure acetic acid


that is needed to make 150.0 ml solution
which is 5.0% acetic acid by volume.
3. Mole fraction
moles of solute
Mole fraction of solute = ---------------------
moles of solution

moles of solvent
Mole fraction of solvent = --------------------
moles of solution

Ex. Calculate the mole fraction of the solute in a


solution containing 75.0 g of ethanol 450
g of water.
4. Molality

moles of solute
Molality (m) = ---------------------
kg of solvent

Ex. Calculate the molality of a solution


containing 75.0 g of ethanol and 450.0 g
of water.
5. Molarity
moles of solute
Molarity (M)=---------------------
L of solution

Ex. A solution is prepared by dissolving 5.0


g of Na2CO3 in water to form 100.0 ml
of solution. Find the concentration of the
solution in molarity.
Osmosis
-the process whereby a solvent flows through a
semi-permeable membrane into a solution or the
flow of the solvent from a more dilute solution to
a more concentrated solution.

Osmotic pressure - the force causing the diffusion,


or the amount of pressure that is required to
stop the diffusion.

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