Chemistry

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LEWIS

STRUCTURE
COVALENT BONDS
In 1916, Gilbert N. Lewis
proposed that atoms combine in
order to achieve a more stable
electron configuration.
OBJECTIVE

Predict and draw the Lewis structure of


simple covalent molecules and compounds
KEY TAKEAWAYS
KEY POINTS KEY TERMS
➔ The outermost principal energy level that contains ➔ octet rule: Atoms try to achieve the electronic
electrons is called the valence level and contains configuration of the noble gas nearest to them in the
valence electrons. periodic table by achieving a full valence level with eight
➔ In many atoms, not all of the electron pairs comprising electrons.
the octet are shared between atoms. These unshared, ➔ exceptions to the octet rule: Hydrogen (H) and helium
non-bonding electrons are called ‘ lone pairs ‘ of (He) only need two electrons to have a full valence level.
electrons. ➔ Lewis structure: Formalism used to show the structure
➔ Although lone pairs are not directly involved in bond of a molecule or compound, in which shared electrons
formation, they should always be shown in Lewis pairs between atoms are indicated by dashes. Non-
structures. bonding, lone pairs of electrons must also be shown.
➔ There is a logical procedure that can be followed to ➔ covalent bond: Two atoms share valence electrons in
draw the Lewis structure of a molecule or compound. order to achieve a noble gas electronic configuration.
THE OCTET
RULE
Noble gases like He, Ne, Ar, Kr, etc., are
stable because their valence level is filled
with as many electrons as possible. Eight
electrons fill the valence level for all
noble gases, except helium, which has
two electrons in its full valence level.
Other elements in the periodic table
react to form bonds in which valence
electrons are exchanged or shared in order
to achieve a valence level which is filled,
just like in the noble gases. We refer to
this chemical tendency of atoms as ‘the
octet rule,’ and it guides us in predicting
how atoms combine to form molecules
and compounds.
VALENCE
ELECTRONS
➔ The electrons of atoms that participate in the
formation of chemical bonds.
➔ It is located in the outermost principal energy level,
which is the level furthest away from the nucleus.
➔ Electrons that are not in the valence level are not
shown in the Lewis symbol. The reason for this is
Al
that the chemical reactivity of an atom of the
element is solely determined by the number of its
valence electrons, and not its inner electrons.
➔ The columns, or groups, in the periodic table are
used to determine the number of valence electrons
for each element.
THINGS TO REMEMBER!
● One line = single bond = 2 electrons
● Two lines = double bond = 4 electrons
● Three lines = triple bond = 6 electrons
● Three is the maximum number of bonds.
● The more shared pairs of electrons the harder the bond will break.
● Shared electrons are counted as owned by both atoms.
STEPS FOR DRAWING LEWIS
STRUCTURE
ELECTRONS
2)DETERMINE THE CENTRAL ATOM
(THE ELEMENT THERE IS ONLY ONE
OF)
3)DRAW SINGLE BONDS TO THE
CENTRAL ATOM
4)PUT ALL REMAINING VALENCE
ELECTRONS ON ATOMS AS LONE
PAIRS
5)TURN LONE PAIRS INTO DOUBLE

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