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    Practical Approach in Fatty Acid Distillation

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    Hari Krishna Shukla
    This document provides information on the practical approach to fatty acid distillation. It discusses the basic principles of boiling point differences, condensation of vapors, and heat of evaporation. It describes the contents of crude fatty acids and how product quality depends on separating impurities like aldehydes, ketones, and air. It recommends operating temperatures below 260°C to prevent degradation and discusses options to improve the process like structured packing, falling film reboilers, and sealed pumps and connections to prevent air ingress. Finally, it outlines the main processing steps of degassing, dehydration, distillation, and pitch removal.

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    Download as PPT, PDF, TXT or read online from Scribd

    Practical Approach in Fatty Acid Distillation

    Uploaded by

    Hari Krishna Shukla
    137 views15 pages
    This document provides information on the practical approach to fatty acid distillation. It discusses the basic principles of boiling point differences, condensation of vapors, and heat of evaporation. It describes the contents of crude fatty acids and how product quality depends on separating impurities like aldehydes, ketones, and air. It recommends operating temperatures below 260°C to prevent degradation and discusses options to improve the process like structured packing, falling film reboilers, and sealed pumps and connections to prevent air ingress. Finally, it outlines the main processing steps of degassing, dehydration, distillation, and pitch removal.

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    This document provides information on the practical approach to fatty acid distillation. It discusses the basic principles of boiling point differences, condensation of vapors, and heat of evaporation. It describes the contents of crude fatty acids and how product quality depends on separating impurities like aldehydes, ketones, and air. It recommends operating temperatures below 260°C to prevent degradation and discusses options to improve the process like structured packing, falling film reboilers, and sealed pumps and connections to prevent air ingress. Finally, it outlines the main processing steps of degassing, dehydration, distillation, and pitch removal.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    137 views15 pages

    Practical Approach in Fatty Acid Distillation

    Uploaded by

    Hari Krishna Shukla
    This document provides information on the practical approach to fatty acid distillation. It discusses the basic principles of boiling point differences, condensation of vapors, and heat of evaporation. It describes the contents of crude fatty acids and how product quality depends on separating impurities like aldehydes, ketones, and air. It recommends operating temperatures below 260°C to prevent degradation and discusses options to improve the process like structured packing, falling film reboilers, and sealed pumps and connections to prevent air ingress. Finally, it outlines the main processing steps of degassing, dehydration, distillation, and pitch removal.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    of 15

    Practical Approach in

    Fatty Acid Distillation

    Hari Krishna Shukla


    Shutek Oleo S A, Costa Rica
    Basic Principles
     Boiling point difference
     Boiling & Non boiling components

     Condensation of vapors

     Heat of evaporation

     Flashing

     Mechanical entrainment
    Contents of crude fatty acids
     Aldehydes, methyle ketones, and unsaturated
    hydrocarbons,(.01 to 0.1%)
     Dissolved air, (0.02 %)
     Moisture, (1 t0 3 %)
     Pitch from polymerization, (.01 to .1 %)
     Triglycerides. ( Subject to split degree)
     Fatty acids
    Product quality

     Product quality in terms of color, heat


    stability of distillates and yield depend on
    the fact how far the process has separated
    the by product of
     Aldehydes,
     Methyle ketones,
     Dissolved air and
     Unsaturated hydrocarbons.
    Nature of fatty acids
     Highly heat sensitive ,
     Oxidation and

     Severe degradation if air


    infiltration at elevated
    temperature.
    Operating temperature ?
     Prior to dissolved gases (air) removal
     140 °C Maximum
     Prior to low boiling by product removal
     200 ° C Even Skin temperature.
     For a maximum stress of 15 Min.
     240 °C for unsaturated fatty acids,
     250 °C for saturated fatty acids.

     For few seconds only


     260 °C and Never above 260 °C
    Prevent air ingress
     Welded connections
     Clamped flanges with sealed welds.
     Tongue and groove flanges
     Improved gasket material

     Seal less pumps


     Canned motor pump
     Magnetic coupling pumps

     Welded fittings, instruments etc.


    Options available
     Structured packing
     Reduced pressure drop
     Facilitates lower operating temperature.
     Falling film reboilers
     Reduction in thermal stress,
     Improved product quality,
     Improved heat transfer.
     In-built condensers
     Quick condensation
     Contd.
    Options available
     Seal less pumps
     Reduction of leak (in & out)
     Improved flange connections,
     Optimal Liquid gas ratio,
     Low rpm pumps at bottom of columns
     Optimum operating vacuum.
    Process Control
     DCS
     Forward or backward feed back control

     Multivariable process optimizer

     Mass flow meters

     Capacitance level indicators


    Processing steps

     Step -I
     Degassing,

     Dehydration and
     Removal of low boiling components.
     Contd.
    Processing steps
     Step-I
     Enough stripping section needed otherwise
     Product will have
     Bad smell,
     Poor quality
     Poor heat stability

    (Mono, di & trialdehydes are formed


    in small quantities during
    Hydrogenation.)
    Processing steps

     Step-II
     Distillation
    and / or
     fractionation of fatty acids

     Contd.
    Processing steps

     Step-III
     Removal of pitch
    High boiling substances
    Residue

    Un-split oil / fat.


    Thanks

     I will be happy to take any question

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