OILS, Fats and Waxes

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OILS, Fats and Waxes

Fats and oils are called triglycerides (or triacylcylgerols) because


they are esters composed of three fatty acid units joined
to glycerol, a trihydroxy alcohol:
• A triglyceride is called a fat if it is a solid at 25°C;
it is called an oil if it is a liquid at that
temperature.

• These differences in melting points reflect


differences in the degree of unsaturation and
number of carbon atoms in the constituent fatty
acids.
• Triglycerides obtained from animal sources are
usually solids, while those of plant origin are
generally oils. Therefore, we commonly speak of
animal fats and vegetable oils.
Physical Properties of Fats and Oils
•  pure fats and oils are colorless, odorless, and
tasteless.
• The characteristic colors, odors, and flavors
that we associate with some of them are
imparted by foreign substances that are lipid
soluble and have been absorbed by lipids.
• For example, the yellow color of butter is due
to the presence of the pigment carotene; the
taste of butter comes from two compounds—
diacetyl and 3-hydroxy-2-butanone—produced
by bacteria in the ripening cream from which
the butter is made.
• Fats and oils are lighter than water, having
densities of about 0.8 g/cm3. They are poor
conductors of heat and electricity and
therefore serve as excellent insulators for the
body, slowing the loss of heat through the skin.
Chemical Reactions of Fats and Oils

• Fats and oils can participate in a variety of chemical reactions—


for example, because triglycerides are esters, they can be
hydrolyzed in the presence of an acid, a base, or specific
enzymes known as lipases.
• The hydrolysis of fats and oils in the presence of a base is used
to make soap and is called saponification.
• Today most soaps are prepared through the hydrolysis of
triglycerides (often from tallow, coconut oil, or both) using water
under high pressure and temperature [700 lb/in2 (∼50 atm or
5,000 kPa) and 200°C]. Sodium carbonate or sodium hydroxide
is then used to convert the fatty acids to their sodium salts (soap
molecules):
VEGETABLE OIL EXTRACTION
HYDROGENTAION OF OIL

• Hydrogenation process is used to remove double


bonds and to make fats and oil saturated.
• Hydrogenation also raises its melting point and
improves its resistance to rancid oxidation.
• The most common end product of hydrogenation
is Vanaspati ghee. Other products include
vegetable ghee, hardened industrial oils and
partially hydrogenated liquid oil.
Ni
Technical Aspects
IODINE VALUE
Rancidity
WINTERISNG
Saponification Value

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