Fats and oils are triglycerides composed of fatty acid units joined to glycerol. They are classified as fats if solid at 25°C and oils if liquid. Triglycerides from animals are usually solid fats while plant sources are generally oils. Pure fats and oils are colorless, odorless, and tasteless but can absorb flavors and colors from other substances. They have densities lower than water and act as good insulators. Fats and oils can undergo chemical reactions like hydrolysis and saponification, and hydrogenation is used to remove double bonds and make oils more saturated.
Fats and oils are triglycerides composed of fatty acid units joined to glycerol. They are classified as fats if solid at 25°C and oils if liquid. Triglycerides from animals are usually solid fats while plant sources are generally oils. Pure fats and oils are colorless, odorless, and tasteless but can absorb flavors and colors from other substances. They have densities lower than water and act as good insulators. Fats and oils can undergo chemical reactions like hydrolysis and saponification, and hydrogenation is used to remove double bonds and make oils more saturated.
Fats and oils are triglycerides composed of fatty acid units joined to glycerol. They are classified as fats if solid at 25°C and oils if liquid. Triglycerides from animals are usually solid fats while plant sources are generally oils. Pure fats and oils are colorless, odorless, and tasteless but can absorb flavors and colors from other substances. They have densities lower than water and act as good insulators. Fats and oils can undergo chemical reactions like hydrolysis and saponification, and hydrogenation is used to remove double bonds and make oils more saturated.
Fats and oils are triglycerides composed of fatty acid units joined to glycerol. They are classified as fats if solid at 25°C and oils if liquid. Triglycerides from animals are usually solid fats while plant sources are generally oils. Pure fats and oils are colorless, odorless, and tasteless but can absorb flavors and colors from other substances. They have densities lower than water and act as good insulators. Fats and oils can undergo chemical reactions like hydrolysis and saponification, and hydrogenation is used to remove double bonds and make oils more saturated.
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OILS, Fats and Waxes
Fats and oils are called triglycerides (or triacylcylgerols) because
they are esters composed of three fatty acid units joined to glycerol, a trihydroxy alcohol: • A triglyceride is called a fat if it is a solid at 25°C; it is called an oil if it is a liquid at that temperature.
• These differences in melting points reflect
differences in the degree of unsaturation and number of carbon atoms in the constituent fatty acids. • Triglycerides obtained from animal sources are usually solids, while those of plant origin are generally oils. Therefore, we commonly speak of animal fats and vegetable oils. Physical Properties of Fats and Oils • pure fats and oils are colorless, odorless, and tasteless. • The characteristic colors, odors, and flavors that we associate with some of them are imparted by foreign substances that are lipid soluble and have been absorbed by lipids. • For example, the yellow color of butter is due to the presence of the pigment carotene; the taste of butter comes from two compounds— diacetyl and 3-hydroxy-2-butanone—produced by bacteria in the ripening cream from which the butter is made. • Fats and oils are lighter than water, having densities of about 0.8 g/cm3. They are poor conductors of heat and electricity and therefore serve as excellent insulators for the body, slowing the loss of heat through the skin. Chemical Reactions of Fats and Oils
• Fats and oils can participate in a variety of chemical reactions—
for example, because triglycerides are esters, they can be hydrolyzed in the presence of an acid, a base, or specific enzymes known as lipases. • The hydrolysis of fats and oils in the presence of a base is used to make soap and is called saponification. • Today most soaps are prepared through the hydrolysis of triglycerides (often from tallow, coconut oil, or both) using water under high pressure and temperature [700 lb/in2 (∼50 atm or 5,000 kPa) and 200°C]. Sodium carbonate or sodium hydroxide is then used to convert the fatty acids to their sodium salts (soap molecules): VEGETABLE OIL EXTRACTION HYDROGENTAION OF OIL
• Hydrogenation process is used to remove double
bonds and to make fats and oil saturated. • Hydrogenation also raises its melting point and improves its resistance to rancid oxidation. • The most common end product of hydrogenation is Vanaspati ghee. Other products include vegetable ghee, hardened industrial oils and partially hydrogenated liquid oil. Ni Technical Aspects IODINE VALUE Rancidity WINTERISNG Saponification Value