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CHEMISTRY

CHEMICAL REACTIONS
Review
• Heat of reaction – heat absorbed or evolved by a process
• Exothermic reaction - negative heat of reaction; heat is given off;
spontaneous
• Endothermic reaction – positive heat of reaction; heat is absorbed;
non spontaneous
• Isothermic process – change in a system at constant temperature
• Specific heat – heat capacity of one gram of substance; heat required
to raise the temperature of one gram of a substance by 1 C
CHEMICAL REACTIONS
Review
• System – singled out portion for the study
• Surrounding – everything outside the system
• Natural or spontaneous reaction – reaction proceeds on its own;
occurs without outside assistance (rusting, mixing of gas)
COLLISION THEORY
For a chemical reaction to occur:
• molecules must collide
• must have sufficient energy
• must be properly oriented
FACTORS AFFECTING THE RATE OF CHEMICAL
REACTIONS
• Surface area
• Concentration
• Temperature
• absolute zero
• Presence of catalyst
ACIDS AND BASES
Properties

Acid – sour taste, blue litmus to red, pH 0 to 7


Base – bitter taste, red litmus to blue, pH 7 to 14
ACIDS AND BASES
• Arrhenius
• Acid-H containing (HCl)
• Base-OH containing (NaOH)
• Bronsted-Lowry
• Acid-proton donor
• Base-proton acceptor
• Lewis
• Acid-electron pair acceptor
• Base-electron pair donor
ORGANIC CHEMISTRY
• study of all factors pertaining to carbon-containing compounds or
organic compounds
• organic compounds - carbon with hydrogen, nitrogen and/ or sulfur
• inorganic compounds- compounds that generally do not have any
carbon
• hydrocarbons - groups of organic compounds that contain only the
elements of carbon and hydrogen
• nomenclature - system of naming compounds
• functional group- specific groups of atoms within a molecule that are
responsible for the characteristic chemical behavior on a molecule
PROPERTIES
CLASSES OF HYDROCARBONS
FUNCTIONAL GROUPS
NUCLEAR CHEMISTRY
• radioactivity- spontaneous decay of an unstable nucleus
• nuclei
• divide (nuclear fission) - bombarding a large isotope with a neutron; collision
causes the larger isotope to break apart into two or more elements
• combine (nuclear fusion)- lighter nuclei are fused into a heavier nucleus in a
fusion
• alpha decay- emits an alpha particle (defined as a positively charged
particle of a helium nucleus)
NUCLEAR CHEMISTRY
• beta decay- a neutron in the nucleus is converted (decayed) into a
proton and an electron, and the electron is emitted from the nucleus
as a beta particle.
NUCLEAR CHEMISTRY
• gamma radiation- emits photons, no mass change is associated with
gamma emission

• positron emission- positron is an electron that has a positive charge;


formed when a proton in the nucleus decays into a neutron and a
positively charged electron
NUCLEAR CHEMISTRY
• electron capture - rare type of nuclear decay in which the nucleus
captures an electron from the innermost energy level. This electron
combines with a proton to form a neutron
• half-life - the time required for one of the reactant to be consumed
such as radioactive decay
HALF LIFE
Steps in Determining half life
1. Divide the amount of time that’s passed by the length of a half-life.
2. Multiply 1/2 by itself, once for each half-life, to find the fraction of
the sample that’s left.
3. To get the number of radioactive atoms remaining, multiply the
fraction from Step 2 by the number of atoms you started with.
HALF LIFE
• ln2/k
• N(t)=No e^(t/t0.5)

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