Chemistry 2014

AnnualExamination Question Papers 2014
Time : 3Hours 15 Minutes Full Marks : 70

Section -I
Answer the following multiple choice questions : 1x 14 =14
choose the correct answer :
1. In Bohr's mode of atomthe lowest angular momentum, that an
Chemistry 617
clectron may have 0s, (a) h (b) 0 (c) (d)
h
is not 2T T .2. Which of the following
paramagnetic?
the following (a) N, (b) (c) O, (d)
is least ionic? (a) Li, H,".3. Which bond among
P F (b) S -F (c) Cl -F (d) F-F. 4.
For a definite mass of an
ideal gas at constant
plot is a (a) parabola (b) temperature, Vversus p
bola. 5. Which of the straightisline (c) hyperbola (d) rectangular hyper
hot water filled following an example of aclosed system? (a) A
(c) A water filledthermoflask
(b) An ice water filled
stainless steel bowl (d) A hot waterairtight
filled
metallic bottle
Which of the following is an glass beaker. 6.
energy (b) Entropy (c) Mass (d)intensive property of a system? (a) internal
of a gaseous reaction is (a) Denstiy:7. Theequilibrium constant (K)
on the temperature (c) dependent on the total pressure (b) dependent
dependent on the
dependent on the presence of an inert gas. concentration of the reactants (d)
8. Which of the following is less
stable thermally? (a) LiF (b) KCI (c)
RbF
following pairs is responsible for developing an(d) CsF. 9. Which of the
the membrane of living cells? (a) Ca'*
electric potential across
and K* (d) Mg* and Ca*.10. Which of and Nat (b) K and Ba?* (c) Na*
the following conmpounds does not
respond to Lasaigne test for nitrogen? (a) CH,NH, HCI (b)
NO
H,NCONHNH,.HCI (c) NH,OH.HCI ()
11. Which of the following species is stabilised by
CH,
hyperconjugation?
CH,
(a) CH,=CH-CH, (b) CH, -C® (c) CH, -C - (d) CH,=CH-CH
CH, CH,
12. The reaction condition leading to best yield of methyl chloride is
(a) CH,(excess) + Cl,; UVlight (b) CH, +Cl, dark
(c) CH, +Cl, (excess) - uv light ’ (d) CH, +CI, Sunlight
13. How many types of carbon atoms are persent in 2, 2, 3
hmethylpentane? (a) 1 (b)2 (c)3 (d) 4. 14. Acidrain is a dilute aqueous
SOlution of which of the following pairs of acids? (a) H,SO, and HCI (b)
1CO, and HCI (c) H:SO, and HNO, (d) HNO, and HCI.
618 Test Papers (X)
Section - II
Group - A
Answer the following questions (Alternatives are to be noted) :
1x4 =4
1. What will be the change of mass when 10 g of magnesium is heated
strongly in oxygen? (Mg = 24)
2. Fill in the blank:
Metallic property of elements down the group in periodic
table.
Or, Arrange the following in increasing order of ionic radius
Na, F, O, AI*, N
3. In a process, 600J of heat is absorbed by a system and 300 J of work
is done by the system. Calculate the change in internal energy of the
system.
Or, Latent heat of vaporisation of the water at normal boiling point is
40.75 kJmol". Calculate the change in entropy of vaporisation.
4. How would you convert?
CH, = CH, ’ HC=CH
Group-B
2 x 5 = 10
5. A compound, on analysis shows C=40%, H =6.67% and O =
53.33%.Determine the cmpirical formula of the compound. If molar
mass of the compound is 30 gm mol',what is its molecular formula?
1+1=2
Or, Calculate the percentage composition of the compound having the
molecular formula of C,H,0, (H =1, C=l2, O = 16). 2
6.Calculate the number of photons of light having wavelength 500 nm
that would provide 0.1 J of energy. (Plank's constant,
h6626 x 10-4 Js)
7. PbCI, is less stable than SnCl, while PbCI, is more stable SnCI,.
Justify or contradict.
Or, B- F bond is polar but BF, does not have a dipole moment - why?
8. What type of fission of a covalent bond products free radicals? Give

an example with proper sign. 1+1=2
Chemistry 619
Or, (i) Write down the IUPAC name of the following compound :
Br
CI C - CH,0H
H
(ii) Dravw the structure of the following compound :
3. 4 - dimethylpentanoic acid.
9. Write one effect of depletion of ozone layer and one measure for the
prevention of ozone layer depletion.
Group- C
3.x 9 = 27
10. State the Heisenberg uncertainty principle. Calculate the de Broglie
wavelength associated with an clectron moving with velocity of
1.0x10" ms. (Mass of an electron :9.1 x 10 kg). 1+2 = 3
Or, Write down the electronic configuration of ,Si and ,Mn
25
stating the
underlying principle. Which of the following orbitals are not possi
ble? lp, 2d, 3s, 3f. 2 + 1 = 3
11. (1) Why does nitrogen have a higher ionization enthalpy than that
of oxygen?
(ii) Arrange the following in increasing order of acidity :
NO,, Al,0,, Sio,, CIO.,. 2+ 1 3
12. ()When hydrogen combines with oxygen, a polar covalent product
is formed Explain.
(ii) What types of bonds are present in KHF,? 2 + 1 = 3
Or, (i) Why H, is a stabl molecule but He, is not?
(ii) Write canonicals of CI0, 2 + 1 =3
13. A gas of molar mass 84.5 g/mol is enclosed in a flask at 27°C has
a pressure of 2 atm. Calculate the density of the gas. [R = 0.082 L
atm K! mol] 3
14. Calculate the enthalpy of formation of liquid ethyl alcohol from the
following data :
C,H,OH(I)+30, (g)-’ 2C0,(g) +3H,0(1) AH =-1368kJ
C(s) +O, (g) ’CO,(g) AH-393kJ
H,(g) +o, (g)H,O) AH =-287 kJ
State the condition of spontaneity and equilibrium in terms of Gibbs
Iree energy change of a system. 2 + 1=3
620 Test Papers (XI)
Or, For a gaseous reaction in a closed container establish the
namic relation, AH = AE + An RT. (H =Enthalpy, E = Internal thermody-
energy, N=No. of moles).
Which variable is kept constant in an isochoric process?2 +1=3
15. Balance the following reaction by ion-electron method
K,Cr,0, +FeSO, +H,SO,, K,SO, +Cr, (SO), +Fe, (SO), +H0
Determine the oxidation number of P in Na,PO, 2 + 1=3
Or, Balance the following reaction by oxidation number method :
1,+HNO, ’ HIO, +NO, +H,0
Calculate the oxidation number of C1 in HCIO,. 2+ 1 =3
16. (i) Hydrogen can be placed in Group 17 instead of Group 1 of
periodic table. Give reason.
(i) What is heavy water? Why is it so called? 2 + (/,+ /,) = 3
17. (i)The halides of alkali metals are soluble in water eXcept for LiF.
Why?
(i) What is diagonal relationship? Give one example.
2 +/,+, =3
18. Draw the canonicals of CH,COOH and CH,CO0
In which case resonance is more important? Answer with reason.
1+1 + l=3
Or, Write the principle of estimation of carbon and hydrogen in an
organic compound.
Group- D
5 x3 =15
19. Consider the equilibrium:
N, (g) + 3H, (g) 2NH, (g) + heat
Apply the Le Chatelier's principle to explain the effects of pressure,
temperature, and addition of inert gas at constant volume on the
equilibrium yield of NH,.
What is buffer solution? Give one example of the. buffer solution.
3 +2 =5
Or, At 318 K and 2 atm total pressure the degree of dissociation (a) is
28% at the equilibrium condition for the reaction.
N, 0, (g) 2NO, (g)
Calculate K, and K. of the reaction.
Calculate the pH of 0.1 (M) NH,OH at 25°C. The dissociation
constant of NH,OH at 25°C is 1.75x10s.
20. (a) (i) Why PbO, is oxidising?
(ii) Explain why TICl is known but AICI is not known.
Chemistry 621
(b) Which of the following is thermodynamically
of carbon? most stable form
Coke. diamond, graphite, fullerene.
(2 +
21. (i) What is effective electrophile in the nitration of +2) + l= 5
mixed acid? How is it generated? Write benzene with
of the reaction. down the mechanistic steps
(i) Two different compounds produce only
acetaldehyde on
0zonolysis. Draw the structures of the two compounds.
1+1+ 1 +2 =5
Or. i) Draw the eclipsed and staggered conformations of ethane and
comment on the relative stabilities of the two conformations.
(ii) Identify (A) (F) in the following reactions:
Ag fowder () NaNH2liq NH,
CHI3 ’(AJ (C)
Heat
1%HgSO4,
2mol 20% HSO4,
H2|Pd-BaSso4
HOCl S.quinoline 60°C- 80°C
(B) (E) (D)

HCI, peroxide
(F)
(1 + 1)+ (½x 6) =5

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AnnualExamination Question Papers 2014

Time : 3Hours 15 Minutes Full Marks : 70

8. What type of fission of a covalent bond products free radicals? Give

(B) (E) (D)

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