TENDER HEART SR. SEC. SCHOOL TUPUDANA, RANCHI.

MOCK 2 EXAMINATION ,2024-25

CHEMISTRY (043)

CLASS 12 F.M.:70 Time:3hrs

Instructions:

i)This question paper contains 33 questions. All questions are compulsory.

ii) This question paper is divided into five sections A,B,C,D and E.

iii)Section A : questions number 1to16 are multiple choice type questions . Each question carries 1 mark

iv)Section B: questions number 17 to 21 are very short answer type questions . Each question carries 2 marks .

v) Section C : questions number 22 to 28 are short answer type questions . Each question carries 3 marks .

vi)Section D :questions number 29 and 30 are case-based questions. Each question carries 4 marks.

vi) Section E: questions number 31 to 33 are long answer type questions . Each question carries 5 marks.

---------------------------------------------------------------------------------------------------------------
---------------------------

SECTION A

1) Solubility of gas in liquid decreases with increase in

a) pressure b) temperature c)volume d)number of solute particle

2) Which of the following cell have a constant value throughout its life

a) Dry cell. b) Electrolytic cellc) Mercury cell d) Daniel cell

3) In two tetrahedral structures of dichromate ion

a) 4 Cr-O bonds are equivalent in length

b) 6 Cr-O bonds are equivalent in length

c) all Cr-O bonds are equivalent in length

d) all bonds are non equivalent.

4) The slope in the plot of [ R ] vs time for a zero order reaction is

a) +K / 2.303 b)- k c) - K / 2.303 d)+ k.

5) The crystal field splitting energy for octahedral (∆o) and tetrahedral (∆t) complexes is related as

a) ∆t=2/9 ∆o. b)∆t=5/9 ∆oc) ∆t=4/9 ∆o. d)∆t= 2 ∆o

6) In the following reaction :

CH3-Br--Mg in dry ether--- A-----H2O---------B 'B'. will be :

a) CH4. b) CH3MgBrc)CH3-OH. d) CH3-CH3

7) Which of the following acids reacts with acetic anhydride to form a compound Aspirin ?

a) Benzoic acid b) Salicylic acid c) Phthalic acid d) Acetic acid

8) Aldehydes and ketones react with hydroxyl amine to form :

a) hydrazones b) cyanohydrinec) semicarbazones d) oximes

9) The action of nitrous acid on ethylamine gives mainly :

a) Ethyl nitrite. b) Ethyl alcoholc) nitro ethane d) ethane

10) Which of the following B group vitamins can be stored in our body ?

a) B1. b) B6 c) B12. d) B2

11) All the lanthanoids show + 3 as the common oxidation state , yet Ce shows + 4 state because

a)It has tendency to attain noble gas configuration

b)It has variable ionization enthalpy

c) lt has tendency to gain one more electron

d) lt has an unpaired electron in 6s.

12) Zinc is coated over iron to prevent rusting of iron because

a) E° Zn2+/Zn = E°Fe2+/Fe

b) E° Zn2+/Zn < E°Fe2+/Fe

c) E° Zn2+/Zn > E°Fe2+/Fe

d) None of these

For questions number 13 to 16 two statements are given one labelled as Assertion (A) and the other labelled as Reason
(R).

Select the correct answer to these questions from the codes (a),(b),(c)and (d) as given below :

a) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A)

b) Both Assertion (A)and Reason (R)are true but Reason (R)is not the correct explanation of Assertion (A)

c) Assertion (A)is true but Reason (R)is false

d) Assertion (A)is false but Reason (R)is true.

13) Assertion (A): 0.1 M solution of KCl has greater osmotic pressure then 0.1 M solution a glucose at same temperature

Reason (R): ln solution, KCl dissociates to produce more number of particles.

14) Assertion (A): Order of reaction is applicable to elementary as well as complex reaction.

Reason (R) For complex reaction molecularity has no meaning.

15) Assertion (A): Low spin tetrahedral complexes are rarely observed.

Reason (R): Crystal field splitting energy (CFSE) is less than pairing energy for tetrahedral complexes.

16) Assertion (A): Ammonolysis of alkyl halide is not a suitable method for the preparation of pure primary amines.

Reason (R): Ammonolysis of alkyl halides mainly yields secondary amines.

SECTION B

17) State Raoult's law for a solution containing volatile components . What is the similarity between Raoult's law and
Henry's law ?

18) Out of [CoF6]3- and [Co(C2O4)3]3- ,which one complex is

a) diamagnetic b) most stable c) c) outer orbital complex d) low spin complex ?

19) An alkyl halide (A) of molecular formula C6H13Cl on treatment with alcoholic KOH give two isomeric alkene (B)and (C)
of molecular formula C6H12 . Both alkanes on hydrogenation gave 2 ,3 -dimethyl butane. Write the structures of A, B and
C.

20) Name the different reagents needed to perform the following reactions :

a) Phenol to benzene

b) Dehydration of propan-2-ol to propene

c) Friedel - Crafts acetylation reaction of Anisole

d) Dehydrogenation of ethanol to ethanal.

21) Predict the products formed when CH3CHO reacts with the following reagents:

a) HCN. b) Zn(Hg)/conc. HCl.

SECTION C

22) a)Calculate the freezing point of solution when 1.9 g of MgCl2 was dissolved in 50 g of water, assuming MgCl2
undergoes complete ionization.(Kf for water= 1.86 K kg per mol-1).

b)i) Out of 1M glucose and 2 M glucose which one has a higher boiling point and why ?

ii) What happens when the external pressure applied becomes more than the osmotic pressure of solution ?

23)a)The standard Gibb's energy (∆G°) for the following cell reaction is - 300 kJ mol-1. Zn(s)+2Ag+(aq)-----Zn2+(aq)
+2Ag(s)
Calculate E°cell for the reaction.

b) Calculate ^° MgCl2 if ^° values of Mg2+ and Cl -1 are 106 S cm 2 mol-1 and 76 S cm2 mol-1 respectively .

24)a) Draw the geometrical isomers of [PtCl2(en)2]2+ ion.

b)[NiCl4]2- is paramagnetic while [Ni(CN)4]2- is diamagnetic.Explain .

c) Give IUPAC name and electronic configuration of central atom in terms of

t2g and eg of K4[ Mn(CN)6].

25) i)Write short notes on:

a) Gabriel Phthalimide synthesis

b) Riemer Tiemann reaction

ii) Write the mechanism of the conversion of ethene to ethyl alcohol.

26) How do you convert the following:

a) Phenol to acetophenone b) Benzene to 3- nitro toluene

c) Ethanoic acid to methanamine.

27) a) What happens when glucose reacts with HI and conc. HNO3 .Give reactions.

b) Amino acids show amphoteric behaviour ,why ?

28)a) What are essential and non essential amino acids ?

b) Water soluble vitamins must be taken regularly in diet ,why ?

c) Write two differences between DNA and RNA.

SECTION D

29) Read the following passage and answer the questions that follow:

Amines can be considered as derivatives of ammonia by replacement of hydrogen atoms with alkyl or arrayl groups .Like
ammonia ,all the three types are amines have one unshared electron pair on nitrogen atom due to which they behave like
Lewis bases.Alkyl amines are found to be stronger bases than NH3. In aromatic amines ,electron releasing and electron
withdrawing groups ,respectively, increase or decrease their basic character.

a) Out of Aniline and methylamine which is stronger base and why ?

b) What happens when Benzene diazonium chloride is treated with ethanol ?

c) Write short notes on acetylation of aniline

d) How can you distinguish the aliphatic and aromatic primary amines?

30) Electrochemistry plays a very important part in our daily life .Primary cells like dry cell is used in torches ,wall clock.
Mercury cell is used in watches. Lithium battery is used in laptop, mobile phones. Lead storage battery is used in vehicles
and inverters.Fuel cell was used in Apollo space programme.
a) Write the chemical reaction at anode when lead storage battery is in before charging and during charging ?

b) How many Faradays are required to carry out reduction of one mole of PbO2 ?

c) Name two substances which can be used as fuel in fuel cell in place of hydrogen.

SECTION E

30) a) A blackish brown solid 'A' when forced with alkali metal hydroxide in presence of air, produces a dark green coloured
compound 'B' which gives a dark purple coloured compound 'C' on oxidation. Identify A, B, C and write the reactions
involved.

b) Calculate the spin magnetic moment of M2+(aq) ion .(Atomic number =27).

c) Why is Cu+ ion unstable in aqueous solution ?

Or

31) a) Give reasons:

i) Transition metals show variable oxidation States.

ii)Transition metals are widely used as catalyst.

iii)The enthalpy of atomization of transition metals is very high.

b) Complete and balance the following equation:

Cr2O7 (2-) + S2O3 (2-) + H+------------

c) What is lanthanoid contraction ?

32)a) Write the differences between order and molecularity.

b) Derive the integrated rate equation for first order reaction.

c) A first order reaction is 50% complete in 30 minutes at 300 K and in 10 minutes at 320 K. Calculate activation energy for
the reaction .(R = 8.314 J K-1 mol -1)

Or

32)a) The first order reaction is 75% completed in 40 minutes. Calculate its t1/2.

( Iog 2= 0.3010)

b) Predict the order of the reaction in the given plots :

where [Ro] is the initial concentration of the reactant.

33)a) Distinguish the following compounds by the suitable chemical test.

i)Ethanal and propanal

ii)Aacetophenone and benzophenone

b) Give IUPAC name of salicylaldehyde.

c) Give reasons:

i)4-Nitro benzoic acid is stronger acid than benzoic acid.

ii) Benzaldehyde is less reactive than propanal in nucleophilic addition reaction.

Or

33) a)Arrange the following in increasing order of the property mentioned.

i) CH3COOH , CICH2COOH , FCH2COOH

(Acidic strength)

ii) C6H5NH2 , CH3CH2NH2, CH3NHCH3

(Basic strength).

b) What happens when:

i) Propanone is treated with CH3Mgl and then hydrolysed.

ii) Benzene is treated with CH3COCI in presence of anhydrous AICI3.

c) Name the reagents of HVZ reaction.