SAFETY DATA SHEET

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Version 1.4 Revision Date 08/12/2019 Print Date 05/08/2020

SECTION 1. IDENTIFICATION

Product name : Solstice® ZD, Solstice® 1233zd (E)

Number : 000000018007

Product Use Description : Refrigerant, Heat transfer fluid

Manufacturer or supplier's : Honeywell International Inc.

details 115 Tabor Road
Morris Plains, NJ 07950-2546
For more information call : 800-522-8001
+1-973-455-6300(Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701 or +1-303-389-1414

: Transportation (CHEMTREC): 1-800-424-9300 or +1-703-
527-3887
:
: (24 hours/day, 7 days/week)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Liquefied gas

Form : liquid, clear

Color : colourless

Odor : slight

Classification of the substance or mixture

Classification of the : Gases under pressure, Liquefied gas
substance or mixture Simple Asphyxiant

GHS Label elements, including precautionary statements

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Symbol(s) :

Signal word : Warning

Hazard statements : Contains gas under pressure; may explode if heated.

May displace oxygen and cause rapid suffocation.

Precautionary statements : Prevention:

Use personal protective equipment as required.

Storage:
Protect from sunlight. Store in a well-ventilated place.

Carcinogenicity

No component of this product present at levels greater than or equal to 0.1% is identified as a known
or anticipated carcinogen by NTP, IARC, or OSHA.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : Substance

Chemical name CAS-No. Concentration

trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 >99.00 %

SECTION 4. FIRST AID MEASURES

Inhalation : Remove to fresh air. If not breathing, give artificial respiration.

If breathing is difficult, give oxygen. Use oxygen as required,
provided a qualified operator is present. Call a physician.

Skin contact : After contact with skin, wash immediately with plenty of water.
If symptoms persist, call a physician. Take off all contaminated
clothing immediately. Wash contaminated clothing before re-
use.

Eye contact : Rinse immediately with plenty of water, also under the eyelids,
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for at least 15 minutes. Call a physician if irritation develops or

persists.

Ingestion : If victim is fully conscious, give a cupful of water. Do not induce

vomiting without medical advice. Never give anything by mouth
to an unconscious person. Call a physician immediately.

Notes to physician

Indication of immediate : Treat symptomatically.

medical attention and
special treatment needed, if
necessary

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : The product is not flammable.

Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Carbon dioxide (CO2)
Dry chemical
Foam

Specific hazards during : This product is not flammable at ambient temperatures and
firefighting atmospheric pressure.
However, this material can ignite when mixed with air under
pressure and exposed to strong ignition sources.
Container may rupture on heating.
Cool closed containers exposed to fire with water spray.
Do not allow run-off from fire fighting to enter drains or water
courses.
Vapours are heavier than air and can cause suffocation by
reducing oxygen available for breathing.
Exposure to decomposition products may be a hazard to
health.
Fire may cause evolution of:
Hydrogen fluoride
Gaseous hydrogen chloride (HCl).
Carbon oxides
Halogenated compounds
Carbonyl halides

Special protective equipment : In the event of fire and/or explosion do not breathe fumes.
for firefighters Wear self-contained breathing apparatus and protective suit.
No unprotected exposed skin areas.
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SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Immediately evacuate personnel to safe areas.

protective equipment and Keep people away from and upwind of spill/leak.
emergency procedures Wear personal protective equipment. Unprotected persons
must be kept away.
Remove all sources of ignition.
Ventilate the area.
Vapours are heavier than air and can cause suffocation by
reducing oxygen available for breathing.
Avoid accumulation of vapours in low areas.
Unprotected personnel should not return until air has been
tested and determined safe.
Ensure that the oxygen content is >= 19.5%.

Environmental precautions : Do not flush into surface water or sanitary sewer system.
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil
barriers).

Methods and materials for : Contain spillage, and then collect with non-combustible
containment and cleaning absorbent material, (e.g. sand, earth, diatomaceous earth,
up vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe : Handle with care.

handling Do not use in areas without adequate ventilation.
Do not breathe vapours or spray mist.
Avoid contact with skin, eyes and clothing.
Follow all standard safety precautions for handling and use of
compressed gas cylinders.
Use authorized cylinders only.
Protect cylinders from physical damage.
Do not puncture or drop cylinders, expose them to open flame
or excessive heat.
Do not pierce or burn, even after use. Do not spray on a naked
flame or any incandescent material.
Do not remove screw cap until immediately ready for use.
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Always replace cap after use.

Advice on protection : Can form a combustible mixture with air at pressures above
against fire and explosion atmospheric pressure.
Keep product and empty container away from heat and
sources of ignition.

Storage
Conditions for safe storage, : Pressurized container. Protect from sunlight and do not expose
including any to temperatures exceeding 55 °C.
incompatibilities Keep containers tightly closed in a dry, cool and well-ventilated
place.
Storage rooms must be properly ventilated.
Ensure adequate ventilation, especially in confined areas.
Protect cylinders from physical damage.
Store away from incompatible substances.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Protective measures : Ensure that eyewash stations and safety showers are close to
the workstation location.
Do not breathe vapours or spray mist.
Avoid contact with skin, eyes and clothing.

Engineering measures : Use with local exhaust ventilation.

Perform filling operations only at stations with exhaust
ventilation facilities.

Eye protection : Wear as appropriate:

Safety glasses with side-shields
Safety goggles

Hand protection : Impervious gloves

Gloves must be inspected prior to use.
Replace when worn.

Skin and body protection : Wear as appropriate:

Solvent-resistant gloves
Solvent-resistant apron and boots
If splashes are likely to occur, wear:
Protective suit

Respiratory protection : In case of insufficient ventilation wear suitable respiratory

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equipment.
Wear a positive-pressure supplied-air respirator.
For rescue and maintenance work in storage tanks use self-
contained breathing apparatus.
Use NIOSH approved respiratory protection.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
Avoid contact with skin, eyes and clothing.
Do not breathe vapours or spray mist.
Ensure adequate ventilation, especially in confined areas.
Remove and wash contaminated clothing before re-use.
Contaminated work clothing should not be allowed out of the
workplace.
Keep working clothes separately.
Wash hands before breaks and immediately after handling the
product.

Exposure Guidelines
Components CAS-No. Value Control Upda Basis
parameters te
trans-1-Chloro- 102687-65-0 TWA : (800 ppm) 2014 WEEL:US. OARS.
3,3,3- Time WEELs Workplace
trifluoropropene weighted Environmental
average Exposure Level
Guide

trans-1-Chloro- 102687-65-0 TWA : (800 ppm) 2014 WEEL:US. OARS.

3,3,3- Time WEELs Workplace
trifluoropropene weighted Environmental
average Exposure Level
Guide

trans-1-Chloro- 102687-65-0 TWA : (800 ppm) 2013 Honeywell:Limit

3,3,3- Time established by
trifluoropropene weighted Honeywell
average International Inc.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Liquefied gas
liquid, clear
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Color : colourless

Odor : slight

Melting point/range : < -90 °C

Method: OECD Test Guideline 102

Boiling point/boiling range : 19 °C

Method: OECD Test Guideline 103

Flash point : Method: ISO 2719

Note: Not applicable

Flammability : The product is not flammable.

Method: Flammability (gases)

Lower explosion limit : Note: None

Upper explosion limit : Note: None

Vapor pressure : 1,516 hPa

at 30 °C(86 °F)

Vapor density : Note: (Air = 1.0), not determined

Density : 1.27 g/cm3

Water solubility : 1.90 g/l at 20 °C

Method: OECD Test Guideline 105

Partition coefficient: n- : log Pow: 2.2 at 25 °C

octanol/water

Ignition temperature : 380 °C at 986.8 - 1,035.9 hPa

Method: DIN 51794

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Decomposition temperature : > 250 °C

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Molecular weight : 130.5 g/mol

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : Stable under recommended storage conditions.

Possibility of hazardous : Polymerisation can occur.

reactions
Conditions to avoid : Pressurized container. Protect from sunlight and do not
expose to temperatures exceeding 55 °C.
Can form a combustible mixture with air at pressures above
atmospheric pressure.
Do not mix with oxygen or air above atmospheric pressure.

Incompatible materials : Strong oxidizing agents

Finely divided magnesium
Finely divided aluminium

Hazardous decomposition : Halogenated compounds

products Carbon oxides
Hydrogen fluoride
Carbonyl halides
Gaseous hydrogen chloride (HCl).

SECTION 11. TOXICOLOGICAL INFORMATION

Acute inhalation toxicity : LC50: 120000 ppm

Exposure time: 4 h
Species: Rat

Skin irritation : Species: Rabbit

Result: No skin irritation
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Classification: Not classified as a skin irritant in animal testing.

Method: OECD Test Guideline 404
Exposure time: 4 h

Sensitisation : Result: Does not cause skin sensitisation.

Classification: Patch test on human volunteers did not
demonstrate sensitisation properties.

Repeated dose toxicity : Species: Rat

Application Route: Inhalation
Exposure time: 4 Weeks
NOEL: 4500 ppm
Note: Subacute toxicity

Genotoxicity in vitro : Test Method: Mutagenicity (Salmonella typhimurium - reverse

mutation assay)
Metabolic activation: with and without metabolic activation
Result: negative

: Test Method: Mutagenicity (Escherichia coli - reverse mutation

assay)
Metabolic activation: with and without metabolic activation
Result: negative
Method: OECD Test Guideline 471

: Test Method: Chromosome aberration test in vitro

Cell type: Human lymphocytes
Result: negative
Method: OECD Test Guideline 473

Genotoxicity in vivo : Species: Rat

Cell type: Bone marrow
Method: Mutagenicity (micronucleus test)
Result: negative

Genotoxicity in vivo : Test Method: Unscheduled DNA synthesis

Species: Rat
Result: negative

Genotoxicity in vivo : Species: Mouse

Cell type: Bone marrow
Method: Mutagenicity (micronucleus test)
Result: negative

Reproductive toxicity : Species: Rabbit

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Note: No-observed-effect level - 15,000 ppm

: Species: Rat
Note: No-observed-effect level - 10,000 ppm

Teratogenicity : Species: Rabbit

Note: No-observed-effect level - 15,000 ppm

: Species: Rat
Note: No-observed-effect level - 10,000 ppm

Further information : Note: Excessive exposure may cause central nervous system
effects including drowsiness and dizziness. Cardiac
Sensitization (dog): No effects for exposures up to 100000
ppm.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects

Toxicity to fish : LC50: 38 mg/l

Exposure time: 96 h
Species: Oncorhynchus mykiss (rainbow trout)
Method: OECD Test Guideline 203

Toxicity to daphnia and other : Immobilization

aquatic invertebrates EC50: 82 mg/l
Exposure time: 48 h
Species: Daphnia magna (Water flea)
Method: OECD Test Guideline 202

Toxicity to algae : Growth inhibition

EC50: > 215 mg/l
Exposure time: 72 h
Species: Pseudokirchneriella subcapitata (green algae)
Method: OECD Test Guideline 201

: Growth rate
NOEC: 115 mg/l
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Exposure time: 72 h
Species: Pseudokirchneriella subcapitata (green algae)
Method: OECD Test Guideline 201

Elimination information (persistence and degradability)

Bioaccumulation : Note: Due to the distribution coefficient n-octanol/water,

accumulation in organisms is not expected.

Biodegradability : Result: Not readily biodegradable.

Value: 0 %
Method: OECD 301 D

Further information on ecology

Ecotoxicology Assessment
Results of PBT assessment
This substance is not considered to be very persistent and very bioaccumulating (vPvB)., This
substance is not considered to be persistent, bioaccumulating and toxic (PBT).

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Observe all Federal, State, and Local Environmental

regulations.

Note : Where possible recycling is preferred to disposal or

incineration.

SECTION 14. TRANSPORT INFORMATION

DOT UN/ID No. : UN 3163
Proper shipping name : LIQUEFIED GAS, N.O.S.
(Trans-1-Chloro-3,3,3-trifluoropropene)
Class 2.2
Packing group
Hazard Labels 2.2

IATA UN/ID No. : UN 3163

Description of the goods : LIQUEFIED GAS, N.O.S.
(Trans-1-Chloro-3,3,3-trifluoropropene)
Class : 2.2
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Hazard Labels : 2.2

Packing instruction (cargo : 200
aircraft)
Packing instruction : 200
(passenger aircraft)

IMDG UN/ID No. : UN 3163

Description of the goods : LIQUEFIED GAS, N.O.S.
(TRANS-1-CHLORO-3,3,3-
TRIFLUOROPROPENE)
Class : 2.2
Hazard Labels : 2.2
EmS Number : F-C, S-V
Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

Inventories

US. Toxic Substances : On TSCA Inventory

Control Act

Australia. Industrial : On the inventory, or in compliance with the inventory

Chemical (Notification and
Assessment) Act

Canada. Canadian : All components of this product are on the Canadian DSL
Environmental Protection
Act (CEPA). Domestic
Substances List (DSL)

Japan. Kashin-Hou Law : On the inventory, or in compliance with the inventory

List

Korea. Existing Chemicals : On the inventory, or in compliance with the inventory

Inventory (KECI)

Philippines. The Toxic : Not in compliance with the inventory

Substances and Hazardous
and Nuclear Waste Control
Act

: trans-1-Chloro-3,3,3- 102687-65-0
trifluoropropene
China. Inventory of Existing : On the inventory, or in compliance with the inventory
Chemical Substances

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(IECSC)

New Zealand. Inventory of : On the inventory, or in compliance with the inventory

Chemicals (NZIoC), as
published by ERMA New
Zealand

National regulatory information

SARA 302 Components : No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.

SARA 313 Components : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards : Acute Health Hazard

Sudden Release of Pressure Hazard

California Prop. 65 : This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.

New Jersey RTK : trans-1-Chloro-3,3,3- 102687-65-

trifluoropropene 0

Pennsylvania RTK : trans-1-Chloro-3,3,3- 102687-65-

trifluoropropene 0

SECTION 16. OTHER INFORMATION

HMIS III NFPA
Health hazard : 2 2
Flammability : 0 0
Physical Hazard : 0
Instability : 0

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Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the
use of individuals trained in the particular system.

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. Final determination of suitability of any
material is the sole responsibility of the user. This information should not constitute a guarantee for
any specific product properties.

Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
Previous Issue Date: 08/08/2019
Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group

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