SAFETY DATA SHEET

Aristoflex Velvet Page 1

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

SECTION 1. IDENTIFICATION

Identification of the Clariant Produkte (Deutschland) GmbH

company: Frankfurt am Main, 65926
Telephone No.: +49 69 305 18000

Information of the substance/preparation:

Product Stewardship, +1-704-331-7710
e-mail: [email protected]
Emergency tel. number: +1 800-424-9300 CHEMTREC

Trade name: Aristoflex Velvet

Material number: 248710
CAS number: 1355508-95-0

Primary product use: Thickener for emulsions

Chemical family: A polymeric sulphonic acid , partially neutralized

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Combustible dust

GHS label elements

Signal word : Warning

Hazard statements : May form combustible dust concentrations in air.

Precautionary statements :
Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P243 Take precautionary measures against static discharge.
P233 Keep container tightly closed.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Substance

Substance name : A polymeric sulphonic acid , partially neutralized

CAS-No. : 1355508-95-0
SAFETY DATA SHEET

Aristoflex Velvet Page 2

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

Components
Chemical name CAS-No. Concentration (% w/w)
tert-Butyl alcohol 75-65-0 >= 1 - < 5
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : Remove/ Take off immediately all contaminated clothing.

Show this safety data sheet to the doctor in attendance.

If inhaled : Move the victim to fresh air.

Give oxygen or artificial respiration if needed.
Get immediate medical advice/ attention.
Never give anything by mouth to an unconscious person.

In case of skin contact : Wash thoroughly with soap and water for 15 minutes. If skin
irritation occurs, seek medical attention.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Get medical attention immediately if irritation develops and
persists.

If swallowed : If swallowed, DO NOT induce vomiting.

Do not give anything to drink.
Call a physician immediately.

Most important symptoms : The possible symptoms known are those derived from the
and effects, both acute and labelling (see section 2).
delayed No additional symptoms are known.

Notes to physician : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray jet

Alcohol-resistant foam

Unsuitable extinguishing : Dry powder

media Carbon dioxide (CO2)
High volume water jet

Specific hazards during : In case of fire hazardous decomposition products may be

firefighting produced such as:
Carbon monoxide
Nitrogen oxides (NOx)
Sulphur dioxide
Ammonia
SAFETY DATA SHEET

Aristoflex Velvet Page 3

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

Carbon dioxide (CO2)

Further information : If heated to decomposition, may emit very toxic fumes.

In the event of fire and/or explosion do not breathe fumes.
Do not allow run-off from fire fighting to enter drains or water
courses.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment : Wear an approved positive pressure self-contained breathing

for firefighters apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Wear suitable protective equipment.

protective equipment and Avoid dust formation.
emergency procedures Ensure adequate ventilation.
Small spills may be flushed to sewer or swept up. Larger
spills should be shovelled up or otherwise collected for
disposal. Clean up may be accomplished by removal of
contaminated soil or by flushing with water if appropriate.
Place soil or material in appropriate waste disposal
containers.

Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.

Methods and materials for : Non-sparking tools should be used.

containment and cleaning up Avoid dust formation.
Take measures to prevent the build up of electrostatic charge.
Sweep up and shovel into suitable containers for disposal.
Clean contaminated surface thoroughly.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Keep away sources of ignition.

fire and explosion Take precautionary measures against build-up of electrostatic
charges, e.g earthing during loading and off-loading
operations.
Dust can form an explosive mixture in air.

Advice on safe handling : Avoid dust formation. Keep away from sources of ignition.
Lead off electrostatic charges.
Avoid inhalation, ingestion and contact with skin and eyes.
Wash thoroughly after handling.

Further information on : Store in original container.

storage conditions Store in a cool, dry, well-ventilated area.
SAFETY DATA SHEET

Aristoflex Velvet Page 4

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

Materials to avoid : Do not store with alkalies

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
tert-Butyl alcohol 75-65-0 TWA 100 ppm ACGIH
TWA 100 ppm NIOSH REL
300 mg/m3
ST 150 ppm NIOSH REL
450 mg/m3
TWA 100 ppm OSHA Z-1
300 mg/m3
TWA 100 ppm OSHA P0
300 mg/m3
STEL 150 ppm OSHA P0
450 mg/m3
Engineering measures : A system of local and/or general exhaust is recommended
where employee exposures are at or above Occupational
Exposure Limits (OEL).

Personal protective equipment

Respiratory protection : Wear NIOSH approved particulate filtering respirator rated N,
R, or P95 or 100 or equivalent in the absence of proper
environmental control. Type of respirator depends on level of
exposure.

Hand protection
Remarks : Butyl Rubber, PVC Or Neoprene.

Eye protection : Safety glasses with side-shields

Skin and body protection : Wear protective clothing, including long sleeves and gloves,
to prevent skin contact.

Protective measures : Observe the usual precautions for handling chemicals.

Do not breathe dust.

Hygiene measures : Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it
before reuse.
SAFETY DATA SHEET

Aristoflex Velvet Page 5

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : powder

Colour : white

Odour : characteristic

Odour Threshold : not determined

pH : approx. 4 - 6 (68 °F / 20 °C)

Concentration: 1 g/l
Method: DIN EN 1262

Melting point : Decomposes before melting.

Boiling point : Not applicable

Flash point : Not applicable

Evaporation rate : not determined

Flammability (solid, gas) : not determined

Self-ignition : no data available

Burning number : 3
Local combustion without spreading

Upper explosion limit / upper : Not applicable

flammability limit

Lower explosion limit / Lower : Not applicable

flammability limit

Vapour pressure : Not applicable

Relative vapour density : Not applicable

Density : no data available

Bulk density : 230 kg/m3Method: ISO 697

Solubility(ies)
Water solubility : Gel formation (68 °F / 20 °C)

Partition coefficient: n- : Not applicable

SAFETY DATA SHEET

Aristoflex Velvet Page 6

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

octanol/water

Auto-ignition temperature : Not applicable

Decomposition temperature : approx. 482 °F / 250 °C

Viscosity
Viscosity, dynamic : Not applicable

Viscosity, kinematic : Not applicable

Explosive properties : Not explosive

Method: Expert judgement

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Method: Expert judgement

Molecular weight : 100 - 500 kg/mol

Dust explosion class : St1

Metal corrosion rate : < 6.25 mm/a

Not corrosive to metals

Minimum ignition energy : 100 - 300 mJ

Particle size : 0.2 - 282.5 µm

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous : Contact with strong bases liberates ammonia.

reactions The product is not a dust explosion risk as supplied; however
the build-up of fine dust can lead to a risk of dust explosions.

Conditions to avoid : Keep away from heat.

Incompatible materials : Alkalis

Hazardous decomposition : When handled and stored appropriately, no dangerous

products decomposition products are known
SAFETY DATA SHEET

Aristoflex Velvet Page 7

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Skin contact
Eye contact
Inhalation
Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg
Method: OECD Test Guideline 401

LD50 (Rat): > 2,000 mg/kg

Method: OECD Test Guideline 423

Acute inhalation toxicity : Acute toxicity estimate: 50 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method

Acute dermal toxicity : Remarks: not tested.

Components:
tert-Butyl alcohol:
Acute oral toxicity : LD50 (Rat, male and female): 3,046 mg/kg
Method: Other

Acute inhalation toxicity : Assessment: The component/mixture is moderately toxic after

short term inhalation.

Acute dermal toxicity : > 2,000 mg/kg

Assessment: The substance or mixture has no acute dermal
toxicity

Skin corrosion/irritation
Product:
Species: Rabbit
Method: OECD Test Guideline 404
Result: No skin irritation

Serious eye damage/eye irritation

Product:
Species: rabbit eye
Result: No eye irritation
Method: OECD Test Guideline 405
SAFETY DATA SHEET

Aristoflex Velvet Page 8

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

Components:
tert-Butyl alcohol:
Result: Irritating to eyes.

Respiratory or skin sensitisation

Product:
Test Type: Skin
Species: Guinea pig
Method: OECD Test Guideline 406
Result: non-sensitizing

Test Type: Skin

Species: Mouse
Method: OECD Test Guideline 429
Result: non-sensitizing

Germ cell mutagenicity

Product:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: yes

Test Type: Bacterial reverse mutation assay

Test system: Escherichia coli
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: yes

Germ cell mutagenicity - : Not mutagenic in Ames Test

Assessment

Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment

IARC No component of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

OSHA No component of this product present at levels greater than or

equal to 0.1% is on OSHA’s list of regulated carcinogens.
SAFETY DATA SHEET

Aristoflex Velvet Page 9

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

NTP No component of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment

No information available.

STOT - single exposure

Product:
Remarks: not tested.

Components:
tert-Butyl alcohol:
Assessment: May cause respiratory irritation.

STOT - repeated exposure

Product:
Remarks: not tested.

Repeated dose toxicity

Product:
Remarks: not tested.

Aspiration toxicity
Product:
no data available

Experience with human exposure

Product:
General Information : The possible symptoms known are those derived from the
labelling (see section 2).
SAFETY DATA SHEET

Aristoflex Velvet Page 10

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 1,000 mg/l
End point: mortality
Exposure time: 96 h
Method: OECD Test Guideline 203
Remarks: By analogy with a product of similar composition

Toxicity to daphnia and other :

aquatic invertebrates Remarks: not tested.

Toxicity to algae/aquatic :
plants Remarks: not tested.

Toxicity to microorganisms : EC50 (activated sludge): > 3,200 mg/l

Method: OECD Test Guideline 209

Persistence and degradability

Product:
Biodegradability : Result: Not readily biodegradable.
Biodegradation: 7 %
Exposure time: 28 d
Method: OECD Test Guideline 301B

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: not tested.

Mobility in soil
Product:
Distribution among : Remarks: not tested.
environmental compartments

Other adverse effects

Product:
Environmental fate and : Remarks: no data available
pathways

Results of PBT and vPvB : The substance is not identified as a PBT or as a vPvB
assessment substance.

Additional ecological : no data available

information
SAFETY DATA SHEET

Aristoflex Velvet Page 11

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
RCRA - Resource : No -- Not as sold.
Conservation and Recovery
Authorization Act
Waste Code : None

Waste from residues : Small quantities may be treated in aerobic wastewater

treatment systems. Larger quantities may be landfilled in
approved systems.

Contaminated packaging : Packaging that cannot be cleaned should be disposed of as

product waste

SECTION 14. TRANSPORT INFORMATION

DOT not restricted

IATA not restricted
IMDG not restricted

SECTION 15. REGULATORY INFORMATION

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : Combustible dust

SARA 313 : The following components are subject to reporting levels

established by SARA Title III, Section 313:

tert-Butyl alcohol 75-65-0 >= 1 - < 5 %

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
SAFETY DATA SHEET

Aristoflex Velvet Page 12

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI
Intermediate or Final VOC's (40 CFR 60.489):
tert-Butyl alcohol 75-65-0 >= 1 - < 5 %
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
This product does not contain any priority pollutants related to the U.S. Clean Water Act
The components of this product are reported in the following inventories:
TSCA : This product is not listed on the TSCA Inventory. It is to be
used as a cosmetic ingredient only. Any other use will subject
the user to penalties under the Toxic Substances Control Act
and the regulations issued thereunder.

SECTION 16. OTHER INFORMATION

Further information

NFPA 704:

Flammability

3
Health Instability
1 0

Special hazard

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated
values)
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1
Limits for Air Contaminants
SAFETY DATA SHEET

Aristoflex Velvet Page 13

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

ACGIH / TWA : 8-hour, time-weighted average

NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded
at any time during a workday
OSHA P0 / TWA : 8-hour time weighted average
OSHA P0 / STEL : Short-term exposure limit
OSHA Z-1 / TWA : 8-hour time weighted average

AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response,
Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL -
Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS -
Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS -
Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; ERG - Emergency Response Guide;
GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous
Materials Identification System; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise
Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals;
OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical
Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS
- Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation
(EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-
Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization
Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand
Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative

Observe national and local legal requirements

Handle with care. Organic dusts have the potential to be explosive with static spark or flame
initiation.

Revision Date : 02/24/2022

SAFETY DATA SHEET

Aristoflex Velvet Page 14

Substance key: 000000472194 Revision Date: 02/24/2022

Version : 3 - 1 / USA Date of printing :05/25/2022

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information’s accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application. NO
EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR
SERVICE. Nothing included in this information waives any of Clariant’s General Terms and
Conditions of Sale, which control unless it agrees otherwise in writing. Any existing
intellectual/industrial property rights must be observed. Due to possible changes in our products
and applicable national and international regulations and laws, the status of our products could
change. Material Safety Data Sheets providing safety precautions, that should be observed when
handling or storing Clariant products, are available upon request and are provided in compliance
with applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.

US / EN