According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

SAFETYDATA SHEET
PARCYANINE GREEN P- 4100
Section 1: Identification
1.1 Productidentifier
Product Form : Pigment
Trade Name : Parcyanine Green P-4100
Product Name : Pigment Green 7
Synonyms : Synthetic organic pigment

1.2 Intended use of the Product

Use of the Substance/Mixture : Sytheticorganicpigmentsarelargelyusedincolored
productslikeinks and paintsmaterialetc.
1.3 Manufacturer/Supplier
Name : ParshwnathDyechem Industries Pvt. Ltd.
Address : A-Wing, 801 to 806, The First, B/H. KeshavBaug Party
plot, Off. 132 Ft. Ring Road, Vastrapur, Ahmedabad –
380015.
1.4 Contact Details :
PhoneNo. : 91-079-26580151,26580170
Fax Nos : 0091-79-26582085,26581629
Email : [email protected]>
WebAddress : http://www.parshwnath.com

Section 2: Hazards identification

2.1 Classification of the substance or mixture
Not classified.

2.2GHS label elements, including precautionary statements

Pictogram(s) : No symbol.
Signal word : No signal word
Hazard statement(s) : none

Precautionary statement(s) :
Prevention : none
Response : none
Storage : none
Disposal : none

2.3Other hazards which do not result in classification

no data available
 Section 3: Composition/informationon ingredients
3.1 Substance
Chemical Name Common names and CAS Number EC Number Concentration
synonyms
C.I. Pigment Green 7 C.I. Pigment Green 7 1328-53-6 215-524-7 100%
3.2Mixture
Not Applicable

Section 4: First aidmeasures

4.1 Description of first aid measures
Afterinhalation : Supply fresh air;consultdoctorincaseofcomplaints.
Afterskincontact : Immediately wash with water and soap and rinse
thoroughly.Generallytheproductdoesnotirritate the
skin.
Aftereyecontact : Rinseopenedeye forseveralminutesunderrunning
water.Ifsymptomspersist, consulta doctor.
Afterswallowing : Do not induce vomiting; call for medical help
immediately.Drinkplentyofwater.
Informationfordoctor : Treatsymptomatically.

4.2 Mostimportant symptoms andeffects,bothacute anddelayed

Skin Contact : May cause irritation
EyeContact : Maycauseirritation

4.3 Indicationof any immediate medicalattention andspecialtreatment needed

Nofurtherrelevantinformationavailable.

Section 5: Fire-fightingmeasures

5.1 Extinguishing Media

Suitable Extinguishing Media : Dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2). Water may be ineffective butwater should
be used to keep fire-exposed container cool.
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of
water may spread fire.

5.2. Special Hazards Arising From the Substance or Mixture

Fire Hazard : Highly flammable liquid and vapor.
Explosion Hazard : May form flammable or explosive vapor-air mixture.
When mixed with air and exposed to an ignition source,
flammable vapors can burn in the open or explode in
confined spaces. Being heavier than air, vapors may travel
long distances toan ignition source and flash back. Runoff
to sewer may cause fire or explosion hazard.
Reactivity : Reacts violently with strong oxidizers. Increased risk of
fire or explosion.
5.3. Advice for Firefighters
Precautionary Measures Fire : Exercise caution when fighting any chemical fire.
Firefighting Instructions : Use water spray or fog for cooling exposed containers.
Remove containers from fire area if this can be
done without risk. In case of major fire and large
quantities: Evacuate area. Fight fire remotely due to the
risk of explosion. Donot breathe fumes from fires or
vapors from decomposition.
Protection During Firefighting : Do not enter fire area without proper protective
equipment, including respiratory protection.
Hazardous Combustion Products: Thermal decomposition generates: Carbon oxides (CO,
CO2). Sulfur oxides. Corrosive vapors.
Other Information : Do not allow run-off from fire fighting to enter drains or
water courses

Section 6: Accidentalreleasemeasures
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
Do not get in eyes, on skin, or on clothing. Do not breathe vapor, mist or spray. Keep away from
heat, hotsurfaces, sparks, open flames, and other ignition sources. No smoking. Use special care to
avoid static electric charges. Use onlynon-sparking tools.

6.1.1. For Non-Emergency Personnel

Protective Equipment : Use appropriate personal protective equipment (PPE).
Emergency Procedures : Evacuate unnecessary personnel. Stop leak if safe to do so.

6.1.2. For Emergency Personnel

Protective Equipment : Equip cleanup crew with proper protection.
Emergency Procedures : Eliminate ignition sources. Ventilate area. Upon arrival at
the scene, a first responder is expected torecognize the
presence of dangerous goods, protect oneself and the
public, secure the area, and call for the assistance of
trainedpersonnel as soon as conditions permit.

6.2. Environmental Precautions

Prevent entry to sewers and public waters.

6.3. Methods and Materials for Containment and Cleaning Up

For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into
sewers or streams. As animmediate precautionary measure, isolate spill or leak area in all
directions.

Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Absorb and/or
contain spill with inertmaterial. Do not take up in combustible material such as: saw dust or
cellulosic material. Use only non-sparking tools. Transferspilled material to a suitable container for
disposal. Contact competent authorities after a spill.

6.4. Reference to Other Sections

See Section 8 for exposure controls and personal protection and Section 13 for disposal
considerations
Section 7: Handlingand storage

7.1 Precautionsforsafe handling

Preventformationofdust.
Informationaboutfire-andexplosionprotection:Dustcancombinewithairtoformanexplosivemixture.
7.2 Conditionsforsafe storage,includinganyincompatibilities
Requirementsto be metbystoreroomsandreceptacles:Storeonly inunopened originalreceptacles.

Informationaboutstorage inonecommonstorage facility:

Donotstore withreducingagents,strongacidsandalkalies

Furtherinformationaboutstorageconditions :
Donotallowtofreeze, storeabove5°C

Specificenduse(s)
Syntheticorganicpigmentsarelargelyusedincoloredproductslikeplastics,paints,cosmetics,printingin
ks,rubber,crayons,artmaterialetc.

Section 8 :Exposure controls/personalprotection

8.1 Control parameters
Occupational Exposure limit values: no data available
Biological limit values : no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks
and at the end of workday.

8.3Individual protection measures, such as personal protective equipment (PPE)

Personal Protective Equipment: Protective clothing. Protective goggles. Gloves. Insufficient

ventilation: wearrespiratory protection. Face shield.
Materials for Protective Clothing: Chemically resistant materials and fabrics. Wear
fire/flame resistant/retardantclothing. Corrosion-proof
clothing.
Hand Protection : Wear protective gloves.
Eye Protection : Chemical safety goggles.
Skin and Body Protection : Wear suitable protective clothing. A full face shield is
recommended.
Respiratory Protection : If exposure limits are exceeded or irritation is experienced,
approved respiratoryprotection should be worn. In case of
inadequate ventilation, oxygen deficientatmosphere, or
where exposure levels are not known wear approved
respiratoryprotection.
Environmental Exposure Controls : Avoid release to the environment.
Other Information : When using, do not eat, drink or smoke
Thermal hazards : no data available

Section 9 : Physicalandchemical properties

Informationonbasic physicalandchemicalproperties
General Information
Appearance
Form Fine Dry Powder
Colour Green
Odour Odourless
pH Value 5.00 – 8.00
Changeincondition
Melting point/Meltingrange: 480 °C
Boiling point/Boilingrange: Undetermined.
Flash Point Not applicable
Self igniting point Product is not self-igniting
Danger of explosion Not explosive
Vapourpressure at25°C <0.001Pa
Density 2.3000 g/cm3
<0.1 g/l
Solubilityin/Miscibilitywithwaterat20°C Insoluble.
Partition Coefficient: n-octanol/water: log Kow:
Other Information
17.4

Section 10 : Stabilityandreactivity
10.1 Reactivity : No Data Available
10.2 Chemicalstability : Stableatenvironmenttemperature.No
decompositionifusedaccordingto specifications.
10.3 Possibilityofhazardous
reactions: C.I. PIGMENT GREEN 7 is incompatible with oxidizing
and reducing agents. Likely to react as a weak base in
aqueous solution.
10.4 Conditionstoavoid : Nofurtherrelevantinformationavailable.
10.5 Incompatiblematerials : No data available
Hazardousdecompositionproducts:Hydrogenchloridecan beformedduring combustion.
Additionalinformation:The substance islikely to behaveasaweakbase in aqueoussolution.

Section 11 : Toxicologicalinformation
Acute toxicity:
Oral:
Type of value : LD50
Species : rat and mice
Value : > 5,000 mg/kg (rat), >10000 mg/kg bw (mouse);
>3000 mg/kg (Rat (Fischer 344) Female) ((OECD Guideline 401
Acute Oral Toxicity))

Dermal : No effects Known

Skin corrosion/irritation:
Draize test : The substance was found to be non irritating in the Draize tests
conducted in Rabbit and Guinea Pig

Serious eye damage/irritation:

Draize test : The substance was found to be non irritating in the Draize tests
 conducted in Rabbit and Guinea Pig
Sensitisation
Respiratory or skin sensitisation:
The substance was found to be non-sensitising in Guinea pigs.

Inhalation : Not determined

Skin Corrosion/irritation: No data available

Serious eye damage/irritation: no data available

Respiratory or skin
Sensitization : no data available

Germ cell mutagenicity: The substance was found to be non-mutagenic as per Ames test.

Carcinogenicity : no data available

Reproductive toxicity : no data available

STOT-single exposure : no data available

STOT-repeated exposure:
Test description : 90 days repeated dose toxicity test on rat (strain- Fischer 344)
through oral administration did not produce any substance related
toxicity/ adverse effects.
Doses given were : 0.3, 0.6, 1.25, 2.5 and 5% in diet (approx. 150, 300, 625, 1250, 2500
mg/kgbw)
Result : no toxic effect was observed.

Aspiration hazard : no data available

Additional Information: No any

Section 12:Ecologicalinformation

12.1 Toxicity
Acquatic toxicity:
48 hour LC50 : >250 mg/l (Oryziaslatipes)
96 hour LC 50 : >752.4 mg/l (Lepomismacrochirus)
96 hour LC50 : 355.6 mg/l (Salmogairdneri)
24 hour EC50 : >500 mg/kg (daphnia)

12.2 Behaviourinenvironmental systems:

Persistence and degradability: Not easily biodegradable

Other information : Degradation in environment :

Degradation through hydroxyl radical Degradation half- lives :
The half-time was calculated as 1.9 hours (12 hour day, 1.5 * 106
OH/cm3) and 5.9 hours (24 hour day, 0.5*106OH/cm3).

Biodegradation or other processes such as oxidation or hydrolysis :

According to the structure and the low solubility in water, C.I.Pigment Green 7 is not expected to
be biodegradable.

12.3 Bioaccumulative potential

Since organic pigments are generally insoluble compounds, they are believed to have minimal
bioaccumulation and bio-availability characteristics.

10.6 Mobilityinsoil
Mobility
The substance is expected to sorb readily to soils and sediments. Thus, the mobility in soil is likely
to be limited.

Bioaccumulation:
BCF (Bio Concentration Factor)= ca. 0.51-4.8 for Cyprinuscarpio and Oryziaslatipes (fresh water
fishes) when exposed to 0.1 mg/l of the substance for 42 days at 25 C (OECD Guideline 305C).

Mobility in soil No further relevant information available.

10.7 Additionalecologicalinformation:
Generalnotes:Waterhazardclass1,silightlyhazardousforwater.Assessmentbylist.
Resultsof PBT andvPvBassessmentTOBEPROVIDEDINTHEREGISTRATIONDOSSIER
PBT:Notapplicable.
vPvB:Not applicable.

10.7 Otheradverseeffects
Nofurtherrelevantinformationavailable.

Section 13: Disposal considerations

13.1 Waste treatment methods/ Disposal Methods

Product
The material can be disposed of by removal to a licensed chemical destruction plant or by
controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed
by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to make it unusable for other purposes and then be
disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for
combustible packaging materials.
Section 14 : Transportinformation
UN-Number
DOT,ADN,IMDG,IATA Void
UNpropershippingname
DOT,ADN,IMDG,IATA Void
Transporthazardclass(es)
DOT,ADN,IMDG,IATA
Class Void
 Packing group
DOT,IMDG,IATA Void
Environmentalhazards:
Marinepollutant: No
· Specialprecautionsforuser Notapplicable.
· Transport in bulk according to Annex II ofMARPOL73/78andtheIBCCode Notapplicable.
· UN"ModelRegulation": -

Section 15 : Regulatoryinformation
15.1 Regulations:
CANADA : Listed on Canadian Domestic Substance (DSL) Inventory
USA (TSCA) : Listed on United States Toxic Substance Control Act (TSCA)
Inventory
USA (SARA Section 313): Not reporting requirements for this product
OSHA Regulatory Status: Not Listed
California Proposition 65: No proposition 65 substances

HazardpictogramsPlease refersection2
Hazard-determiningcomponentsof labelling: Pleaserefersection 2
HazardstatementsPleaserefersection 2
Precautionarystatementspleaserefersection2
Substances of very high concern (SVHC) according to REACH, Article 57 The substance
isnotlistedasSVHC.
Chemicalsafety assessment:A Chemical Safety Assessment has not been carried out and shall be
available at the time ofREACHregistration.

Section 16 : Other information

ThisSDS was prepared in accordance with the requirements of 2012 OSHA Hazaard
Communication Standard (29 CFR 1910.1200) and CandianHazrdous Products Regulations (HDR).

· DepartmentissuingMSDS:Productsafetydepartment.
· Contact:
PhoneNo.:91-079-26580151,26580170
Fax Nos :0091-79-26582085,26581629
Email:<[email protected]>Web Address:http://www.parshwnath.com

· Abbreviationsand acronyms:
TSCA:Toxic Substace Control Act in United States Regulation
OSHA : Occupational Safety and health Administration
DSL : Domestic Substance List Inventory in Canadian Regulation
RID:Règlementinternationalconcernantletransportdesmarchandisesdangereusesparchemindefer(RegulationsConcerningtheI
nternationalTransportofDangerousGoodsbyRail)
IMDG: InternationalMaritimeCodeforDangerousGoods IATA: InternationalAirTransportAssociationICAO:
InternationalCivilAviationOrganization

GHS: GloballyHarmonizedSystem ofClassificationandLabellingofChemicalsEINECS:

EuropeanInventoryofExistingCommercialChemicalSubstancesCAS:
ChemicalAbstractsService(divisionoftheAmericanChemicalSociety) LC50:Lethalconcentration,50percent
LD50: Lethaldose,50percent
· References
· IPCS - The International Chemical Safety Cards (ICSC), website:
http://www.ilo.org/dyn/icsc/showcard.home
· HSDB - Hazardous Substances Data Bank, website:
https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
· IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
· eChemPortal - The Global Portal to Information on Chemical Substances by OECD,
website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
· CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
· ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
· ERG - Emergency Response Guidebook by U.S. Department of Transportation, website:
http://www.phmsa.dot.gov/hazmat/library/erg
· Germany GESTIS-database on hazard substance, website:
http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
· ECHA - European Chemicals Agency, website: https://echa.europa.eu/

RevisionDate Preparedby Approvedby

Page9of 9
02/11/2024 I.P. RomalJobaliya