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    1812

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    vaishav12191

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    1812

    Uploaded by

    vaishav12191
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    1812

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    of 4

    MORE THAN ONE CORRECT TYPE

    (+4 if all correct options chosen, +1 for partial , -1 if incorrect)

    1. Among the given pairs, in which pair second compound has less enol content :

    O
    (A) and || (B) and
    CH3 – C – CH3

    (C) and (D) and

    2. When NaNO 3 is heated in a closed vessel, oxygen is liberated and NaNO 2 is left behind. At

    equilibrium . NaNO 3 (s) NaNO 2 (s) + 2 1 O (g)


    2

    (A) addition of NaNO2 favours reverse reaction


    (B) addition of NaNO 3 favours forwards reaction
    (C) increasing temperature favours forward reaction
    (D) increasing pressure favours reverse reaction

    3. Which of the following is the correct relationship ?

    NH2
    NHCH3 CH2 – CH2 – NH2 CH2 – NHC2H5
    CH3 CH3

    CH3 CH3 CH3


    CH3
    I II III IV

    (A) I & II are functional isomers. (B) II & IV are metamers.


    (C) I & IV are position isomers. (D) I & III are chain isomers.
    4. N2 (g) + O 2 (g) 2NO(g) , K1 ;
     1  1
      N (g) +   O (g) NO (g) , K2
    2 2
    2 2
    2 NO(g) N2(g) + O 2(g) , K3 ;

     1  1
    NO (g)   N (g) +   O (g) , K
    2 2 2 2 4

    Correct relation between K1 , K2 and K4 is :


    (A) K1 × K3 = 1 (B) K1  K 4 = 1 (C) K3  K2 = 1 (D) None of these

    5. If for 2 A2B(g) 2 A2 (g) + B2 (g) , Kp = TOTAL PRESSURE (at equilibrium) and starting the
    dissociation from 4 mol of A2B then :
    2
    (A) degree of dissociation of A2B will be
    3
    14
    (B) total number of moles at equilibrium will be
    3
    (C) at equilibrium the number of moles of A2B are equal to the no. of moles of B2 .
    (D) at equilibrium the number of moles of A2B are equal to the no. of moles of A2 .
    SINGLE CORRECT TYPE: (+4/-1)

    6. The value of k p for the reaction at 27 ºC , Br2 () + Cl2 (g) 2 BrCl (g)
    is ‘1 atm’ . At equilibrium in a closed container partial pressure of BrCl gas is 0.1 atm and at this
    temperature the vapour pressure of Br 2 () is also 0.1 atm . Then what will be minimum moles
    of Br 2 () to be added to 1 mole of Cl2 , initially, to get above equilibrium situation :
    10 5 15
    (A) moles (B) moles (C) moles (D) 2 moles
    6 6 6

    7. N2O 4 (g) 2 NO 2 (g) , Kc = 4 . This reversible reaction is


    studied graphically as shown in figure . Select the correct statements
    out of ,  and .
     : Reaction quotient has maximum value at point A
     : Reaction proceeds left to right at a point when
    [N2O 4] = [NO 2] = 0.1 M
     : Kc = Q when point D or F is reached :
    (A) ,  (B) ,
    (C) ,  (D) , , 

    8. N2 and H2 are taken in 1 : 3 molar ratio in a closed vessel to attained the following equilibrium
    P
    N2 (g) + 3 H 2 (g) 2 NH3 (g) . k p for reaction at total pressure of 2 p if PN2 at equilibrium
    3
    is :
    1 4 4 P2
    (A) 2
    (B) 2
    (C) (D) None of these
    3P 3P 3
    9. Number of structurally isomeric ethers with molecular formula C5H12O.
    (A) 4 (B) 5 (C) 6 (D) 7

    10. For the equilibrium SrCl2 · 6H2O(s) SrCl2 · 2H2O(s) + 4H2O (g) the equilibrium constant
    KP = 16 x 1012 atm 4 at 10C. If one litre of air saturated with water vapour at 10C is exposed to a large
    quantity of SrCl2· 2H2O(s), what weight of water vapour will be absorbed? Saturated vapour pressure
    of water at 10C = 7.6 torr.
    (A) 6.4 mg (B) 3.25 mg (C) 2.3 mg (D) 8.5 mg

    11. The two equilibria, AB(aq) A+(aq) + B(aq) and AB(aq) + B(aq) AB2(aq) are
    simultaneously maintained in a solution with equilibrium constants, K1 and K2 respectively . The
    ratio of A+ to AB2 in the solution is :
    (A) directly proportional to the concentration of B
    (B) inversely proportional to the concentration of B
    (C) directly proportional to the square of the concentration of B
    (D) inversely proportional to the square of the concentration of B

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