Pre Quarterly Examination - (1) 2023

Class – 11 CHEMISTRY Time ; 3.00Hrs

Section I
Answer all the questions. 15 x 1 = 15
Choose the most suitable answer from the given four alternatives and write the option code
and corresponding answer
1. The equivalent mass of a trivalent metal element is 9 g eq-1 the molar mass of its anhydrous oxide is
(a) 102 g (b) 27 g (c) 270 g (d) 78 g
2. According to the Bohr Theory, which of the following transitions in the hydrogen atom will give rise to
the least energetic photon ?
(a) n = 6 to n = 1 (b) n = 5 to n = 4 (c) n = 5 to n = 3 (d) n = 6 to n = 5
3. Which one of the following is the least electronegative element?
(a) Bromine (b) Chlorine (c) Iodine (d) Hydrogen
4. Ionic hydrides are formed by
(a) halogens (b) chalogens (c) inert gases (d) group one elements
5. The temperatures at which real gases obey the ideal gas laws over a wide range of pressure
is called
(a) Critical temperature (b) Boyle temperature
(c) Inversion temperature (d) Reduced temperature
6. The intensive property among the quantities below is
(a) mass (b) volume (c) enthalpy (d) mass / volume
7. In which of the following equilibrium, KP and KC are not equal?
(a) 2 NO(g) ⇌ N2(g) + O2(g) (b) SO2 (g) + NO2 (g) ⇌ SO3(g) + NO(g)
(c) H2 (g) + I2 (g) ⇌ 2HI(g) (d) PCl5 (g) ⇌ PCl3(g) + Cl2 (g)
8. The number of stereoisomers of 1, 2 – dihydroxy cyclopentane
(a) 1 (b)2 (c) 3 (d) 4
9. What is the hybridisation state of benzyl carbonium ion?
(a) sp2 (b) spd2 (c) sp3 (d) sp2d
10. Which of the following is the group number of element whose atomic no is 80
a) 4 b) 12 c) 14 d) 2
11. Which of the following atoms and ions are isoelectronic
I, Al3+ II, F III, Mg2+ IV, Na
a) I, II, III b) I, IV c) II, IV d) I, III, IV
12. The colour of Ferric sulphocyanide is
a) Blood red b) Prussian blue c) White d) Pale yellow
13. Pyrrole is a _____________ compound
a) Open chain (b) Aromatic c) Hetero cyclic d) Carbo cyclic
-1 -1
14. Molar heat capacity of Water is __________ KJ K mol
a) 4148 b) 4841 c) 4481 d) 4184
15. Keto – enol tautomerism is observed in
(a) C6H5CHO (b) C6H5OCH3 (c) C6H5COCH2COOH (d) C6H5COC6H5
Section II
Answer any six questions and question number 24 is compulsory. 6 x 2 = 12
16. Calculate Oxidation number of oxygen in KO2 and Na2O
17. State Pauli’s Exclusion Principle
18. Explain diagonal relationship
19. Complete the following equation. Na2O2 + ?  Na2SO4 + H2O2
20. State Dalton Law of partial pressures
21. Define molar heat capacity. Give its unit
22. Define – Le - Chatelierprinciple
23. Which element exhibits maximum catenation and why ?
H2O / H+ H2O / H+
24. Identify the compound (A) and (B). R – C  N (A) (B)
Section III
Answer any six questions and question number 33 is compulsory. 6 x 3 = 18
25. Define basicity. Find the basicity of ortho-phosphoric acid
26. Give the electronic configuration of Cr and Cu
27. How do you convert para hydrogen into orthohydrogen ?
28. What is Boyle’s temperature ? What happens to real gases above and below the Boyle’s temperature ?
29. C(s) + O2(g) CO2(g) Calculate the standard entropy change for the above reaction, given the standard
entropies of CO2(g), C(s) and O2(g) are 213.6, 5.740 and 205 JK-1 respectively
30. Explain Homogeneous and Heterogeneous equilibria
31. How do you detect the presence of Nitrogen and sulphur together in an organic compound ?
32. Write short notes on Hyper Conjugation
33. Calculate the effective nuclear charge on 4s electron and 3d electron in Scandium
Section IV
Answer all the questions. 5 x 5 = 25
34. a, Explain the Pauling method of calculating Ionic radius (OR)
b, i, What is the difference between molecular mass and molar mass?.
ii, Which has stable electronic configuration ? Ni2+ or Fe3+ . Give the reason.
35. a, i, What is water-gas shift reaction ?
ii, What happens Chlorine react with water ? and write the equation (OR)
b, Write down the Born-Haber cycle for the formation of CaCl2
36. a, i, The equilibrium constant of a reaction is 10, what will be the sign of ΔG? Will this reaction be
spontaneous?
ii, What are the consequence of Boyles law (OR)
b, Derive the relation between Kp and Kc
37. .a, Derive the relation between ΔH and ΔU for an ideal gas. (OR)
b,i, Define Reaction Quotient ‘Q’
ii, List the application of Equilibrium constant .
38. a, i, Write a note on homologous series.
ii, Describe optical isomerism with suitable example (OR)
b, i, What is Positive Mesomeric effect ? Give example.
ii, Explain electromeric effect.
 Pre Quarterly Examination - (2) 2023
Class – 11 CHEMISTRY Time ; 3.00Hrs

Section I
Answer all the questions. 15 x 1 = 15
Choose the most suitable answer from the given four alternatives and write the option
code
1. The equivalent mass of potassium permanganate in alkaline medium is
MnO4- + 2H2O+3e-MnO2 + 4OH-
(a) 31.6 (b) 52.7 (c) 79 (d) None of these
2. The energy of light of wavelength 45 nm is
(a) 6.67 × 1015J (b) 6.67 × 1011J (c) 4.42 × 10–18J (d) 4.42 × 10–15J
3. Increasing order of Electro negativity of F, Cl, Br and I is
a) I < Br < Cl < F b) F < Br < Cl < I c) I < Cl < F < Br d) F < Cl < Br < I
4. Elements of which group form anions most readily ?
a) 13 b) 14 c) 17 d) 1
5. Water gas is
(a) H2O(g) (b) CO + H2O (c) CO + H2 (d) CO + N2
6. Example of State function is
a) Work b) Heat c) Enthalpy d) None of these
o
7. What is the density of N2 gas at 227 C and 5.00 atm pressure? (R = 0.082 L atm K–1mol–1)
(a) 1.40 g/L (b) 2.81 g/L (c) 3.41 g/L (d) 0.29 g/L
–1 –1 –1
8. The values of ΔH and ΔS for a reaction are respectively 30 kJ mol and 100 JK mol . Then the
temperature above which the reaction will become spontaneous is
a) 300 K (b) 30 K (c) 100 K (d) 200C
9. The values of for the reactions X ⇌ Y + Z ; A ⇌ 2B are in the ratio 9 : 1 if degree of dissociation and
initial concentration of X and A be equal then total pressure at equilibrium P1, and P2 are in the ratio
(a) 36 : 1 (b) 1 : 1 (c) 3 : 1 (d) 1 : 9
10. Select the molecule which has only one π bond.
(a) CH3– CH = CH – CH3 (b) CH3– CH = CH – CHO
(c) CH3– CH = CH – COOH (d) All of these
11. Which of the following species does not acts as a nucleophile?
(a) ROH (b) ROR (c) PCl3 (d) BF3
12. In an organic compound, phosphorus is estimated as
(a) Mg2P2O7 (b) Mg3(PO4)2 (c) H3PO4 (d) P2O5
13. Which of the following is reversible process?
(a) Diffusion (b) melting (c) neutralization (d) combustion
14. 3d orbitals have :
(a) n = 3,l = 2 (b) n=3, l = 0 (c) n = 2, l = 3 (d) n = 3, l = 1
15. Diagonal relationship is for
a) B  Al b) Li  Be c) B  Si d) F  Na
Section II
Answer any six questions and question number 24 is compulsory. 6 x 2 = 12
16. What are auto redox reactions ? Give an example
17. State Heisenberg’s Uncertainty Principle
18. State Modern Periodic law
19. An the cube at 00 C is placed in some liquid water at 00 C, the ice cube sinks - Why ?
20. Define Gay-Lussac’s law
21. Explain Intensive properties with two examples
22. Give the general characteristics of organic compounds?
23. Explain inductive effect with suitable example.
24. Give a balanced chemical equation for the equilibrium reaction for which the equilibrium constant is
3
[H 2 ]3 [S 2 ]2
given by expression Kc =
[ H 2 S]3

Section III
Answer any six questions and question number 33 is compulsory. 6 x 3 = 18
25. Calculate the empirical and molecular formula of a compound containing 76.6% carbon, 6.38% of
hydrogen and rest oxygen. Its vapour density is 47
26. Define Exchange energy
27. Describe about the merits of Mendeleev’s periodic table.
28. Compare the structures of H2O and H2O2.
29. What are state and path functions? Give two examples.
30. Write Kp and Kc for the reaction 2CO(g)⇌ CO2(g) + C(s)
31. Explain paper chromatography
32. Give any three differences between Nucleophiles and Electrophiles
33. Explain the following observations
a, Aerated water bottles are kept under water during summer
b, Aerosol cans carry clear warning of heating of the can. Why?

Section IV
Answer all the questions. 5 x 5 = 25
34. a, i, The density of carbon dioxide is equal to 1.965 kgm at 273 K and 1 atm pressure. Calculate the
-3

molar mass of CO2.

ii, State the Newland’s law of Octaves (OR)
2+ 3+
b, i, Which has stable electronic configuration ? Ni or Fe . Give the reason.
ii, Write the electronic configuration of Lanthanides and actinides
35. a, i, How would you explain the fact that the second ionization potential is always higher than first
ionization potential.
ii, Mention the uses of deuterium (OR)
b, Explain the removing of Temporary hardness of water ?
36. a, i, Write the expected formulas for the hydrides of 4th period elements. What is the trend in the
formulas? In what way the first two numbers of the series different from the others
ii,. What is 100 volume of hydrogen peroxide? (OR)
b, i, Derive Van der Walls equation
37. a, i, What is inversion temperature ?
ii, Define the calorific value of food. What is the unit of calorific value? (OR)
b, Define Internal energy and List the Characteristics of internal energy
38. a, Derive the Kp and Kc for the following equilibrium reaction PCl5(g)⇌ PCl3(g) + Cl2(g) (OR)
b, Explain varions types of constitutional isomerism (structural isomerism) in organic compounds
 Pre Quarterly Examination - (3) 2023
Class – 11 CHEMISTRY Time ; 3.00Hrs

Section I
Answer all the questions. 15 x 1 = 15
Choose the most suitable answer from the given four alternatives and write the option code
1. Carbon forms two oxides, namely carbon monoxide and carbon dioxide. The equivalent mass of which
element remains constant?
(a) Carbon (b) oxygen (c) both carbon and oxygen (d) neither carbon nor oxygen
2. The maximum number of electrons in a sub shell is given by the expression
(a) 2n2 (b) 2l + 1 (c) 4l + 2 (d) none of these
3. In the third period the first ionization potential is of the order.
(a) Na > Al > Mg > Si > P (b) Na < Al < Mg < Si < P
(c) Mg > Na > Si > P > Al (d) Na< Al < Mg < Si < P
4. Tritium nucleus contains
(a).1p + 0 n (b).2p + 1n (c) 1p + 2n (d) none of these
5. The hybridisation of oxygen atom is H2O and H2O2 are, respectively
(a) sp and sp3 (b) sp and sp (c) sp and sp2 (d) sp3 and sp3
6. The value of universal gas constant depends upon
(a) Temperature of the gas (b) Volume of the gas
(c) Number of moles of the gas (d) units of Pressure and volume
7. In an adiabatic expansion of an ideal gas
(a) w = – Δu (b) w = Δu + ΔH (c) Δu = 0 (d) w = 0
8. Consider the following reversible reaction at equilibrium, A + B ⇌ C, If the concentration of the
reactants A and B are doubled, then the equilibrium constant will
(a) be doubled (b) become one fourth (c) be halved (d) remain the same
9. Example of Imines
(a) R – CH = NH (b) R – CH2– NH2 (c) R – C N (d) R – NH – CH3
10. Which of the following species is not electrophilic in nature?
(a) Cl+ (b) BH3 (c) H3O+ (d) +NO2
11. Which of the following compounds will show metamerism?
a) CH3–O–C2H5 (b) CH3–O–CH3 (c) CH3–CO–C2H5 (d) C2H5–O–C2H5
12. An organic dibasic acid is used in volumetric analysis.The percentage of elements are C = 26.7%,
H = 2.2% and O = 71.1%. Find the empirical formula of the acid.
(a) CH2O (b) CHO2 (c) C2H2O2 (d) CH4O
13. The Gibbs free energy is defined as:
(a) G = H – T.S (b) G = H + T.S (c) G = E – T.S (d) G = E + T.S
14. The outermost electronic configuration of the most electronegative element is:
(a) ns2 np3 (b) ns2 np4 (c) ns2 np5 (d) ns2 np6
15. To which of the following gaseous mixtures is Dalton’s law not applicable?
(a) Ne + He + SO2 (b) NH3 + HCl (c) O2 + N2 + CO2 (d) N2 + H2 + O2
Section II
Answer any six questions and question number 24 is compulsory. 6 x 2 = 12
16. What is the empirical formula of the following ? a) CH3COOH b) C8H10N4O2
17. State Aufau principle
18. Define Atomic radius
19. Define Grahams law of Diffusion
20. Define Heat and mention its unit.
21. What is Boiling point (or) Condensation point.
22. Give the structure for the following compound. a, 2-methylbutanal b, 3-methylpentane
23. What is Free radical Substitution reaction?
24. Explain the exchange reactions of deuterium.
 Section III
Answer any six questions and question number 33 is compulsory. 6 x 3 = 18
25. Calculate the amount of water produced by the combustion of 16 g of methane.
26. What are the limitations of Bohr’s atom model?
27. Write a note on period and group in long form of the periodic Table.
28. What are the applications of Dalton law.
29. Define system and explain its types?
30. Write Kp and Kc for the reaction. SrCO3 (s) ⇌ SrO(s)+ CO2(g)
31. Give the general formula for the following class of organic compounds.
a) Alkanes b) Alkenes c) Alkynes
32. What is Electrophilic Substitution reaction? and give one example
33. Hydrogen peroxide can function as an oxidising agent as well as reducing agent. Substantiate this
statement with suitable examples.
Section IV
Answer all the questions. 5 x 5 = 25
34. a, Balance the following equations by oxidation number method
i) K2Cr2O7 + KI + H2SO4  K2SO4 + Cr2(SO4)3 +I2+H2O
ii) KMnO4+FeSO4 + H2SO4  K2SO4 + MnSO4 + Fe2(SO4)3 + H2O (OR)
b, i) Derive de-Broglie equation
ii) What are degenerate orbitals?
35. a, K+ and Cl- ions are isoelectronic ions, compare the effective nuclear charge value for these ions.
(OR)
b, i) Give the difference ( Compare ) between Ortho and para hydrogen
ii) Give the preparation of Tritium
36. a, i, Why hydrogen peroxide is store in Plastic bottles not in Glass bottles
ii) What is hydrogen bonding and explain its types (OR)
b, i, Can a Van der Waals gas with a = 0 be liquefied? Explain.
ii, Explain Common Ion effect with an example.
37. a, State the various statements of second law of thermodynamics. (OR)
b, Define the following terms: a. isothermal process , b. adiabatic process
c. isobaric process and d. isochoric process
38. a, i, Derive the Kp and Kc for the following equilibrium reaction N2(g) + 3H2(g)⇌2NH3(g) (OR)
b, 0.355 g of an organic substance gave 0.287 g AgCl in a carius method for the estimation of
halogen. Find the Percentage of Cl in the compound.

V.SURESHKANNA, PG.ASST, GHSS, THIRUMANJOLAI.