Set 2 Part 2 White Equilibrium

Call: 93111 43200 EDU Station Set: 2
Q 1. The equilibrium concentration of x, y and z are 4, 2 and 2 molar respectively for the
equilibrium 2x + y ↔ z. The value of Kc is:
(a) 1/4 (b) 1/8 (c) 1/12 (d) 1/16
Q 2. Ten times increase in the pressure of reaction N2(g) + 3H2(g) ↔ 2NH3(g) at equilibrium
results in:
(a) increase in KP in multiples of 10 (b) decrease in KP in multiples of 10
(c) no change in KP (d) initial increase and then decrease KP
Q 3. The equilibrium, P4(g) + 6Cl2(g) ↔ 4PC13(g) is attained by mixing equal moles of P4 and
Cl2 in an evacuated vessel. Then at equilibrium:
(a) [Cl2] > [PCl3] (b) [Cl2] > [P4] (c) [P4] > [Cl2] (d) [PCl3] > [P4]
Q 4. Pure ammonia is placed in a vessel at a temperature where its dissociation is appreciable.

{2NH3 (g) ↔ N2(g) + 3H2(g)} At equilibrium:
(a) KP does not change ‘significantly with pressure
(b) concentration of N2 does not change with pressure
(c) concentration of NH3 does not change with pressure
(d) concentration of H2 is less than that of N2
Q 5. When reactants A and B are mixed to give products C and D, the reaction quotient (Q) at
the initial stage of reaction:
(a) is one (b) decreases with time
(c) independent of time (d) increases with time
Q 6. Choose the correct statement:

(a) If equilibrium constant for the reaction A2 + B2 ↔ 2AB is k than for the backward
1 1 1
reaction AB ↔ A2 + B the equilibrium constant k’ =
2 2 k
(b) The value of k is dependent on catalyst
(c) The rate of an exothermic reaction increases with increase in temperature
(d) Degree of dissociation of PCl5 increases with decrease in pressure
Q 7. Iron fillings and water were placed in a 5 litre vessel and sealed. The tank was heated to
1000°C. Upon analysis the tank was found to contain 1.10 gram of hydrogen and 42.5
gram of water vapour. If the reaction in the tank is represented by
3Fe(s) + 4H2O(g) ↔ Fe3O4(s) + 4H2(g)
The value of equilibrium constant is approximately:
(a) 0.003 (b) 30 (c) 0.03 (d) 3
EDU Station
Q 8. When sulphur in the form of S8 is heated at 900 K the initial pressure of S8 at 1 atm falls
by 29% at equilibrium (as S8 is converted to S2) The value of kp for this conversion will
be:
(a) 0.71 (b) 2.55 (c) 8.94 (d) 3.56
Q 9. The equilibrium of the reaction N2(g) + 3H2(g) ↔ 2NH3(g) will shift to the product side
when:
(a) Kp > l (b) Q < Kp (c) Q = Kp (d) Q > 2Kp
Q 10. One mole of acetic acid was allowed to react with one mole of ethyl alcohol till the
following equilibrium was established CH3COOH + C2H5OH ↔ CH3COOC2H5 + H2O
At equilibrium, it was found that 1/3 mole of acetic acid is present. The equilibrium
constant (Kc) for the reaction is:
(a) 1 (b) 1/9 (c) 4/9 (d) 4
1
Q 11. In the following equilibrium N2(g) + O2 (g) ↔ NO2(g) + heat
2
(a) the equilibrium will shift to the right due to decrease in the concentration of N2
(b) the equilibrium will shift to the right due to an increase in temperature
(c) the equilibrium will shift to the left due to an increase in volume
(d) the equilibrium will shift to the left due to an increase in the concentration of O2
Q 12. For which of the following reactions KP = KC:

(a) N2(g) + 3H2(g) ↔ 2NH3 (g) (b) 2NOCl (g) ↔ 2NO(g) + Cl2(g)
(c) H2(g) + I2(s) ↔ 2HI (g) (d) H2(g) + Cl2(g) ↔ 2HCl(g)
Q 13. On decomposition of NH4HS, the following equilibrium is established:

NH4HS(s) ↔ NH3(g) + H2S(g)
If the total pressure is P atm, then the equilibrium constant KP, is equal to:
(a) P atm (b) P2 atm2 (c) P2/4 atm2 (d) 2P atm
Q 14. In a reversible reaction two substances are in equilibrium. If the concentration of each
one is reduced to half, the equilibrium constant will be:
(a) reduced to 1/2 of its original value (b) doubled
(c) remains same (d) reduced to 1/4 of its original value
Q 15. One mole of N2O4(g) at 300K is kept in a closed container at one atmosphere. It is heated
to 600 K when 20% by mass of N2O4(g) decomposes to NO2(g) (N2O4 ↔ 2NO2).
The total resultant pressure is:
(a) 1.2 atm (b) 2.4 atm (c) 2.0 atm (d) 1.0 atm
EDU Station
Q 16. Which of the following statements is correct:

(a) At equilibrium concentrations of reactants and products become constant because the
reaction stops
(b) Addition of catalyst speeds up the forward reaction more than the backward reaction
(c) Equilibrium constant of an exothermic reaction decreases with increase of
temperature
(d) KP is always greater than Kc
Q 17. For the gas phase reaction C2H4 + H2 ↔ C2H6, H = -136.8 kJ mol-1 carried out in a
vessel the equilibrium concentration of C2H4 cannot be increased by:
(a) increasing the temperature (b) decreasing the pressure
(c) removing some H2 (d) removing some C2H6
Q 18. The decomposition of N2O4 to NO2 is carried out at 280° in chloroform. When
equilibrium is reached 0.2 mol of N2O4 and 2 × 10-3 mol of NO2 are present in 2 litre
solution. The equilibrium constant for the reaction N2O4 ↔ 2NO2 is:
(a) 1 × 10-3 (b) 2 × 10-3 (c) 1 × 10-5 (d) 2 × 10-5
Q 19. In which of the following equilibrium, the equilibrium constant is not greater than one?
(a) HC1(g) + NH3(g) ↔ NH4 Cl(s)
(b) Fe(s) + H2S(g) ↔ FeS(s) + H2(g)
(c) 2H2O2(l) + H2S(g) ↔ H2SO4(l) + 2H2(g)
(d) 2Al2O3(s) + 3Si(s) ↔ 3SiO2(s) + 4Al(s)
Q 20. Consider the general reaction A(s) ↔ 2B(g) + 3C(g) If the concentration of C at
equilibrium is doubled, then after the equilibrium is re-established, the concentration of B
will be:
(a) 22 times the original value (b) one half of its original value
(c) 1/(22) times the original value (d) Can’t be determined
EDU Station

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Call: 93111 43200 EDU Station Set: 2

Q 4. Pure ammonia is placed in a vessel at a temperature where its dissociation is appreciable.

Q 6. Choose the correct statement:

Q 12. For which of the following reactions KP = KC:

Q 13. On decomposition of NH4HS, the following equilibrium is established:

Q 16. Which of the following statements is correct:

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