Chapter (2)
Chapter (2)
Chapter (2)
Chapter (2)
Properties States of Matter
State of Matter
States of matter are considered physical properties. Solids have particles
packed in a regular pattern and are dense. There is very little space between the
particles. Most metals, such as gold and silver, are in a solid state at room
temperature. When a solid is heated, its particles gain energy and expand.
When the particles reach the melting point, they break away from their
positions and enter a liquid state.
Liquids take the shape of the container in which they are placed, meaning that
the particles are not in a fixed position. Liquids are less dense than solids
because there is a small amount of space between the particles. Mercury (a
metal) and bromine (a nonmetal) are in a liquid state at room temperature.
When a liquid is heated to the boiling point, the particles gain energy and
expand, changing state into a gas. When the particles contain even more
energy, evaporation can take place. When liquids are cooled, they can solidify
and enter a solid state.
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Gases have very low densities because there are huge amounts of space
between the particles. Gases are easily compressed and have no shape, filling
up whatever space is available as the particles move around. Many nonmetals,
including helium, oxygen, and hydrogen, are in a gas state at room
temperature. When a gas is cooled, the particles lose energy, causing them to
move more slowly and closer together until the gas becomes a liquid. This
change of state is called condensation.
SOLIDS
• definite shape and volume but cannot flow
• fixed pattern
• only vibrate
• close together
LIQUIDS
• a definite volume but takes the shape of its container. It can flow.
• random – no fixed pattern
• slide past each other
• close together
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GASES
• no definite volume. It can spread every where through its container.
• random
• move everywhere rapidly
• far apart
Compressing gases
➢ a gas as a collection of randomly moving particles
➢ which collide with each other and with the walls of their container.
➢ When increasing the pressure, the particles get closer to each other.
➢ So the volume of the gas decreases.
Fig. When the volume of the container is decreased, the gas molecules are squashed closer
together and hit the walls of the container more frequently.
Fig. As the pressure of a gas increases, its volume decreases (at constant temperature).
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Heating gases
➢ When the volume of gas is not fixed, for example in a gas syringe, the volume of gas
increases as the temperature increases.
➢ At higher temperatures, the particles have more kinetic energy.
➢ So they move faster and hit the walls of the syringe with greater force.
➢ So the plunger in the syringe is pushed outwards, and the volume of the gas increases.
Fig. As the temperature of a gas increases, its volume increases (at constant pressure).
Note that increasing the temperature increases the average speed of the gas particles, but
increasing the pressure at constant temperature has no effect on the speed of the gas
particles.
SUMMARY QUESTIONS
1 Which of these phrases refers to
a gases b liquids c solids?
●● The particles are close together
●● The particles are randomly arranged
●● The particles only vibrate.
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Changes of state
What happens when matter changes state?
The three most familiar states of matter are solid, liquid, and gas.
A change of state is the change of a substance from one physical form of matter to another.
To change a substance from one state to another, energy must be added or removed.
When a substance gains or loses energy, its temperature changes or its state changes.
All matter is made of tiny particles that are in constant motion. During a change of state,
the motion of the particles changes.
Particles can break away from each other and gain more freedom to move, or they may
attract each other more strongly and have less freedom to move.
During a change of state, a substance gains energy from or loses energy to the environment,
but the total amount of energy is conserved.
Melting
When a solid is heated, energy is transferred to the solid.
Its particles gain energy and their vibrations are stronger.
The forces of attraction between the particles are weakened and the solid melts. The solid
turns to a liquid.
The melting point is the temperature at which a solid turns to a liquid.
Freezing
Freezing is the process by which a substance changes from a liquid to a solid.
The temperature at which a liquid becomes a solid is called freezing point.
A pure substance melts and freezes at the same temperature.
Boiling
Heating a liquid to a higher temperature weakens the forces of attraction between particles
further.
When a high enough temperature is reached, the attractive forces keeping the liquid's
particles grouped together are broken.
The particles can form bubbles of gas that escape from the surface of the liquid. So as the
bubbling liquid turns into a gas, we say that the liquid boils. The boiling point is the
temperature at which a liquid turns to a gas.
What happens to the particles of a liquid that is heated until its boils?
4
Boiling curves
Evaporation
At temperatures below the boiling point of a liquid, some of its particles have enough energy
to escape from the surface.
They form a vapour.
This process is called evaporation. Energy needs to be taken in to melt, boil or evaporate a
substance.
Evaporation Boiling
Condensing
Cooling a gas makes it condense into a liquid.
Further cooling results in the liquid freezing (solidifying).
Energy is released (given out or transferred) to the surroundings when a substance condenses
or freezes.
As the temperature decreases, the gas particles lose energy and move slowly. So, the
movement of the particles becomes slow enough for the gas to change to a liquid.
The surroundings include the air as well as the container in which the solid, liquid or gas is
placed.
Sublimation
A few substances change directly from a solid to a gas when heated.
No liquid state is seen. On cooling, the gas turns back to the solid state.
This change is known as sublimation.
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Deposition
The opposite of sublimation is deposition.
Deposition is a substance changes directly from a gas to a solid without going throughout the
liquid state.
It occurs when gas particles become very cold.
An example of deposition is when water vapor in the atmosphere changes directly into ice,
such as the formation of frost.
Fig. When the volume of the container is decreased, the gas molecules are squashed closer
together and hit the walls of the container more frequently.
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SUMMARY QUESTIONS
1 Give the names of these changes of state:
a liquid to gas b solid to liquid c gas to liquid
2. Describe what happens to the energy and motion of the particles when ice changes to water.
3. Explain, using the kinetic particle theory, how the volume of a gas in a gas syringe changes when
the temperature decreases. The pressure is constant.
4. Explain, using the kinetic particle theory, how the volume of a gas in a gas syringe changes when
the pressure decreases
1
PRACTICAL
A heating curve for stearic acid
➢ A sample of solid stearic acid is heated at a constant rate using the apparatus shown.
➢ The temperature of the stearic acid is recorded every 30 seconds.
➢ The flat part of the graph in Fig. shows where the solid is changing to liquid.
➢ This is the melting point of stearic acid. There is no temperature rise here.
➢ So the energy supplied is not raising the temperature.
➢ The energy is being absorbed to overcome the attractive forces holding the particles of solid
in position.
D – E : Boiling
The force of attraction between the particles are weaken enough so that the particles move well away
from each other. The temperature is constant because the energy supplied is going to overcome the
forces between the particles instead of raising the temperature. The substance boils.
E : The liquid boils and completely turns to gas
The change of state from liquid to gas is complete.
E – F : heating of gas
Increasing heat energy increases the speed of the particles in the gas . So the temperature if the gas
increases.
A – B : cooling of gas
Decreasing the kinetic energy decreases the speed of the gas particles. So the temperature of the gas
falls.
B - C : Condensing
The forces of attraction between the particles are strengthened. The temperature is constant here
because heat energy is released when intermolecular attractive forces are formed. The heat given out
during condensation stops the temperature from falling.
C–D: Liquid cooling
Decreasing the kinetic energy decreases the speed of the particles in the liquid. So the temperature
of the liquid falls.
D–E: freezing
The temperature is constant because heat energy is released when a liquid changes to a solid. The
heat given out during freezing stops the temperature from falling.
E–F: Solid cooling
Decreasing kinetic energy decreases the vibration of the particles in the solid. So the temperature
decreases.
➢ The horizontal (flat) parts of cooling and heating curves show the melting point and boiling
point.
4
Compare the heating curves for pure substance and not pure substance
Fig. heating curves for pure substance Fig. heating curves for pure substance
The heating/cooling curve of a pure substance always has plateaus or flat sections where it melts or
boils because it melts/boils at fixed temperatures whereas impure substances melt/boil at variable
temperatures.
5
SUMMARY QUESTIONS
1. Sodium chloride melts at 801°C and boils at 1413°C. Describe the physical state of sodium
chloride at a 970°C b 1500°C. Explain your answers.
2. Methane condenses at –164°C and freezes at –182°C. Describe the physical state of methane at
a –190°C b –150°C. Explain your answers.
3. Copy and complete using the words below:
absorbed flat forces energy melting
When we heat a solid, …………. is absorbed and raises the temperature of the solid. At the
……….. point, the energy is ………. to overcome the attractive ………… between the particles
rather than raising the temperature. That is why there is ……… a part to the heating curve
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Fig. The colour of the ink spreads because the moving particles of ink mix with the moving water
particles.
Explain using the kinetic particle theory why the colour of a crystal spreads through the water
in which it is placed.
The colour of a crystals (particles) go from close together to spread out into solution.
Diffusion occurs due to the random and continuous movement of particles in all direction.
The movement of particles from higher to lower concentration.
When the concentration of the particles is even throughout a given space, diffusion of
particles stops.
Other examples can be explains for liquid form such as preparation of tea and coffee in water.
Diffusion in gases
Diffusion provides evidence for the kinetic particle theory.
Diffusion occurs in gases because the molecules in gases are constantly moving, colliding
with each other and changing directions.
This results in the gases spreading out and mixing.
a gas jar containing (colourless) oxygen above a gas jar of bromine vapour (brown), the
molecules of the bromine vapour and oxygen gradually mix because all the particles are
moving and colliding randomly.
PRACTICAL
Diffusion along a glass tube
A long glass tube is set up as shown.
Concentrated hydrochloric acid gives off fumes of a colourless gas called hydrogen chloride.
Concentrated ammonia solution gives off colourless ammonia gas. These gases diffuse along
the tube.
After a few minutes a white ring is seen nearer one end of the tube.
When the molecules of ammonia and hydrogen chloride collide with each other they react
and form a white solid, ammonium chloride.
caused by the random, irregular bombardment (hitting) of visible particles, by even smaller
particles of the liquid or gases they are suspended in, which cannot be seen.
smaller particles can be molecules, atoms or ions.
When the collision on one side of the particle are stronger, or greater in number, than those
on the other sides, the particles move slightly.
Because the bombardment is random and irregular, the particles also moves irregularly.
Fig. The unequal bombardment of water molecules on a tiny grain causes it to move in the
direction shown
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SUMMARY QUESTIONS
1. Copy and complete using the words below:
different diffusion gases mixed particles random
The kinetic particle theory states that the ………. in liquids and ………. are in constant ………..
motion. When freely moving particles collide, they bounce off each other ……….. in directions.
If the particles are different, they get …………up together. This process is called …………… .
3. The relative molecular masses of four gases are: carbon dioxide 44; methane 16; nitrogen 28;
oxygen 32. Put these gases in order of their rate of diffusion, with the fastest first.
1
Practice Questions
1. Use the kinetic particle model to describe the differences between liquid lead and lead gas in terms of:
● the separation of the particles ............................................................................................
....................................................................................................................................................
....................................................................................................................................................
● the motion of the particles. .................................................................................................
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.................................................................................................................................................... [4]
2. Use the kinetic particle model to describe the differences between solid aluminium and liquid
aluminium in terms of:
● the arrangement of the particles .........................................................................................
....................................................................................................................................................
....................................................................................................................................................
● the separation of the particles. ...........................................................................................
....................................................................................................................................................
................................................................................................................................................... [4]
3. Use the kinetic particle model to describe the differences between solid sulfur and sulfur gas in terms of:
● the arrangement of the particles
....................................................................................................................................................
....................................................................................................................................................
● the motion of the particles.
....................................................................................................................................................
....................................................................................................................................................[4]
4. Use the kinetic particle theory to describe the differences between nitrogen gas and liquid nitrogen in
terms of:
● the separation of the particles
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
● the motion of the particles.
.............................................................................................................................................
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5. Use the kinetic particle theory to describe the differences between sulfur gas and solid sulfur in terms of:
● the arrangement of the particles
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
● the separation of the particles.
....................................................................................................................................................
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6. Use the kinetic particle theory to describe the differences between solid aluminium and liquid
aluminium in terms of:
● the separation of the particles
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
● the motion of the particles.
.............................................................................................................................................
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11. Use the kinetic particle model to describe the arrangement and motion of the particles in molten
(liquid) lead.
arrangement ..............................................................................................................................
motion ........................................................................................................................................[2]
13. Use the kinetic particle model to describe the arrangement and separation of the particles in solid
sodium.
arrangement ..............................................................................................................................
separation ..................................................................................................................................[2]
15. (a) Complete the table about solids, liquids and gases.
(b) The graph shows the change in temperature as a sample of a gas is cooled.
(b) Use the kinetic particle model to describe the arrangement and separation of the particles in:
solid sodium ........................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
liquid sodium. ......................................................................................................................
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.............................................................................................................................................[4]
18. Watch-glasses of aqueous ammonia and concentrated hydrochloric acid were placed near each other on
a table.
At first no white fumes were seen.
After a short time, white fumes were seen between the watch-glasses.
20. When a piece of solid carbon dioxide is placed in a warm room, it undergoes sublimation.
(i) What is meant by the term sublimation?
.............................................................................................................................................
....................................................................................................................................... [2]
(ii) Use the kinetic particle model to describe the motion and separation of the particles in:
solid carbon dioxide ............................................................................................................
.............................................................................................................................................
.............................................................................................................................................
carbon dioxide gas. ............................................................................................................
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.............................................................................................................................................[4]
(b) The graph shows how the volume of iodine gas changes with pressure. The temperature is kept
constant.
Describe how the volume of the bromine gas changes with temperature.
....................................................................................................................................................
.............................................................................................................................................. [1]
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Describe how the pressure of the chlorine gas changes with temperature.
....................................................................................................................................................
.............................................................................................................................................. [1]
26. The melting point of pure S is 159°C.
The boiling point of pure S is 200°C.
(i) What is the physical state of pure S at 100°C?
Explain your answer.
.............................................................................................................................................
....................................................................................................................................... [2]
(ii) Which one of these statements about an impure sample of compound S is correct?
Tick one box.
(ii) Use the kinetic particle model to describe the separation and motion of the particles in water when
it is:
● a liquid
.............................................................................................................................................
.............................................................................................................................................
● a vapour
.............................................................................................................................................
.............................................................................................................................................[4]
28. Bromine is a volatile liquid. Potassium bromide is a compound made from bromine.
Use the kinetic particle model to describe the arrangement and motion of the particles in bromine when
it is:
● a liquid
....................................................................................................................................................
....................................................................................................................................................
● a gas
....................................................................................................................................................
.................................................................................................................................................... [4]
29. When sulfur vapour falls on to a cold surface, small crystals of solid sulfur form.
Use the kinetic particle model to describe the arrangement and motion of the particles in sulfur when it is:
● a gas
....................................................................................................................................................
....................................................................................................................................................
● a solid
....................................................................................................................................................
....................................................................................................................................................[4]
30. Limonene is a volatile liquid which smells of oranges.
A teacher placed a beaker of limonene at the front of a classroom.
At first, the students at the back of the classroom could not smell the limonene.
After two minutes, the smell of limonene had spread throughout the classroom.
The air in the classroom was still and calm.
(i) Explain these observations using the kinetic particle model.
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33. Potassium bromide has a melting point of 734 °C.
Iodine monochloride has a melting point of 27 °C.
In terms of attractive forces, explain why there is a large difference between these melting points.
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34. A drop of sulfur dichloride was placed in the corner of a glass box.
The glass box was closed and left for 12 hours.
After 12 hours a red vapour had spread to fill the whole box.
36. The graph shows how the temperature of a substance changes as it is cooled over a period of 30
minutes. The substance is a gas at the start.
Each letter on the graph may be used once, more than once or not at all.
(a) Which letter, S, T, V, W, X, Y or Z, shows when
(i) the particles in the substance have the most kinetic energy,
....................................................................................................................................... [1]
(ii) e particles in the substance are furthest apart,
....................................................................................................................................... [1]
(iii) e substance exists as both a gas and a liquid?
....................................................................................................................................... [1]
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(b) Use the graph to estimate the freezing point of the substance.
…............................... °C [1]
(c) Name the change of state directly from a solid to a gas.
.............................................................................................................................................. [1]
(d) When smoke is viewed through a microscope, the smoke particles in the air appear to jump
around.
(i) What term describes this movement of the smoke particles?
....................................................................................................................................... [1]
(ii) plain why the smoke particles move in this way.
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37. (a) Dust particles in the air move around in a random way.
(i) What term describes the random movement of the dust particles?
....................................................................................................................................... [1]
(ii) Identify the particles in the air which cause the random movement of the dust particles.
....................................................................................................................................... [2]
(iii) Explain why the dust particles move in this way.
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(b) When chlorine gas, Cl2, is put into a gas jar, it spreads out to fill the gas jar.
When bromine gas, Br2, is put into a gas jar, it also spreads out to fill the gas jar.
The process takes longer for bromine gas than for chlorine gas.
(i) What term describes the way that the gas particles spread out?
....................................................................................................................................... [1]
(ii) Use data from the Periodic Table to explain why bromine gas takes longer to fill a gas jar than
chlorine gas.
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....................................................................................................................................... [2]
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(iii) Explain why increasing the temperature increases the rate at which the gas particles spread out.
.............................................................................................................................................
....................................................................................................................................... [1]
Describe what happens to the volume of substance X in the syringe when the pressure is increased.
The temperature remains constant. Explain your answer in terms of particles.
....................................................................................................................................................
.............................................................................................................................................. [2]
Describe what happens to the volume of substance Z in the syringe when the temperature is increased.
The pressure remains constant. Explain your answer in terms of particles.
....................................................................................................................................................
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40. A closed gas syringe contains substance R. The syringe is heated in a water bath.
Describe what happens to the volume of substance R in the syringe. The pressure remains constant.
Explain your answer in terms of particles.
....................................................................................................................................................
.............................................................................................................................................. [2]
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After five minutes, a red solid appeared along the line marked S on the diagram.
(i) Explain why a red solid appeared along the line marked S.
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(ii) The experiment was repeated at a higher temperature.
What effect, if any, would this have on the time taken for the red solid to appear? Explain your
answer.
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42. A porous pot has tiny holes in its walls which allow gases to move in or out of the pot.
A teacher filled a porous pot with green chlorine gas. The teacher then placed the pot in a large jar of
air. After 10 minutes, a green colour was seen outside the porous pot.
43. Methyl orange and methyl red are both dyes which can be used as indicators.
(a) The actual value for the melting point of methyl red is 180°C.
A chemist prepares a sample of methyl red and finds that it melts over the range 173°C to 177°C.
Suggest why the melting point of this sample was different from the actual value.
.............................................................................................................................................. [1]
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(b) A concentrated solution of methyl orange was placed at the bottom of a beaker containing an
organic solvent.
After 5 hours, the orange colour had spread throughout the solvent.
45. Matter can exist as solid, liquid or gas. The arrows show some changes of state.
(b) Complete the table to show the separation, arrangement and movement of particles in each
physical state.
47. The diagram shows the changes of state when zinc vapour is cooled slowly to room temperature.
48. The melting point of bromine is –7 ºC. The boiling point of bromine is +59 ºC.
Deduce the state of bromine at +6 ºC. Explain your answer.
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49. The graph shows how increasing the pressure at constant temperature changes the volume of a fixed
mass of carbon dioxide gas.
50. Concentrated ammonia solution gives off ammonia gas. Concentrated hydrochloric acid gives off
hydrogen chloride gas. Ammonia, NH3, and hydrogen chloride, HCl, are both colourless gases.
Ammonia reacts with hydrogen chloride to make the white solid ammonium chloride.
Apparatus is set up as shown.
After ten minutes a white solid form in the tube where the gases meet.
(i) Name the process by which the ammonia and hydrogen chloride gases move in the tube.
....................................................................................................................................... [1]
(ii) At which point, A, B, C or D, does the white solid form? Explain why the white solid forms at that
point.
the solid forms at ..............
explanation .........................................................................................................................
.............................................................................................................................................[3]
(iii) The experiment was repeated at a higher temperature.
Predict how the results of the experiment would be different. Explain your answer.
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51. A student left a cube of ice on a plate in a warm room. The diagrams below show what happened to the
ice.
52. Mercury is a liquid at room temperature. When heated, it changes to mercury vapour.
Explain, using the kinetic particle theory, the differences in the arrangement and motion of the
particles in liquid mercury and mercury vapour.
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Describe and explain these results using ideas about particles in liquids and gases.
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54. The diagram shows the arrangement of carbon dioxide molecules at –25 °C and 100 atmospheres
pressure.
56. Gases diffuse, which means that they move to occupy the total available volume.
(i) Explain, using kinetic particle theory, why gases diffuse.
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(ii) When the colourless gases hydrogen bromide and ethylamine come into contact, a white solid is
formed.
Predict at which position, A, B or C, the white solid will form. Explain your choice.
.............................................................................................................................................
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57. A student placed a crystal of purple potassium manganate (VII) on a fi lter paper which had been
soaked in water.
After 5 minutes, a purple colour had spread out from the crystal.
After 30 minutes, the purple colour had spread further out.
59. Use ideas about the movement and arrangement of particles to explain why:
● solids have a definite volume and shape,
● liquids have a definite volume but no definite shape,
● gases have no definite volume or shape.
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61. The diagram shows the changes of state when tin vapour is cooled slowly to room temperature.
Explain what happens to the arrangement and motion of the atoms during these changes.
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62. Explain each of the following in terms of the kinetic particle theory.
A liquid has a fixed volume but takes up the shape of the container. A gas takes up the shape of the
container but it does not have a fixed volume.
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64. Garlic is a vegetable that is often used in cooking. It has a strong smell.
A student is cutting up garlic in the kitchen.
After a time, the smell of the garlic travels all over the house even though there are no currents of air.
Use the kinetic particle theory to explain why the smell of garlic travels all over the house.
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65. Fluorine is a diatomic molecule. It melts at –220 °C and boils at –188 °C.
What is the physical state of fluorine
at room temperature, .................................................................................................
at –200 °C? .......................................................................................................... [2]
67. A student placed a spoonful of sugar in the bottom of a glass of cold tea and left it undisturbed for
several minutes.
After 2 minutes, she used a straw to taste some of the tea from the top of the glass. It did not taste
sweet.
After 10 minutes, the sugar had disappeared and the solution at the top of the glass tasted sweet.
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68. A student placed some crystals of salt at the bottom of a beaker of distilled water. She left the contents
of the beaker to stand for one hour.
The diagram below shows her observations.
After one hour, all the salt had disappeared but the solution at point X tasted salty.
Use the kinetic particle theory to explain these observations.
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Multiple Choice Questions
1. Diagrams of the three states of matter for carbon dioxide are shown.
Which two diagrams show the states of matter before and after the sublimation of carbon dioxide?
A 2 to 1 B 2 to 3 C 3 to 1 D 3 to 2
4. Which two gases will diffuse at the same rate, at the same temperature?
A carbon monoxide and carbon dioxide
B carbon monoxide and nitrogen
C chlorine and fluorine
D nitrogen and oxygen
8. Decane has a freezing point of –30 °C and a boiling point of 174 °C.
2
A small sample of decane is placed in an open beaker in an oven at a temperature of 120 °C and at
atmospheric pressure for 24 hours.
What happens to the sample of decane?
A It boils.
B It evaporates.
C It melts.
D It sublimes.
9. Which row describes what happens to the particles in solid iodine when it is heated and turned into a
gas?
10. The particles in a substance are far apart, randomly arranged and moving.
The substance changes state and the particles are now close together. The particles are still randomly
arranged and able to move.
What is the change of state of the substance?
A gas to liquid
B liquid to gas
C liquid to solid
D solid to gas
12. Brownian motion and the diffusion of gases provide evidence for the particulate nature of matter.
3
Which row identifies an example of Brownian motion and how molecular mass determines the rate of
diffusion of gas molecules?
13. Which row describes the arrangement and movement of particles in a liquid?
14. Iodine changes directly from a grey solid to a purple gas when it is heated.
What is the name of this process?
A condensation
B evaporation
C separation
D sublimation
16. Solid carbon dioxide changes directly into a gas under suitable conditions of temperature and pressure.
Carbon dioxide gas moves from a high concentration to a low concentration.
Which row names these two processes?
Which gas turns the damp universal indicator paper red most quickly?
A ammonia, NH3
B chlorine, Cl2
C hydrogen chloride, HCl
D sulfur dioxide, SO2
20. ‘The movement of a substance very slowly from an area of high concentration to an area of low
concentration.’
Which process is being described?
A a liquid being frozen
B a solid melting
C a substance diffusing through a liquid
D a substance diffusing through the air
21. What happens to the average speed of gas particles when pressure and temperature are increased?
22. Oxygen melts at –219 C and boils at –183 C. At which temperature is oxygen a liquid?
A –225 C B –189 C C –175 C D 25 C
23. When a dark grey solid element is heated, it changes directly into a purple gas.
Which word describes this change?
A boiling
B evaporation
C melting
D sublimation
26. Each rectangle shows the arrangement of particles in each of the three states of matter.
X, Y and Z represent the processes needed to change from one state to another.
28. A mixture of ice and water is left to stand and the ice melts.
Which row describes what happens as the ice is melting?
29. Which row represents the particles of a gas colliding most frequently?
30. The formula of methane is CH4 and the formula of ethane is C2H6. Which row describes diffusion and
the relative rates of diffusion of methane and ethane?
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32. Samples of four gases are released in a room at the same time.
The gases are carbon dioxide, CO2, hydrogen chloride, HCl, hydrogen sulfide, H2S, and nitrogen dioxide,
NO2.
Which gas diffuses fastest?
A carbon dioxide
B hydrogen chloride
C hydrogen sulfide
D nitrogen dioxide
33. The rate of diffusion of a gas depends on its molecular mass and the temperature.
Which combination of molecular mass and temperature gives the slowest rate of diffusion?
34. Which two gases will diffuse at the same rate, at the same temperature?
A carbon monoxide and carbon dioxide
B carbon monoxide and nitrogen
C chlorine and fluorine
D nitrogen and oxygen
36. Which row describes the arrangement and motion of particles in a solid?
37. Which row describes the arrangement and motion of the particles in a liquid?
38. Which statement explains why ammonia gas, NH3, diffuses at a faster rate than hydrogen chloride gas,
HCl?
A Ammonia expands to occupy all of the space available.
B Ammonia has a smaller relative molecular mass than hydrogen chloride.
C Ammonia is an alkali and hydrogen chloride is an acid.
D Ammonia molecules diffuse in all directions at the same time.
39. The apparatus shown is set up. After 20 minutes a white ring of ammonium chloride is seen at position Y.
Which statement about the molecules of ammonia and hydrogen chloride is correct?
A Molecules in ammonia have a larger Mr than molecules of hydrogen chloride and so they move more
slowly.
B Molecules in ammonia have a larger Mr than molecules of hydrogen chloride and so they move more
quickly.
C Molecules in ammonia have a smaller Mr than molecules of hydrogen chloride and so they move
more slowly.
D Molecules in ammonia have a smaller Mr than molecules of hydrogen chloride and so they move
more quickly
40. Hydrogen chloride gas (Mr = 36.5) is released at P in the apparatus shown.
The Universal Indicator paper turns red after 38s.
8
43. A beaker containing solid carbon dioxide is placed in a fume cupboard at room temperature. The carbon
dioxide becomes gaseous.
Which process describes this change of state?
A boiling
B condensation
C evaporation
D sublimation
44. The pressure of a sample of gas is decreased. The temperature is kept constant.
Which row describes the effects on the particles?
D solid
49. When smoke particles are observed with a microscope they are seen to move around randomly.
This is called Brownian motion.
What causes Brownian motion?
A diffusion of the smoke particles
B molecules in the air hitting the smoke particles
C sublimation of the smoke particles
D the smoke particles hitting the walls of the container
50. Oxygen and fluorine are gaseous elements next to each other in the Periodic Table.
Under the same conditions of temperature and pressure, oxygen diffuses ......1...... than fluorine because
its ......2...... is less than that of fluorine.
Which words correctly complete gaps 1 and 2?
51. Gases are separated from liquid air by fractional distillation. The boiling points of four gases are shown.
Which gas is both monatomic and a liquid at –200 °C?
54. Mineral wool soaked in aqueous ammonia is placed in the apparatus shown.
After five minutes, the damp red litmus paper turned blue.
Which process led to this change?
A crystallisation
B diffusion
C distillation
D sublimation
55. A student investigated the diffusion of ammonia gas, NH3, and hydrogen chloride gas, HCl.
Two sets of apparatus were set up as shown at room temperature and pressure.
The damp red litmus paper in apparatus 1 changed colour after 30 seconds.
How long does it take for the damp blue litmus paper to change colour in apparatus 2?
A 64 seconds
B 30 seconds
C 21 seconds
D The blue litmus paper would not change colour.
56. Ammonia gas is reacted with hydrogen chloride gas using the apparatus shown.
Solid ammonium chloride is produced.
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Which statement explains why the solid ammonium chloride is formed nearer to the hydrogen chloride?
A Ammonia solution is a base and hydrogen chloride solution is an acid.
B Ammonia molecules diffuse more slowly than hydrogen chloride molecules.
C Hydrogen chloride has a greater molecular mass than ammonia.
D Hydrogen chloride moves by Brownian motion.
58. Hydrogen chloride gas, HCl, reacts with ammonia gas, NH3, to form solid ammonium chloride.
The apparatus is set up as shown.
After a few minutes, solid ammonium chloride forms where the two gases meet.
60. The diagram shows how the arrangement of particles changes when a substance changes state.
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61. The melting points and boiling points of four elements are shown.
63. Which process causes the greatest increase in the distance between particles?
A condensation
B freezing
C melting
D sublimation
64. The diagram shows the arrangement of particles in the three states of matter.
B Particles vibrating next to each other become mobile and move slowly past each other.
C Particles vibrating next to each other start to move rapidly and move further apart.
D Rapidly moving particles slow down and move closer together.
69. Small crystals of purple KMnO4 (Mr = 158) and orange K2Cr2O7 (Mr = 294) were placed at the centres
of separate petri dishes filled with agar jelly. They were left to stand under the same physical conditions.
After some time, the colour of each substance had spread out as shown.
The lengths of the arrows indicate the relative distances travelled by particles of each substance.
Which statement is correct?
A Diffusion is faster in dish 1 because the mass of the particles is greater.
B Diffusion is faster in dish 2 because the mass of the particles is greater.
C Diffusion is slower in dish 1 because the mass of the particles is smaller.
D Diffusion is slower in dish 2 because the mass of the particles is greater.
70. Pure water has a boiling point of 100 °C and a freezing point of 0 °C.
What is the boiling point and freezing point of a sample of aqueous sodium chloride?
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71. A compound, X, has a melting point of 71 °C and a boiling point of 375 °C.
Which statement about X is correct?
A It is a liquid at 52 °C and a gas at 175 °C.
B It is a liquid at 69 °C and a gas at 380 °C.
C It is a liquid at 75 °C and a gas at 350 °C.
D It is a liquid at 80 °C and a gas at 400 °C.
74. ‘Particles moving very slowly from an area of higher concentration to an area of lower concentration.’
Which process is being described?
A a liquid being frozen
B a solid melting
C a substance diffusing through a liquid
D a substance diffusing through the air
76. The rate of diffusion of two gases, methane, CH4, and ethene, C2H4, is measured using the apparatus
shown.
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77. The particles of a substance gain energy and change from a regular ordered structure to a disordered
structure with large distances between the particles.
Which change of state is described?
A boiling
B evaporation
C melting
D sublimation
Which statement explains why the ring of ammonium chloride appears as shown?
A Ammonia solution only produces a gas which moves until it meets the hydrochloric acid.
B Both solutions produce a gas, but ammonia moves quicker than hydrogen chloride because it is
lighter.
C Hydrochloric acid produces hydrogen chloride which stays at one end of the tube until the ammonia
reaches it.
D The two solutions run along the tube until they meet.
The lid is removed and the gas jars are left to stand. After some time the contents of both gas jars are
brown.
Which process causes this to happen?
A condensation B diffusion C evaporation D filtration
80. Diagrams X, Y and Z represent the three states of matter.
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82. In which process do particles move closer together but remain in motion?
A condensation
B diffusion
C evaporation
D freezing
83. The changes that occur when a substance changes state are shown below.
86. A crystal of purple potassium manganate(VII) was added to each of the beakers shown in the diagram.
One beaker contained hot water and the other beaker contained cold water.
In both beakers the purple colour of the potassium manganate(VII) spreads out.
Which result and explanation are correct?
88. A few drops of perfume were spilt on the floor. A few minutes later the perfume could be smelt a few
metres away.
Which two processes had taken place?
A distillation and condensation
B distillation and diffusion
C evaporation and condensation
D evaporation and diffusion
89. The diagram shows the result of dropping a purple crystal into water.
90. Two gas jars each contain a different gas. The gas jars are connected and the cover slips are removed.
The diagram shows what happens to the particles of the gases.
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92. A few drops of perfume were spilt on the floor. A few minutes later the perfume could be smelt a few
metres away.
Which two processes had taken place?
A distillation and condensation
B distillation and diffusion
C evaporation and condensation
D evaporation and diffusion
93. An attempt was made to compress a gas and a solid using the apparatus shown.
94. A gas jar of bromine vapour and a gas jar of air are set up as shown in diagram 1.
The glass slide is removed. Diagram 2 shows the appearance of the gas jars after one hour.
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Which statement explains why the bromine and air mix together?
A Bromine is denser than air.
B Bromine is lighter than air.
C Bromine molecules moved upwards and molecules in air moved downwards.
D Molecules in bromine and air moved randomly.
Which one of the containers holds the water with the highest average
kinetic energy?
A. W
B. X
C. Y
D. Z
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12. From the cooling curves, find the decrease in temperature of liquid A
in the first six minutes.
A. 40°
B. 50°
C. 55°
D. 35°
Questions 25–27 refer to the following information.
An important effect of heat is that it can produce a change of state. Matter
exists in any of the three states–solid, liquid, or gas. In a gas, the particles
can move around freely and independently. In a liquid, particle
movement is a bit constrained and limited to sliding and flow movement
within its volume. In a solid, particle movement is restricted to only
vibrational motion of particles in their fixed positions.
Extended Materials
States of matter Worksheet
1. Name the three states of matter and draw a particle diagram for each.
6. On the diagram above, label the melting point and boiling point on the y axis.
7. Explain, in terms of particles, what is happening at points a, b & c
a) …………………………………………………………………………………
…………………………………………………………………………………
b) …………………………………………………………………………………
…………………………………………………………………………………
c) …………………………………………………………………………………
…………………………………………………………………………………
8. The diagram below shows a bottle of fizzy drink. Label the state of a-d.
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9. Wet clothes are put on a washing line to dry. The water in the clothes turns into
water vapour in the air as the clothes dry.
a) Name the change as water turns into water vapour ……………………………
b) Rain forms from water vapour in the air. Name this change ………………….
c) The clothes dry much faster on a sunny day, explain why in terms of particles.
………………………………………………………………………………………..
………………………………………………………………………………….….….
10. Some substances can change directly from a solid to a gas, research the name
of this process. Can you find an example of a substance that behaves like this?
………………………………………………………………………………………..
………………………………………………………………………………….….….