Senior 1 Chemistry Unified Test 2

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FOON YEW HIGH SCHOOL SERI ALAM

Unified Test Year 2024


Senior Middle One Chemistry
Name:_______________( ) Marks: ____________
Class:S1S( )Student ID: __________ Date:16-08-2024 Time: 7:35-8:15 am
A. Objective Questions(45%@ 3%)【**Choose the best answer and shade the answer box in the O card
provided**】
1. What is the definition of equivalence point for an acid-base reaction? 6.11
A. The point at which the pH of the solution is 7.
B. The point at which the solution changes colour.
C. The point at which the amount of acid and the amount of base present exactly neutralize one another.
D. The point at which the first drop of titrant is added to the solution.

2. When preparing a standard solution, why is it important to use deionized or distilled water instead of tap water?
A. Tap water is too acidic. 6.9
B. Tap water contains impurities that affect the solution’s concentration.
C. Deionized water and the distilled water have a higher boiling point.
D. Deionized water and the distilled water evaporate more slowly.

3. If it takes 54 mL of 0.1 M NaOH to neutralize 125 mL of an HCl solution, what is the concentration of the HCl
solution? 6.11
A. 0.02 M B. 0.2 M C. 0.04 M D. 0.4 M

4. Arrange the following oxygen-containing compounds in order of increasing oxidation state of oxygen. 7.3
A. H2 O, H2 O2 , F2 O, O2 B. H2 O, H2 O2 , O2 , F2 O
C. F2 O, O2 , H2 O2 , H2 O D. O2 , F2 O, H2 O2 , H2 O

5. In which of the following particle does nitrogen has the highest oxidation number? 7.3
A. N2 O B. NH4+ C. NO3− D. Li3 N

6. In which of the following reactions does SO2 act as a reducing agent? 7.4
A. SO2 + 2 Mg → MgO + S B. SO2 + NaOH → NaHSO3
C. 2 H2 S + SO2 → 2 S ↓ +2H2 O D. 2 H2 O + SO2 + Fe2 (SO4 )3 → 2 FeSO4 + 2 H2 SO4

7. Which of the following is a redox reaction? 7.1


A. NaCl + KNO3 → NaNO3 + KCl B. HCl + NaOH → NaCl + H2 O
C. Mg(OH)2 + 2 NH4 Cl → MgCl2 + 2 NH4 OH D. Zn + 2 AgCN → 2 Ag + Zn(CN)2

8. In the reaction H2 S + Cl2 → S + 2 HCl , which substance acts as the oxidizing agent? 7.4
A. H2 S B. Cl2 C. S D. HCl

9. Which of the following statements about redox reactions is true? 7.1


A. A substance that is oxidized is called an oxidizing agent. B. Reduction involves the loss of hydrogen.
C. Oxidation and reduction do not occur simultaneously. D. Oxidation involves the loss of electrons.

10. Which metal will not react with hydrochloric acid? 8.1
A. Mg B. Zn C. Cu D. Fe

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11. What will happen when a piece of zinc is placed in a solution of copper (II) sulfate (CuSO4)? 8.2
A. Zinc dissolves and copper precipitates. B. Copper dissolves and zinc precipitates.
C. No reaction occurs. D. Zinc and copper both dissolves.

12. Metal pieces A and B are placed into a solution of nitrate salt of metal C. Metal C precipitates on the surface of metal
A, but there is no change on the surface of metal B. Based on this, what is the order of reactivity for the three
metals? 8.2
A. A > B > C B. A > C > B C. B > A > C D. C > A > B

13. Which of the following processes is required for extracting metal from cinnabar ore? 8.5
A. Roasting B. Electrolytic reduction C. Thermit process D. Calcination

14. When metal reacts with liquid water, the products are _______. 8.1
A. metal hydroxide and hydrogen gas B. metal hydroxide and oxygen gas
C. metal oxide and oxygen gas D. metal oxide and hydrogen gas

15. Based on the titration curve in Figure 1, which indicator is suitable for this titration?
A. Methyl orange 6.11 B. Litmus
C. Phenolphthalein D. None of the above

Figure 1

B. True or False Questions(15%@ 3%)【**Shade the box A if the statement is true, shade the box B if the
statement is false**】

16. A standard solution is a solution whose concentration is accurately known. 6.9---------------------------------------------(A)

17. All salts are soluble in water. 6.7----------------------------------------------------------------------------------------------------------(B)

18. Reactivity of metals increases as the elements move from left to right across the periodic table. 8.1 -----------------(B)

19. Potassium is the most reactive metal. 8.1----------------------------------------------------------------------------------------------(B)

20. All displacement reactions must be redox reactions. 7.1---------------------------------------------------------------------------(A)

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FOON YEW HIGH SCHOOL SERI ALAM
Unified Test Year 2024
Senior Middle One Chemistry
Name:_______________( ) Marks: ____________
Class:S1S( )Student ID: __________ Date:16-08-2024 Time: 7:35-8:15 am

A. Subjective questions(40%)
1. Manganate (VII) ion reacts with oxalate in acidic solution to produce manganese ion and carbon dioxide. 7.3
MnO4− (aq) + C2 O42−(aq) → Mn2+(aq) + CO2 (g)

(a) Identify the oxidizing and reducing agents in this reaction. (4%)
Oxidizing agent: Reducing agent:
MnO4− C2 O42−

(b) Balance the redox reaction above by using the ion-electron method (half equation) if they are in acidic solution.
(6%)
Oxidation half equation: C2 O42−(aq) → 2 CO2 (g) + 2e− -------------------------①
Reduction half equation: MnO4− (aq) + 5e− + 8H + → Mn2+(aq) + 4H2 O -----②

① × 5: 5 C2 O42−(aq) → 10 CO2 (g) + 10e−


② × 2: 2 MnO4− (aq) + 10e− + 16 H + → 2Mn2+(aq) + 8 H2 O

Overall ionic equation:


5 C2 O42−(aq) + 2 MnO4− (aq) + 10e− + 16 H + → 10 CO2 (g) + 10e− +2Mn2+(aq) + 8 H2 O
5 C2 O42−(aq) + 2 MnO4− (aq) + 16 H + → 10 CO2 (g) + 2Mn2+(aq) + 8 H2 O

(c) State the reaction type of this chemical reaction. (2%)


Redox reaction.

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2. Before the titration experiment, a 0.10 M NaOH solution needs to be prepared from NaOH pellets, and a 0.20 M HCl
standard solution needs to be prepared from a 0.40 M HCl stock solution. The resulting 0.10 M NaOH solution will
be used to titrate the 100 mL of 0.20 M HCl solution. 6.9 & 6.11

(a) Arrange the following steps for preparing 0.10 M NaOH solution by writing the alphabet. (2%)
A - Transfer the solution to a volumetric flask using a funnel.
B - Add distilled water to the volumetric flask until the mark is reached (e.g., 100.0 mL).
C - Weigh the required amount of NaOH pellets using an analytical balance.
D - Dissolve the NaOH in a small amount of distilled water in a beaker.
E - Rinse the beaker and funnel with distilled water to ensure complete transfer.
F - Stopper the flask and invert it several times to mix the solution thoroughly.
G - Label the flask with the concentration and date of preparation.

C → D → A → E → B → F → G
_______ _______ _______ _______ _______ _______ _______

(b) Calculate the volume of the 0.40 M HCl solution needed to prepare 100 mL of 0.20 M HCl solution. (6%)
C1 V1 = C2 V2
100
0.40 M × V1 = 0.20 M × dm3
1000
V1 = 0.05 dm3 (0.05 L/50mL/50cm3 )

(c) If 0.10 M NaOH solution will be used to titrate the 100 mL of 0.20 M HCl solution to reach the endpoint,
calculate the volume of the NaOH solution. (6%)
Ma Va a
=
Mb Vb b
100
0.20 mol dm−3 × 1000 dm3 1
=
0.10 mol dm−3 × Vb 1
Vb = 0.20 dm3 (0.20 L/200mL/200cm3 )

(d) Name a suitable indicator for this titration experiment. (3%)


Methyl orange / Methyl red / Methyl yellow / Phenolphthalein/ pH meter

(e) If sulfuric acid is used instead of hydrochloric acid, write down the chemical equation for the titration of NaOH
with H2SO4. (3%)
2 NaOH(aq) + H2 SO4 (aq) → Na2 SO4 (s) + 2 H2 O(l)

(f) If the concentration and volume of H2SO4 is same with HCl in this titration experiment, what is the volume of
NaOH solution used? (6%)
Ma Va a
=
Mb Vb b
100
0.20 mol dm−3 × 1000 dm3 1
=
0.10 mol dm−3 × Vb 2
Vb = 0.40 dm3 (0.40 L/400mL/400cm3 )

(g) Determine the equivalence point in this titration experiment. (2%) Ans: Around pH = 7.

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