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David Robinson
What is a theory?
A theory is an intelligent
History of heat explanation about some
phenomenon.
● In the 18th century there was the caloric theory which suggested that:
● Heat was a fluid or substance that travelled through all matter.
● Each body possessed a certain amount of caloric. A hot body was said to
possess more caloric than a cold body.
● Caloric particles were supposed to repel each other so they would tend to
leave the hot object and flow to the cold object thus explained why bodies
when heated, gaining caloric, would expand.
● Since caloric was a substance it had volume and this fact explained why
bodies when heated, gaining caloric, would expand.
● Caloric being a fluid would have mass and therefore a body, when hot,
would have a bigger mass than when cold.
Weaknesses of the caloric theory
1. Lack of experimental evidence. Due to technological
limitations they couldn’t weight objects properly while
heating.
2. No explanation for why when 2 objects were heated
together they wouldn’t reach the same temperature at the
same time.
3. It could not explain why when heat was supplied during
melting , the temperature did not rise.
Story Time
Brownian motion
Boiling
water with a
blender.
Remember the scientific method
Theory Caloric theory Theory Kinetic theory
Data analysis Heat is a form of energy Data analysis Heat is a form of energy
David Robinson
Recall: Kinetic Theory
Kinetic theory – particles are constantly moving
and have kinetic energy. The higher the
temperature, the faster they move, so the more
kinetic energy they contain.
More Heat
Higher
energy
Temperature
Which has the most
energy?
Which has the
higher temperature?
Heat vs Temperature
Are Heat and Temperature describes the average
Heat - describes the transfer of
Temperature thermal energy between molecules
kinetic energy of molecules within a
material or system and is measured in
the same? within a system and is measured in
Celsius(oC) or Kelvin (K)
joules.
1, What happens
when a material is
heated.
3. Does it happen
at the same rate in
all materials.
Where else should we take thermal
Tell me why expansion into account?
😊 Buildings
Or you can ask (if
you are too chicken Bridges
to tell me) Bottles
All of these properties can be used to see Who is hot and who
is not.
Here are some examples of
thermometers.
Lab thermometer
Infrared thermometer
Clinical thermometer
Thermocouple
Lab Thermometer
Liquid
Gas
Solid
● The intermolecular forces between neighboring
molecules are strong enough to keep them locked in
position
● Solids (like liquids) are not very compressible due to the
lack of space between molecules
● If the molecules in a solid adopt a highly ordered packing
arrangement, the structures are said to be crystalline.
Liquid
The intermolecular attractive forces are strong enough to
hold molecules close together
Liquids have a definite volume, independent of the size and
shape of their container
The attractive forces are not strong enough to keep
neighboring molecules in a fixed position and molecules are
free to move past or slide over one another.
Slightly Compressible hence why it is said to be
incompressible at times.
Gas
A collection of widely separated molecules
Melting Freezing
Boiling Condensation
Sublimation Deposition
Adding heat energy Removing heat energy
Where you paying attention!
Gas Laws
What do we notice about the Pressure against
Temperature graph below. (P/T)
Is there a difference
between the:
Pressure /temperature
and the
volume /temperature
graphs.
Simulation
https://phet.colorado.edu/sims/html/gas-properties/latest/ga
s-properties_en.html
go read up
about them Charles’ Law ( V/T = constant)
for next
Pressure Law ( P/T = constant)
class.
Combined Gas Law ( (PV)/ T = constant)
For CSEC Physics :
Don’t sweat the moles.
Don’t sweat the “R”
R is the Ideal Gas constant
Pressure = Pascals = Pa
Volume = meters cube = m3
Temperature= Kelvin = K
P ∝1/V or P = constant x 1/ V
PV = constant
p1V1 = p2V2
Boyle's law
As the volume of the gas decreases, the gas particles have less
room to move around in, and they collide more often with the
walls of the container, thus increasing the pressure:
Boyle’s Law
Eg.
V1=20m3 P2 = 100kPa
V2 = 10m3
Charles’ Law
The volume of a given amount of gas held at constant pressure is
directly proportional to the Kelvin temperature.
The constant depends on amount of gas and pressure. So, as
volume goes up, so does temperature, and vice versa.
This equation can also be described as saying that the volume
divided by the temperature of a gas is constant:
V ∝ T or V/T = constant
V1/T1 = V2/T2
Charles’ Law example
V2 = 100cm3 T2 = 33.3K
T2 = ?
Pressure Law
This law states that the pressure of a given amount of gas held
at constant volume is directly proportional to the Kelvin
temperature.
So, if pressure increases, so will the temperature, and vice
versa.
This is the same as saying that the pressure of a gas divided by
the temperature will be constant.
P ∝ T or P / T = constant
P1/T1 = P2/T2
P1/T1 = P2/T2 P1/T1 = P2/T2
P1 = ? P1 / 10℃ = 65 kPa / 30℃
P2 = 65kPa P1 = 21.7kPa
T2 = 30K
Gay Lussac’s pressure law
General Gas Law
V ∝ T/P
P1V1 / T1 = P2V2 / T2
P1 = 350kPa
V1 = 50cm3
T1 = 300K
P2 = 900kPa
V2 = 90cm3
T2 = ?
Revision
Remember Pressure
We made reference to how pressure under your feet can compress
soft ground making you sink.
Plus describe the Formulas used using terms like directly proportional or
inversely proportional.
This task should be done in your book, this is to help you to have explanation
that is easy for you to remember.
Heat Capacity
Heat Capacity
Water must be
supplied with nearly
five times as much
energy as aluminium
for the same rise in
temperature.
EH = CΔT
Specific Heat capacity “c”
Specific heat capacity refers to 1kg of a substance. We use the
word specific in physics to mean per unit mass.
The Specific Heat Capacity, c, of a substance is the heat energy
needed to , raise the temperature of 1kg of the substance by 1K (or
1℃)
Specific heat capacity = heat energy / (mass x temperature change)
c = EH / (m x ΔT) units in Jkg-1K-1
Rearranged to find the heat needed:
EH = mcΔT
Get the calculators!
What do we know:
Recall: Power = energy / time Power (P) = 2.5kW = 2500W
Time (t) = 2 minutes = 120s
Hence: Energy = power x time ΔT = T2- T1= 60℃ -20℃ =40℃ or 40K difference
Mass of water = 1.6kg
The power of the electric
Calculate the energy
kettle is 2.5kW the time spent EH = 2500W X120s = 300,000J
heating was 2 minutes, the
Calculate the heat capacity:
initial temperature of 1.6kg of C = EH /ΔT =
water was 20℃ and the final is C = 300,000J / 40K = 7,500JK-1
Melting Vaporisation
Cooling Curve Heating Curve
Fusion vs Vaporisation
The specific latent heat of fusion, The specific latent heat of
l , of a solid substance is the heat vaporisation , l , of a liquid
energy required to change 1 kg of substance is the heat energy
it from solid to liquid without any required to change 1 kg of it
temperature change. from liquid to gas without any
temperature change.
Difference in heat of fusion and Vaporization
Latent Heat formula
EH = l m
= 340,000Jkg-1 x 0.1kg
= 34,000J
Evaporation
Wind
Evaporation Boiling
Have you ever cleaned off nail polish and feel the skin on your
fingers get super cold! I wonder why?
This is because the Acetone takes the heat energy from your
skin, for it to vaporize, hence cooling you down.
Heat lost by can from 15℃ to - 5℃ Heat lost by water from 15℃ to 0℃
Formulas:
EHc = mc x cc x ΔT EHw = mw x cw xΔT
Heat capacity
= 0.1kg x 900 Jkg-1℃-1 x (15℃-(-5℃)) = 0.2kg x 4200Jkg-1℃-1 x 15℃
C = EH / ΔT
=0.1kg x 900 x 20 EHw=12600J
Specific Heat capacity
c = EH / (m x ΔT) EHc= 1800J
Conduction
Convection
Radiation
Conduction
Conduction of heat