PRE-MEDICAL : ENTHUSIAST COURSE

ALL PHASE
TEST PATTERN : BOARD PATTERN
MAJOR TEST # (GSEB) PAPER-2
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CHEMISTRY

PART-A
Time Allowed : 1 Hour Maximum Marks : 50
Instructions :
l There are 50 objective type (M.C.Q.) questions in Part-A and all questions are compulsory.
l The questions are serially numbered from 1 to 50 and each carries 1 mark.
l Read each question carefully, select proper alternative and answer in the O.M.R. sheet.
l The O.M.R. sheet is given for answering the questions. The answer of each question is represented
by (1) O, (2) O, (3) O, (4) O. Darken the circle of the correct answer with ball-pen.
l Rough work is to be done in the space provided for this purpose in the Test Booklet only.
l Set No. of question paper printed on the upper-most right side of the question paper is to be written
in the column provided in the O.M.R. sheet.

SECTION-A
Choose correct answer from the given options. [Each carries 1 Mark] [50]
1. While charging the lead storage battery ....... .
(1) PbSO4 at electrochemical cathode is reduced to Pb.
(2) PbSO4 at electrochemical cathode is reduced to PbO2 .
(3) PbSO4 at electrochemical anode is reduced to Pb.
(4) PbSO4 at electrochemical anode is oxidised to PbO2 .

2. CH 3 - CH 3 + Cl 2 ¾¾
hv
® X ¾¾ ¾ ¾¾
Mg/dry ether
® Y ¾¾¾
H 2O
® Z Identify X, Y and Z.

(1) C2H5Cl ; C2H5MgCl ; C2H6 (2) 2–Chloropropane ; C3H7MgCl ; Ethyne

(3) C2H5Cl ; C2H5MgCl ; Ethene (4) C2H5Cl ; C2H6 ; Ethyne
3. By which general symbol lanthanides are expressed ?
(1) Ld (2) La (3) Ln (4) Ls
4. Which element is not able to form dp-pp bonds ?

(1) P (2) S (3) N (4) Bi

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5. Which of the following alcohol yields immediately corresponding alkyl chloride on reaction with conc. HCl
at room temperature ?

(1) CH3 –CH2–CH2–OH (2) CH3 CH2 CH OH

CH3

CH3

(3) CH3CH2 CH2 CH OH (4) CH3 CH 2 C OH

CH3 CH3
6. Addition of Grignard reagent to carbonyl compounds can result into which alcohol ?

(1) 1° (2) 2° (3) 3° (4) All of these

7. The co-ordination number of copper which crystallise in close-packed structure is ..........

(1) 6 (2) 8 (3) 12 (4) 4

8. A compound is formed of two element “A” and “B”. The atoms of element “A” forms face centred cubic
close packing and atoms of “B” occupies all the tetrahedral voids. The formula of compound is ...........

(1) AB2 (2) AB8 (3) A4B (4) A2 B

9. Freezing point of urea solution is –0.60 C. How much urea is required to be dissolved in 3 kg water? [M(urea)
= 60 g mol–1, Kf = 1.50C Kg mol–1]

(1) 2.4 g (2) 3.6 g (3) 6.0 g (4) 72 g

10. Which pair is isotonic at same temperature ?

(1) 0.1 M urea and 0.1 M KCl (2) 0.1 M Ba(NO3)2 and 0.1 M Na2SO4

(3) 0.2 M NaCl and 0.2 M Na2SO4 (4) 0.2 M BaCl2 and 0.2 M Surcrose

11. From the given graph at constant temperature, which gas has the least solubility ?

(1) gas – D (2) gas – B (3) gas – A (4) gas – C

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12. Which of the following reaction can be possible with electrochemical cell by using

E oCl |2Cl- = 1.36 V and E oBr |2Br- = 1.09V

2 2

(1) Br2 + 2Cl– ® 2Br– + Cl2 (2) 2Br– + Cl2 ® Br2 + 2Cl–

(3) 2Cl– + 2Br– ® Cl2 + Br2 (4) Cl2 + Br2 ® 2Cl– + 2Br–

13. Which one is right for adsorption phenomenon ?

(1) DH = +ve, DS = –ve (2) DH = –ve, DS = +ve

(3) DH = –ve, DS = –ve (4) DH = +ve, DS = +ve

14. At very low pressure, what is the equation of Langmuir Adsorption Isotherm ?

(1) (2) (3) (4)

15. The order of basic nature of hydride compound of Group-15 is .........

(1) NH3 < PH3 < AsH3 < BiH3 < SbH3 (2) BiH3 < SbH3 < AsH3 < PH3 > NH3

(3) NH3 > PH3 > BiH3 > AsH3 > SbH3 (4) NH3 > PH3 > AsH3 > SbH3 > BiH3

16. Which of the following is a composition of bleaching powder ?

(1) Ca(OCl)2 . CaCl2 (2) Ca(OCl)2 × Ca(OH)2

(3) CaOCl × CaCl2 (4) CaOCl . H2O

17. Which of the following ion is colourless ?

(1) Sc3+ (2) Ti3+ (3) Mn2+ (4) Cu2+

18. What is the number of ions separated from aqueous solution of [Co(NH3)6]Cl3 ?

(1) 2 (2) 3 (3) 4 (4) 6

19. In which of the following, halogenated carbon possesses sp3 hybridization ?

(1) (2) (3) CH2 = CH–Cl (4)

20. Which reagents from the following give aldehyde by reacting with primary alcohol ?

(1) PCC + CH2C12 (2) KMnO4 + H2SO4

(3) KMnO4 + KOH (4) Na2Cr2 O7 + H2SO4

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21. Which of the following order of acidic strength is correct for the following compounds ?

(i) (ii) (iii) (iv)

(1) iii < iv < ii < i (2) ii < iv < i < iii (3) ii < i < iv < iii (4) iii < iv < i < ii
22. Which of the following substance does not react with C6H5SO2Cl ?
(1) (C2H5)3 N (2) (CH3)2NH (3) CH3 NH2 (4) C2H5NH2
23. Which of the following is the structure of Phthalimide ?

(1) (2) (3) (4)

24. What is relation between a-D-(+)-glucose and b-D-(-)-glucose of Haworth structure ?

(1) Mirror image isomers (2) Chain Isomers
(3) Homologous (4) Anomers
25. Which of the following substance does not melt at definite temperature ?
(1) Plastic (2) Magnesium (3) Sodium Chloride (4) All of above
26. Which of the following can conduct electricity in its liquid state ?
(1) Iodine (2) Sodium chloride (3) Carborundum (4) All of above
27. Which one of the following would produce maximum elevation in boiling point
(1) 0.1 M glucose (2) 0.2 M sucrose

(3) 0.1 M barium chloride (4) 0.1 M magnesium sulphate

28. What is the ratio of Al, Cu and Na which deposited on cathode by passing 3F current through different
electrolytes having molten Al2O3, aqueous CuSO4 and molten NaCl solution ?
(1) 3 : 4 : 6 (2) 2 : 1 : 6 (3) 3 : 2 : 1 (4) 2 : 3 : 6
29. E° for Cu /Cu = 0.52 V and E° Cu /Cu = 0.34 V. Check whether the reaction Cu + Cu+2 ¾® 2 Cu+ is :-
+ +2

(1) spontaneous (2) non spontaneous

(3) cannot determine (4) at equilibrium
30. Unit of rate constant for third order of reaction is ……....

(1) Liter2/(mole)2 s–1 (2) Second–1 (3) (mole/liter)–1 s–1 (4) (liter/mole)2 second

31. Which of the following gas adsorbed in more amount in same condition ?

(1) O2 (2) N2 (3) CO2 (4) H2

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32. In which condition reaction become spontaneous ?

(1) Value of E° and DG° is negative

(2) Value of E° and DG° is positive

(3) Value of E° is negative and DG° is positive

(4) Value of E° is positive and DG° is negative

33. In preparation of HNO3, NO gas is obtained on oxidation of ammonia. If 2 mole of ammonia is taken in this
reaction then how much mole of NO gas will obtained ?

(1) 2 (2) 3 (3) 4 (4) 6

34. Electronic configuration of Cu (II) is 3d9, while that of Cu(I) is 3d10. Then which will be true from the
following ?

(1) Cu (II) is more stable in aqueous state.

(2) Cu (II) is less stable in aqueous state.

(3) Cu (I) and Cu (II) are equally stable in aqueous state.

(4) Stability of Cu (I) and Cu (II) depends on nature of copper salt.

35. Which of the following complex ion is useful in photography ?

(1) [Ag(S 2O3 )2 ]3– (2) [Au(S2O3)2 ]3– (3) [Ag(CN)2 ] (4) [Au(CN)2 ]

36. Which of the following molecules are chiral (Assymetrical) ?

(i) Propane-2-ol (ii) Butan-2-ol

(iii) 2-chloropentane (iv) 3-chloropentane

(1) (i) and (ii) (2) (ii) and (iv) (3) (iii) and (iv) (4) (ii) and (iii)

37. What is ‘X’ in the following reaction ?

CH3 – CH2 – Cl + KOH ¾¾¾¾®

CH2 CH 2OH
X + KCl + H2O

(1) Butane (2) Ethane (3) Ethene (4) Diethyl ether

38. What is correct reactivity order of alkyl halide reaction with amines ?

(1) R – I > R – Br > R – Cl (2) R – Cl > R – Br > R – I

(3) R – Br > R – I > R – Cl (4) R – I < R – Br > R – Cl

39. Which product is obtained on reaction of ethyl amine with HNO2 followed by hydrolysis ?

(1) Ethanamide (2) Ethanol (3) Methenal (4) Ethenoic acid

40. Which of the following is non-reducing sugar ?

(1) Lactose (2) Glucose (3) Sucrose (4) Maltose

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COOH

41. what is the configuration of the above amino acids ?

(1) D-configuration (2) L-configuration (3) Racemic mixture (4) None of these

42. Which of the following mixture of metals can not form alloy?

(1) Ni + Mg + Cr (2) Au + Cu + Cr (3) Fe + Cr + Cu (4) Ni + Cu + Cr

43. The half life period for a radioactive substance is 15 minutes. How many gms of this radioactive substance is
decayed from 50 gm of substance after one hour?

(1) 25 (2) 46.875 (3) 43.75 (4) 37.5

44. What is indicated by the following structure ?

CH3 H
CH3–C–N
CH3
CH3

(1) Primary amine (2) Secondary amine (3) Tertiary amine (4) Ammonium salt

45. By which reaction caprolactum gives amino acid?

(1) Hydration (2) Hydrolysis (3) Dehydration (4) Esterification

46. What is the name of the following reaction?

Benzoyl chloride + H 2 ¾¾¾¾

Pd/BaSO 4
® C6H5CHO + HCl

(1) Rosenmund reaction (2) Cannizzaro reaction

(3) Perkin reaction (4) Sandmeyer reaction

47. Which of the following vitamins cannot be stored in our body?

(1) Vitamin K (2) Vitamin C (3) Vitamin E (4) Vitamin D

48. The elevation in boiling point of the solution prepared by dissolving 0.6 gram urea to 200 gram water is
0.50ºC. What will be the molal elevation constant?

(1) 10 K kg mole (2) 10 K kg mole–1 (3) 1.0 K kg mole (4) 100 K kg mole–1

49. Which of the following is bacteriostatic ?

(1) Penicillin (2) Erythromycin (3) Ofloxacin (4) Bithionol

50. 2-Acetoxy banzoic acid is used as...

(1) Antimalaria (2) Antidepressant (3) An angalgesic (4) Antipyretic

•••••

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PART-B
Time Allowed : 2 Hour Maximum Marks : 50
Instructions :
l Write in a clear legible handwriting.
l There are three sections in Part-B of the question paper and total 1 to 18 question are there.
l All the questions are compulsory. Internal options are given.
l Start new section on new page.
l The numbers at right side represent the marks of the question.
l Maintain sequence.

Write the answer of the following questions. [Each carries 2 Marks]

1. What is half-life time of a reaction ? Derive half-life time for zero order reaction.

2. What is leaching process ? Explain it with example.

3. Explain Werner theory.

4. Give difference of SN1 and SN 2

5. Explain Hoffmann-bromamide degradation reaction.

6. Give reasons of denaturation of protein.

7. Give preparation and uses of terylene

8. Explain cleansing action of soap.

9. Explain ferromagnetism

10. Mg | Mg2+ (0.001M) || Cu2+ (0.0001M) | Cu , calculate the Ecell of cell. (E°cell = 2.71V)

11. Write a note on Nylon–6, 6.

12. Give preparation reaction of iron in blast furnace

Write the answer of the following questions. [Each carries 3 Marks]

1. Explain packing efficiency in BCC.
2. In a reaction between A and B. the initial rate of reaction (r 0 ) was measured for different initial
concentrations of A and B as given below :

A /mol L -1 0.2 0.2 0.4

B/mol L -1 0.3 0.1 0.05
-1 -1 -5 -5
r0 /molL s 5.07 × 10 5.07 × 10 1.43 × 10 -4
What is the order of the reaction with respect to A and B?

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3. Write a note on lyophilic and lyophobic colloids.

4. Write a note on interstital compounds.

5. Explain the contact process for the preparation of H2SO4 .

6. Explain Williamson synthesis for the preparation of ether.

7. Explain Gabriel phthalimide reaction ?

8. Explain Cannizzaro reaction.

Write the answer of the following questions. [Each carries 4 Marks]

1. 0.6 mL of acetic acid (CH3COOH). having density 1.06 g mL–1, is dissolved in 1 litre of water. The depression
in freezing point observed for this strength of acid was 0.0205°C. Calculate the van't Hoff factor and the
dissociation constant of acid.

2. Resistance of a conductivity cell filled with 0.1 mol L–1 KCl solution is 100 W. If the resistance of the same cell
when filled with 0.02 mol L–1 KC1 solution is 520 W. calculate the conductivity and molar conductivity of 0.02
mol L–1 KCl solution. The conductivity of 0.1 mol L–1 KCl solution is 1.29 S/m.

3. [Cr(NH3)6]2+ is paramagnetic and [Ni(CN)4]2– is diamagnetic explain why?

4. Write the reaction of acetaldehyde and acetone with NaHCO3 & HCN.

5. Explain integrated rate equation of first order reaction with graph.

6. What is the product of hydroboration and hydrolysis in presence of dil. H2SO4 of propene ?

•••••

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