Thermodynamics - The Basics
Thermodynamics - The Basics
Thermodynamics - The Basics
cold?
Can we trust our sense of hot and
cold?
What is temperature?
Sun
Chemical action
Mechanical action
Electrical energy
Nuclear energy
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How is heat produced?
It is produced by matter.
convection
radiation
When will heat transfer
stop?
THERMAL EQUILIBRIUM
What is Temperature?
the average kinetic energy of the
individual atoms in matter.
mercury thermometer
thermogram
Digital thermometer
Temperature Scale
Temperature Conversion
Convert
Effects of Heat
Change in temperature
Thermal expansion
Phase Change
Metals
THERMAL
expands more
EXPANSION than the glass
Most
materials
expand when
heated and
contract when
cooled
THERMAL EXPANSION
a fractional change in size of a material
in response to a change in temperature.
Linear Expansion
changes in length compared to original length
Areal Expansion
changes in area compared to original area
Volume Expansion
changes in volume compared to original
volume
Linear Expansion
an increase in any one dimension of a solid
coef cient of linear
expansion occurs along a line expansion
(1/C0 = (C0)-1
Temperature = To
ΔL = αLoΔT
The length Lo of an
Lo
object changes by an
Temperature = To + ΔT amount ΔL when its
temperature changes
by an amount ΔT
Lo ΔL
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(1/C0)
Solids Liquids
ΔA = 2αAoΔT
ΔV = βVoΔT
ΔV = 3αVoΔT Gases
R = 8.314 J/mol K
PV = nRT
Buckling of a Sidewalk
A concrete sidewalk is
constructed between two
buildings on a day when the
tem perature is 250C. The
sidewalk consists of two slabs,
each 3m in length and of
neg ligible t hic kness. As t he
temperature rises to 380C, the
slabs expand, but no space is
provided for thermal expansion.
The building do not move, so the
slabs buckle upward. Determine
the vertical y (height of buckled
slabs).
Expansion joints
The Golden Gate Bridge
The main span of San Francisco’s Golden Gate Bridge
is 1275 m long at its coldest. The bridge is exposed to
temperatures ranging from –15ºC to 40ºC. What is its
change in length between these temperatures?
Assume that the bridge is made entirely of steel.
Gas vs. Gas Tank
Suppose your 60.0-L
(15.9-g al) s t eel
gasoline tank is full of
gas, so both the tank
and the gasoline have
a temperature of
15 . 0 º C . H o w m u c h
gasoline has spilled by
the time they warm to
35.0ºC?
Solve…
1. Two blocks, A and B, are made of the same
material. Block A has dimensions l × w × h = L × 2L × L
and Block B has dimensions 2L × 2L × 2L. If the
temperature changes, what is
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