SAFETY DATA SHEET

DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
1.1 04/04/2023 S00030636291

SECTION 1. IDENTIFICATION

Product name : DEMAND CS INSECTICIDE

Design code. : A12690A

Product Registration number : 100-1066

Manufacturer or supplier's details

Company name of supplier : Syngenta Crop Protection, LLC

Address : Post Office Box 18300

Greensboro NC 27419
United States of America (USA)

Telephone : 1 800 334 9481

Telefax : 1 336 632 2192

E-mail address : [email protected]

Emergency telephone : 1 800 888 8372

Recommended use of the chemical and restrictions on use

Recommended use : Insecticide

Restrictions on use : General Use Pesticide

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Acute toxicity (Inhalation) : Category 4

Skin sensitization : Category 1

GHS label elements

Hazard pictograms :

Signal Word : Warning

Hazard Statements : H317 May cause an allergic skin reaction.

H332 Harmful if inhaled.

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SAFETY DATA SHEET

DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
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Precautionary Statements :
Prevention:
P261 Avoid breathing mist or vapors.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/
doctor if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P363 Wash contaminated clothing before reuse.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
May cause temporary itching, tingling, burning or numbness of exposed skin, called paresthesia.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Components
Chemical name CAS-No. Concentration (% w/w)
lambda-cyhalothrin 91465-08-6 9.5511
Hydrocarbons, C9, Aromatics 128601-23-0 >= 5 - < 10
propane-1,2-diol 57-55-6 >= 1 - < 5
orthophosphoric acid 7664-38-2 >= 1 - < 5
dioxosilane 14808-60-7 >= 0.1 - < 1
1,2-benzisothiazol-3(2H)-one 2634-33-5 >= 0.1 - < 1
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : Have the product container, label or Safety Data Sheet with
you when calling the emergency number, a poison control
center or physician, or going for treatment.

If inhaled : Take the victim into fresh air.

If breathing is irregular or stopped, administer artificial
respiration.
Keep patient warm and at rest.
Call a physician or poison control center immediately.

In case of skin contact : Take off all contaminated clothing immediately.

Wash off immediately with plenty of water.
If skin irritation persists, call a physician.

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DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
1.1 04/04/2023 S00030636291

Wash contaminated clothing before re-use.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Remove contact lenses.
Immediate medical attention is required.

If swallowed : If swallowed, seek medical advice immediately and show this

container or label.
Do NOT induce vomiting.

Most important symptoms : Aspiration may cause pulmonary edema and pneumonitis.
and effects, both acute and Skin contact paresthesia effects (itching, tingling, burning or
delayed numbness) are transient, lasting up to 24 hours.

Notes to physician : Do not induce vomiting: contains petroleum distillates and/or

aromatic solvents.
Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Extinguishing media - small fires

Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
Extinguishing media - large fires
Alcohol-resistant foam
or
Water spray

Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread
media fire.

Specific hazards during fire : As the product contains combustible organic ingredients, fire
fighting will produce dense black smoke containing hazardous
products of combustion (see section 10).
Exposure to decomposition products may be a hazard to
health.

Further information : Do not allow run-off from fire fighting to enter drains or water
courses.
Cool closed containers exposed to fire with water spray.

Special protective equipment : Wear full protective clothing and self-contained breathing
for fire-fighters apparatus.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Refer to protective measures listed in sections 7 and 8.

tive equipment and emer-
gency procedures

Environmental precautions : Prevent further leakage or spillage if safe to do so.

Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.

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SAFETY DATA SHEET

DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
1.1 04/04/2023 S00030636291

Methods and materials for : Contain spillage, and then collect with non-combustible
containment and cleaning up absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Clean contaminated surface thoroughly.
Clean with detergents. Avoid solvents.
Retain and dispose of contaminated wash water.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : No special protective measures against fire required.

Avoid contact with skin and eyes.
When using do not eat, drink or smoke.
For personal protection see section 8.

Conditions for safe storage : No special storage conditions required.

Keep containers tightly closed in a dry, cool and well-
ventilated place.
Keep out of the reach of children.
Keep away from food, drink and animal feedingstuffs.

Further information on stor- : Physically and chemically stable for at least 2 years when
age stability stored in the original unopened sales container at ambient
temperatures.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
lambda-cyhalothrin 91465-08-6 TWA 0.04 mg/m3 Syngenta
(Skin)
Hydrocarbons, C9, Aromatics 128601-23-0 TWA 19 ppm Supplier
100 mg/m3
propane-1,2-diol 57-55-6 TWA 10 mg/m3 US WEEL
orthophosphoric acid 7664-38-2 TWA 1 mg/m3 ACGIH
STEL 3 mg/m3 ACGIH
TWA 1 mg/m3 NIOSH REL
ST 3 mg/m3 NIOSH REL
TWA 1 mg/m3 OSHA Z-1
TWA 1 mg/m3 OSHA P0
STEL 3 mg/m3 OSHA P0
dioxosilane 14808-60-7 TWA (respir- 10 mg/m3 OSHA Z-3
able) / %SiO2+2
TWA (respir- 250 mppcf OSHA Z-3
able) / %SiO2+5
TWA (respir- 0.1 mg/m3 OSHA P0
able dust
fraction)
TWA (Res- 0.025 mg/m3 ACGIH
pirable par- (Silica)

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DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
1.1 04/04/2023 S00030636291

ticulate mat-
ter)
TWA (Res- 0.05 mg/m3 NIOSH REL
pirable dust) (Silica)
TWA (Res- 0.05 mg/m3 OSHA Z-1
pirable dust)
Engineering measures : THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE
CONTROLS/PERSONAL PROTECTION ARE INTENDED
FOR THE MANUFACTURE, FORMULATION AND
PACKAGING OF THE PRODUCT. FOR COMMERCIAL
APPLICATIONS AND/OR ON-FARM APPLICATIONS
CONSULT THE PRODUCT LABEL.

Containment and/or segregation is the most reliable technical

protection measure if exposure cannot be eliminated.
The extent of these protection measures depends on the
actual risks in use.
Maintain air concentrations below occupational exposure
standards.
Where necessary, seek additional occupational hygiene
advice.

Personal protective equipment

Respiratory protection : Where concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.

Hand protection

Remarks : Wear protective gloves. The choice of an appropriate glove

does not only depend on its material but also on other quality
features and is different from one producer to the other.
Please observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local
conditions under which the product is used, such as the
danger of cuts, abrasion, and the contact time. The break
through time depends amongst other things from the
material, the thickness and the type of glove and therefore
has to be measured for each case. Gloves should be
discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Eye protection : No special protective equipment required.

Skin and body protection : Choose body protection in relation to its type, to the

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SAFETY DATA SHEET

DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
1.1 04/04/2023 S00030636291

concentration and amount of dangerous substances, and to

the specific work-place.
Remove and wash contaminated clothing before re-use.
Wear as appropriate:
Impervious clothing

Protective measures : The use of technical measures should always have priority
over the use of personal protective equipment.
When selecting personal protective equipment, seek
appropriate professional advice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : white to light brown

Odor : aromatic, like solvent

Odor Threshold : No data available

pH : 4-8
Concentration: 1 %w/v

Melting point/range : No data available

Boiling point/boiling range : No data available

Flash point : Method: Pensky-Martens closed cup

does not flash

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapor pressure : No data available

Relative vapor density : No data available

Density : 1.047 g/cm3

Solubility(ies)
Water solubility : completely miscible

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SAFETY DATA SHEET

DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
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Partition coefficient: n- : No data available

octanol/water

Autoignition temperature : 1175 °F / 635 °C

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : 79.5 - 448 mPa.s (68 °F / 20 °C)

58.1 - 334 mPa.s (104 °F / 40 °C)

Viscosity, kinematic : No data available

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Particle size : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : None reasonably foreseeable.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : No dangerous reaction known under conditions of normal use.
tions

Conditions to avoid : No decomposition if used as directed.

Incompatible materials : None known.

Hazardous decomposition : No hazardous decomposition products are known.

products

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Ingestion
Inhalation
Skin contact
Eye contact
Acute toxicity

Product:
Acute oral toxicity : LD50 (Rat, male and female): > 5,000 mg/kg

Acute inhalation toxicity : LC50 (Rat, male and female): > 4.62 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The component/mixture is moderately toxic after

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DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
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short term inhalation., The substance/mixture is not toxic on

inhalation as defined by dangerous goods regulations.
Remarks: Based on data from similar materials

Acute dermal toxicity : LD50 (Rat, male and female): > 4,000 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity

Components:

lambda-cyhalothrin:
Acute oral toxicity : LD50 (Rat, female): 56 mg/kg

Acute inhalation toxicity : LC50 (Rat, male and female): 0.06 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist

Acute dermal toxicity : LD50 (Rat, male): 632 mg/kg

Hydrocarbons, C9, Aromatics:

Acute oral toxicity : LD50 (Rat, female): 3,492 mg/kg

orthophosphoric acid:
Acute oral toxicity : LD50 (Rat): 301 mg/kg

Acute dermal toxicity : LD50 (Rabbit): 2,750 mg/kg

1,2-benzisothiazol-3(2H)-one:
Acute oral toxicity : LD50 (Rat, male): 670 mg/kg

Acute dermal toxicity : LD50 (Rat, male and female): > 2,000 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity

Skin corrosion/irritation

Product:
Species : Rabbit
Result : No skin irritation
Remarks : May cause temporary itching, tingling, burning or numbness of
exposed skin, called paresthesia.

Components:

lambda-cyhalothrin:
Species : Rabbit
Result : No skin irritation
Remarks : May cause temporary itching, tingling, burning or numbness of
exposed skin, called paresthesia.

Hydrocarbons, C9, Aromatics:

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DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
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Result : Repeated exposure may cause skin dryness or cracking.

Species : Rabbit
Result : Mild skin irritation

orthophosphoric acid:
Result : Corrosive after 3 minutes to 1 hour of exposure

1,2-benzisothiazol-3(2H)-one:
Species : Rabbit
Result : Mild skin irritation

Serious eye damage/eye irritation

Product:
Species : Rabbit
Result : No eye irritation

Components:

lambda-cyhalothrin:
Species : Rabbit
Result : No eye irritation

1,2-benzisothiazol-3(2H)-one:
Species : Rabbit
Result : Risk of serious damage to eyes.

Respiratory or skin sensitization

Product:
Test Type : Maximization Test
Species : Guinea pig
Result : Did not cause sensitization on laboratory animals.

Species : Humans
Result : Probability or evidence of skin sensitization in humans

Components:

lambda-cyhalothrin:
Test Type : Maximization Test
Species : Guinea pig
Result : Does not cause skin sensitization.

Test Type : Local lymph node assay (LLNA)

Species : Mouse
Result : Does not cause skin sensitization.

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DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
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1,2-benzisothiazol-3(2H)-one:
Result : Probability or evidence of skin sensitization in humans

Germ cell mutagenicity

Components:

lambda-cyhalothrin:
Germ cell mutagenicity - : Animal testing did not show any mutagenic effects.
Assessment

orthophosphoric acid:
Germ cell mutagenicity - : In vitro tests did not show mutagenic effects
Assessment

1,2-benzisothiazol-3(2H)-one:
Germ cell mutagenicity - : Weight of evidence does not support classification as a germ
Assessment cell mutagen.

Carcinogenicity

Components:

lambda-cyhalothrin:
Carcinogenicity - Assess- : Weight of evidence does not support classification as a car-
ment cinogen

dioxosilane:
Carcinogenicity - Assess- : Weight of evidence does not support classification as a car-
ment cinogen

IARC has concluded that there is sufficient evidence in hu-

mans for the carcinogenicity of inhaled crystalline silica in the
form of quartz or cristobalite from occupational sources and in
experimental animals from quartz and cristobalite (Group 1). It
was noted however, that carcinogenicity was not detected in
all industrial circumstances and may be dependent on inher-
ent characteristics of the crystalline silica or external factors
affecting its biological activity.

IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.

OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.

NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

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DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
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Reproductive toxicity

Components:

lambda-cyhalothrin:
Reproductive toxicity - As- : Weight of evidence does not support classification for
sessment reproductive toxicity

orthophosphoric acid:
Reproductive toxicity - As- : No toxicity to reproduction
sessment

STOT-single exposure

Components:

lambda-cyhalothrin:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.

Hydrocarbons, C9, Aromatics:

Assessment : The substance or mixture is classified as specific target organ
toxicant, single exposure, category 3 with narcotic effects.,
The substance or mixture is classified as specific target organ
toxicant, single exposure, category 3 with respiratory tract
irritation.

STOT-repeated exposure

Components:

lambda-cyhalothrin:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.

dioxosilane:
Routes of exposure : Inhalation
Target Organs : Lungs
Assessment : The substance or mixture is classified as specific target organ
toxicant, repeated exposure, category 1.

Aspiration toxicity

Components:

Hydrocarbons, C9, Aromatics:

May be fatal if swallowed and enters airways.

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DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
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SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

lambda-cyhalothrin:
Toxicity to fish : LC50 (Leuciscus idus (Golden orfe)): 0.000078 mg/l
Exposure time: 96 h

LC50 (Ictalurus punctatus (channel catfish)): 0.00016 mg/l

Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.00036 mg/l
aquatic invertebrates Exposure time: 48 h

LC50 (Americamysis): 0.000007 mg/l

Exposure time: 48 h

EC50 (Hyalella azteca (Amphipod)): 0.000002 mg/l

Exposure time: 48 h

Toxicity to algae/aquatic : ErC50 (Raphidocelis subcapitata (freshwater green alga)): >

plants 0.31 mg/l
Exposure time: 96 h

M-Factor (Acute aquatic tox- : 100,000

icity)

Toxicity to fish (Chronic tox- : NOEC (Pimephales promelas (fathead minnow)): 0.000031
icity) mg/l
Exposure time: 300 d

Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.000002 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity)

NOEC (Americamysis): 0.00022 µg/l

Exposure time: 28 d

M-Factor (Chronic aquatic : 100,000

toxicity)

Toxicity to microorganisms : EC50 (activated sludge): > 100 mg/l

Exposure time: 3 h

Hydrocarbons, C9, Aromatics:

Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 9.2 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): 3.2 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae/aquatic : ErC50 (Raphidocelis subcapitata (freshwater green alga)): 2.9

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DEMAND CS INSECTICIDE
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plants mg/l
Exposure time: 72 h

NOELR (Raphidocelis subcapitata (freshwater green alga)):

1.0 mg/l
End point: Growth rate
Exposure time: 72 h

Toxicity to fish (Chronic tox- : NOELR (Oncorhynchus mykiss (rainbow trout)): 1.228 mg/l
icity) Exposure time: 28 d

Toxicity to daphnia and other : NOELR (Daphnia magna (Water flea)): 2.144 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity)

Ecotoxicology Assessment
Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects.

orthophosphoric acid:
Toxicity to fish : LC50 (Lepomis macrochirus (Bluegill sunfish)): 3 - 3.25 mg/l
Exposure time: 96 h

Ecotoxicology Assessment
Chronic aquatic toxicity : This product has no known ecotoxicological effects.

1,2-benzisothiazol-3(2H)-one:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.18 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 2.94 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae/aquatic : ErC50 (Raphidocelis subcapitata (freshwater green alga)):

plants 0.15 mg/l
Exposure time: 72 h

EC10 (Raphidocelis subcapitata (freshwater green alga)):

0.04 mg/l
End point: Growth rate
Exposure time: 72 h

Toxicity to fish (Chronic tox- : NOEC (Oncorhynchus mykiss (rainbow trout)): 0.3 mg/l
icity) Exposure time: 28 d

Toxicity to daphnia and other : NOEC (Daphnia): 1.7 mg/l

aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity)

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DEMAND CS INSECTICIDE
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Persistence and degradability

Components:

lambda-cyhalothrin:
Biodegradability : Result: Not readily biodegradable.

Stability in water : Degradation half life (DT50): 7 d

Remarks: Product is not persistent.

Hydrocarbons, C9, Aromatics:

Biodegradability : Result: Readily biodegradable.

1,2-benzisothiazol-3(2H)-one:
Biodegradability : Result: rapidly degradable

Bioaccumulative potential

Components:

lambda-cyhalothrin:
Bioaccumulation : Remarks: Bioaccumulates

1,2-benzisothiazol-3(2H)-one:
Bioaccumulation : Remarks: Bioaccumulation is unlikely.

Mobility in soil

Components:

lambda-cyhalothrin:
Distribution among environ- : Remarks: immobile
mental compartments

Stability in soil : Dissipation time: 56 d

Percentage dissipation: 50 % (DT50)
Remarks: Product is not persistent.

Other adverse effects

Components:

lambda-cyhalothrin:
Results of PBT and vPvB : This substance is not considered to be persistent, bioaccumu-
assessment lating and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulating (vPvB).

orthophosphoric acid:
Results of PBT and vPvB : This substance is not considered to be persistent, bioaccumu-
assessment lating and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulating (vPvB).

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1,2-benzisothiazol-3(2H)-one:
Results of PBT and vPvB : This substance is not considered to be persistent, bioaccumu-
assessment lating and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulating (vPvB).

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not contaminate ponds, waterways or ditches with
chemical or used container.
Do not dispose of waste into sewer.
Where possible recycling is preferred to disposal or
incineration.
If recycling is not practicable, dispose of in compliance with
local regulations.

Contaminated packaging : Empty remaining contents.

Triple rinse containers.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(LAMBDA-CYHALOTHRIN)
Class : 9
Packing group : III
Labels : 9
IATA-DGR
UN/ID No. : UN 3082
Proper shipping name : Environmentally hazardous substance, liquid, n.o.s.
(LAMBDA-CYHALOTHRIN)
Class : 9
Packing group : III
Labels : Miscellaneous
Packing instruction (cargo : 964
aircraft)
Packing instruction (passen- : 964
ger aircraft)
Environmentally hazardous : yes
IMDG-Code
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(LAMBDA-CYHALOTHRIN)
Class : 9

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Packing group : III

Labels : 9
EmS Code : F-A, S-F
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49 CFR
Not regulated as a dangerous good
Remarks : Shipment by ground under DOT is non-regulated; however it
may be shipped per the applicable hazard classification to
facilitate multi-modal transport involving ICAO (IATA) or IMO.

Special precautions for user

The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject
to certain labeling requirements under federal pesticide law. These requirements differ from the classi-
fication criteria and hazard information required for safety data sheets, and for workplace labels of
non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
Caution
Harmful if absorbed through skin.
Avoid breathing spray mist.
Avoid contact with skin, eyes or clothing.
Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using
tobacco or using the toilet.
Remove and wash contaminated clothing before re-use.
Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : Acute toxicity (any route of exposure)
Respiratory or skin sensitization

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

SECTION 16. OTHER INFORMATION

Further information

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NFPA 704: HMIS® IV:

Flammability
HEALTH / 2

0 FLAMMABILITY
0
Health Instability
2 0 PHYSICAL HAZARD
0

HMIS® ratings are based on a 0-4 rating

scale, with 0 representing minimal haz-
ards or risks, and 4 representing signifi-
cant hazards or risks. The "*" represents
Special hazard a chronic hazard, while the "/" represents
the absence of a chronic hazard.

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated
values)
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants
OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-
eral Dusts
US WEEL : USA. Workplace Environmental Exposure Levels (WEEL)
ACGIH / TWA : 8-hour, time-weighted average
ACGIH / STEL : Short-term exposure limit
NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded
at any time during a workday
OSHA P0 / TWA : 8-hour time weighted average
OSHA P0 / STEL : Short-term exposure limit
OSHA Z-1 / TWA : 8-hour time weighted average
OSHA Z-3 / TWA : 8-hour time weighted average
US WEEL / TWA : 8-hr TWA

AIIC - A ustralian Invent ory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concent ration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemic al Substances (Japan); ErCx - Conc entration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IA RC - In-
ternational Agency for Research on Cancer; IA TA - International Air Trans port Association; IBC -
International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in
Bulk; IC50 - Half maximal inhibitory concentration; ICA O - International Civil A viation Organization;
IECS C - Inventory of Existing Chemical S ubstances in China; IMDG - International Maritime Dan-

17 / 18
SAFETY DATA SHEET

DEMAND CS INSECTICIDE
Version Revision Date: SDS Number: This version replaces all previous versions.
1.1 04/04/2023 S00030636291

gerous Goods; IMO - International Maritime Organization; IS HL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Let hal Concentration to 50 % of a test population; LD50 - Let hal Dose to
50% of a test population (Median Lethal Dose); MARPOL - Int ernational Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
erwis e Specified; NFPA - National Fire P rotection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A )EL - No Observed (A dverse) Effect Level; NOE LR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution P revention; PB T - P ersistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Invent ory of Chemicals and Chemical Substances; (Q)SA R - (Quanti-
tative) Structure Activity Relationship; RCRA - Resourc e Conservation and Recovery Act;
REACH - Regulation (E C) No 1907/2006 of the E uropean Parliament and of the Council concern-
ing the Registration, E valuation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act
(Unit ed States); UN - United Nations; UNRTDG - United Nations Recommendations on the
Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative

Revision Date : 04/04/2023

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

US / Z8

18 / 18
Safety Data Sheet
ARCHER® Insect Growth Regulator
Date: 12/8/2015
Replaces: 5/8/2015

1. PRODUCT IDENTIFICATION

Product identifier on label: ARCHER® Insect Growth Regulator

Product No.: A12861A
Use: Insect Growth Regulator
Manufacturer: Syngenta Crop Protection, LLC
Post Office Box 18300
Greensboro NC 27419

Manufacturer Phone: 1-800-334-9481

Emergency Phone: 1-800-888-8372

2. HAZARDS IDENTIFICATION

Classifications: Skin Corrosion/Irritation: Category 2

Specific Target Organ Toxicity: Drowsiness Category 3
Specific Target Organ Toxicity: Respiratory Irritation Category 3
Aspiration Hazard: Category 1
Flammable Liquid: Category 4
Eye Damage/Irritation: Category 2B
Signal Word (OSHA): Danger

Hazard Statements: Combustible liquid

May be fatal if swallowed and enters airways
Causes skin irritation
Causes eye irritation
May cause respiratory irritation
May cause drowsiness or dizziness

Hazard Symbols:

Precautionary Statements: Keep away from heat, sparks, open flames, hot surfaces. No smoking.
Avoid breathing mist, vapors, spray.
Wash hands and face thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves, protective clothing, eye protection.
If swallowed: Immediately call a poison center, doctor or Syngenta.
If on skin: Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice.

Page 1 of 8
Safety Data Sheet
ARCHER® Insect Growth Regulator
Date: 12/8/2015
Replaces: 5/8/2015

If inhaled: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice.
Call a poison center, doctor or Syngenta if you feel unwell.
See Section 4 First Aid Measures.
Do NOT induce vomiting.
Take off contaminated clothing and wash it before reuse.
In case of fire: Use dry chemical, foam or CO2 for extinction.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents and container in accordance with local regulations.

Other Hazard Statements: None

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Common Name CAS Number Concentration

Petroleum Solvent Petroleum Solvent Trade Secret Trade Secret
Other ingredients Other ingredients Trade Secret 98.7%
2-[1-Methyl-2-(4-phenoxyphenoxy) Pyriproxifen 95737-68-1 1.3%
ethoxyl] pyridine

Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.

4. FIRST AID MEASURES

Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center
or doctor, or going for treatment.

Ingestion: If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment
advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so after calling 800-888-
8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person.
Eye Contact: If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if
present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or
doctor for treatment advice.
Skin Contact: If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice.
Inhalation: If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial
respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or
doctor for further treatment advice.
Most important symptoms/effects:
Eye irritation
Skin irritation
Drowsiness or dizziness
Respiratory irritation

Page 2 of 8
Safety Data Sheet
ARCHER® Insect Growth Regulator
Date: 12/8/2015
Replaces: 5/8/2015
Indication of immediate medical attention and special treatment needed:
There is no specific antidote if this product is ingested.
Treat symptomatically.
Contains petroleum distillate - vomiting may cause aspiration pneumonia.

5. FIRE FIGHTING MEASURES

Suitable (and unsuitable) extinguishing media:

Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect runoff.
Specific Hazards:
Combustible liquid. Can release vapors that form explosive mixtures at temperatures at or above the flash point. Heavy
vapors can flow along surfaces to distant ignition sources and flash back.

During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.

Special protective equipment and precautions for firefighters:

Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to
prevent human exposure to fire, smoke, fumes or products of combustion.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures:

Follow exposure controls/personal protection outlined in Section 8.

Methods and materials for containment and cleaning up:

Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and
drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Cover
entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g.
commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into
compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and
arrange for disposition.

7. HANDLING AND STORAGE

Precautions for safe handling:

Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food,
beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas
where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.

Conditions for safe storage, including any incompatibilities:

Store locked up.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR
THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT.
FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL.

Occupational Exposure Limits:

Chemical Name OSHA PEL ACGIH TLV Other Source

Petroleum Solvent Not Established Not Established 50 mg/m³ TWA Manufacturer

Page 3 of 8
Safety Data Sheet
ARCHER® Insect Growth Regulator
Date: 12/8/2015
Replaces: 5/8/2015

Other ingredients Not Established Not Established Not Established Not Applicable

Pyriproxifen Not Established Not Established Not Established Manufacturer

Appropriate engineering controls:

Use effective engineering controls to comply with occupational exposure limits (if applicable).
Individual protection measures:

Ingestion:
Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the
material. Wash thoroughly with soap and water after handling.
Eye Contact:
Where eye contact is likely, use chemical splash goggles.

Skin Contact:
Where contact is likely, wear chemical-resistant gloves (such as barrier laminate or Viton), coveralls, socks and chemical-
resistant footwear.
Inhalation:
A combination particulate/organic vapor respirator should be used until effective engineering controls are installed to
comply with occupational exposure limits, or until exposure limits are established. Use a NIOSH certified respirator with an
organic vapor (OV) cartridge or canister with any R, P or HE filter.

Use a self-contained breathing apparatus in cases of emergency spills, when exposure levels are unknown, or under any
circumstances where air-purifying respirators may not provide adequate protection.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Colorless liquid

Odor: Petroleum solvent
Odor Threshold: Not Available
pH: Not Available
Melting point/freezing point: Not Applicable
Initial boiling point and boiling range: Not Available
Flash Point (Test Method): 153°F (Setaflash)
Flammable Limits (% in Air): Not Available
Flammability: Combustible liquid.
Vapor Pressure: Pyriproxifen < 1.0 x 10(-7) mmHg @ 73.06°F (22.81°C)
Vapor Density: Not Available
Relative Density: 0.847 g/ml @ 68°F (20°C)
Solubility (ies): Pyriproxifen 0.367 +/- 0.004 mg/l

Partition coefficient: n-octanol/water: Not Available

Autoignition Temperature: Not Available

Decomposition Temperature: Not Available

Viscosity: Not Available
Other: None

Page 4 of 8
Safety Data Sheet
ARCHER® Insect Growth Regulator
Date: 12/8/2015
Replaces: 5/8/2015

10. STABILITY AND REACTIVITY

Reactivity: Not reactive.

Chemical stability: Stable under normal use and storage conditions.
Possibility of hazardous reactions: Will not occur.
Conditions to Avoid: Heat and acidic or alkaline conditions may cause this product to break down.

Incompatible materials: None known.

Hazardous Decomposition Products: None known.

11. TOXICOLOGICAL INFORMATION

Health effects information

Likely routes of exposure: Dermal, Inhalation

Symptoms of exposure: Eye irritation, Drowsiness or dizziness, Skin irritation, Respiratory irritation

Delayed, immediate and chronic effects of exposure: Eye irritation, Skin irritation, Drowsiness or dizziness, Respiratory
irritation

Numerical measures of toxicity (acute toxicity/irritation studies (finished product))

Ingestion: Oral (LD50 Rabbit) : > 5000 mg/kg body weight

Dermal: Dermal (LD50 Rabbit) : > 2000 mg/kg body weight

Inhalation: Inhalation (LC50 Rat) : > 7.6 mg/l air - 4 hours

Eye Contact: See "Other Toxicity Information", Sec. 11

Skin Contact: See "Other Toxicity Information", Sec. 11

Skin Sensitization: Not a skin sensitizer.

Reproductive/Developmental Effects
Pyriproxifen: No test article related reproductive effects were observed.
NOEL for systemic toxicity was 1000 ppm. The NOEL for reproductive effects was 5000 ppm.

No test article related teratogenic effects were observed.

Teratology (rat): No Observable Effect Level (NOEL), Dams-100 mg/kg/day, Fetuses-100 mg/kg/day, Offspring-1000
mg/kg/day. Not a reproductive toxin.
Teratology (rabbit): No Observable Effect Level (NOEL), Dams-100 mg/kg/day, Fetuses-100 mg/kg/day. Not a
reproductive toxin.
Gene Mutation: Negative.
Chromosomal Aberration: Negative.
Unscheduled DNA synthesis: Negative.
Chronic/Subchronic Toxicity Studies
Pyriproxifen: None available.

Carcinogenicity

Page 5 of 8
Safety Data Sheet
ARCHER® Insect Growth Regulator
Date: 12/8/2015
Replaces: 5/8/2015
Carcinogenicity
Pyriproxifen: No test article related carcinogenic effects were observed. The No Observable Effect Level was 30
mg/kg/day. No evidence of increased tumor incidence when fed in the diet at 0, 120, 600 & 6000 ppm/day. The NOEL for
systemic effects was 120 ppm/day.

No test article related oncogenic effects were observed. No evidence of increased tumor incidence when fed in the diet at
0, 120, 600 & 6000 ppm/day. The NOEL for systemic effects was 600 ppm/day for males, 120 ppm/day for females.

Chemical Name NTP/IARC/OSHA Carcinogen

Petroleum Solvent No
Other ingredients No
2-[1-Methyl-2-(4-phenoxyphenoxy) ethoxyl] No
pyridine

Other Toxicity Information

Eye contact can cause temporary irritation, tearing and blurred vision.
Repeated and/or prolonged skin contact may cause irritation and dermatitis.
Toxicity of Other Components
Other ingredients
Not Established
Petroleum Solvent
Inhalation of vapors at high concentrations can cause central nervous system effects (dizziness, headache),
irritation to eyes or respiratory tract.
Target Organs
Active Ingredients
Pyriproxifen: Not available
Inert Ingredients
Other ingredients: Not Established
Petroleum Solvent: Respiratory tract, stomach, liver, thyroid, urinary bladder, CNS, skin

12. ECOLOGICAL INFORMATION

Eco-Acute Toxicity
Pyriproxifen:
Fish (Rainbow Trout) 96-hour LC50 >0.325 mg/L
Bird (Bobwhite Quail) LD50 Oral >2000 mg/kg
Invertebrate (Water Flea) Daphnia Magna 48-hour EC50 0.40 mg/L
Algae 72-hour EC50 0.064 mg/L

Environmental Fate
Pyriproxifen:
Not available

13. DISPOSAL CONSIDERATIONS

Disposal:
Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state,
and federal health and environmental regulations.

Page 6 of 8
Safety Data Sheet
ARCHER® Insect Growth Regulator
Date: 12/8/2015
Replaces: 5/8/2015
Characteristic Waste: Not Applicable
Listed Waste: Not Applicable

14. TRANSPORT INFORMATION

DOT Classification
Ground Transport - NAFTA
< 119 gallons: Not regulated
> 119 gallons:
Proper Shipping Name: Combustible Liquid, N.O.S. (Petroleum Distillates)
Hazard Class: Combustible Liquid
Identification Number: NA 1993
Packing Group: PG III
Comments
Water Transport - International
Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Pyriproxifen), Marine Pollutant
Hazard Class: Class 9
Identification Number: UN 3082
Packing Group: PG III

Air Transport - International

Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Pyriproxifen)
Hazard Class: Class 9
Identification Number: UN 3082
Packing Group: PG III

15. REGULATORY INFORMATION

Pesticide Registration:
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard
information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard
information as required on the pesticide label:
Caution: Causes moderate eye irritation. Harmful if absorbed through skin, swallowed, or inhaled. Avoid contact with
skin, eyes, or clothing. Avoid breathing vapor or spray mist. Wash thoroughly with soap and water after handling and
before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove and wash contaminated clothing before

EPA Registration Number(s):

100-1111
EPCRA SARA Title III Classification:
Section 311/312 Hazard Classes: Acute Health Hazard
Fire Hazard

Section 313 Toxic Chemicals: None

CERCLA/SARA 304 Reportable Quantity (RQ):

None
RCRA Hazardous Waste Classification (40 CFR 261):
Not Applicable

Page 7 of 8
Safety Data Sheet
ARCHER® Insect Growth Regulator
Date: 12/8/2015
Replaces: 5/8/2015

TSCA Status:
Exempt from TSCA, subject to FIFRA

16. OTHER INFORMATION

NFPA Hazard Ratings HMIS Hazard Ratings 0 Minimal

Health: 1 Health: 1 1 Slight
Flammability: 2 Flammability: 2 2 Moderate
Instability: 0 Reactivity: 0 3 Serious
4 Extreme
Syngenta Hazard Category: B * Chronic

For non-emergency questions about this product call:

1-800-334-9481

Original Issued Date: 8/19/1998

Revision Date: 12/8/2015 Replaces: 5/8/2015
Section(s) Revised: 15
The information and recommendations contained herein are based upon data believed to be correct.
However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the
information contained herein.

Page 8 of 8