PT Fendona SDS 3-16-21

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Safety Data Sheet

PT Fendona Pressurized Insecticide


Revision date : 2021/03/16 Page: 1/13
Version: 5.0 (30702757/SDS_CPA_US/EN)

1. Identification

Product identifier used on the label

PT Fendona Pressurized Insecticide


Recommended use of the chemical and restriction on use

Recommended use*: insecticide

* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of
the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or
implied, including by incorporation into or reference in the seller's sales agreement.

Details of the supplier of the safety data sheet

Company: Contact address:


BASF Canada Inc. BASF CORPORATION
100 Milverton Drive 100 Park Avenue
Mississauga, ON L5R 4H1, CANADA Florham Park, NJ 07932
USA
Telephone: +1 973 245-6000

Emergency telephone number

24 Hour Emergency Response Information


CHEMTREC: 1-800-424-9300
BASF HOTLINE: 1-800-832-HELP (4357)

Other means of identification


Substance number: 620729
EPA Registration number: 499-569
Synonyms: Alphacypermethrin

2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Classification of the product

Asp. Tox. 1 Aspiration hazard


Skin Corr./Irrit. 2 Skin corrosion/irritation
Aquatic Acute 1 Hazardous to the aquatic environment - acute
Aquatic Chronic 1 Hazardous to the aquatic environment - chronic

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Safety Data Sheet
PT Fendona Pressurized Insecticide
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Version: 5.0 (30702757/SDS_CPA_US/EN)
Flam. Aerosol 2 Flammable aerosols

Label elements

Pictogram:

Signal Word:
Danger

Hazard Statement:
H223 Flammable aerosol.
H315 Causes skin irritation.
H304 May be fatal if swallowed and enters airways.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements (Prevention):


P210 Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P264 Wash contaminated body parts thoroughly after handling.

Precautionary Statements (Response):


P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or physician.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P391 Collect spillage.
P332 + P313 If skin irritation occurs: Get medical attention.
P331 Do NOT induce vomiting.
P362 + P364 Take off contaminated clothing and wash it before reuse.

Precautionary Statements (Storage):


P410 + P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/
122°F.
P405 Store locked up.

Precautionary Statements (Disposal):


P501 Dispose of contents/container in accordance with local regulations.

Hazards not otherwise classified

Labeling of special preparations (GHS):


May cause paraesthesia. Contains: alpha-Cypermethrin
Contains: 97 % m/m flammable components 2-Propanol, Distillates, petroleum

3. Composition / Information on Ingredients


According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

alpha-Cypermethrin
CAS Number: 67375-30-8

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Version: 5.0 (30702757/SDS_CPA_US/EN)
Content (W/W): 0.05 %
Synonym: No data available.

2-Propanol
CAS Number: 67-63-0
Content (W/W): 10.0 - 15.0%
Synonym: Isopropyl alcohol

Distillates, petroleum
CAS Number: 64742-47-8
Content (W/W): 75.0 - 100.0%
Synonym: Distillates, petroleum, hydrotreated light

carbon dioxide
CAS Number: 124-38-9
Content (W/W): < 5.0%
Synonym: No data available.

4. First-Aid Measures

Description of first aid measures

General advice:
First aid personnel should pay attention to their own safety. If the patient is likely to become
unconscious, place and transport in stable sideways position (recovery position). Immediately
remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

If on skin:
Immediately wash thoroughly with soap and water, seek medical attention.

If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.

If swallowed:
Do not give solids or liquids. Do not induce vomiting due to aspiration hazard. Immediate medical
attention required. Never induce vomiting or give anything by mouth if the victim is unconscious or
having convulsions.

Most important symptoms and effects, both acute and delayed

Symptoms: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11., (Further) symptoms and / or effects are not known so far

Indication of any immediate medical attention and special treatment needed

Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no
known specific antidote.

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Version: 5.0 (30702757/SDS_CPA_US/EN)
5. Fire-Fighting Measures

Extinguishing media

Suitable extinguishing media:


water spray, carbon dioxide, foam, dry powder

Special hazards arising from the substance or mixture


Hazards during fire-fighting:
carbon monoxide, carbon dioxide, hydrogen bromide, Hydrogen chloride, hydrogen fluoride, nitrogen
oxides, halogenated compounds
The substances/groups of substances mentioned can be released in case of fire. Aerosol container
contains flammable gas under pressure.

Aerosol container contains flammable gas under pressure. Risk of explosion at


excessive temperatures.

Advice for fire-fighters


Protective equipment for fire-fighting:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if
exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage
or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with
official regulations.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures


Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Do not breathe
vapour/spray.

Environmental precautions
Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.

Methods and material for containment and cleaning up


For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose
binder, kieselguhr).
For large amounts: Dike spillage. Pump off product.
Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers,
which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and
detergents, observing environmental regulations.

7. Handling and Storage

Precautions for safe handling


RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND
PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product
Label and Directions for Use attached to the product. Provide good ventilation of working area (local
exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container
tightly sealed. Protect against heat. Handle and open container with care. Do not open until ready to
use. Once container is opened, content should be used as soon as possible. Provide means for

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Safety Data Sheet
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Version: 5.0 (30702757/SDS_CPA_US/EN)
controlling leaks and spills. Follow label warnings even after container is emptied. The substance/
product may be handled only by appropriately trained personnel. Avoid all direct contact with the
substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of
dusts/mists/vapours. Wear suitable personal protective clothing and equipment.

Protection against fire and explosion:


Aerosol container contains flammable gas under pressure. The relevant fire protection measures
should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks,
open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic
discharge. Electrostatic discharge may cause ignition.

Conditions for safe storage, including any incompatibilities


Segregate from foods and animal feeds.

Further information on storage conditions: Keep away from heat. Protect from direct sunlight. Keep
only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or
flame.
Protect from temperatures above: 130 °F
Explosive at or above indicated temperature.

8. Exposure Controls/Personal Protection


Users of a pesticidal product should refer to the product label for personal protective
equipment requirements.

Components with occupational exposure limits

2-Propanol ACGIH, US: STEL value 400 ppm ;


ACGIH, US: TWA value 200 ppm ;
NIOSH, US: STEL value 500 ppm 1,225 mg/m3 ;
NIOSH, US: REL value 400 ppm 980 mg/m3 ;
OSHA Z1: PEL 400 ppm 980 mg/m3 ;
OSHA Z1A: STEL value 500 ppm 1,225 mg/m3 ;
OSHA Z1A: TWA value 400 ppm 980 mg/m3 ;

carbon dioxide ACGIH, US: TWA value 5,000 ppm ;


ACGIH, US: STEL value 30,000 ppm ;
NIOSH, US: REL value 5,000 ppm 9,000 mg/m3 ;
NIOSH, US: STEL value 30,000 ppm 54,000 mg/m3 ;
OSHA Z1: PEL 5,000 ppm 9,000 mg/m3 ;
OSHA Z1A: TWA value 10,000 ppm 18,000 mg/m3 ;
OSHA Z1A: STEL value 30,000 ppm 54,000 mg/m3 ;

Personal protective equipment


RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING
WORKERS:

Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent)
organic vapour/particulate respirator. For situations where the airborne concentrations may exceed
the level for which an air purifying respirator is effective, or where the levels are unknown or
Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure
demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air
respirator (SAR) with escape provisions.

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Version: 5.0 (30702757/SDS_CPA_US/EN)

Hand protection:
Chemical resistant protective gloves, Protective glove selection must be based on the user's
assessment of the workplace hazards.

Eye protection:
Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if
splashing hazard exists.

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. head protection,
apron, protective boots, chemical-protection suit.

General safety and hygiene measures:


The statements on personal protective equipment in the instructions for use apply when handling
crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended.
Store work clothing separately. Keep away from food, drink and animal feeding stuffs.

9. Physical and Chemical Properties

Form: liquid
Odour: of isopropanol
Odour threshold: Not determined due to potential health hazard by inhalation.
Colour: pale yellow, clear
pH value: approx. 6 - 8
(approx. 20 °C)
Melting point: -33 °C
Information applies to the solvent.
Boiling point: 221 - 271 °C
( 1,013.25 hPa)
Information applies to the solvent.
Flash point: 11.7 °C
Information applies to the solvent.
Information on: 2-Propanol
Flash point: 11.7 °C
Literature data.
Information on: Distillates, petroleum
Flash point: 73 °C (ASTM D93, closed
Literature data. cup)
----------------------------------
Flammability: Flammable.
Ignition distance test for > 14 in
spray aerosols: no flashback
NFPA 30B flammability: Level 3 Aerosol
Lower explosion limit: As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Upper explosion limit: As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Autoignition: 247 °C
Information applies to the solvent.

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Revision date : 2021/03/16 Page: 7/13
Version: 5.0 (30702757/SDS_CPA_US/EN)
Vapour pressure: approx. 9 Pa (ASTM D323)
( 20 °C)
Information applies to the solvent.
Density: approx. 0.79 g/cm3
(approx. 20 °C)
Vapour density: not applicable
Partitioning coefficient n- not applicable
octanol/water (log Pow):
Thermal decomposition: No decomposition if stored and handled as
prescribed/indicated.
Viscosity, dynamic: approx. 1.55 mPa.s
( 40 °C)
Solubility in water: insoluble
Evaporation rate: not applicable

10. Stability and Reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Oxidizing properties:
Based on its structural properties the product is not classified as oxidizing.

Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions


No hazardous reactions if stored and handled as prescribed/indicated.

Conditions to avoid
See SDS section 7 - Handling and storage.

Incompatible materials
strong bases, strong acids, strong oxidizing agents

Hazardous decomposition products

Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and handled as
prescribed/indicated.

Thermal decomposition:
No decomposition if stored and handled as prescribed/indicated.

11. Toxicological information

Primary routes of exposure

Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route
of entry for liquefied gases.

Acute Toxicity/Effects

Acute toxicity

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Safety Data Sheet
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Version: 5.0 (30702757/SDS_CPA_US/EN)
Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic by
inhalation. Virtually nontoxic after a single skin contact.

Oral
Type of value: LD50
Species: rat (female)
Value: > 5,000 mg/kg (OECD Guideline 425)
No mortality was observed.

Inhalation
Type of value: LC50
Species: rat (male/female)
Value: > 5.1 mg/l (OECD Guideline 403)
No mortality was observed.

Dermal
Type of value: LD50
Species: rat (male/female)
Value: > 5,000 mg/kg (OECD Guideline 402)
No mortality was observed.

Assessment other acute effects


Assessment of STOT single:
Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.

The product has not been tested. The statement has been derived from the properties of the
individual components.

Irritation / corrosion
Assessment of irritating effects: Not irritating to the eyes. Skin contact causes irritation.

Skin
Species: rabbit
Result: moderately irritating
Method: OECD Guideline 404

Eye
Species: rabbit
Result: non-irritant
Method: OECD Guideline 405

Sensitization
Assessment of sensitization: There is no evidence of a skin-sensitizing potential.

Buehler test
Species: guinea pig
Result: Non-sensitizing.
Method: similar to OECD guideline 406

Aspiration Hazard
The product has not been tested. The statement has been derived from the properties of the
individual components. May also damage the lung at swallowing (aspiration hazard).

Chronic Toxicity/Effects

Repeated dose toxicity

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Safety Data Sheet
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Version: 5.0 (30702757/SDS_CPA_US/EN)
Assessment of repeated dose toxicity: The product has not been tested. The statement has been
derived from the properties of the individual components.

Information on: alpha-cypermethrin


Assessment of repeated dose toxicity: Repeated oral exposure may affect certain organs. Damages
the peripheral nerve system.

Information on: 2-Propanol


Assessment of repeated dose toxicity: No adverse effects were observed after repeated inhalative
exposure in animal studies. The substance may cause damage to the liver after repeated inhalation
of high doses.

Information on: carbon dioxide


Assessment of repeated dose toxicity: Prolonged or repeated exposure by inhalation to high
concentrations may cause circulatory insufficiency leading to headache, nausea, vomiting and
potentially death.
----------------------------------

Genetic toxicity
Assessment of mutagenicity: The product has not been tested. The statement has been derived from
the properties of the individual components. Mutagenicity tests revealed no genotoxic potential.

Carcinogenicity
Assessment of carcinogenicity: The product has not been tested. The statement has been derived
from the properties of the individual components.

Information on: Distillates, petroleum


Assessment of carcinogenicity: Long-term exposure to highly irritating concentrations resulted in skin
tumors in animals. A carcinogenic effect in humans can be excluded after brief skin contact. The
product has not been tested. The statement has been derived from substances/products of a similar
structure or composition.
----------------------------------

Reproductive toxicity
Assessment of reproduction toxicity: The product has not been tested. The statement has been
derived from the properties of the individual components. The results of animal studies gave no
indication of a fertility impairing effect.

Teratogenicity
Assessment of teratogenicity: The product has not been tested. The statement has been derived
from the properties of the individual components. Animal studies gave no indication of a
developmental toxic effect at doses that were not toxic to the parental animals.

Other Information
Has a degreasing effect on skin.
Misuse can be harmful to health.

12. Ecological Information

Toxicity

Aquatic toxicity
Assessment of aquatic toxicity:
Very toxic to aquatic life with long lasting effects.

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Version: 5.0 (30702757/SDS_CPA_US/EN)
The product has not been tested. The statement has been derived from the properties of the
individual components.

Toxicity to fish

Information on: alpha-cypermethrin


LC50 (96 h) 0.00093 mg/l, Pimephales promelas (OPP 72-1 (EPA-Guideline), Flow through.)
----------------------------------

Aquatic invertebrates

Information on: alpha-cypermethrin


EC50 (48 h) 12,6 ng/l, Chironomus riparius
----------------------------------

Aquatic plants

Information on: alpha-cypermethrin


EC50 (7 d) > 0.00139 mg/l (growth rate), Lemna gibba (OECD Guideline 201)
No observed effect concentration (7 d) > 0.00139 mg/l (growth rate), Lemna gibba (OECD guideline
221, static)
EC50 (72 h) > 0.027 mg/l (growth rate), Anabaena flos-aquae (OECD Guideline 201)
----------------------------------

Chronic toxicity to fish

Information on: alpha-cypermethrin


No observed effect concentration (34 d) 0,03 µg/L, Pimephales promelas (OPP 72-4 (EPA-
Guideline), Flow through.)
----------------------------------

Chronic toxicity to aquatic invertebrates

Information on: alpha-cypermethrin


No observed effect concentration (21 d) 0,03 µg/L, Daphnia magna (OPP 72-4 (EPA-Guideline),
semistatic)
----------------------------------

Persistence and degradability

Assessment biodegradation and elimination (H2O)


The product has not been tested. The statement has been derived from the properties of the
individual components.

Assessment biodegradation and elimination (H2O)

Information on: alpha-cypermethrin

Not readily biodegradable (by OECD criteria).


----------------------------------

Bioaccumulative potential

Assessment bioaccumulation potential


The product has not been tested. The statement has been derived from the properties of the
individual components.

Bioaccumulation potential

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Revision date : 2021/03/16 Page: 11/13
Version: 5.0 (30702757/SDS_CPA_US/EN)

Information on: alpha-cypermethrin

Bioconcentration factor: 155 - 910 (73 d), Cyprinus carpio (OECD Guideline 305 C)
----------------------------------

Mobility in soil

Assessment transport between environmental compartments


The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: alpha-cypermethrin

Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of
groundwater is not expected.
----------------------------------

Additional information

Other ecotoxicological advice:


Do not discharge product into the environment without control.

13. Disposal considerations


Waste disposal of substance:
Must be disposed of or incinerated in accordance with local regulations.

Container disposal:
Do not cut, puncture, crush, or incinerate empty aerosol containers. Consult state or local disposal
authorities for approved alternative procedures such as container recycling. Empty aerosol cans may
meet the definition of RCRA D003. Consult local and/or regional EPA for further guidance.

14. Transport Information


Land transport
USDOT
Hazard class: 2.1
ID number: UN 1950
Hazard label: 2.1, EHSM
Proper shipping name: AEROSOLS

Sea transport
IMDG
Hazard class: 2.1
ID number: UN 1950
Hazard label: 2.1, EHSM
Marine pollutant: YES
Proper shipping name: AEROSOLS (contains PROPAN-2-OL, ALPHA-CYPERMETHRIN)

Air transport
IATA/ICAO
Hazard class: 2.1
ID number: UN 1950

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Version: 5.0 (30702757/SDS_CPA_US/EN)
Hazard label: 2.1
Proper shipping name: AEROSOLS, FLAMMABLE

Further information
This product may be classified as limited quantity in selected package sizes.

15. Regulatory Information

Federal Regulations

Registration status:
Biocide TSCA, US released / exempt

crop protection product

Crop Protection TSCA, US released / exempt

Chemical TSCA, US blocked / not listed

EPCRA 311/312 (Hazard categories): Refer to SDS section 2 for GHS hazard classes applicable
for this product.

EPCRA 313:
CAS Number Chemical name
67-63-0 2-Propanol

State regulations
State RTK CAS Number Chemical name
NJ 67-63-0 2-Propanol
124-38-9 carbon dioxide
64742-47-8 Distillates, petroleum
PA 67-63-0 2-Propanol
124-38-9 carbon dioxide
64742-47-8 Distillates, petroleum

Safe Drinking Water & Toxic Enforcement Act, CA Prop. 65:

BASF Risk Assessment, CA Prop. 65:

Based on an evaluation of the product's composition and the use(s), this product does not require a
California Proposition 65 Warning.

Labeling requirements under FIFRA

This chemical is a pesticide product registered by the Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements differ from
the classification criteria and hazard information required for safety data sheets, and workplace
labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide
label.
CAUTION:
KEEP OUT OF REACH OF CHILDREN.
Avoid contact with the skin, eyes and clothing.

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Version: 5.0 (30702757/SDS_CPA_US/EN)
Wash thoroughly after handling.

16. Other Information


SDS Prepared by:
BASF NA Product Regulations
SDS Prepared on: 2021/03/16

We support worldwide Responsible Care® initiatives. We value the health and safety of our
employees, customers, suppliers and neighbors, and the protection of the environment. Our
commitment to Responsible Care is integral to conducting our business and operating our facilities in
a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring
the safe and environmentally sound handling of our products, and minimizing the impact of our
operations on society and the environment during production, storage, transport, use and disposal of
our products.

END OF DATA SHEET

Internal

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