Topic 3

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3 lhe,rrnoJ ?

~y-sics
~ ., Thermo.\ CQ"\(fP-t-S
- -- - KE o+ +he roJtide

lntemal er.e~y == 6um of +'rie. PE Q. KE J- a II


mo\ecoles. ·,n °'- csoo~ta()le.
I

texYJpero-\ure_ = rne~ure. Ot -I-he o.ve m~ KE


I
(TJ ot +he mo\eco\es ,n °'-~obsta.nc.e.
CV\i iher fur match~ttc..k..)
heat= trao&\er ot en~y ,b e~( ) -\wo bodie.~ due
(Q) -1-v °'- +erwp~ru\ure d.i~fereoce_ 'oe\w ~ then'\ ,

\~c\ ~·c\
• -\herma I e1ui Ii briurn
t° So.me_ krnperq,ure__)
~l~ c heat ca.po_ci~= e,ne~y neeckd -to rui~e ~e
( c.) ~Hh-l vre of 1"-d' oh~bs~oce
. by 1l(. •

, C.vo.ltr ~ LU. kJ k( ~
1
1

C iron x 0 .4l kJ k ~
~ spec hea~ cap. 0
~ l-he sobs!.

Ex. carper
~ot

o.) Q re~u ireJ. -Iv raise. +he.. kmp ot f-he_ block in ~(:1
'oJ -final kmp ot -s.'/skM 2 Ce,=-0.41 Kl kg' k..~
Cw-= LJ.11:.\ Kf \<..·I
o) Q =Mc.~T c
= 0 S-60 )(. 0. 4lx \0) X ( '80-10')
= 1~1t:L ~ 1Y k;p

bj Q~i,,.en = Or<X.i,ve.&...
y1\:.Lc. DTc.. =: VT'lw CV-, LJTv1
0 .5b>"0 .4~10\(20-T) = 1.5)( ~.;).xlO?> 'f- (T -14)
18 8 \6 - 2'2>5.lT = b300T-1 5 12.0D
0
T?Gl.b C.,1
r----------------------
Lo_lent heed:= eJ'ieITfi y rec~?·,re_ol for a. rno.-\erio. I
to cV\oie ph0-se o/-col'lstni,t \e.M~.

Lt=lolw-t heoJ cl- tsion


O=m C:::t1 I;cl -~ li l:\-~.11 o)
Lv = -11 - vopor·1satio~
(_\ i":\-vi ol -"> ~05}
yY)[AS.5
heat
I
l I l5()o.
l@ _10rc_o
'2>.~ Hodellini a. oas
• 1 mole. == 6.0 lx IOn (- N,. J
(mol)
• mo\ar rY)QSS = mCt SS ot one mole ~ ~(05ta()C.e
11
Q mo ss of i rnol 0~ (. = IJ~
I
~() , o~ 'b = 48~
2
6 . mo.__s~ o~ \0 is nitro~en-lY atoms~
~\'Y\O\t.s *abrns/Molsec.,ole.s \J
1 rn o \ = 1.4~
n = l:l # mal · = 10
25
2
~ /6.b1mob
N,.. b.02 X10 ?>

-Ioto. \ mo..ss : IHx lb.b1~ 12>:> 0 j'

G~s law'.:> (p·;VJTJ .I

~con'::>~n t_ p •con~to.nt V
1 V1 -= Vi. I
1
!p, - . _a-;
: T, T-z. i' ~ !, - - -T1- / ,
- - - - I.
50kP~
5kPet. ~ p~ 'bO\cPo.
0.2>.m. 1'
T~ I it0°( '80°( V? .'
:)

20°C. 5em'!,
i,
'.!> 3
-<>
'?, 8Ox\0 ~ V = 50x l0 ~03
~xlO
-b
_ 5xl0 ox{O -= p
(~1-~~20) /T (?_1-0 +~0) ◊,_l~t80 J . ·,,1 \J~ O.\ ~m ~

~~ 1 T =½i3K=i'~k
0

:;;--
p~ 5.(; kP ~ I
,,
I , r
I
I
-idea\

14m 3 m0- s"::> o~ · co,.~


3Yt
150k.Pa. pV=n RT
<
m. 1
n 'I- i. i I x (3 ~ 1-.212,)
CO2 150 x10 x Iy =
n ~ ??l~.1:5
molo.r mo.~~'. O=lba
C-= IJ. t)1 d rn ().S~ =s 1~. \s ~ LP1 .o 1
CO2..= 12,01 t 2xlb=- 4~.01~ ::: 5 6 2.26 i :=< Ob kV .
- ----- - - --
- - - - - - -

I
· Avero.t lkE of-. o. JY1olecule: 8.3\

or

1.38 xlO-'2~(J k'.._, ) b.01 x1cl1.>

~- lnlema\ erw.~1 o~ +he. 0 3~~ Co.~~rne i+'~ ick,d) .


IE = 0um o~ PE r KE ( iol.eo.\ C/"·s '7 \>c =O) · · ·
. -2~ -11
kE ot ooe.. 'ID'.lk ~ ~ ke,T" ~ .. l.'1>'8(\0-.(oo~m)-:: l51~1(\0 ·

pV=n R.T · ' 1


,

~O I{ \O~x IY = tJ )l ~.'b\ x (~Orl 1:>J v n~ 1~2.05


• I \
' .
16
~I t1=of molecules = ;).2>~ 05 )(. b.01x 10~ ""1. ?:>~)1-dO •
1~ -LI
IE =~urn 0 t KE= 1.b<:)1xlO xl-.51~1 xlO ~10t.tO OOOJ = 1.0~ H)#
• Hicroscopic explo.nation of ~a~ la.ws (bcos 00 T'f\olewb)
* pC i
\J.
=con~+ ..E_
T con~l.
'J con~l Ti :con~t
_ 1

Of')"& · Ti ·

[§ ~ □ ~ ~
T
I '
T I

Tt Tt T con~i. Vt
·"
~ k
i
E1
_-&
KE (Of\:>t. V
kFi ~ le.!>s collis,oro
~
~ :;ame spud ~I" '/ .5econJ
w/ +he w 11 Y
molecoles move l'os!e.r t>p -11con~.
1Ylo ecule~ movt ~l er r/ ~

4 ~
Wore n~l \ Fcon
~ 1 - /
I

, q::Ali~io ~i..
''6P j ( wher'\ malecule-5 Ft(on +h~ llAI) w/ #le ~
1 ~
· hit the woll ) ~ ✓ p~ ,
~
Fi (CTI the v..,all)
pi
J
i Vi

(jm~ \
F =-Llt~ +- la~Uer .6p :?, la.~er F ~-,laraer P

• fl)ola::_ule-:, Mqve 11.i:iler ~--, lo.~ er P


~□
• rnol oc \JI e. s cdlic~e l'YIO 1e_ 0 11,en =.:> lo'"fl er i)

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