Calorimetry

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Mol~ &fec.i~'c ~etrt-
CD rx., L\ T -S -= ~ coJ./qA\ _oc_
VVl~T 0 .s == ~ to..t IVV1 0 1- k
~~1
T~T +~T CD= 'YY'JL ir

~~"'1
s,
-'k i "iti(, De.w:, ~ I ~r ,ci-\i t (kQvi~ I !'cl~ Vt De.vi& i1;,

= Dwu.i?J cf ~u.bstoJl\ce
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s p~He_ He..o:r:
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~w = lrfu .
i7 i · fo'H sh,a,m
""- L1?00 -J / k~ - i<
~ ~ 'Ylof n
s~ ; oJ/Jm C.

Si z- ~ (O(_t / dt'\1- o C == '2.IO0J I~ -K

: ~100 0/ ~-k
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It i ' 1~ ~ o~ >te \,'-4,u d +,, cJ,,M r ivi b~ 1•c.
a
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B ~ f'\19-,e' - - l Pho.!.~,_ 9 Cl_= W\ L

(Q
u.vu+ Mo»-, of s.u bsro.Vl ~ o.,\- C ( ) ~ ~ - temp Q),\ o)-W-l,L t

-, Ql'Yl r -=- Cov\,(,fo,l ~


Cl co..Llt! h1at"Z-i1 poi v-.l-
1'.l"C fV\eJt,''cj fo/v--t
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L+ ::: LoJ-e;J- he,~ of t~OV L

Li\u.iJ ;::=.====- ~ TetY\.r -::: <'111'-~ ~f'J.A)'...l-

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l v .,. Lok~+ ~oJ- d Vllf O~~oifov\ Tunt

Tf l-o~ wo.t~ = 0 ° C.
Tf
LF /oh wa¾e}i = io ~ tr- == 3 '3b KT 11~
L v lo,-.. t,J ate>, ~ 5 yo oJ_ /t-" ~ 2. 2. i', 'il t<J/ ~
T ~ -to)) WQ,fQY\ =- l00°G P-l 'MS 11 'T; Q ::ft: ~ML
Ct -==

TrML
[,11 l~,1)+j
3pt c-dic l-u,ol r ~ .Si-Ope j,
*P>-Jr-ic.ip.k
r TWtf. C40Y'r
Cl ::: Pt = VYV:.ll.T
f-' = ►'vv. d1
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~t~r
G:n=~L
P L~
dt
of CoJo0Wlek,¼ d
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H erJ- Lo c,,c = Heo± C>1oJV\,
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0
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9 [0 ~ ClL = ~Xl,e!Xro+<tox10+
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b a
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= 1550 c.u Jd ~ c:2o::s ~
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Cl = V'M 6, 10

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'X ~ x:2..0 + eo ~ -z.o-t I x 1-0 x 10 o
a_= )~tiT. v
+ SYO X 20
fr + \b 00 t
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c!.©. = J~fl T ~
dx d,t ~ \~ 6 c_oJ, 00

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l-t,
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= l :) r I
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lo½ > G-t~ V\.


~= J_'1-l OOXl +-IX5 YO+I X\XIO O
.:2.. [HD. ::: 1... 0 0 <' c..-(
+ ~ox I + _!_ x 11.8
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~
~ ,..,,lunY\ b~<--k_ +, •~\vM
, =c- S O ~- S 4 D + I OO + ~O -t S
== 175 ctl
~00 = I~>< I '/, (_ T- 0)
~ ~/vtd. -fi\/\o..f ~ . ruAd wux ~ v<11At ~

\ • wo..t~ \\)()a"' +- w ~ o~o "(111\


?..C)"C.. lfJ C.. w@}v,
'1'i'1 · I c.e, -t
Ce.tfip =- eY, ~ / 10~ ~or

/ l• .< = ~o Xj,-D X ( ~ ~Oifca::j -2.0 C. 0 'JQI:, I'


-.::, l.....

Cn~V\ =
;_
~ e,,._; V\ : ID 'X _I XJLO -t- '60 X 10
/2-
= 300
~;<- 1x(,- ~ 0)
~ :=: -30 X ~o XI
~ ~XI 'x (10- T) -== \ 2..C, 0
~T - '-l Q :::a::,o- T •
5 0 ~ WO-fe.>-t , O c.
~ 3T ~110
9 , :::. 1\0 -=- 3G -£6°C
~ 3 oo = i~ax \ ( T- o)
. \ ' e..
l l, l C..
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er
O"l

~~V\ = io )< ~- -=- y 00 col,,


lo~s ~ lO XIX£ 0 = GO o ccJ..,
---- ---- ---~ ""1 1:-.....-.oo:a- ~-::r:,
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v, '

G-tcJ V\ ::: '60 'x I 0


G-t~v\ = 8() X 10 = ~DO
::~oo c~
lo½ ::: ~ cQ. X ~4 () t- ~ X f + I00 X 1
• (;O)('L A__ Lo&~ .. \ X ~L\ C)
== 6Y0c°"-'\
=- 11:6 0

J:.. <t = ~io

~ aio = 1Q x I t T - D)
9
I 'L

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5, ice. -\- w ~ Vt\ • I C..Q.. + ~ teCI..V'{)
ooc. to~
Ir, I~
tcr G0°(,
~ 2.0· (_ &t'JOOL
IA'.) o.,f12)'\ • ~ D°C IA:) 04'" ~ o.J· 0 °L
I G_o.,1' VI =
~
,o ><- ~o
ioO
C,,a.i II) ~ 1-~
\C
J_ X 1
/2_
+I X i 0

LM-;: e:,oX IOX I = 30 ('~


=- GbO L«½ = ~x~ >< 1 + ~'!,,,<;'{O + 1oox I ,,_I
11 CO. ?- ~00 ~ 690

~ m X io ~ '.lO() La-0 {; oc t ~ ~ ~ Q. 'A IX lC)O .:::.100


I

9 vYl :;,. _!z, c;'r, ~ \c e_

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\'loc. l~o c.
-< •~ ~ 0
° c_ t¼.o.-r C-0»\ Yvu.H- 11
\~QC ~~°C

y y'-~ "(__
Q - ~. ~ X ~00 '/- 3 9
',' 4

0
= 3 80 ~I ~ - •C

C. ht\
~ ~- X SO X {s <3~ X 100
I
.1 • "fY> -=
~1 9
YI~ 'I-. ifJ

v-=~~ ~ ~ c. ~ r r V) c.oloN rrtt,hh_ + lAJo.t-Vi


I·~~ ~00~
'YY\'L S'l.X ~ =- 'Yl"l~~.3. X s- '-----
9 ~'W\3$ .1 _ ½
"1Y\ 'L s 1- -t"
"M 1 ~ I = 1§ _ ,-I?_
¼\ '!, ~ "½ I ..(]
lo ~i -r
L\ - ~ ~LJ~ t4T
7 1T- 1½'2.
1tc2-

.71
lf:'X2-% -I~ T-= IGT -12X IG

~ 31 T -= _I .s x -< ~ + I'2- X I6
T ::= '2.0-2.G oe, o·c. J T(')Mf . C> ~ & o.,M i
I~ WO-{"V\ 401) c_
\~O~:: g ~XL1T
z.
R.6 Xi O = l<?:,00 ~ ~ ti T e;y 0
(

-9 ~Uu e-W\IJ = 3 ('.. • C...


J
'\ 0
~ 0
0 ~1-
1- I
3
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7
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r
Cl
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