Answer Key

CARBONYL COMPOUNDS Page # 46
Answers
Exercise-I
1. B 2. C 3. D 4. B 5. D 6. D 7. B
8. C 9. D 10. C 11. A 12. D 13.(i)C(ii)C 14. B
15. D 16. B 17. A 18. A 19. D 20. C 21. C
22. A 23. B 24. B 25. B 26. D 27. C 28. D
29. A 30. D 31. A 32. C 33. A 34. B 35. A
36. B 37. B 38. B 39 C 40. D 41 C 42. D
43. A 44. D 45. C 46. C 47. B 48. D 49. C
50. D 51. C 52. D 53. D 54. C 55. B 56. A
57. D 58. B 59. C 60. B 61. D 62. B 63. B
64. B
Exercise-II
1. C,D 2. AB 3. A,B,CD 4. A,B 5. B,D 6. A,B,C,D 7. B,C

8. A 9. A,B,C 10. A,D 11. A,B,C,D 12. A 13. D 14. C
15. A–R ; B – Q ;C – Q; D – P 16. A  P,S ; B  Q, S ; C  Q, S ; D  R , S
17. A  P ; B  Q ; C  R ; D  S
Exercise-III
1. (a) CH3—CH2—CH2—OH (b) CH3—CH2—CH2—OH (c) CH3—CH2—CH2—OH

OH OH OH
(d) CH3—CH2— CH —CH3 (e) CH3 —CH2— CH —CCH (f) CH3 —CH2— CH — Ph
O
(g) CH3—CH2— CH —OCH3 (h) CH3–CH2–CH (i) CH3—CH2—CH= N —Ph
O
OCH 3
OH
(j) CH3 —CH2— CH — N —CH3 (k) C—C—C=N—OH (l) CH3—CH2—CH=N—NH2

CH3
(m) CH3—CH2—CH3 (p) P-Nitro phenyl hydrazone (o) semi carbazane

OH
(p) CH3—CH2—CH=CH—CH3 (q) CH3—CH2— CH —CN (r) CH3—CH2—CO2H
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, [email protected]
Page # 47 CARBONYL COMPOUNDSE
O
2. (a) C—C—C— C —OH (b) CH3–CH2–CH2–CH=C–CH2–CH3 (c) C—C—C—C—C=N—OH

CHO OH
OH
(d) C—C—C— C–Ph (e) Ph–CH=C–CH 2–CH3 (f) C—C—C— CH —CCH
O CHO
(g) C—C—C—C (h) C—C—C—C (i) 2º alcohol
O
OH
(j) Cyanohydrine (k) 1° alcohol (l) CH3—CH2—CH2— CH — CH—CO2H
Et
3. (a) 3 > 2 > 1 > 4 4. R —Mg—X

OH OH
(b) (i) (CH3)2 CCN (ii) C6H5 CCN
CH3
•• •••
•
(CH3)3C O O
5. C CH2 OCH3 (CH3) 3C
Cl C–CH2OCH3
Cl
O
(CH3)C–C–CH2OCH3
O
6. (a) CH3— CH —NH—CH2—CH2—OH (b) (c) CHCl3 + C— OH

N
CH3 |
H
7. HO  /Br2; H2/Ni; NaOH
O O O
CH2CH2CH2CH2–Br CH2 CH2 CH2 CH2 –Br



Acid Base reaction
8.
(CH3)3CO
O
O CHO
C— CH 3
9. (a) (X) CH3 (Y) (b) CH2—C—CH3
CHO O CH3 O
O Ph
CH =
Ph
10. (a) CH CH—S—CH—Ph
2
(b)
3 2
Cl
Exercise-IV (A)
1. C 2. B 3. C 4. D 5. B 6. D 7. D
8. A 9. B 10. D 11. B 12. ABD 13. B 14. A
15. C 16. A 17. C 18. C 19. A 20. C 21.C
22. B 23. C 24. A 25. C
26. A  P,Q,S;B  Q,R;C  Q,R,S;D  Q,R
,R
27. A—R,S;B—P,Q:C—P,Q,R;D—P,S (OR) A—R; B—P,Q; C—P,Q,R; D—P
28. B 29. A 30. D 31. B 32. A 33. B 34 B

35. A 36. D
Exercise-IV (B)
3 CH MgBr
1. HCHO   CH CH OH
H / H O 3 2
2
CH3CH2OH  PCC
 CH3CHO
2. False
3. A: CH3— CH —CH3
OH
B: CH3—CH=CH2
C:CH3—C  CH
D: CH3COCH3
4. Cl3C–CHO NaOH
 CHCl3+HCOONa
Page # 49 CARBONYL COMPOUNDSE
3 4 AgNO /NH OH
5. CH3CH2CHO  CH3CH2COOH
Oxidation
2 5 PO
2CH3CH2COOH 
 (CH3CH2CO)2O
H 2O
O O O
OH

6.  H3C—CH2— CH — CH — C —H 
2 H3C—CH2— C —H NaOH  H C—CH —CH= C — C —H
 H 2O 3 2
CH3 CH3
+ –
CHO COOH NO2 NH2 N2Cl CN
NaOH
KCN
NaNO2
7. PCC
    
 

CaO HCl
CHO
–H2O
CH–CH2–CHO CH=CH–CHO
8. +CH3CHO NaOH

OH
9. sodium potassium tartrate which is known as Rochells salt.
CHO CH2OH
O O
10. + H— C —H 50
% 
NaOH
 + H— C —ONa
OCH3 OCH3
Sodium formate
11. dil
KMnO CH3
4  H3C OH OH
H3C CH3
Hydroxylation
O O
H3C CH3 HIO

4  H3C–C–CH2–CH2–CH2–C–CH3
OH OH
CH 3
O O H3C OH
—
OH –H2O
H3C–C–CH2–CH2–CH2–C–CH3
O O
12. C6H 5–C–CH3 and C6H5–C–CH3
N–OH HO–N
syn anti (isomers)
O
CHO CHO CH2CHO COOH O–CH=CH2
C–CH3
or
13. (A) (B) (C) (D) (E)
OCH3 CH2OH OH CH3 OH

OH
14. Me3C—CH=CH2 HCl

 Me2 C —CHMe2+Me3C— CH–Me
Cl Cl
(A) (B) (C)
alc. KOH
Ozonolysis NaOH
(A) HCHO+Me3C–CHO
(F) (G)
HCOONa+Me3C–CH2OH(1°alcohol)
CONHCH 3
CN COOH
CH2–CN CH = C
CH=C CH=C
15. (A) (B) (C) (D)
(i) SOCl2
(D) (ii) CH3NH2
16. In structure (P) both the rings are present in acetyl form therefore it will not hydrolyse in solution that
why Tollen’s solution connot react with this.
In structure (Q) one ring present in the form of hemiacetal. This will hydrolysed in solution it can reduce
Tollen’s solution.
17. (X) (Y) CH3— C —(CH2)4—CH=O 18. 1
CH3

Answer Key

Uploaded by

Copyright:

Available Formats

Answer Key

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Answer Key

Uploaded by

Copyright:

Available Formats

CARBONYL COMPOUNDS Page # 46

1. C,D 2. AB 3. A,B,CD 4. A,B 5. B,D 6. A,B,C,D 7. B,C

1. (a) CH3—CH2—CH2—OH (b) CH3—CH2—CH2—OH (c) CH3—CH2—CH2—OH

(j) CH3 —CH2— CH — N —CH3 (k) C—C—C=N—OH (l) CH3—CH2—CH=N—NH2

(m) CH3—CH2—CH3 (p) P-Nitro phenyl hydrazone (o) semi carbazane

(p) CH3—CH2—CH=CH—CH3 (q) CH3—CH2— CH —CN (r) CH3—CH2—CO2H

2. (a) C—C—C— C —OH (b) CH3–CH2–CH2–CH=C–CH2–CH3 (c) C—C—C—C—C=N—OH

(j) Cyanohydrine (k) 1° alcohol (l) CH3—CH2—CH2— CH — CH—CO2H

3. (a) 3 > 2 > 1 > 4 4. R —Mg—X

(b) (i) (CH3)2 CCN (ii) C6H5 CCN

6. (a) CH3— CH —NH—CH2—CH2—OH (b) (c) CHCl3 + C— OH

CH2CH2CH2CH2–Br CH2 CH2 CH2 CH2 –Br

28. B 29. A 30. D 31. B 32. A 33. B 34 B

9. sodium potassium tartrate which is known as Rochells salt.

H3C CH3 HIO

12. C6H 5–C–CH3 and C6H5–C–CH3

OCH3 CH2OH OH CH3 OH

14. Me3C—CH=CH2 HCl

17. (X) (Y) CH3— C —(CH2)4—CH=O 18. 1

You might also like