DPP Iupacquestions

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1

QUALITY SPEAKS KOTA


CHEMISTRY
IUPAC
DPP
1. The hybrid state of C-atoms which are attached to a 8. The number of C-atoms in second member of an ester
single bond with each other in the following structure is/are :
are : CH2 = CH – C  CH (1) 2 (2) 3
(1) sp2, sp (2) sp3, sp (3) 4 (4) 5
2 2
(3) sp , sp (4) sp2, sp3
9. Which of the following is an example of symmetrical
2. The third member of the homologous series of or simple ether :
aliphatic aldehydes has the structure : (1)
(1) CH3CH2CHO (2) CH3(CH2)2CHO
(3) CH3COCH2CH3 (4) CH3COCH3
(2) CH3 – O – CH2 – CH3
3. Molecular formula C4H8O2 represents :- (3) CH3 – CH2 – O – CH2 – CH2 – CH3
(1) An acid only (4)
(2) An ester only
(3) An alcohol only
(4) An acid and an ester also
10. The number of hetero atoms present in the following
4. The higher homologue of dimethylamine compound is/are :
(CH3 – NH – CH3) has the structure :
(1)

(2) CH3 – CH2 – CH2 – NH2


(1) 2 (2) 3
(3) CH3 – NH – CH2 – CH3
(3) 1 (4) 4
(4)
11. The minimum number of carbon atoms in an alkane
5. The third member of the family of alkenynes has the having four primary carbon atoms are :-
molecular formula :- (1) 4 (2) 8
(1) C6H6 (2) C5H6 (3) 5 (4) 6
(3) C6H8 (4) C4H4
12. Which of the following compound has sp-hybridised
6. The number of olefinic bonds in the given compound carbon atom :-
is/are :- (1) CH3COOH (2) CH3COCH3
(3) CH3CH2CN (4) CH2 = CH – CH = CH2

13. In compound HC  C – CH2 – CH – CH – CH3, the


(1) 2 (2) 3 C2 – C3 bond is the type of :-
(3) 1 (4) 4 (1) sp - sp2 (2) sp3 - sp3
3
(3) sp - sp (4) sp2 - sp2
7. The number of acetylinilic bonds in the given
14. Which of the following represents the given mode of
compound is/are :
hybridization sp2-sp2-sp-sp from left to right :-
(1) H2C = CH – C  CH
(2) HC  C – C  CH
(1) 2 (2) 3 (3) H2C = CH – CH = CH2
(3) 1 (4) 4 (4) H2C = C = C = CH2
2

QUALITY SPEAKS KOTA


15. Which of the following pair of compounds are 22. Common name of the given compound is :-
homologues :-
(1) 1-Propanol & 2-Propanol
(2) Ethanol & Propanal (1) vinyl acetate (2) acryl acetate
(3) Acetone & Acetaldehyde (3) methyl acrylate (4) Vinyl ethanoate
(4) Acetic acid & Butyric acid
23. A primary amine has amino group (–NH2) attached
16. Which of the following homologous series has to:-
incorrect general formula :- (1) A primary carbon atom only
(1) Alkyne CnH2n–2 (2) A secondary carbon atom only
(2) Alkanol CnH2n+2O (3) A tertiary carbon atom only
(4) A primary, secondary or tertiary carbon atom
(3) Alkanal CnH2n+1O
(4) Carboxylic acid CnH2nO2
24. Which of the following area secondary radicals :
(a) CH3 – CH – C2H5
17. The Cl – C – Cl bond angle in 1, 1, 2, 2 – tetrachloro (b) CH2 = C – CH3
ethene and tetrachloro methane respectively are:- (c) CH2 = CH –
(1) 120° and 109.5° (d) (CH3)2CH –
(2) 90° and 109.5° (1) a, b, c (2) a, d, c
(3) 109.5° and 90° (3) b, c, d (4) a, b, d
(4) 109.5° and 120°
25. Examine the following structures :
18. Minimum number of carbon atoms present in an ester
are :-
(1) 2 (2) 1
(3) 4 (4) 3
Which of the following statement is correct :
(1) A is tertiary alcohol while B is tertiary amine
19. Which of the following has general formula CnH2n
(2) A is primary alcohol while B is primary amine
(1) Only Alkyne
(3) A is tertiary alcohol while B is primary amine
(2) Only Alkane (4) A is primary alcohol while B is tertiary amine
(3) Aromatic hydrocarbon
(4) Alkene & cyclic Alkane 26. Which of the following is not a correct match

20. Which compound has alkyne group


(1)
(1) C7H14 (2) C10H22
(3) C9H16 (4) C16H32

21. Which of the following are tertiary radicals :


(2)

(3) HC  C – CH2 –  Propargyl


(4) CH2 = CH – CH2 –  Allyl

27. The IUPAC name for isobutyl chloride is :-


(1) 2-Methyl-2-chloro butane
(2) 2-Chloro-2-methyl butane
(1) a and b (2) b and c (3) 1-Chloro-2-methyl propane
(3) a and c (4) b and d (4) 2-Methyl-3-chloro propane
3

QUALITY SPEAKS KOTA


28. The IUPAC name of given compound is :- 33. The IUPAC name of the compound is :-

(1) 3-Carboxy-2-pentene (1) 4-Amino-2-methoxy-1-amino-2-butene


(2) 4-Amino-3-methoxy-2-butenamide
(2) 2-Ethylidene butanoic acid (3) 2-Methoxy-1,4-diamino-2-butenal
(3) 2-Ethyl-2-butenoic acid (4) 1-Amino-2-methoxy-3-amino propene
(4) 3-Ethyl-2-buten-4-oic acid
34. The IUPAC name of CH3 – CH2 – NH – CH3 is :
29. The IUPAC name for the given structure is :- (1) Methyl ethyl amine
(2) 1-methyl amino ethane
(3) N-methyl ethan amine
(4) N-ethyl methan amine

35. The IUPAC name for the compound is :-


(1) 3-Isopropyl-4-methylhexane
(2) 4-Isopropyl-3-methylhexane
(3) 3-Ethyl-2, 5-dimethylhexane (1) Cyclohexanoyl chloride
(2) Cyclohexane carbonyl chloride
(4) 2-Ethyl-3-isopropylpentane
(3) 1-Chloro cyclohexanal
(4) Chloro cyclohexyl methanal
30. The IUPAC name for
36. The IUPAC name of is

(1) 1-Amino-1-oxo ethane, 1-chloro ethanal (1) 3-Methyl-2-penten-4-yne


(2) 1-Amino ethanal, acetoyl chloride (2) 3-Methyl-3-penten-1-yne
(3) 3-Methyl-4-pentyn-1-ene
(3) 1-Oxoethanamine, ethanoyl chloride
(4) 3-Methyl pentenyne
(4) Ethanamide, Ethanoyl chloride
37. The IUPAC name of the structure is :-
31. The number of carbon atoms in the principle chain of
the given compound are :-

(1) 3-Isopropyl-5,5-dimethyl heptane


(1) 7 (2) 5 (2) 5-Ethyl-3,3,6-trimethyl heptane
(3) 4 (4) 6 (3) 3,3-Dimethyl-5-isopropyl heptane
(4) 3-Ethyl-2,5,5-trimethyl heptane
32. The IUPAC name of given compound is :

38. has the IUPAC name :

(1) 3-Chloro-1-ethyl-2-methyl cyclopentane


(1) Methyl tertiarybutyl acetylene (2) 1-Chloro-3-ethyl-2-methyl cyclopentane
(2) t-Butyl propyne (3) 4-Chloro-1-ethyl-5-methyl cyclopentane
(3) 4, 4-Dimethyi-2-pentyne (4) All are correct
(4) 1, 3, 3, 3-Tetramethyl ethyne
4

QUALITY SPEAKS KOTA


45. The IUPAC name of the given compound is :

39. The IUPAC name of is

(1) 1-Methyl-5-ethyl cyclohex-2-ene


(2) 5-Ethyl-3-methyl cyclohex-1-ene (1) 1,2,3-Tricarbonitrile propane
(2) Propane-1,1,1-tricarbylamine
(3) 4-Ethyl-6-methyl cyclohex-1-ene (3) Propane-1,2,3-tricarbonitrile
(4) 1-Ethyl-5-methy! cyclohex-3-ene (4) 3-Cyano pentane dicyanide

40. in IUPAC called : 46. Number of carbon atoms in the principle carbon chain
in the given compound are :-

(1) Cyano methanal


(2) 2-Oxo ethane nitrile
(3) Cyano ethanal (1) 4 (2) 3
(4) Formonitrile (3) 2 (4) 5

47. Wrong IUPAC name is :


41. The IUPAC name for the compound is :- (1) CH3CH2CONH2 - Propanamide
(2) CH3CH2COOCH - Methyl propanoate

(1) 2-Acetyl prop-1-ene (3) - 2-Methyl pent-3-ene


(2) Pent-1-en-4-one (4) - 2-Ethoxy butane
(3) Pent-4-en-2-one
(4) Formyl propene
48. The IUPAC name of the compound :
42. Which is incorrect IUPAC name :-
(1) 3-Pentyne
(2) 3-Methyl-2-butanone
(3) 2-Ethyl-3-methyl-1-butene
(1) 2-Methyl cyclopent-1-en-2-ol
(4) 3-Ethyl-2-methyl pentane
(2) 3-Methyl cyclopent-2-en-1-ol
(3) 2-Methyl cyclopent-2-en-1-ol
43. The IUPAC name of is : (4) 3-Methyl cyclopent-1-en-2-ol

(1) 1-Methoxy-4-amino benzene 49. The IUPAC name of the is :


(2) Aminophenyl methyl ether
(1) Acetic anhydride
(3) 4-Methoxy aniline
(2) Formyl ethanoate
(4) None of the above (3) Butane- 2, 4-dione
(4) Ethanoic methanoic anhydride
44. The IUPAC name of the given compound is :
50. The IUPAC name of given compound is :

(1) 3-Hydroxymethyl pentane-1,4,5-triol


(2) 3-Hydroxyethyl butane-1,2,4-triol (1) 3,3-Dimethyl-1-hydroxy cyclohexane
(3) 4-Hydroxyethyl-1,2,4-trihydroxy butane (2) 1,1-Dimethyl-3-hydroxy cyclohexane
(4) 3-Hydroxymethyl pentane-1,2,5-triol (3) 3,3-Dimethyl-1-cyclohexanol
(4) 1,1-Dimethyl-3-cyclohexanol
5

QUALITY SPEAKS KOTA


51. IUPAC name of (CH3)2CHCH(CH3)2 is :- 54. CH3 – CH = CH – C  CH has IUPAC name :
(1) 2,2-Dimethyl butane (1) Pent-2-en-4-yne
(2) 2,3-Dimethyl butane (2) Pent-4-yn-2-ene
(3) 2,4-Dimethyl butane (3) Pent-1-yn-3-ene
(4) 1-Methyl pentane (4) Pent-3-en-1-yne

52. IUPAC name of CH2 = CH – CH2 – Cl is :- 55. The IUPAC name of the following compound
(1) Allyl chloride
(2) 1-Chloro-3-propene
(3) 3-Chloro-1-propene
(4) Vinyl chloride (1) 3, 4 - Dimethyl octane
(2) 3 - sec pentyl pentane
53. The IUPAC name of the following group (3) 3, 4 - Diethyl hexane
is : (4) 3, 4 - Dimethyl hexane

56. Correct IUPAC name is :-


(1) Isopropenyl (1) 3-Methyl-2-ethylpentane
(2) 1-Methylethenyl (2) 2-Ethyl-3-methylpentane
(3) 2-Methylethylnyl (3) 3-Ethyl-2-methylpentane
(4) None of the above (4) 2-Ethyl- 2-methylpentane
6

QUALITY SPEAKS KOTA


Answer Key
1. (1) 15. (4) 29. (3) 43. (3)
2. (1) 16. (3) 30. (4) 44. (4)
3. (4) 17. (1) 31. (2) 45. (3)
4. (3) 18. (1) 32. (3) 46. (2)
5. (3) 19. (4) 33. (2) 47. (3)
6. (1) 20. (3) 34. (3) 48. (3)
7. (3) 21. (3) 35. (2) 49. (4)
8. (2) 22. (1) 36. (2) 50. (3)
9. (4) 23. (4) 37. (4) 51. (2)
10. (1) 24. (4) 38. (2) 52. (3)
11. (3) 25. (3) 39. (2) 53. (2)
12. (3) 26. (2) 40. (2) 54. (4)
13. (3) 27. (3) 41. (3) 55. (3)
14. (1) 28. (3) 42. (1) 56. (3)

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