Scribd Logo
Upload

Welcome to Scribd!

  • 5 views

    Holiday Home Work 2024-25 Class XII

    Uploaded by

    rk2680735

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Holiday Home Work 2024-25 Class XII

    Uploaded by

    rk2680735
    5 views3 pages

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    5 views3 pages

    Holiday Home Work 2024-25 Class XII

    Uploaded by

    rk2680735

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    SIKHSHA NIKETAN

    HOLIDAY HOMEWORK
    CLASS-XII
    SESSION 2024-25

    1. Concentrated nitric acid used in laboratory work is 68% nitric acid by mass in aqueous solution.
    What should be the molarity of such a sample of the acid if the density of the solution is
    1.504 g mL-1 ?
    2. Calculate the molarity of each of the following solutions:

    a) 30 g of Co(NO3)2. 6H2O in 4.3 L of solution

    b) 30 mL of 0.5 M H2SO4 diluted to 500 mL.

    3. If the solubility product of CuS is 6X 10-16, calculate the maximum molarity of CuS in aqueous
    solution.

    4. 100g of liquid A (molar mass 140 g mol-1) was dissolved in 1000 g of liquid B ( Molar mass 180 g
    mol-1). The vapour pressure of pure liquid B was found to be 500 Torr. Calculate the vapour pressure
    of pure liquid A and its vapour pressure in the solution, if the total vapour pressure of the solution is
    475 Torr.

    5. Boiling point of water at 750 mm Hg is 99.63oC. How much sucrose is to be added to 500 g of
    water such that it boils at 100oC? Molal elevation constant for water is 0.52 K kg mol-1.

    6. 1.00g of a non-electrolyte solute dissolved in 50 g of benzene lowered the freezing Point of


    benzene by 0.40 K. The freezing point depression constant of benzene is 5.12 K kg mol-1. Find the
    molar mass of the solute.

    7. At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the
    osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its
    concentration?

    8. 19.5 g of CH2FCOOH is dissolved in 500g of water. The depression in the freezing point of water
    observed is 1.0oC. Calculate the van’t Hoff factor and dissociation constant of fluroacetic acid.

    9. Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added
    to 250g of water. Ka= 1.4 X 10-3, Kf = 1.86 K kg mol-1.

    10. The freezing point of benzene decreases by 2.12 K when 2.5 g of benzoic acid (C6H5COOH) is
    dissolved in 25 g of benzene. If benzoic acid forms a dimer in benzene, calculate the van’t Hoff factor
    and percentage association of benzoic acid.

    11. Using the standard electrode potentials given below, predict if the reaction between the
    following is feasible:
    i) Fe3+(aq) and Br-(aq)

    ii) Ag(s) and Fe3+(aq)

    E0Br2/Br- =1.09V , E0Ag+/Ag =0.80V , E0Fe3+/Fe2+ =0.77V

    12. Write the cell reaction and calculate the e.m.f of the following cell at 298 K:

    Sn(s) │Sn2+ (0.004M) ‖ H+(0.020M)) ‖ H2(g) (1 bar) │ Pt(s)

    (Given : EᴓSn2+/Sn = -0.14V)

    13. A volatile cell is et up at 25OC with the following half cell ;

    Al/Al3+ (0.001M) and Ni/Ni2+ (0.50 M)

    Calculate the cell voltage.

    [EᴓNi2+/Ni = -0.25V, EᴓAl3+/Al = -0.166V ]

    14. calculate the emf of following cell at 25OC:

    Sn(s) │Sn2+ (0.001M) ‖ H+(0.01M)) ‖ H2(g) (1 bar) │ Pt(s)


    1
    EᴓSn2+/Sn = -0.14V ; EᴓH+/ H2= 0
    2

    15. Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10.

    16. Represent the cell in which the following reaction takes place

    Mg(s) + 2Ag+(0.0001) M → Mg2+(0.13) M + 2Ag(s)

    Calculate E(cell), If Eᴓcell = +3.17V

    17. Calculate the equilibrium constant of the reaction:

    Cu(s) + 2Ag+(aq) → Cu2+(aq) + 2Ag(s)

    Given, Eᴓcell = 0.46 V

    18. The standard electrode potential for Daniell cell is 1.1 V. calculate the standard Gibbs
    energy for the reaction:

    Zn(s) + Cu+(aq) → Zn2+(aq) + Cu(s)

    19. Calculate the standard cell potentials of galvanic cells in which reactions take place.

    a) 2Cr(s) + 3Cd2+(aq) → 2Cr2+(aq) + 3Cd

    b) Fe2+ (aq) + Ag+(aq) →Fe3+(aq) + Ag(s)


    Calculate the ∆r Gᴓ and equilibrium constant of the reaction.

    20. In the button cells widely used in watches and other devices the following reaction takes place:

    Zn(s) + Ag2O(s) + H2O(l) → Zn2+(aq) + 2Ag (s) + 20H-

    Determine ∆r Gᴓ and Eᴓ for the reaction.

    XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX

    You might also like