Chem!stry: Notes On Atomic Structure - Macroconcept: Models

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Name: …………………… ( )

Chem!stry Class: ………………

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Notes on Atomic Structure – Macroconcept: Models – Answers

Learning Outcomes:
• By the end of the unit, students should understand the concept of atom.
• Students will demonstrate their understanding of atomic structure by being able to…
(a) State the relative charges and approximate relative masses of a proton, a neutron and an
electron.
(b) Describe, with the aid of diagrams, the structure of an atom as containing protons and
neutrons (nucleons) in the nucleus and electrons arranged in shells (energy levels).
(c) Define proton (atomic) number and nucleon (mass) number.
(d) Interpret and use symbols such as 126C.
(e) Define the term isotope.
(f) Deduce the numbers of protons, neutrons and electrons in atoms and ions given proton and
nucleon numbers.
(g) Draw the electronic configurations of the first twenty elements (hydrogen to calcium).
(h) Understand that atoms with noble gas electronic configurations are inert.
(i) Understand that atoms of metallic elements react by losing their valence electrons to form
positively charged ions (cations) with a noble gas electronic configuration.
(j) Understand that atoms of non-metallic elements react by gaining electrons into their valence
shell to form negatively charged ions (anions) with a noble gas electronic configuration.
(k) Understand generalisations about models and how models are used by scientists to visualise
and understand complex ideas.

• The concept of scale, from the extremely small to the extremely large.
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1. What is the definition of atom?
An atom is the smallest part of a chemical element that demonstrates all of the typical
properties of that element.

2. Atoms are extremely small (see diagram on page 1). Even with the use of modern technology,
it is not possible to observe the detailed structure of an individual atom. On what evidence do
scientists base their understanding of atomic structure?
Atomic structure is based on experimental evidence, e.g. the fact that atoms can be broken
down into smaller particles (protons and electrons) which in turn can be deflected by positively
and negatively charge electrodes. Other experiments (e.g. Rutherford’s gold leaf experiment)
demonstrate that atoms are mostly empty space with a small, dense nucleus at the centre.

3. Modern understanding of atomic structure is a conceptual model. Ideas about atomic structure
may change as new evidence is discovered. What are some generalisations about models?
Models simulate real world processes. Models facilitate testing and prediction. Models can be
physical, conceptual or mathematical. Models simplify real world processes or behaviours.
Models involve variables.

4. At the centre of every atom is a small dense nucleus. This is composed of two sub-atomic
particles known as protons (which carry a charge of +1) and neutrons (which carry a charge
of 0)*. A third sub-atomic particle known as an electron (which carries a charge of –1) orbits
around the centre of the atom in energy levels that are often referred to as electron shells. The
inner shell (closest to the centre) can hold a maximum number of 2 electrons while the second
and third shells can hold a maximum number of 8 electrons each.
*Note: There is one exception. The nucleus of a hydrogen atom does not contain any neutrons.

5. Label the diagram shown below to summarise the fundamental structure of an atom.

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6. Complete the table shown below to summarise the fundamental properties of protons,
neutrons and electrons.

Name of Sub Particle’s Location Particle’s Particle’s


Atomic Particle in Atom Relative Charge Relative Mass

Proton nucleus +1 1

Neutron nucleus 0 1

orbits the nucleus in


Electron –1 1
/1840
electron shells

7. Explain why atoms are electrically neutral.


The number of negatively charged electrons in an atom (each electron has a charge of –1) is
exactly equal to the number of positively charged protons (each proton has a charge of +1).

8. (a) Define the term atomic number.


The number of protons in the nucleus of a single atom of the chemical element.
(b) Define the term mass (nucleon) number.
The total number of protons and neutrons in the nucleus of a single atom of the element.
(c) How are the number of neutrons in an atom calculated?
Number of neutrons = mass number (protons and neutrons) – atomic number (protons).

9. Which particle, the proton, neutron or electron, determines which chemical element an atom
belongs to (i.e. the number of which particle is unique for each chemical element)?
The number of protons is unique for each chemical element and determines which chemical
element an atom belongs to, e.g. 6 protons = carbon atom and 12 protons = magnesium atom.

10. How many protons, neutrons and electrons do the atoms of the following elements contain?
(a) 7
Li
3 protons = 3 neutrons = 7 – 3 = 4 electrons = 3
(b) 19
9 F protons = 9 neutrons = 19 – 9 = 10 electrons = 9
(c) 23
11 Na protons = 11 neutrons = 23 – 11 = 12 electrons = 11

11. (a) What is the relationship between an element’s position in the Periodic Table and the total
number of electrons contained within a single atom of that element?
The total number of electrons in a single atom of the chemical element is the same as the
element’s atomic number (number of electrons = number of protons for a neutrally
charged atom).

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(b) What is the relationship between an element’s position in the Periodic Table and the
number of electron shells in an atom of that chemical element?
The number of electron shells in a single atom of the chemical element is the same as the
element’s Period number (Periods = horizontal rows).
(c) What is the relationship between an element’s position in the Periodic Table and the
number of electrons in the valence shell of an atom of that chemical element?
The number of electrons in the valence shell of a single atom of the chemical element is
the same as the units value of the element’s Group number (Groups = vertical columns).
12. Based upon its electronic configuration, how can you determine whether an atom belongs to a
metallic element or a non-metallic element?
In general, atoms with only 1, 2 or 3 electrons in their valence shells belong to metallic
elements. Atoms with 4, 5, 6, 7 or 8 electrons in their valence shells belong to non-metallic
elements.
13. In the space provided below, draw the full electronic configuration of (a) an atom of oxygen
(b) an atom of aluminium.

(a) Electronic configuration of a single (a) Electronic configuration of a single


oxygen atom. aluminium atom.

14. (a) Define the term isotope.


Isotopes are atoms of the same chemical element with the same number of protons in
their nuclei (same atomic number) but a different number of neutrons (different mass
number).
(b) Complete the table below to show the numbers of each sub-atomic particle present in the
three isotopes of carbon; 126C, 13 14
6 C and 6 C.

Isotope of Number of Number of Number of


Carbon Protons Electrons Neutrons
12
C
6 6 6 12 – 6 = 6

13
C
6 6 6 13 – 6 = 7

14
C
6 6 6 14 – 6 = 8

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(c) There are two isotopes of the chemical element chlorine. 75% of naturally occurring
chlorine is 35 37
17Cl and 25% of naturally occurring chlorine is 17Cl. Use this information to

explain why the relative atomic mass of chlorine is not a whole number.
75 chlorine atoms out of 100 have a mass of 35. Their total mass = 75  35 = 2625
25 chlorine atoms out of 100 have a mass of 37. Their total mass = 25  37 = 925
The total mass of 100 chlorine atoms = 2625 + 925 = 3550
Hence the average mass of a single chlorine atom = 3550  100 = 35.5

15. The electronic configurations of helium, neon and argon are given below.

Helium – He Neon – Ne Argon – Ar

(a) What is unique about the electronic configurations of helium, neon and argon?
Atoms of the Group 18 elements all have complete / full valence shells. This is known as
the noble gas electronic configuration.
(b) How do the unique electronic configurations of helium, neon and argon affect their
reactivity?
Elements whose atoms have noble gas electronic configurations are very stable and
therefore very unreactive. They are often described as being chemically inert.

16. Atoms react to lose or gain electrons so that they can obtain the electronic configuration of a
Noble gas. Atoms do this to become chemically stable. During a chemical reaction, the
number of protons and neutrons in the nuclei of the atoms remains the same.
(a) What happens to the charge on a neutral atom if it gains electrons to complete its valence
electron shell?
If an atom gains electrons to complete its valence shell, then there will be more negative
electrons than positive protons, resulting in the formation of a negative ion (anion).

(b) What happens to the charge on a neutral atom if it loses electrons to complete its valence
electron shell?
If an atom loses electrons to complete its valence shell, then there will be more positive
protons than negative electrons, resulting in the formation of a positive ion (cation).

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17. The diagram below shows the full electronic configuration of a sodium atom.

With the aid of a diagram, explain how a sodium atom reacts to obtain a noble gas electronic
configuration.
• If the sodium atom loses the single
electron in its valence shell, then the old
valence shell will no longer exist. The
second electron shell from the nucleus will
become the new valence shell, and it is
complete with 8 electrons. Therefore, by
losing its single valence electron, sodium
obtains a noble gas electronic
configuration. Note: The sodium is now a
positively charged ion, because it has one
more (+) proton that it has (–) electrons.

18. The diagram below shows the full electronic configuration of a chlorine atom.

With the aid of a diagram, explain how a chlorine atom reacts to obtain a noble gas electronic
configuration.

• The chlorine atom has 7 electrons in its


valence shell. If it gains 1 more electron,
then it will obtain the electronic
configuration of a noble gas. Note: The
chlorine is now a negatively charged
chloride ion because it contains one more
(–) electron than it has (+) protons.

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Self-checklist on Atomic Structure

Yes, I No, I need


Aspect of atomic structure:
understand more help
I understand that Scientists use models to represent and
understand things that are complex and / or cannot be
1.
observed directly (because they are either extremely small
 
or extremely large).
I understand that atoms are the building-blocks of all
matter; solids, liquids and gases. A knowledge and
2.
understanding of atoms helps to explain how the world
 
around us works.
I understand that atoms are made-up of smaller (sub-
3.
atomic) particles called protons, neutrons and electrons.
 
I understand that, although atoms, protons, neutrons and
4. electrons are too small to be observed, there is strong  
experimental evidence to support their existence.
I can recall the relative masses and charges of protons,
5.
neutrons and electrons.  
I am able to draw the basic structure of an atom, clearly
6. showing the locations of the protons, neutrons, electrons  
and electron shells.
I can define the terms atomic number and mass number,
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and I can interpret symbols such as 11 Na to state how
7.
many protons, neutrons and electrons there are in a
 
particular atom.
I am able to define the term isotope, and I understand why
8. the relative atomic mass of an element is not always a  
whole number.
I understand that atoms of the different chemical elements
9. have different numbers of protons and different numbers of  
electrons (in different electronic configurations).
I am able to draw the electronic configurations of the first
10. 20 chemical elements (when given an element’s atomic  
number or allowed to reference the Periodic Table).
I know that the Noble gases (Group 18) have a complete
11.
valence shell, and this makes them chemically stable.
 
I understand that metals can obtain the same electronic
configurations as Noble gases, and hence become
12.
chemically stable, by losing all of their valence electrons
 
and forming positively charged ions (cations).
I understand that non-metals can obtain the same
electronic configurations as Noble gases, and hence
13. become chemically stable, by gaining electrons to  
complete their valence electron shells and forming
negatively charged ions (anions).

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• Scan the QR code below for the answers to this assignment.

http://www.chemist.sg/chemical_bonding/notes_atomic_structure/notes_atomic_structure_ans.pdf

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Periodic Table

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