Class XI-Unit-3-Assignment

VISHWA BHARATI PUBLIC SCHOOL, NOIDA
CLASS: XI (2024-25)
SUBJECT: CHEMISTRY
Assignment Type: Objective and Subjective Questions
Unit 3: Classification of Elements and Periodicity in Properties Prepared By: Ms. Manisha Sareen
PART-1: SUBJECTIVE QUESTIONS
1. a. Considering the elements B, Al, Mg and K, write the correct order of their metallic character.
b. Considering the elements B, C, N, F and Si, write the correct order of their non-metallic
character.
c. Arrange the following ions in order of increasing size ;Be2+,Cl–, S2-, Na+ ,Mg2+, Br– .
2. Explain why 4th Period contains 18 elements and not 8 or 32.
3. Electronic configuration of four elements A, B, C and D are given below:

(a) 1s22s22p6 (b) 1s22s22p4 (c) 1s22s22p63s1 (d) 1s22s22p5
Write in the correct order of increasing tendency to gain electron.
4. Ionization enthalpies of elements of second period (Li to Ne) are given below:
Ionization enthalpy/kJ mol-1: 520, 899, 801, 1086, 1402, 1314, 1681, 2080.
a. What is the general trend of I.E. across the period?
b. Explain deviation from general trend in the second period.
5. Arrange the elements N, P, O and S in the order of

a. Increasing first ionization enthalpy.
b. Increasing non-metallic character.
Give reason for the arrangement assigned.
6. Why is ∆iH1 of Mg more than that of Al?
7. The first (∆iH1) and (∆iH2) ionization enthalpies (kJ mol-1) of a few elements designed by roman
numerals are shown below:
∆iH1 ∆iH2
I 2372 5251
II 520 7300
III 900 1760
IV 1680 3380
Which of the above elements is likely to be
i) a reactive metal
ii) a reactive nonmetal
iii) a noble gas
iv) a metal that forms a stable binary halide of the formula AX2 (X = Halogen)
Vbpsnoida/XI/2024-25/Chemistry
8. Which of the following pairs of elements has lesser electron gain enthalpy?
a. N or O
b. F or Cl
c. Be or B.
Explain your answer.
9. a. Predict the position of the element in the periodic table satisfying the configuration: (n-1) d1
ns2 for n=4.
b. To which block, group & period does the element with atomic number 50, 37, 29 and 18
belong?
10. Variation in atomic radii (in pm) of the elements are given below. Using the given data,
answer the following questions:
a. How do atomic radii vary in a period and in a group?

b. Why Ga is smaller than Al?
c. Which element has least Ionisation enthalpy and why?
d. Which group elements are most metallic?
PART-2: OBJECTIVE TYPE QUESTIONS
1. Which Statement is not correct for the element with an electronic configuration - 1s2, 2s2,
2p6, 3s1?
a. This is a non-metal
b. This creates basic oxide.
c. This element is with a low electron affinity.
d. This is a monovalent electropositive.
2. Which one is the smallest ion?

a. Al3+
b. Mg+
c. Na+
d. Ba2+
3. IP1 and IP2 of Mg are 178 and 348 kcal mole–1. The energy required for the reaction
Mg → Mg2+ + 2e– is
a. +170 kcal
b. +526 kcal
c. –170 kcal
d. –526 kcal
4. The IP1, IP2, IP3, IP4 and IP5 of an element are 7.1, 14.3, 34.5, 46.8, 162.2 eV respectively.
The element is likely to be
a. Na
b. F
c. Si
d. Ca
5. Which is correct in the following

a. Radius of Cl atom is 0.99 Å, while that of Na+ ion is 1.54 Å
b. Radius of Cl atom is 0.99 Å while that of Na atom is 1.54 Å
c. Radius of Na atom is 0.95 Å, while that of Na+ ion is 1.54 Å
d. The radius of Cl atom is 0.95 Å while that of Cl– ion is 0.81 Å
6. Find the successive elements of the periodic table with ionisation energies, 2372, 520 and
890 kJ per mol respectively
a. Li, Be, B
b. H, He, Li
c. B, C, N
d. He, Li, Be
7. For the same value of n, the penetration power of orbital follows the order
a. s = p = d = f
b. p > s > d > f
c. f < d < p < s
d. s < p < d < f
8. Which of the reactions will need the maximum amount of energy?
a. Na → Na+ + e–
b. Ca+ → Ca++ + e–
c. K+ → K2++ e–
d. C2+ → C3+ + e–
9. The correct order of electronegativity is

a. Cl > F > O > Br
b. F > O > Cl > Br
c. F > Cl > Br > O
d. O > F > Cl > Br
10. Which one will have the highest 2nd ionisation energy?
a. 1s2 2s2 2p6 3s1
b. 1s2 2s2 2p4
c. 1s2 2s2 2p6
d. 1s2 2s2 2p6 3s2
11. In the modern periodic table, the number of period of the element is the same as
a. principal quantum number
b. atomic number
c. azimuthal quantum number
d. atomic mass
12. The correct order for the size of I, I+, I– is

a. I > I– > I+
b. I > I+ > I–
c. I– > I > I+
d. I+ > I– > I
13. Across the period the atomic size decreases due to

a. shielding effect
b. photoelectric effect
c. increase in nuclear force of attraction
d. decrease in nuclear force of attraction
14. An element having low value of ionization energy and low value of electron affinity is likely
to belong to
a. Group 1
b. Group 2
c. Group 17
d. Group 18
15. F has Electron Affinity less than

a. Na
b. K
c. Cl
d. O

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VISHWA BHARATI PUBLIC SCHOOL, NOIDA

PART-1: SUBJECTIVE QUESTIONS

2. Explain why 4th Period contains 18 elements and not 8 or 32.

3. Electronic configuration of four elements A, B, C and D are given below:

5. Arrange the elements N, P, O and S in the order of

6. Why is ∆iH1 of Mg more than that of Al?

a. How do atomic radii vary in a period and in a group?

2. Which one is the smallest ion?

5. Which is correct in the following

9. The correct order of electronegativity is

12. The correct order for the size of I, I+, I– is

13. Across the period the atomic size decreases due to

15. F has Electron Affinity less than

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