Chemistry Assignment 3 Class 11

PP3/CHEM11 /23-
DELHI PUBLIC SCHOOL VADODARA

Academic Session 2022 -23
Practice Paper - 3
Class : XI
SUBJECT: Chemistry
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1 The order of screening effect of the electrons of s, p, d and f orbitals for the given shell of an atom on
their outer shell electrons will:
(a) s > p > d > f
(b) f > p > s > d
(c) p < d < s > f
(d) f > d > p > s
2 Among halogens, correct order of the amount of the energy released in the given electron gain (electron
gain enthalpy) will:
(a) F < Cl < Br < I
(b) F > Cl > Br > I
(c) F < Cl > Br > I
(d) F < Cl < Br < I
3 The period number at the long form of the given periodic table is equal to
(a) the magnetic quantum number of any given element of the period.
(b) an atomic number of any given element of the period.
(c) maximum Principal quantum number of any given period element.
(d) maximum Azimuthal quantum number of any given period element.
4 The correct increasing order of electronegativity is

(a) Bi < P < S < Cl
(b) P < Bi < S < Cl
(c) S < Bi < P < Cl
(d) Cl < S < Bi < P
5 The chemistry of lithium is very similar to that of magnesium even though they are placed in different
groups. Its reason is:
(a) Both are found together in nature
(b) Both have nearly the same size
(c) Both have similar electronic configuration
(d) The ratio of their charge and size (i.e. charge density) is nearly the sameAnswer
6 The elements in which the given electrons progressively fill in the 4f-orbitals are called….
(a) actinoids
(b) transition elements
(c) lanthanoids
(d) halogens
7 The largest ion among the following is

(a) Na+ (b) Al3+
(c) Mg2+ (d) Si4+
8 The correct order of first ionization enthalpy among following elements, Be, B, C, N and O is
1
(a) B < Be < C < O < N
(b) B < Be < C < N < O
(c) Be < B < C < N < O
(d) Be < B < C < O < N
9 Electronic configurations of the following four elements, A, B, C and D, have given below :
(A) 1s2 2s2 2p6
(B) 1s2 2s2 2p4
(C) 1s2 2s2 2p6 3s1
(D) 1s2 2s2 2p5
Which among the following is the correct order of increasing the tendency to gain the electrons :
(a) A < C < B < D
(b) D < A < B < C
(c) D < B < C < A
(d) A < B < C < D
10 Which of the following utermost electronic configuration represents the last element of the existing p-
block in the 6th period.
(a) 4f14 5d10 6s2 6p4
(b) 5f 14 6d10 7s2
(c) 4f 14 5d10 6s2 6p6
(d) 7s2 7p6
11 The size of an anion is larger than the parent atom ….

(a) Due to increased repulsion among the electrons.
(b) Due to decrease in effective nuclear charge.
(c) Due to increased in effective nuclear charge.
(d) Both (a) and (b)
12 The group number, number of valence electrons, and valency of an element with the atomic number 16 ,
respectively, are:
(a) 16, 5 and 2
(b) 15, 5 and 3
(c) 16, 6 and 2
(d) 15, 6 and 2
13 Assertion (A): Boron has a smaller first ionisation enthalpy than beryllium.
Reason (R): The penetration of the 2s electron to the nucleus is more than the 2p electron; therefore, the
2p electron is more shielded by the inner core of the electron than 2s electrons.
(a) Assertion is correct, reason is correct; reason is a correct explanation for assertion.
(b) Assertion is correct, reason is correct; reason is not a correct explanation for assertion.
(c) Assertion is correct, reason is incorrect.
(d) Assertion is incorrect, reason is correct.
14 Assertion : larger the size of an atom greater is the electronegativity.

Reason : Electronegativity refers to the tendency of atom to attract the share electrons with other atom.
2
15 Assertion (A): Electron gain enthalpy becomes less negative as we go down a group.
Reason (R): The size of the atom decreases on going down the group, and the added electron would be
more closer to the nucleus.
16 Explain why the electron gain enthalpy of the elemental fluorine is less negative than the elemental
chlorine.
17 Define the ionisation enthalpy. Discuss the factors affecting ionisation enthalpy of elements and their
trends in the periodic table.
18 Among the given elements B, Al, C and Si,

(i) which of the following elements has the highest first ionisation enthalpy?
(ii) which element contains the most metallic character? Explain your answer in each case.
19 The first member of each group of the representative elements, s and p-block elements, shows abnormal
behaviour. Illustrate with the help of two examples.
20 How will you explain that the first ionisation enthalpy of sodium is quite lower than that of magnesium;
however, its second ionisation enthalpy is quite higher than that of magnesium?
21 Give reasons for:

(a) The radius of the Na+ cation is less than that of the Na atom.
(b) Among alkali metals Cesium is the least electronegative.
22 Arrange the following elements N, P, O and S in the order of increasing first ionisation enthalpy and
explain.
23 In terms of the period and group and block, where would you locate the element with Z =116?
24 Explain the following:

(a) Electronegativity of the given elements increases as we move from left to right in the periodic table.
(b) Ionisation enthalpy decreases in a group from top to bottom.
(c) The electron gain enthalpies of noble gases are positive.
25 In the modern periodic table, elements are arranged in order of their increasing atomic number related to
the electronic configuration. Depending upon the type of the orbitals that receive the last electron, the
periodic table elements are categorised into four blocks, viz, s, p, d and f. The modern periodic table has
7 periods and 18 groups. Each period starts with the filling of the new energy shell. By the Aufbau
principle, the seven periods (1 to 7) contain 2, 8, 8, 18, 18, 32 and 32 elements, respectively. The
seventh period is still incomplete. To avoid today’s periodic table being too long, the two series of the f-
block elements, called lanthanoids and actinoids, are placed at the bottom of the main body of today’s
periodic table.
(a) The element having the atomic number 57 belongs to which group, period and the block.
(b) Representative belong to which blocks?
(c) In the modern periodic table, What does the period indicates?
(d) write the general outer electronic configuration of
(i) d-block elements. (ii) f-block elements.
3
26 How many groups and periods are there in the modern periodic table? How do the atomic size and
metallic character of elements vary as we move:
(a) down a group?
(b) from left to right in a period?
27 State any two limitations to Mendeleev’s classification. How does electronic configuration of atoms
change in period with increase in atomic number?
28 Given below are some elements of the modern periodic table:

4Be, 9Fe, 14Si, 19K, 20Ca
(i) Select the element that has one electron in the outermost shell and write its electronic
configuration.
(ii) Select two elements that belong to the same group. Give reason for you answer.
(iii) Select two elements that belong to the same period. Which one of the two has larger
atomic size?
29 Illustrate by taking examples of transition elements and non-transition elements that oxidation states of
elements are largely based on electronic configuration.
30 Discuss the factors affecting electron gain enthalpy and the trend in its variation in the periodic table.
31 What are the advantages of the long form of periodic table over Mendeleev’s periodic table? Explain
with examples.
32 Write the outer electronic configuration of alkali metals and justify their position in the periodic table.
33 Justify giving suitable examples— “The Properties of the elements are a periodic function of their
atomic numbers”.
34 Discuss and compare the trend in ionisation enthalpy of the elements of group 1 with those of group 17
elements.
35 p-Block elements can form acidic, basic and amphoteric oxides. Explain each by giving one example
and write the reactions of these oxides with water.
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PP3/CHEM11 /23-

DELHI PUBLIC SCHOOL VADODARA

4 The correct increasing order of electronegativity is

7 The largest ion among the following is

11 The size of an anion is larger than the parent atom ….

14 Assertion : larger the size of an atom greater is the electronegativity.

18 Among the given elements B, Al, C and Si,

21 Give reasons for:

24 Explain the following:

28 Given below are some elements of the modern periodic table:

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