Date Printed: 06/09/2023 Product: 8848B1NL

Safety Data Sheet

Prepared in Accordance with HCS 29
C.F.R. 1910.1200

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 8848B1NL Revision Date: 12/05/2022

Product Name: POLYCLAD 777 Supercedes Date: 04/15/2019

FAST-SET PART B
Component of
1.2 Relevant identified uses of the multicomponent industrial
substance or mixture and uses coatings - Industrial use.
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Global Inc.

2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:

Contact Carboline Technical Services at
1-800-848-4645

Schlereth, Ken - [email protected]

Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)

Emergency telephone number:
CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Eye Irritation, category 2

2.2 Label elements

Symbol(s) of Product

Signal Word
Warning

Named Chemicals on Label

None

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HAZARD STATEMENTS

Eye Irritation, category 2 H319 Causes serious eye irritation.

PRECAUTION PHRASES

P280 Wear protective gloves/protective clothing/eye protection/

face protection.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so.
Continue rinsing.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous ingredients
Name According to EEC EINEC No. CAS-No. % Classifications
TETRAHYDROXYPRO 203-041-4 102-60-3 25 - <50 H319 Eye Irrit. 2
PYLEHTYLENDIAMINE

TITANIUM DIOXIDE 236-675-5 13463-67-7 2.5 - <10

CARBON BLACK 215-609-9 1333-86-4 1.0 - <2.5

SILANE 219-785-8 2530-85-0 1.0 - <2.5 H315-319-335 Eye Irrit. 2, Skin Irrit. 2, STOT
SE 3 RTI

ORGANIC TIN 201-039-8 77-58-7 0.1 - <1.0 H312-314-317-341-360-372-410 Acute Tox. 4 Dermal, Aquatic
Chronic 1, Muta. 2, Repr. 1A,
Skin Corr. 1, Skin Sens. 1,
STOT RE 1

CAS-No. M-Factors
102-60-3 0
13463-67-7 0
1333-86-4 0
2530-85-0 0
77-58-7 1
Remarks: CAS No 13463-67-7: Note 10

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.

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4.2 Most important symptoms and effects, both acute and delayed
Irritating to eyes, respiratory system and skin. May be harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
When symptoms persist or in all cases of doubt seek medical advice.

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Beware of vapours accumulating to form explosive concentrations. Vapours
can accumulate in low areas. Vapors may spread long distances and ignite.
FOR SAFETY REASONS NOT TO BE USED: No Information

5.2 Special hazards arising from the substance or mixture

No Information

5.3 Advice for firefighters

SPECIAL FIREFIGHTING PROCEDURES: In the event of fire, wear self-contained breathing apparatus. Evacuate personnel
to safe areas. Use NIOSH approved respiratory protection. Use water spray to cool unopened containers.
SPECIAL FIREFIGHTING PROTECTION EQUIPMENT: No Information

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. To avoid ignition of vapours
by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment. For
personal protection see section 8.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up

Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).
6.4 Reference to other sections

No Information

7. Handling and Storage

7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Ensure all equipment is
electrically grounded before beginning transfer operations. Do not get in eyes, on skin, or on clothing. Use only with
adequate ventilation/personal protection. Avoid breathing vapors, mist or gas. Wash thoroughly after handling.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and at the end of workday. When using, do not eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Heat, flames and sparks.

STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight.

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7.3 Specific end use(s)

No specific advice for end use available.

8. Exposure Controls/Personal Protection

8.1 Control parameters
Ingredients with Occupational Exposure Limits
(US)

Name CAS-No. ACGIH TWA ACGIH STEL ACGIH Ceiling

TETRAHYDROXYPROPYLEHTYLENDIAMI 102-60-3 N/E N/E N/E
NE
TITANIUM DIOXIDE 13463-67-7 10 mg/m3 N/E N/E
CARBON BLACK 1333-86-4 3 MGM3 N/E N/E
SILANE 2530-85-0 N/E N/E N/E
ORGANIC TIN 77-58-7 N/E N/E N/E

Name CAS-No. OSHA PEL OSHA STEL

TETRAHYDROXYPROPYLEHTYLENDIAMIN 102-60-3 N/E

N/E
E

TITANIUM DIOXIDE 13463-67-7 15 MGM3

N/E

CARBON BLACK 1333-86-4 3.5 MGM3

N/E

SILANE 2530-85-0 N/E

N/E

ORGANIC TIN 77-58-7 0.10 mg/m3

N/E

FURTHER ADVICE: Refer to the regulatory exposure limits for the workforce enforced in each country. Some components may
not have been classified under the EU CLP Regulation.

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must
be done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION: Safety glasses with side-shields.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier. Lightweight
protective clothing
OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Use only in an area equipped with explosion proof
exhaust ventilation. Ensure adequate ventilation, especially in confined areas.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Viscous Liquid, Various Colors
Physical State Liquid

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Odor Slight

Odor threshold N/D

pH N/D
Melting point / freezing point (°C) N/D
Boiling point/range (°C) 149 F (65 C) - 595 F (313 C)
Flash Point (°C) 330F (165.6C)
Evaporation rate Slower Than Ether

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 0.5 - 36.0

limits
Vapour Pressure, mmHg N/D
Vapour density Heavier than Air
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information

VOC Content g/l: 0

Specific Gravity (g/cm3) 1.05

10. Stability and Reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous polymerisation does not occur.

10.4 Conditions to avoid

Heat, flames and sparks.

10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition products

Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

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11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Skin Irritation, category 2

Corrosivity: Serious Eye Damage, category 1

Sensitization: Unknown

Repeated dose toxicity: Unknown

Carcinogenicity: Unknown

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

STOT-single exposure: Unknown

STOT-repeated exposure: Unknown

Aspiration hazard: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

Chemical Name Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist
CAS-No.
LC50
25000 mg/kg, No No
13463-67-7 TITANIUM DIOXIDE oral (rat)
Not Available Not Available
Information Information
8000 mg/kg
1333-86-4 CARBON BLACK oral, rat
Not Available Not Available

2530-85-0 SILANE Not Available Not Available 0.000 0.000

2071 mg/kg, 2000 mg/kg,

77-58-7 ORGANIC TIN oral, rat rat
Not Available 0.000 0.000

Additional Information:
No Information

12. Ecological Information

12.1 Toxicity:

EC50 48hr (Daphnia): Unknown

IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

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12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

TETRAHYDROXYPROPYLEHTYLENDIAMIN
102-60-3 No information No information No information
E
13463-67-7 TITANIUM DIOXIDE No information No information No information
1333-86-4 CARBON BLACK No information No information No information
2530-85-0 SILANE No information No information No information
77-58-7 ORGANIC TIN No information No information No information

13. Disposal Considerations

13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be
taken to an approved waste handling site for recycling or disposal.

14. Transport Information

14.1 UN number None
14.2 UN proper shipping name Not Regulated
Technical name N/A
14.3 Transport hazard class(es) None
Subsidiary shipping hazard N/A
14.4 Packing group N/A
14.5 Environmental hazards Unknown
14.6 Special precautions for user Unknown
EmS-No.: N/A

14.7 Transport in bulk according to Annex II Unknown

of MARPOL 73/78 and the IBC code

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -

CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Serious eye damage or eye irritation

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Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No. %

METHYL ALCOHOL 67-56-1 0.0096249

ETHYL ACRYLATE 140-88-5 0.0005115
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:

No TSCA 12(b) components exist in this product.

U.S. State Regulations: As follows -
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS-No.

CASTOR OIL 8001-79-4
POLYETHER POLYOL 25322-69-4
ALUMINOSILICATE 1318-02-1
Pennsylvania Right-To-Know

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS-No.

CASTOR OIL 8001-79-4
POLYETHER POLYOL 25322-69-4
ALUMINOSILICATE 1318-02-1
CALIFORNIA PROPOSITION 65

WARNING: Cancer and Reproductive Harm -- www.P65Warnings.ca.gov

International Regulations: As follows -

* Canadian DSL:

All chemical ingredients included on inventory (DSL)

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.

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H319 Causes serious eye irritation.

H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H360 May damage fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.

Reasons for revision

No Information

The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.

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