Thermodynamics - DTS - JEE Adv - 2

Date Planned : __ / __ / __ Daily Tutorial Sheet-2 Expected Duration : 90 Min
Actual Date of Attempt : __ / __ / __ JEE Advanced (Archive) Exact Duration :_________
16. An insulated container contains 1 mole of a liquid, molar volume 100 ml, at 1 bar. When liquid is steeply
pressed to 100 bar, volume decreases to 99 ml. Find H  U for the process. (2004)
17. 1 mole of a monoatomic ideal gas at T K undergoes adiabatic expansion under a constant external
pressure of 1 atm from 1 L to 2 L. The final temperature (in K) would be : (2005)
T 2
(A) (B) T
2/3 3  0.0821
2
2
(C) T (D) T
3  0.0821
18. A monotomic ideal gas undergoes a process in which the ratio of P to V at any instant is constant and
equals to 1. What is the molar heat capacity of the gas ? (2006)
4R 3R 5R
(A) (B) (C) (D) 0
2 2 2
19. The direct conversion of A to B is difficult, hence it is carried out by the following shown
path ? Given S( A  C)  50 e.u., S(C  D)  30 e.u., S(D  B)   20 eu where e.u. is entropy
unit, then S(A  B) is :
(A)  60 e.u. (B)  100 e.u. (2006)

(C)  60 e.u. (D) 100 e.u.
*20. N2  3H2 ↽ ⇀ 2NH3. Which is correct statement if N2 is added at equilibrium condition ? (2006)
(A) The equilibrium will shift to forward direction because according to IInd law of the
thermodynamics the entropy must increase in the direction of spontaneous reaction.
(B) The condition for equilibrium is G N  3GH  2G NH , where G is Gibbs free energy per mole of
2 2 3
the gaseous species measured at that partial pressure. The condition of equilibrium is unaffected
by the use of catalyst, which increases the rate of both the forward and backward reactions to
the same extant.
(C) The catalyst will increase the rate of forward reaction by  and that of backward reaction by .
(D) Catalyst will not alter the rate of either of the reaction.
21. The value of log10 K for reaction A ↽ ⇀ B is :
(Given:  r H298 K   54.07 kJ mol 1,  r S298 K  10 J K 1 mol 1 and R  8.314 JK 1 mol 1 ;
2.303  8.314  298  5705) (2007)
(A) 5 (B) 10 (C) 95 (D) 100
22. For the process: H2O(l)(1bar, 373 K)  H2O(g)(1bar, 373 K), the correct set of thermodynamic
parameters is : (2007)
(A) G  0, S   ve (B) G  0, S   ve
(C) G   ve, S  0 (D) G   ve, S   ve
VMC | Thermodynamics 68 DTS-2 | JEE Advanced (Archive)

23. Statement I: For every chemical reaction at equilibrium, standard Gibbs energy of reaction is zero.
Statement II: At constant temperature and pressure, chemical reactions are spontaneous in the
direction of decreasing Gibbs energy. (2008)
(A) Statement-I is True, Statement-II is True and Statement-II is a correct explanation for
Statement-I.
(B) Statement-I is True, Statement-II is True and Statement-II is NOT a correct explanation for
Statement-I.
(C) Statement-I is True, Statement-II is False.
(D) Statement-I is False, Statement-II is True.
24. Assertion : There is a natural asymmetry between converting work to heat and converting heat to work.
Reason : No process is possible in which the sole result is the absorption of heat from a reservoir and its
complete conversion into work. (2008)
(A) Statement-I is True, Statement-II is True and Statement-II is a correct explanation for
Statement-I.
(B) Statement-I is True, Statement-II is True and Statement-II is NOT a correct explanation for
Statement-I.
(C) Statement-I is True, Statement-II is False.
(D) Statement-I is False, Statement-II is True.
25. Among the following the state function(s) is (are) : (2009)

(A) internal energy (B) irreversible expansion work
(C) reversible expansion work (D) molar enthalpy
26. One mole of an ideal gas is taken from a to b

along two paths denoted by the solid and the
dashed lines as shown in the graph below. If the
work done along the solid line path is w s and
that along the dotted line path is w d , then the
integer closest to the ratio wd / ws is :
(2010)
27. To an evacuated vessel with movable piston under external pressure of 1 atm, 0.1 mol of He and 1.0 mol
of an unknown compound (vapour pressure 0.68 atm. at 0°C) are introduced. Considering the ideal gas
behaviour, the total volume (in litre) of the gases at 0°C is close to : (2011)
28. Match the transformations in Column I with appropriate option in Column II. (2011)
Column I Column II
(A) CO2(s)  CO2(g) (p) Phase transition
(B) CaCO3(s)  CaO(s)  CO2(g) (q) Allotropic change
•
(C) 2 H  H2 (g) (r) H is positive
(D) P(white, solid)  P(red, solid) (s) S is positive

(t) S is negative

29. Match the thermodynamics processes given under Column I with the expressions given under
Column II. (2011)
Column I Column II
(A) Freezing of water at 273 K and 1 atm (p) q 0
Expansion of 1 mol of an ideal gas into a vacuum under
(B) (q) w 0
isolated conditions
Mixing of equal volumes of two ideal gases at constant Ssys  0
(C) (r)
temperature and pressure in an isolated container
Reversible heating of H2 (g) at 1 atm from 300 K, followed
(D) (s) U  0
by reversible cooling to 300 K at 1 atm
(t) G  0
*30. For an ideal gas, consider only P  V work in going from an initial state X to the final state Z. The final
state Z can be reached by either of the two paths shown in the figure. Which of the following choice(s) is
(are) correct? [Take S as change in entropy and W as work done]. (2012)
(A) S x  z  S x  y  S y  z
(B) Wx  z  Wx  y  Wy  z
(C) Wx  y  z  Wx  y
(D) S x  y  z  S x  y

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Date Planned : / / __ Daily Tutorial Sheet-2 Expected Duration : 90 Min

Actual Date of Attempt : / / JEE Advanced (Archive) Exact Duration :_______

unit, then S(A  B) is :

(A)  60 e.u. (B)  100 e.u. (2006)

21. The value of log10 K for reaction A ↽ ⇀ B is :

2.303  8.314  298  5705) (2007)

(A) 5 (B) 10 (C) 95 (D) 100

(C) G   ve, S  0 (D) G   ve, S   ve

VMC | Thermodynamics 68 DTS-2 | JEE Advanced (Archive)

25. Among the following the state function(s) is (are) : (2009)

26. One mole of an ideal gas is taken from a to b

that along the dotted line path is w d , then the

integer closest to the ratio wd / ws is :

(D) P(white, solid)  P(red, solid) (s) S is positive

VMC | Thermodynamics 69 DTS-2 | JEE Advanced (Archive)

VMC | Thermodynamics 70 DTS-2 | JEE Advanced (Archive)

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