SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Sikafloor®-264 (B)

Product code : 000000121422

Type of product : liquid

Recommended use of the chemical and restrictions on use

Product use : Epoxy coating, Product is not intended for consumer use

Manufacturer or supplier's details

Company : Sika (NZ) Ltd.
85-91 Patiki Road
Avondale
Auckland AKL 1026

Telephone : +64 9 820 2900

Emergency telephone num- : 0800 734 607

ber

Telefax : +64 9 828 4091

E-mail address : [email protected]

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable Liquids : Category D

Acute toxicity (Oral) : Category D

Acute toxicity (Dermal) : Category D

Skin corrosion : Category C

Serious eye damage : Category A

Skin sensitisation : Category B

Toxic to Reproduction : Category B

Aquatic toxicity (Acute or : Category B

Chronic)

Ecotoxic to soil environment : Category B

Ecotoxic to terrestrial verte- : Category C

brates

GHS label elements

1 / 11
SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

Hazard pictograms :

Signal word : Danger

Hazard statements : H227 Combustible liquid.

H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H361 Suspected of damaging fertility or the unborn child.
H411 Toxic to aquatic life with long lasting effects.
H422 Toxic to the soil environment.
H433 Harmful to terrestrial vertebrates.

Precautionary statements : Prevention:

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
Response:
P301 + P312 IF SWALLOWED: Call a POISON
CENTER/doctor if you feel unwell.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 IF INHALED: Remove victim to fresh air and keep
at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P322 Specific measures (see supplemental first aid instructions
on this label).
P333 + P313 If skin irritation or rash occurs: Get medical ad-
vice/ attention.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam for extinction.
P391 Collect spillage.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:

2 / 11
SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

P501 Dispose of contents/ container to an approved waste

disposal plant.

Other hazards which do not result in classification

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Polyaminoamide

Hazardous components
Chemical name CAS-No. Concentration (%)
benzyl alcohol 100-51-6 >= 30 - < 50
3-aminomethyl-3,5,5-trimethylcyclohexylamine 2855-13-2 >= 10 - < 20
m-phenylenebis(methylamine) 1477-55-0 >= 10 - < 20
Hydrocarbons, C9, aromatics 64742-95-6 >= 1 - < 10
Phenol, dodecyl-, branched 121158-58-5 >= 1 - < 10
2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 >= 1 - < 10

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Consult a physician.
Show this safety data sheet to the doctor in attendance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with difficul-
ty.

In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-
sue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Keep eye wide open while rinsing.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.

Most important symptoms : Health injuries may be delayed.

and effects, both acute and corrosive effects
delayed sensitising effects
Gastrointestinal discomfort

3 / 11
SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

Allergic reactions
Dermatitis
See Section 11 for more detailed information on health effects
and symptoms.
Harmful if swallowed or in contact with skin
May cause an allergic skin reaction.
Causes serious eye damage.
Suspected of damaging fertility or the unborn child.
Causes severe burns.

Notes to physician : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Carbon dioxide (CO2)

Unsuitable extinguishing : Water

media

Specific hazards during fire- : Do not allow run-off from fire fighting to enter drains or water
fighting courses.

Hazardous combustion prod- : No hazardous combustion products are known

ucts

Specific extinguishing meth- : Collect contaminated fire extinguishing water separately. This
ods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Deny access to unprotected persons.
gency procedures

Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Normal measures for preventive fire protection.

fire and explosion

Advice on safe handling : Do not breathe vapours or spray mist.

4 / 11
SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

Avoid exceeding the given occupational exposure limits (see

section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitisation problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Follow standard hygiene measures when handling chemical
products

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

Conditions for safe storage : Store in original container.

Keep in a well-ventilated place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Store in accordance with local regulations.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
m-phenylenebis(methylamine) 1477-55-0 WES-Ceiling 0.1 mg/m3 NZ OEL
Further information: Skin absorption
C 0.1 mg/m3 ACGIH
Hydrocarbons, C9, aromatics 64742-95-6 TWA 200 mg/m3 ACGIH
(total hydrocarbon
vapor)
Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.

Hand protection : Chemical-resistant, impervious gloves complying with an ap-

proved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.

5 / 11
SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

Eye protection : Safety eyewear complying with an approved standard should

be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : yellow

Odour : amine-like

Odour Threshold : No data available

pH : ca. 11

Melting point/range / Freezing : No data available

point

Boiling point/boiling range : No data available

Flash point : ca. 68 °C (154 °F)

Method: closed cup

Evaporation rate : No data available

Flammability : No data available

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapour pressure : 4.9996 hPa (3.750 mmHg)

Relative vapour density : No data available

Density : ca. 1 g/cm3 (20 °C (68 °F) ())

Solubility(ies)
Water solubility : insoluble

Partition coefficient: n- : No data available

octanol/water

Auto-ignition temperature : ca.

420 °C (788 °F)

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

6 / 11
SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

Viscosity, kinematic : > 20.5 mm2/s (40 °C)

Explosive properties : No data available

Molecular weight : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardous reac- : Stable under recommended storage conditions.

tions

Conditions to avoid : No data available

Incompatible materials : No data available

No decomposition if stored and applied as directed.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Harmful if swallowed or in contact with skin
Components:
benzyl alcohol:
Acute oral toxicity : LD50 Oral (Rat): 1,620 mg/kg

Acute inhalation toxicity : LC50 (Rat): > 4.178 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist

3-aminomethyl-3,5,5-trimethylcyclohexylamine:
Acute oral toxicity : LD50 Oral (Rat): 1,030 mg/kg

Acute dermal toxicity : LD50 Dermal (Rabbit): > 2,000 mg/kg

m-phenylenebis(methylamine):
Acute oral toxicity : LD50 Oral (Rat): 930 mg/kg

Acute inhalation toxicity : LC50 (Rat): 1.34 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist

Acute dermal toxicity : LD50 Dermal (Rat): > 3,100 mg/kg

Hydrocarbons, C9, aromatics:

Acute oral toxicity : LD50 Oral (Rat): > 2,000 mg/kg

Acute dermal toxicity : LD50 Dermal (Rabbit): > 2,000 mg/kg

Phenol, dodecyl-, branched:

7 / 11
SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

Acute oral toxicity : LD50 Oral (Rat): 2,140 mg/kg

Acute dermal toxicity : LD50 Dermal (Rabbit): 5,000 mg/kg

Skin corrosion/irritation
Causes severe burns.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Skin sensitisation: May cause an allergic skin reaction.
Respiratory sensitisation: Not classified based on available information.
Components:
3-aminomethyl-3,5,5-trimethylcyclohexylamine:
Assessment: The product is a skin sensitiser, sub-category 1A.
Result: The product is a skin sensitiser, sub-category 1A.

Chronic toxicity

Germ cell mutagenicity

Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Suspected of damaging fertility or the unborn child.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:
benzyl alcohol:
Toxicity to fish : LC50 (Fish): > 100 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h

3-aminomethyl-3,5,5-trimethylcyclohexylamine:
Toxicity to algae : ErC50 (Desmodesmus subspicatus (green algae)): > 10 - 100
mg/l
Exposure time: 72 h

m-phenylenebis(methylamine):

8 / 11
SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

Toxicity to fish : LC50 (Oryzias latipes (Japanese medaka)): > 10 - 100 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10 - 100 mg/l
aquatic invertebrates Exposure time: 48 h

Hydrocarbons, C9, aromatics:

Toxicity to algae : (Pseudokirchneriella subcapitata (green algae)): 2.6 - 2.9
mg/l
Exposure time: 72 h

Phenol, dodecyl-, branched:

Toxicity to fish : LC50 (Fish): 0.14 mg/l
Exposure time: 96 h
Method: see user defined free text

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 0.01 - 0.1 mg/l
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202

M-Factor (Acute aquatic tox- : 10

icity)

M-Factor (Chronic aquatic : 10

toxicity)

2,4,6-tris(dimethylaminomethyl)phenol:
Toxicity to algae : EC50 (Scenedesmus capricornutum (fresh water algae)): > 10
- 100 mg/l
Exposure time: 72 h

Persistence and degradability

No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : An environmental hazard cannot be excluded in the event of
mation unprofessional handling or disposal.
Very toxic to aquatic life with long lasting effects.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Send to a licensed waste management company.

9 / 11
SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

SECTION 14. TRANSPORT INFORMATION

International Regulations

IATA-DGR
UN/ID No. : UN 1760
Proper shipping name : Corrosive liquid, n.o.s.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine, solvent
naphtha)
Class : 8
Packing group : III
Labels : 8
Packing instruction (cargo : 856
aircraft)
Packing instruction (passen- : 852
ger aircraft)
IMDG-Code
UN number : UN 1760
Proper shipping name : CORROSIVE LIQUID, N.O.S.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine, solvent
naphtha)
Class : 8
Packing group : III
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

NZS 5433
UN number : UN 1760
Proper shipping name : CORROSIVE LIQUID, N.O.S.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine, solvent
naphtha)
Class : 8
Packing group : III
Labels : 8

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
International Chemical Weapons Convention (CWC) : Not applicable
Schedules of Toxic Chemicals and Precursors

10 / 11
SAFETY DATA SHEET

Sikafloor®-264 (B)
Version 0.0 SDS Number: 000000121422 Revision Date: 2016/09/16

HSNO Approval Number

HSR002659
HSNO Controls
Approved handler certificate not required.
HSNO tracking not required.
Refer to EPA user guide to the HSNO control regulations for further information.
The components of this product are reported in the following inventories:
NZIoC : On the inventory, or in compliance with the inventory

SECTION 16. OTHER INFORMATION

Date format : dd.mm.yyyy

The information contained in this Safety Data Sheet corresponds to our level of knowledge at
the time of publication. All warranties are excluded. Our most current General Sales Condi-
tions shall apply. Please consult the product data sheet prior to any use and processing.

11 / 11