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“The Right to Information, The Right to Live” “Step Out From the Old to the New”

IS 309 (2005): Compressed Oxygen gas [CHD 6: Industrial

Gases]

“!ान $ एक न' भारत का +नम-ण”

Satyanarayan Gangaram Pitroda
“Invent a New India Using Knowledge”

“!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता ह”

है”
ह
Bhartṛhari—Nītiśatakam
“Knowledge is such a treasure which cannot be stolen”
 r

IS 309:2005

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Indian Standard
COMPRESSED OXYGEN GAS — SPECIFICATION
(Fourth Revision)

Ics 71.100.20

0 BIS 2005
BUREAU OF INDIAN STANDARDS
MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG
NEW DELHI 110002
September 2005 Price Group 4
Industrial Gases Sectional Committee, CHD 6

FOREWORD

This Indian Standard (Fourth Revision) was adopted by the Bureau of Indian Standards, after the draft finalized
by the Industrial Gases Sectional Committee had been approved by the Chemical Division Council.

This standard was originally published in 1956 and then subsequently revised in 1965, 1974 and 1992 respectively.
In third revision, a new method of test for determination of moisture has been incorporated. The requirements for
packing and sampling have also been modified. The packing of compressed oxygen gas in cylinders and the
marking of the cylinders has been made to conform with the provision of the Gas Cylinder Rules, 1981 of the
Government of India, with such modifications as may be issued from time to time by the Chief Controller of
Explosives.

In this standard method of test for determination of carbonmonoxide, carbondioxide and total hydrocarbons have
been incorporated with a view to harmonize it with corresponding British Standard BS 4364:1993 ‘Specification
for industrial oxygen’.

At present, there is no 1S0 Standard on the subject.

The composition of the Committee responsible for the formulation of this standard is given at Annex F.

For the purpose of deciding whether a particular requirement of this standard is complied with, the final value,
observed or calculated, expressing the result of a test or analysis, shall be rounded off in accordance with
IS 2: 1960 ‘Rules for rounding off num~rical values (revised’. The number of significant places retained in the
rounded off value should be the same as that of the specified value in this standard.
 Is 309:2005

Indian Standard
COMPRESSED OXYGEN GAS — SPECIFICATION
(Fourth Revision)

1 SCOPE content in oxygen shall be not more than 0.102 g/Nm3

corresponding to dew point of-40°C when tested by the
1.1 This standard prescribes requirements and methods method prescribed in B-5.
of sampling and test for compressed oxygen gas for
industrial use. 4.3 Volume Fraction of Carbonmonoxide and
Carbondioxide
1.2 This standard does not cover aviation oxygen and
Volume fi-action of carbonmonoxide shall not be more
that for medical or inhalation purposes.
than 2 x 104 and carbondioxide shall not be more than
3 x 10-6 when determined by the method prescribed in
2 REFERENCES
Annex C.
The standards listed below contain provisions, which
through reference in this text constitute provisions of 4.4 Volume Fraction of Hydrocarbons
this standard. At the time of publication, the editions Volume fraction of hydrocarbons expressed as methane
indicated were valid. All standards are subject to revision shall not be more than 50 x 10A when determined by the
and parties to agreements based on this standard are method presented in Annex D.
encouraged to investigate the possibility of applying NOTE — Oxygen gas produced by air separation process shall
the most recent editions of the standards indicated not normally contain any carbonmonoxide, carbondioxide and
below: hydrocarbon. So for presence of these impurities in industrial
oxygen produced by air separation process, tests shall be
carried out only on agreement of such tests between the buyer
[S No. Title and the seller. For oxygen gas produced by other methods,
determination of these impurities, that is, carbonmonoxide,
1070: 1992 Reagent grade water (third revision)
carbondioxide and total hydrocarbon shall be carried out along
1260 Pictorial marking for handling and with other tests mentioned in 4.1 and 4.2.
(Part 1) :1973 Iabelling of goods: Part 1 Dangerous
goods (first revision) 5 PACKING AND MARKING
4379,: 1981 Identification of contents of industrial
5.1 Packing
gas cylinders (@st revision)
The gas shall be supplied compressed in cylinders of
7062: 1973 Glossary of terms used in gas industry approved designs and of suitable capacity, and conforming
to the requirements prescribed in the Gas Cylinder
3 TERMINOLOGY Rules, 1981 of the Government of India, with such
For the purpose of this standard, the definitions given modifications as may be ordered from time to time by
in IS 7062 shall apply. the Chief Controller of Explosives, Government of
India, or any other duly constituted authority.
4 REQUIREMENTS
5.1.1 The quantity of oxygen gas packed in a gas
4.1 Purity cylinder shall be measured at 150C and 760 mm of Hg
The purity of compressed oxygen gas shall be minimum and shall be expressed in cubic metre.
99.0 percent by volume when tested by the method
prescribed in Annex A. 5.2 Marking
The marking, parnting, Iabelling and transport of cylinders
4.2 Dew Point shall be in accordance with the requirements of the Gas
The dew point or oxygen gas shall be at least 400C Cylinder Rules, 1981 of the Government of India, with
measured at atmospheric pressure when tested by the such modification as may be ordered from time to time
method prescribed in B-2, B-3 and B-4 or moisture by the Chief Controller of Explosives, Government of

1
 m
.
!,
,,

IS 309:2005

India, or any other duly constituted authority. of conditions under which the licence for use of the
The cylinders shall also be marked as shown in Standard Mark may be granted to manufacturers or
IS 1260 (Part 1) and IS 4379. producers may be obtained from the Bureau of Indian
Standards.
5.3 BIS Certification Marking
The cylinders may also be marked with the Standard
Mark. 6 SAMPLING
The method of drawing representative samples of the
5.3.1 The use of the Standard Mark is governed by the material and criteria for determining conformity of the
provisions of the Bureau of Indian Standards Act, 1986 material to the requirements of this standard shall be as
and Rules and Regulations made thereunder. The details prescribed in Annex E.

ANNEX A
(Clause 4.1)

DETERMINATION OF PURITY OF OXYGEN GAS

A-1 QUALITY OF REAGENTS capillary f-fis full of liquid. Fill the lute G with a head
Unless specified otherwise, pure chemicals and distilled of about 50 mm of water and connect F with sample gas
water (see IS 1070) shall be employed in tests. and purge the gas ffom the lute G. Draw in the sample
through F (taking care that no air is sucked in through
NOTE— ‘Pure chemicals’ shall mean chemicals that do
F during this operation), until the liquid level in B is-at
not contain impurities, which affect the results of analysis.
the zero mark and is at the same level with that in A.
A-2 APPARATUS
Pass the gas into C by suitably operating the cock B,
and raising A. Shake thoroughly and then draw back the
The apparatus shall be as shown in Fig. 1. unabsorbed gas into B by lowering A and operating the
cock E, until a little solution from the capillary trickles
A-3 REAGENTS down into B in order to ensure that the capillary in the
plug of cock E is filled with liquid before leveling up
A-3.1 Copper Wire and reading the volume of the gas. Repeat the process
a number of times until no further absorption takes
A-3. 1.1 Ammonia Solution — Dissolve 550 g of place.
ammonium chloride (NHqCl) in 1085 ml of water and to
this solution add 917 ml of ammonium hydroxide solution A-4.2 Renewal of the Solution
(relative density 0.90).
When the solution is spent, close E, remove the bung
fkom C and drain out the solution fkom C and D. Invert
A-4 PROCEDURE
C and fill it with fresh solution. Replace the bung and
A-4.1 Invert the copper wire container C, remove the set C and D in proper places and in upright position.
bung and fill it with copper wire in spiral or other form. Now add fresh solution to the partially spent solution of
Then fill it with ammonia solution and replace the bung. t
A and repeat the process as indicated under A-4.1.
Return C to upright position. Pour the ammonia solution
into the levelling tube A until it is about three quarters A-5 CALCULATION
full. Then operate the three-way stopcocks E and lf so
v–v,
that burette B is in communication with the atmosphere Oxygen, percent by volume = x 100
through inlet E, and by raising levelling tube A, completely v
fill burette B. Keeping A raised, turn E, so that B is in
communication with C, and allow the solution to pass where
into C, until D is half full. Close E, lower A and operate
V= volume of the gas sample taken for the test, in ml;
E to draw from C into B. Close E when capillary of E
and
is full of liquid. Raise A and operate E to expel gas from
B to the atmosphere through F, closing E when the V, = volume of the gas after absorption, in ml. *

2
 IS 309:2005

f
FH
J- A

‘n===
E
* 100.0
I

\ 97.5

(
A a!
A B

r ~ .-
Iu (
9
8
7
8
5 1
4

)
G 3
2
c 1’
1
0
1

A = LEVELLING TUBE
B = GRADUATED BURETTE FOR OXYGEN TESTING
c = COPPER WIRE CONTAINER
D = RESERVOIR FOR SOLUTION
E&H= THREE-WAY STOP COCKS
F = INLET FOR GAS SAMPLE
G = LUTE

FIG. 1 ASSEMBLYOF APPARATUSFORDETERMINATION

OF OXYGEN

3
IS 309:2005

ANNEX B
(Clause 4.2)

DETERMINATION OF WATER VAPOUR

.

B-1 GENERAL gas at a particular pressure which may be observed

Presence of moisture in oxygen gas shall be determination optically in the apparatus. The temperature at which
by dew point or by weight of moisture content. For dew the dew or jlost is formed is a measure of water vapour
point determination, electrolytic hygrometer, tlost or content of the gas. The exact procedure to be followed
dew point hygrometer, and capacitance hygrometer shall shall depend upcm the type of apparatus to be used. The
be used. For determination of weight of moisture instrument manufacturer’s instructions in this
content, absorption method shall be followed. The regard shall be followed.
procedure to be followed for determining the dew point
by hygrometer method shall depend upon type of apparatus B-4 CAPACITANCE HYGROMETER
to be used and manufacturer’s instruction. The method is based on the change of capacitance of
the sensor when a sample gas containing water vapour
B-2 ELECTROLYTIC HYGROMETER passes through it. The change in capacitance gives a
The method is based on the absorption and electrolysis direct measurement of water vapour present in the gas.
of the water vapour present in the sample gas. The The procedure to be followed shall depend upon the
electrolytic current given a direct measurement of water type of apparatus to be used. The instrument
vapour present in the gas flowing through the instrument manufacturer’s instructions in this regard shall be followed.
at a steady rate. The exact procedure to be followed
shall depend on the type on apparatus to be used. The B-5 ABSORPTION METHOD
instrument manufacturer’s instructions in this regard
shall be followed. B-5. 1 Apparatus
$
The apparatus consists of the following parts assembled ,’,‘.*
B-3 FROST OR DEW POINT HYGROMETER as shown in Fig. 2. ‘~
A metal surface on the hygrometer is cooled so that dew
or frost is formed fi-omthe water vapour content of the B-5. 1.1 Gas Meter, accurate to 1 percent.
I

II
.

‘%

FIG. 2 ASSEMBLYOF APPARATUSFORTHEDETERMINATION

OF MOISTURE

4
 IS 309:2005

B-5.1.2 Absorption Train, three U tubes containing before commencement of flow of oxygen and after
phosphorus pentoxide connected in series to the gas completion of the flow of oxygen.
meter. The one near to the gas meter will serve as a
guard to prevent moisture from backing into the first B-5.3 Calculation
two tubes.
B-5.3. 1 Volume of total oxygen gas flow shall be
B-5.2 Procedure checked from the flow meter. Alternatively total quantity
of oxygen gas flow can be found out from water capacity
B-5.2.1 Absorption of moisture from a known volume of gas cylinder punched on the body of the cylinder and
of oxygen gas by anhydrous calcium chloride (CaC12) the difference between the initial fill pressure of oxygen
or phosphorous pentoxide (P2 OJ or Silica Gel or mol. gas in the cylinder and the final pressure of oxygen in
Seive held in a series of U tubes. the gas cylinder when flow is stopped. The quantity of
gas flow can be found out in the following manner.
B-5.2.2 Quantity of gas flow through U tube train shall
be measured by a rotometer or any other type of flow The water capacity of gas cylinder : .%’Iitre
meter having accuracy not less than +5 percent. Flow punched on the body
rate shall be about 500 l/h and not more to ensure
complete absorption of oxygen in the hydroscopic Pressure of the gas cylinder full : P} bar
chemicals held in U tube train. with oxygen

B-5.2.3 U tube train filled with hydroscopic chemicals Pressure in oxygen gas cylinder when : Pt bar
shall be initially heated to 10OOCor more depending on gas flow from cylinder is stopped
the chemical for 1 h to drive away any moisture absorbed
previously by the chemicals. The two ends of the U Total quantity of oxygen gas flow from
tube train shall be firmly closed with ruboer stopper not cylinder to the ‘U’ tube train:
to allow ingress of atmospheric air. Weight of the
whole U tube train shall be taken on a sensitive — w?-g)m3
chemical balance of accuracy not less than *1 percent. 1000
The U tube train shall be heated again in two intervals s
for 15 min each and weighed again after each 15- , ...
‘m” shall be converted to ‘N m3’ by @
minutes heating to see that there is no further fall in applying gas law :
weight of the U tube train, ensuring that moisture from Pv
the chemicals have been removed. =K
T

B-5.2.4 At least one cylinder fill of oxygen gas at full If chemical balance employed for weighment is not
enough sensitive, in that case gas from more than one ,;
filling pressure having 6 to 7 m’ of oxygen gas shall
be connected to the U tube train through pressure oxygen cylinder may be passed to increase absorption
regulator and flow meter. The entire quantity of oxygen of more moisture and thereby to increase the weight of
gas from the cylinder shall be passed through U tube the U tube train for easier weighment. .
train at a rate of about 500 I/h and when the cylinder is
empty in about 10 h. Both ends of the U tube train shall B-5.3.2 The weight of moisture absorbed in the U tube
be firmly closed with rubber stopper not to allow any train in grams divided by the volume of the oxygen %
moisture from atmospheric air to get in. passed, in Nm3, shall show moisture content, in g/Nm3.

B-5.2.5 U tube train afler absorption of moisture ffom B-5.3.3 The above test shall be repeated 3 times and
oxygen gas shall be weighed in chemical balance and the average moisture content in @m3 shall be determined.
weight of moisture absorbed from oxygen gas shall be This shall not be more than 0.102 g/Nm3 corresponding
found by the difference in weight of the U tube train to -40”C dew point.
I
IS 309:2005

ANNEX C
(Clause 4.3)

DETERMINATION OF VOLUME FRACTION OF CARBONMONOXIDE

AND CARBONDIOXIDE

C-1 The method for determination of volume fraction spectrometer’ shall be used after calibration. Instruction
of carbonmonoxide and carbondioxide present in oxygen of the manufacturers of the instrument shall be followed
shall use the principle of infrared absorption in specific for calibration and calculation of volume fraction of
wave length by different molecules. ‘ Scanning infrared carbonmonoxide and carbondioxide in oxygen sample.

ANNEX D
(Clause 4.4)

DETERMINATION OF VOLUME FRACTION OF HYDROCARBONS

D-1 Gas chromatography with flame ionization detector, be used as carrier gas. Instruction of the manufacturer
gas samplhg value, suitable valve to ‘backflash’ of the instrument shall be followed for calibration
hydrocarbon to detector shall be used for the determhlation and calculation of volume fraction of hydrocarbons in
of volume fraction of hydrocarbon. Nitrogen gas shall oxygen gas.

ANNEX E
(Clause 6)

SAMPLING OF COMPRESSED OXYGEN GAS

E-1 PROCEDURE to this standards, if the sample passes the oxygen and
moisture content test.
E-1. 1 On regular production, two samples selected at
random shall be tested per hour of compression, E-1.1.2 However, if the sample fails in the oxygen and
moisture content test, then the sampling frequency shall
E-1.1.1 The production shall be declared as conforming be doubled till all the samples pass for consecutive 2 h.
 IS 309:2005

ANNEX F
(Foreword)
COMMITTEE COMPOSITION

Industrial Gases Sectional Committee, CHD 6

Organization Representative(s)

Praxair India Pvt Ltd, Bangalore SHRI R. S. DHULKHEO (Chairman)

All India Industrial Gases Manufacturers’ Association, New Delhi DR P. L. BHATIA

SHRI B. N. QANUNGO (Alfernate)

Association of Automobiles Manufacturers of India, New Delhi REPRESENTATIVE

Bharat Heavy E\ectricals Ltd, Hyderabad SHRI N. V. S. RAMANI

SHRI A. RAJAMOHAN (Alternate)

BOC India Ltd, Kolkata SHRI P. AMARNATH

Central Electronics Ltd, Ghazibabad SHRI M. L ALAM

Chief Controller of Explosives, Nagpur SHRI R. H. BHALEKAR

SHRI S. K. BHARDWAJ(Ahernate)

Department of Electronics, New Delhi DR U. C. PANOEY

Department of Industrial Development, New Delhi SHRI P. K. JAIN

SHRJN. C. TIWARI (Alternate)

Everest Kanto, Mumbai REPRESENTATIVE

k
Gujrat State Fertilizer Corporation Ltd, Vadodai.. SHRI M. C. SHAH
SHRJR. C. MATHUR (Alternate)

Indian Space Research Organization, Shriharikota REPRESENTATIVE

Industrial Oxygen Co Ltd, Mumbai SHiW R. R. SINGANPORIA

Mahalasa Gases & Chemicals Pvt Ltd, Bangalore SHRI A. N. PRABHU

PROF M. G. SUBBA RAO (Afternate)

M/s Mohan Meakin Ltd, Ghaziabad DR E. K. JAYANARAYANAN

Ministry of Defence (DGQA), Kanpur SHRI Y. V. VAILURE

SHRJSUJIT GHOSH (AOernafe)

National Physical Laboratory, New Delhi REPRESENTATIVE

National Test House, Kolkata DR B, B. PAL

Ordnance Factory, Bhandara DR S. K. DESHMUKH .

SHRI V. SRINIVASAN(Alternate)

Rashtriya Chemicals & Fertilizers Ltd, Mumbai DR R. N. TRIVEDI

Semi Conductor Complex Ltd, Punjab SHRI S. S. N. PRASAO

Steel Authority of India, New Delhi SHRI A, NAGARAJAN

SHRI S. G. K. MURTHY (Alternate)

Steel Furnace Association of India, Surat SHRI M. K. GUPTA

Sylvania & Laxman Ltd, New Delhi SHRI S. K. KAPOOR

SHRI NAVEEN SIKKA (Alternate)

The Asiatic Oxygen and Acetylene Co Ltd, Kolkata SHRI B. N, SINHA

The Industrial Gases Ltd, Kolkata SHRI T. GARG

SHRIL. R. GARG (Alternate)

BIS Directorate General DR U. C. SRIVASTAVA,Director& Head (Chem)

[Representing Director General (Ex-oflcio Member)]

Member Secretary
SHRI P. GHOSH
Director (Chem), BIS

7
Bureau of Indian Standards

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harmonious development of the activities of standardization, marking and quality certification of goods
and attending to connected matters in the country.

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Enquiries relating to copyright be addressed to the Director (Publications), BIS.

Review of Indian Standards

Amendments are issued to standards as the need arises on the basis of comments. Standards are also reviewed
periodically; a standard along with amendments is reaffirmed when such review indicates that no changes are
needed; if the review indicates that changes are needed, it is taken up for revision. Users of Indian Standards
should ascertain that they are in possession of the latest amendments or edition by referring to the latest issue of
‘BIS Catalogue’ and ‘Standards : Monthly Additions’.

This Indian Standard has been developed from Doc : No. CHD 6 (1 163).

Amendments Issued Since Publication

Amend No. Date of Issue Text Affected

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