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    Dzexams 2as Physique 1109704

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    faroukafroukh

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    Dzexams 2as Physique 1109704

    Uploaded by

    faroukafroukh
    8 views6 pages

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    dzexams-2as-physique-1109704

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    8 views6 pages

    Dzexams 2as Physique 1109704

    Uploaded by

    faroukafroukh

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 6

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    𝐶4 𝐻10 𝑂

    (𝑃%) 𝐻3 𝑁𝑆𝑂3
    𝑉 = 100𝑚𝐿 𝐶𝐴 (𝑆𝐴 )
    𝑚 = 0.9g
    (𝑁𝑎+ + HO− ) 𝑉𝐴 = 20𝑚𝐿 (𝑆𝐴 )
    𝑉𝑏𝐸 = 15.3𝑚𝐿 𝐶𝑏 = 0.1 𝑚𝑜𝑙 ⁄𝐿

    𝑁𝐻3 𝑆𝑂3 + HO− = 𝑁𝐻2 𝑆𝑂3 − + 𝐻2 𝑂


    1
    2
    3
    𝑚𝐴 (𝑆𝐴 ) 𝐶𝐴 4
    (𝑃%) 5
    𝑴 = 𝟗𝟕𝒈/𝒎𝒐𝒍 𝑵𝑯𝟑 𝑺𝑶𝟑
    ‫‪𝐻2 𝑂2‬‬

    ‫)𝑔( ‪2𝐻2 𝑂2 (𝑎𝑞) = 2𝐻2 𝑂(𝑙) + 𝑂2‬‬


    ‫‪𝐶0‬‬ ‫𝑙𝑚‪𝑉 = 500‬‬
    ‫‪𝑂2‬‬ ‫𝐿‪𝑉𝑔 = 10‬‬

    ‫)𝑑𝑒𝑅‪(𝑂𝑥 ⁄‬‬

    ‫𝑔𝑉‪2‬‬
    ‫= ‪𝐶0‬‬
    ‫𝑀𝑉×𝑉‬

    ‫𝑙𝑚‪𝑉0 = 10‬‬
    ‫‪𝐶′0‬‬ ‫‪𝐻2 𝑂2‬‬
    ‫) ‪(2𝐾 + + 𝐶𝑟2 𝑂72−‬‬
    ‫𝐿𝑚‪𝑉𝐸 = 49.6‬‬ ‫𝑙‪𝐶 = 0.1𝑚𝑜𝑙/‬‬

    ‫) ‪(𝐶𝑟2 𝑂72− ⁄𝐶𝑟 3+ ) (𝑂2 ⁄𝐻2 𝑂2‬‬


    ‫𝐸𝑉‬ ‫‪𝐶 𝑉0‬‬ ‫‪𝐶′0‬‬
    ‫‪𝐶′0‬‬
    ‫‪𝑑 = 1.4‬‬ ‫‪𝑃 = 3%‬‬

    ‫𝒍𝒐𝒎‪𝑶 = 𝟏𝟔𝒈⁄‬‬ ‫𝒍𝒐𝒎‪𝑯 = 𝟏𝒈⁄‬‬ ‫𝒍𝒐𝒎‪𝑽𝑴 = 𝟐𝟐. 𝟒𝑳/‬‬

    ‫اسرة الفيزياء تتمىن لكم التوفيق والنجاح‬


    2

    •
    𝐶4 𝐻10 𝑂

    2 1

    2
    𝑁𝐻3 𝑆𝑂3 = 𝑁𝐻2 𝑆𝑂3 − + 𝐻 +
    HO− + 𝐻 + = 𝐻2 𝑂
    3
    0
    𝑉𝐴 = 20𝑚𝐿
    𝐶𝐴 4
    𝐶𝑏 𝑉𝑏𝐸 0.1×15.3
    𝐶𝐴 𝑉𝐴 = 𝐶𝑏 𝑉𝑏𝐸 ⟹ 𝐶𝐴 = = = 0.0765 𝑚𝑜𝑙/𝐿
    𝑉𝐴 20
    𝑚𝐴
    𝑚𝐴 = 𝐶𝐴 ×𝑉×𝑀 = 0.0765×0.1×97 = 0.742𝑔
    (𝑃%) 5
    𝑚𝐴 0.742
    𝑃= ×100 = ×100 = 82.45%
    𝑚 0.9

    2
    𝐻2 𝑂2 (𝑎𝑞) + 2𝐻+ + 2𝑒 − = 2𝐻2 𝑂(𝑙)
    𝐻2 𝑂2 (𝑎𝑞) = 𝑂2 (𝑔) + 2𝐻+ + 2𝑒 −
    (𝐻2 𝑂2 ⁄𝐻2 𝑂) (𝑂2 ⁄𝐻2 𝑂2 )

    2𝐻2 𝑂2 (𝑎𝑞) = 2𝐻2 𝑂(𝑙) + 𝑂2 (𝑔)


    𝑛0
    𝑛0 − 2𝑥 𝑥
    𝑛0 − 2𝑥𝑓 𝑥𝑓

    2𝑥𝑓
    𝑛0 − 2𝑥𝑓 = 0 ⟹ 𝑛0 = 2𝑥𝑓 ⟹ 𝐶0 𝑉 = 2𝑥𝑓 ⟹ 𝐶0 =
    𝑉
    𝑉𝑔
    𝑛𝑂2 = = 𝑥𝑓
    𝑉𝑀
    𝑉𝑔
    2× 2𝑉𝑔
    𝑉𝑀
    ⟹ 𝐶0 = ⟹ 𝐶0 =
    𝑉 𝑉×𝑉𝑀
    2×10
    ⟹ 𝐶0 = = 1.78 𝑚𝑜𝑙/𝐿
    0.5×22.4
    ‫𝑂 ‪𝐶𝑟2 𝑂7 2− + 14𝐻+ + 6𝑒 − = 2𝐶𝑟 3+ + 7𝐻2‬‬
    ‫‪𝐻2 𝑂2 (𝑎𝑞) = 𝑂2 (𝑔) + 2𝐻+ + 2𝑒 − … … .×3‬‬
    ‫𝑂 ‪𝐶𝑟2 𝑂7 2− + 3𝐻2 𝑂2 + 8𝐻+ = 2𝐶𝑟 3+ + 3𝑂2 (𝑔) + 7𝐻2‬‬

    ‫‪𝑛𝐶𝑟2 𝑂72−‬‬ ‫‪𝑛𝐻2 𝑂2‬‬ ‫‪𝐶𝑉𝐸 𝐶′0 𝑉0‬‬


    ‫=‬ ‫⟹‬ ‫=‬
    ‫‪1‬‬ ‫‪3‬‬ ‫‪1‬‬ ‫‪3‬‬
    ‫‪𝐶′0‬‬
    ‫‪𝐶𝑉𝐸 𝐶′0 𝑉0‬‬ ‫‪3𝐶𝑉𝐸 3×0.1×49.6‬‬
    ‫=‬ ‫= ‪⟹ 𝐶 ′0‬‬ ‫=‬ ‫𝐿‪= 1.488𝑚𝑜𝑙/‬‬
    ‫‪1‬‬ ‫‪3‬‬ ‫‪𝑉0‬‬ ‫‪10‬‬
    ‫نالحظ ان التركيز نقص أي ان الماء االكسجيني تفكك جزئيا ‪.‬‬
    ‫‪6‬‬

    ‫‪10𝑃𝑑 10×3×1.4‬‬
    ‫=𝐶‬ ‫=‬ ‫𝐿‪= 1.235𝑚𝑜𝑙/‬‬
    ‫𝑀‬ ‫‪34‬‬

    ‫𝑉 ‪𝐶(𝑉 + 𝑉𝑒 ) = 𝐶′0‬‬
    ‫𝑉 ‪𝐶′0‬‬ ‫𝑉‪𝐶 ′0‬‬
    ‫= ) 𝑒𝑉 ‪(𝑉 +‬‬ ‫= 𝑒𝑉 ⟹‬ ‫𝑉‪−‬‬
    ‫𝐶‬ ‫𝐶‬
    ‫‪1.488×500‬‬
    ‫= 𝑒𝑉 ⟹‬ ‫𝐿𝑚‪− 500 = 102.4‬‬
    ‫‪1.235‬‬
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