SAFETY DATA SHEET

in accordance with regulation (CE) 1907/2006 REACH and (EU) No. 2015/830
RATING DATE 12/2017 - Rev. N° 0 - 00/00/0000

4107-Blue pack
1 - IDENTIFICATION OF THE SUBSTANCE/ PREPARATION AND COMPANY/ UNDERTAKING
1.1 Identification of the Poliimide fibres with PTFE dispersion
product
Trade name 4107- Blue pack

Grade solid

Structural formula:
+
(of the polymer)

Product code 4107

1.2 Identified uses and

recommended for the
substance or mixture
Recommended use For industrial application only

1.3 Details of the supplier of the safety data sheet

Company name
TEXPACK srl unipersonale
Address
Via Galileo Galilei, 24 25030 Adro (BS)
Telephone and Fax nr +39 030740168 - +39 0307480201

e-mail address [email protected]

1.4 Emergency Calls

+ 39 030 7480168

2 – HAZARD IDENTIFICATIONS
2.1 Classification of the substance or mixture
This mixture is classified as not dangerous in accordance with directives
2.1.1 European Regulation (EC) 1272/2008, as mentioned
2.1.2 Classification according to the CLP (Classification Labelling an Packaging, Regulation (EC) No 1272/2008).

Hazard Class Hazard Category H-phrases

None None None

2.2 Label elements: None

2.2.1 Names on the label: None
2.2.2 Signal word : None
2.2.3 Hazard pictograms: None
2.2.4 Hazard : None
2.2.5 Safety advice: None
2.3 Other hazards: The product is biologically inert.
Not hazardous under normal conditions of handling and use.
Ecological injuries are not known or expected under normal use.
Thermal decomposition can lead to release of toxic and corrosive gases.

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3 – COMPOSITION/ INFORMATION ON INGREDIENTS

3.1 mixture
3.2 Concentration

Name Remarks CAS N° Risk Classification in according to

Phrases (EC) No 1272/2008

Polyimide Yarn 58698-12-2 none No dangerous

Opt: colored
Polytetrafluoroethylene (PTFE) dispersion 9002-84-0 none No dangerous

4 – FIRST AID MEASURES

Description of first aid measures
4.1
Symptomatology following exposure to products of thermal decomposition
4.1.1 If inhaled Headache, short breathing, cough, chills and fever, tachycardia.

4.1.2 In case of contact Redness, irritation, burns

with skin
4.1.3 Eye contact Redness, irritation, burns
4.1.4 Ingestion Not a probable route of exposure. However, in case of accidental ingestion, call a physician
4.2 First Aid Measures in case of exposure to gases from thermal decomposition
4.2.1 Move immediately affected person to fresh air.
Seek medical attention immediately.
If not breathing, supply artificial respiration, preferably mouth to mouth. In case of difficult
If inhaled breathing, give oxygen.
omposition products do not occur until several hours after exposure.
Keep the affected person under medical observation for at least 48 hours.
A timely medical attention is absolutely required.
Flush immediately and copiously with water for at least 15 minutes, retracting eyelids often.
4.2.2 Eye contact Seek medical attention in case burns continues.
In case of contact Wash immediately with water and soap (pay particular attention to flushing skin under nails).
4.2.3
with skin Seek medical attention in case burns continues.

4.2.4 If swallowed Not a probable route of exposure. However, in case of accidental ingestion, call a physician

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5 – FIRE FIGHTING MEASURES
5.1 Specific hazards
5.1.1 The product is neither flammable nor explosive.
In the event of fire, corrosive and toxic gases from thermal decomposition may be formed, like Carbon monoxide (CO)
Hydrofluoric acid (HF)
Carbonil Fluoride (COF2)
Tetrafluoroethylene
Hexafluoroisobutylene
Perfluoroisobutylene
Sulphurous anydride
5.2 Extinguishing media
5.2.1 Water (spray, fog, stream), CO2, chemicals in powder or foam.
5.3 Specific methods
5.3.1 In case of surrounding fire, if possible, remove the containers in a safety place.
To do only if in safe conditions (safety distance from the flames and staying upwind)
In case of impending fire, keep containers cool by spraying with water.
5.4 Protection of fire-fighters
5.4.1 Self contained breathing apparatus.
Full anti-acid clothing

6 – ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions Accidental release measures ccidental release measures
Keep away from hot surfaces and flames.
Stop the release as soon as possible, in safe conditions.
6.2 Environmental precautions ccidentrelease measures
Avoid uncontrolled discharge of the product in the soil and underground waters.
6.3 Methods for cleaning up
Sweep and scoop out the released material, collecting it in suitable container for re-use or disposal according to
applicable regulations.
6.4 Reference to other sections
None

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7 – HANDLING AND STORAGE
7.1 Handling
7.1.1 Precautions
Ensure adequate ventilation
Use personal protective equipment
Avoid creating dust
Do not contaminate products based on tobacco
Keep away from heat and sources of fire
To avoid thermal decomposition do not overheat
Before each operation clean and dry pipes and equipment
Take measures to prevent the build up of electrostatic charge
Ensure all equipment is electrically grounded before beginning transfer operations
7.1.2 Security measures
In working areas where the materials are handled at temperatures higher than 350°C appropriate exhaust ventilation
and smoke down bringing are required.
7.2 Conditions for safe storage, including any incompatibilities
7.2.1 Storage
Keep away from sparks and flames, hot surfaces and inflammable materials.
Do not store near incompatible materials (see par. 10).
7.2.2 Packaging
Cardboard boxes or plastic drums, wooden boxes

8 – EXPOSURE CONTROLS/ PERSONAL PROTECTION

8.1 Control parameters
8.2.1 exposure controls
Appropriate engineering controls
8.2.2 Individual protection measures
8.2.2.1 Respiratory protection
Normally it is required any protective device for the respiratory system.
If dust / mist / fume, dust mask with filter type P2.
Use respirator when performing operations involving potential exposure to vapor of the product.
Use only respiratory protection that conforms to international / national standards.
8.2.2.2 Hand Protection
Latex gloves
When handling hot material, use heat resistant gloves
8.2.2.3 Eye protection
In case of high dust concentration wear safety goggles and appropriate work suits/overalls.
8.2.2.4 Body protection
Long sleeved clothing
Safety shoes
8.2.2.5 Hygiene measures
When using, do not eat, drink or smoke.
Wash hands before breaks and at the end of workday.
Handle in accordance with good practice of industrial hygiene and safety practice
8.2.3 Environmental exposure control
Every four years, the working environment is monitored. Result: not dangerous

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9 – PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical.
Polyimide/PTFE
9.1.1 general information

Appearance Solid
Odour odourless
Colour Natural or coloured
3
Density relative 1,4 – 2,16 g/cm
Point of fusion 327 °C
pH not applicable
Boiling point not applicable
Flash point non flammable
explosive properties not explosive
oxidizing properties non-oxidizing
Vapor Density not applicable
Solubility in water insoluble
Solubility in organic solvent insoluble
Percent volatile 0%
VOC Less H2O & Exempt solvents Not applicable

10 – STABILITY AND REACTIVITY

10.1 Stability
The product is stable in normal condition of use and storage.
10.2 chemical stability
The product is chemically stable.
10.3 Possibility of hazardous reactions
During drying, cleaning and moulding, small amounts of hazardous gases and/or particulate matter may be released.
These may irritate eyes, nose and throat. Large molten masse may give off hazardous gases. Stable under normal
condition.
10.4 Conditions to avoid
To avoid thermal decomposition, do not overheat. Abnormally long processing time or high temperatures can
produce irritating and toxic fumes. Stable under normal conditions
10.5 Materials to avoid
Finely divided aluminium
Powdered metals
Potent oxidizers like fluorine and related compounds. Contact with incompatible materials can cause fire and
explosion
10.6 Hazardous decomposition products
Toxic and corrosive vapour-steam (hydrogen fluoride, carbonyl fluoride, tetrafluoroethylene, hexafluoropropane and
perfluoroisobutane).
The temperature level influences directly the thermal combustion products.

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11 – TOXICOLOGICAL INFORMATION
11.1 Acute toxicity
See 11.1.1
11.1.1 Acute oral toxicity
DL50, ratto > 5000 mg/Kg
11.1.2 Acute inhalation toxicity

The vapors of the thermal decomposition of fluorinated plastics can cause polymer fume fever with flu-like
symptoms in humans, especially when smoking contaminated tobacco
The thermal decomposition products, high temperature, may be irritating to the respiratory system
HF / Cl Severely Irritating to respiratory system. Risk of pulmonary edema
11.2 Corrosion / Skin Irritation
- rabbit
Classification: not classified as irritant
Result: No skin irritation - human
Classification: not classified as irritant
Result: No skin irritation
11.3 Serious eye damage / eye irritation
No eye irritation in normal condition of use
11.4 Sensitisation
- human
Classification: not a skin sensitizer
Result: Does not cause skin sensitisation.
Patch test on human volunteers did not demonstrate sensitisation properties
11.5 Mutagenicity
No data available
11.6 Carcinogenicity
Not classifiable as a human carcinogen
11.7 Toxic for reproduction
No toxicity to reproduction
11.8 Repeated dose toxicity
No date available
11.9 other information
none

12 – ECOLOGICAL INFORMATION
12.1 Toxicity
Toxicity to fish : the substance is a polymer and is not expected toxic effects
12.2 Persistence and Degradability
no data available
12.2.1 Abiotic degradation
no data available
12.2.2 Biodegradation
no data available
12.3 Biocumul potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB
no data available
12.6 Other adverse effects
no data available

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13 – DISPOSAL CONSIDERATIONS
13.1 Waste treatment
The product that can not be recycled must be disposed in authorized landfill or destroyed in a high-temperature
incinerator designed to burn halogen materials.
13.2 Packaging treatment
Dispose of in authorised landfills according to local laws and regulations.

14 – TRANSPORT INFORMATION
14.1 Specific hazards
The product is not classified as dangerous in transportation
14.2 Packaging information
Product usually shipped in bags within plastic canisters, cardboard boxes or plastic drums, wooden boxes
14.3 International transport classification
Packaging group: not assigned
U.N. Number: not assigned

15 – REGULATORY INFORMATION
15.1 EC Regulations
Regulation (CE) n.1907/2006
Regulation (CE) n. 453/2010
Regulation (CE) n. 2015/830
15.2 Classification
Hazard class: none
Classification type not required
15.3 Labelling
Trade name 4107 Blue pack
Risk phrases (R) none
Safety phrases (S) none
Hazard Symbol none
15.4 Chemical Safety Assessment
None

16 – OTHER INFORMATION
16.1 Text of hazard "H" referred to under sections 2-3
none
16.2 Text of risk phrases "R" mentioned in section 2-3
none
16.3 Other information
Safety data sheet according to Regulation (CE) n.1907/2006 and (CE) n.453/2010

Regulation (EC) N.1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
Registration, Evaluation Service, Authorization and Restriction of Chemicals (REACH), establishing a European Agency
for chemicals, What Change 1999/45/EC and repealing Regulation (EEC) 793/93 and Council Regulation (EC) n.1488
/94 the Commission, as well as the Directive 76/769/EEC and Commission Directives 93/67/EEC, 93/105 /EC and
2000/21/EC.

Regulation (EU) 453/2010 of the Commission of 20 May 2010 amending Regulation (EC) No. 1907/2006 of the
European Parliament and the Council.
Regulation EEC / EU n ° 453 of 20/05/2010 of the Commission of 20 May 2010 amending Regulation (EC) n.1907 /
2006 of the European Parliament and the Council.

Regulation EEC/EU n.1272 of 16/12/2008 "Regulation (EC) n.1272/2008 of the European Parliament and of the
Council on classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45 / EC, and amending Regulation (EC) N.1907/2006.

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