Safety Data Sheet according to Regulation (EC) No.
1907/2006 (REACH)
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name/designation Aluminum potassium sulphate dodecahydrate LR
Product No. PRD5107 Substance name Aluminum potassium sulphate dodecahydrate CAS No. 7784-24-9 INDEX no. REACH registration No. Not yet communicated down the supply chain. other means of identification Alum potassium Aluminium potassium bis(sulphate) dodecahydrate
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses for laboratory use and chemical production.
1.3 Details of the supplier of the safety data sheet
: Better Equipped, Wrenbury Business Park, Wrenbury Road, Wrenbury, Nantwich, Cheshire, CW5 8EB, UK Telephone +44 (0) 800 9707142 Fax +44 (0) 800 066 4443 E-mail address [email protected]
1.4 Emergency telephone
Telephone +44 (0)1270 781238
2. Hazards identification
2.1 Classification of the substance or mixture
2.1.1 Classification according to Regulation (EC) No. 1272/2008 [CLP]
This substance is not classified as dangerous according to regulation (EC) 1272/2008 [CLP].
2.1.2 Classification according to Directive 67/548/EEC or 1999/45/EC
1 - 11 This substance is not classified as dangerous according to 67/548/EEC.
2.2 Label elements
2.2.1 Labelling according to Regulation (EC) No. 1272/2008 [CLP]
not applicable
Signal word not applicable
Hazard Statements not applicable
Precautionary statements not applicable
2.2.2 Labelling (67/548/EEC or 1999/45/EC)
Hazard symbols:
not applicable
R-phrases not applicable
S-phrases not applicable
2.3 Other hazards
SVHC No
3. Composition/ Information on ingredients
Molecular formula AlKO8S2.12H2O
Molecular weight (g/mol) 474.39 g/mol CAS No. 7784-24-9 EC No 233-141-3 INDEX no.
4. First-aid measures
4.1 General information
When in doubt or if symptoms are observed, get medical advice. If unconscious place in recovery position and seek medical advice. Never give anything by mouth to an unconscious person or a person with cramps. Change contaminated, saturated clothing. Do not leave affected person unattended.
2 - 11 4.2 After inhalation
Remove casualty to fresh air and keep warm and at rest. If breathing is irregular or stopped, administer artificial respiration. In case of respiratory tract irritation, consult a physician.
4.3 In case of skin contact
After contact with skin, wash immediately with plenty of water and soap. Remove contaminated, saturated clothing immediately. In case of skin reactions, consult a physician.
4.4 After eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Protect uninjured eye. Remove contact lenses, if present and easy to do. Continue rinsing.
4.5 After ingestion
If accidentally swallowed rinse the mouth with plenty of water (only if the person is conscious) and obtain immediate medical attention. Do not induce vomiting. Give nothing to eat or drink.
4.6 Self-protection of the first aider
First aider: Pay attention to self-protection!
4.7 Information to physician:
Symptoms No data available
Hazards No data available Treatment No data available
5. Firefighting measures
5.1 Suitable extinguishing media
The product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.
5.2 Extinguishing media which must not be used for safety reasons:
no restriction
5.3 Special hazards arising from the substance or mixture
In case of fire may be liberated: Sulphur oxides
5.4 Advice for firefighters
DO NOT fight fire when fire reaches explosives. In case of fire: Wear self-contained breathing apparatus.
5.5 Additional information
3 - 11 Do not allow run-off from fire-fighting to enter drains or water courses. Do not inhale explosion and combustion gases. Use caution when applying carbon dioxide in confined spaces. Carbon dioxide can displace oxygen. Use water spray jet to protect personnel and to cool endangered containers.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Avoid generation of dust.
6.2 Environmental precautions
Do not allow to enter into surface water or drains.
6.3 Methods and material for containment and cleaning up
Spilled product must never be returned to the original container for recycling. Take up carefully when dry. Collect in closed and suitable containers for disposal.
6.4 Additional information
Clear spills immediately.
7. Handling and storage
7.1 Precautions for safe handling
All work processes must always be designed so that the following is as low as possible: Inhalation. skin contact eye contact. If handled uncovered, arrangements with local exhaust ventilation have to be used. If local exhaust ventilation is not possible or not sufficient, the entire working area must be ventilated by technical means. Usual measures for fire prevention. Handle under (Gas): Protective gas, dry.
7.2 Conditions for safe storage, including any incompatibilities
storage temperature No data available
Keep container tightly closed in a cool, well-ventilated place.
7.3 Specific end use(s)
No data available
8. Exposure controls / Personal protection
8.1 Control parameters
Does not contain substances above concentration limits fixing an occupational exposure limit.
4 - 11 8.2 Appropriate engineering controls
Technical measures and the application of suitable work processes have priority over personal protection equipment. If handled uncovered, arrangements with local exhaust ventilation have to be used.
8.3 Personal protective equipment
Wear suitable protective clothing. When handling with chemical substances, protective clothing with CE-labels including the four control digits must be worn.
8.3.1 Eye / face protection
Eye glasses with side protection DIN-/EN-Norms: DIN EN 166
8.3.2 Skin protection
When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. Recommended glove articles DIN-/EN-Norms: DIN EN 374 In the case of wanting to use the gloves again, clean them before taking off and air them well.
By short-term hand contact
Suitable material: NBR (Nitrile rubber) Thickness of the glove material 0,12 mm Breakthrough time (maximum wearing time) >480 min Recommended glove articles VWR 112-0998
By long-term hand contact
Suitable material: NBR (Nitrile rubber) Thickness of the glove material 0,38 mm Breakthrough time (maximum wearing time) >480 min Recommended glove articles VWR 112-3717 / 112-1381
8.3.3 Protective clothing
Wash hands before breaks and after work. Avoid contact with skin and eyes. When using do not eat, drink or smoke. Provide eye shower and label its location conspicuously.
8.3.4 Respiratory protection
Usually no personal respirative protection necessary.
Suitable respiratory protection apparatus: No data available
Recommendation No data available Suitable material: No data available Recommendation No data available
8.4 Additional information
Wash hands before breaks and after work. Avoid contact with skin and eyes. When using do not eat, drink or smoke. Provide eye shower and label its location conspicuously.
5 - 11 9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
(a) Appearance Physical state solid Colour white
(b) Odour No data available
(c) Odour threshold No data available
Safety relevant basic data
(d) pH No data available
(e) Melting point/freezing point 92.5°C (f) Initial boiling point and boiling range No data available (g) Flash point No data available (h) Evaporation rate No data available (i) Flammability (solid, gas) not applicable (j) Upper/lower flammability or explosive limits Lower explosion limit (Vol-%) No data available Upper explosion limit (Vol-%) No data available (k) Vapour pressure No data available (l) Vapour density No data available (m) Relative density 1.72 g/cm³ (20°C) (n) Solubility(ies) Water solubility (g/l) 139 g/l (20°C) at °C: 20 Soluble (g/l) in No data available (o) Partition coefficient: n-octanol/water No data available (p) Auto-ignition temperature No data available (q) Decomposition temperature No data available (r) Viscosity Kinematic viscosity No data available Dynamic viscosity No data available (s) Explosive properties not applicable (t) Oxidising properties not applicable
9.2 Other information
Bulk density No data available
refraction index No data available dissociation constant No data available Surface tension No data available Henry constant No data available
10. Stability and reactivity
10.1 Reactivity
No data available
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature).
6 - 11 10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
No data available
10.6 Hazardous decomposition products
No data available
10.7 Additional information
No data available
11. Toxicological information
11.1 Information on toxicological effects
Acute effects
Acute oral toxicity
Effective dose No data available species: No data available Exposure time remark source
Acute dermal toxicity
Effective dose No data available species: No data available Exposure time remark source
Acute inhalation toxicity
Effective dose No data available species: No data available Exposure time remark source
Irritant and corrosive effects
Primary irritation to the skin
7 - 11 Exposure time species: Result
Irritation to eyes Exposure time species: Result
Irritation to respiratory tract
Exposure time species: Result
Sensitisation In case of skin contact not sensitising. After inhalation not sensitising.
Specific target organ toxicity (single exposure)
not relevant
Specific target organ toxicity (repeated exposure)
not relevant
CMR effects (carcinogenicity, mutagenicity and
toxicity for reproduction)
Carcinogenicity
No indication of human carcinogenicity.
Germ cell mutagenicity/Genotoxicity
No indications of human germ cell mutagenicity exist.
Reproductive toxicity
No indications of human reproductive toxicity exist.
Aspiration hazard
not relevant
11.2 Other adverse effects
No data available
8 - 11 11.3 Additional information
No data available
12. Ecological information
12.1 Ecotoxicity
Acute (short-term) fish toxicity
LC50: No data available EC50 species: Exposure time
Chronic (long-term) fish toxicity
LC50: No data available EC50 species: Exposure time
Acute (short-term) daphnia toxicity
LC50: No data available EC50 species: Exposure time
Chronic (long-term) daphnia toxicity
LC50: No data available EC50 species: Exposure time
Acute (short-term) algae toxicity
LC50: No data available EC50 species: Exposure time
Chronic (long-term) algae toxicity
LC50: No data available EC50 species: Exposure time
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
(o) Partition coefficient: n-octanol/water No data available
12.4 Mobility in soil
No data available
9 - 11 12.5 Results of PBT assessment
No data available
12.6 Other adverse effects
No data available
13. Disposal considerations
13.1 Waste treatment methods
Appropriate disposal / Product
Dispose according to legislation. Consult the appropriate local waste disposal expert about waste disposal.
Waste code product No data available
Appropriate disposal / Package
13.2 Additional information
No data available
14. Transport information
14.1 Land transport (ADR/RID)
No dangerous good in sense of these transport regulations.
14.2 Sea transport (IMDG)
No dangerous good in sense of these transport regulations.
14.3 Air transport (ICAO-TI / IATA-DGR)
No dangerous good in sense of these transport regulations.
14.4 Additional information
No data available
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Water hazard class (WGK) 1
10 - 11 15.2 Chemical Safety Assessment
No data available
16. Other information
16.1 Relevant R-, H- and EUH-phrases (Number and full text)
not applicable
not applicable
16.2 Additional information
Indication of changes
general update
The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.
