Chemistry | 27th january 2024 _ Shift-2

SECTION – A

61. The order of relative stability of the contributing structure is

O O

CH2=CH–C–H CH2–CH=C–H
I II


O
CH2–CH= C–H
III

Choose the correct answer from the options given below

(1) I>II>III (2) II>I>III (3) I=II=III (4) III>II>I
Ans. 1
Ist structure is most stable due to complete octate and it is non polar.
IInd structure is more stable than IIIrd because –ve charge on more E.N. atom is more stable than –ve charge
on less E.N. atom.
62. Which among the following halide/s will not show SN1 reaction
(A) H2C=CH–CH2Cl (B) CH3–CH=CH–Cl

CH2–Cl CH3
CH–Cl
H3C
(C) (D)
Choose the most appropriate answer from the options given below :
(1) (A), (B) and (D) only (2) (A) and (B) only
(3) (B) and (C) only (4) (B) only
Ans. 4
CH3 – CH = CH – Cl has double bond character between C & Cl atom due to resonance.

63. Which of the following statements is not correct about rusting of iron?
(1) Coating of iron surface by tin prevents rusting, even if the tin coating is peeling off.
(2) When pH lies above 9 or 10, rusting of iron does not take place.
(3) Dissolved acidic oxides SO2, NO2 in water act as catalyst in the process of rusting
(4) Rusting of iron is envisaged as setting up of electrochemical cell on the surface of iron object.
Ans. 1
Fact

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64. Given below are two statements :
Statement (I) : In the Lanthanoids the formation Ce+4 is favoured by its noble gas configuration
Statement (II) : Ce+4 is a strong oxidant reverting to the common +3 state.
In the light of the above statements, choose the most appropriate answer from the options given below:
(1) Statement I is false but Statement II is true (2) Both Statement I and Statement II are true
(3) Statement I is true but Statement II is false (4) Both Statement I and Statement II are false
Ans. 2
Ce = [Xe] 4f' 5d1 6s2
Ce+4 = [Xe] 4f° 5d° 6x°
(2) Both I and II are correct.

65. Choose the correct option having all the elements with d10 electronic configuration from the following :
(1) 27Co, 28Ni, 26Fe, 24Cr (2) 29Cu, 30zn, 48Cd, 47Ag
(3) 46Pd, 28Ni, 26Fe, 24Cr (4) 28Ni, 24Cr, 26Fe, 29Cu
Ans. 2
Cu = 3d10 4S1
Zn = 3d10 4S2
cd = 4d10 5S2
Ag = 4d10 5S1

66. Phenolic group can be identified by a positive :

(1) Phthalein dye test (2) Lucas test (3) Tollen’s test (4) Carbylamine test

Ans. 1

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67. The molecular formula of second homologue in the homologous series of mono carboxylic acid is_______.
(1) C3H6O2 (2) C2H4O2
(3) CH2O (4) C2H2O2
Ans. 2
Ist homologue of Carboxylic acid = HCOOH
IInd homologue of Carboxylic acid = CH3COOH (C2H4O2)

68. The technique used for purification of steam volatile water immiscible substances is :
(1) Fractional distillation
(2) Fractional distillation under reduced pressure
(3) Distillation
(4) steam distillation
Ans. 4
Stem distillation method is used to separate substance which are stem volatile and are immiscible with water.
however, the impurities should not be steam volatile in or der to purify the substance by steam distillation.
69. The final product A, formed in the following reaction sequence is :
 i  BH3
 ii  H2O2 , OH
Ph–CH=CH2 
A
iii HBr  
 iv  Mg, ether, then HCHO/H3 O

(1) Ph–CH2–CH2–CH3

(2) Ph–CH–CH3
CH3

(3) Ph–CH–CH3
CH2OH
(4) Ph–CH2–CH2–CH2–OH
Ans. 4

(i) BH3 (iii) HBr

Ph–CH=CH2 Ph–CH2–CH2–OH Ph–CH2–CH2–Br
–
(ii) H2O2, OH
Mg/ether

HCHO/H3O+
Ph–CH2–CH2–CH2–OH Ph–CH2–CH2–Mg– Br

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70. Match List-I with List-II
List-I List-II
(Reaction) (Reagent(s))
OH OH
COOH

(A) (i) Na2Cr2O7, H2SO4

OH OH
CHO

(B) (ii) (i) NaOH (ii) CH3Cl

OH O

(C) (iii) (i) NaOH, CHCl3 (ii) NaOH (iii) HCl

O
OH

OCH3
(D) (iv) (i) NaOH (ii) CO2 (iii) HCl
Choose the correct answer from the options given below:
(1) (A)-(IV), (B)-(I), (C)-(III), (D)-(II) (2) (A)-(II), (B)-(III), (C)-(I), (D)-(IV)
(3) (A)-(II), (B)-(I), (C)-(III), (D)-(IV) (4) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
Ans. 4

OH

(B) (i) NaOH, CHCl3 (ii) NaOH (iii) HCl

Reimer Tiemann Reaction

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71. Major product formed in the following reaction is a mixture of :
CH3
HI
O–C–CH3 Major product
CH3

I I

and (CH3)3Cl and (CH3)3COH

(1) (2)
OH
CH3
OH
and CH3–C–I
and (CH3)3COH
(3) (4) CH3

Ans. 4

CH3 CH3
HI
O– C – CH3 OH+ I – C – CH3
CH3 CH3

72. Bond line formula of HOCH(CN)2 is :

H
CN
C–CN HO–CH
CN
(1) HO CN (2)
OH
CN
HO–CH
(3) CN (4) CN CN

Ans. 4
Fact

73. Given below are two statements:

Statement (I): Oxygen being the first member of group 16 exhibits only –2 oxidation state.
Statement (II): Down the group 16 stability of +4 oxidation state decreases and +6 oxidation state increases.
In the light of the above statements, choose the most appropriate answer from the options given below:
(1) Statement I is correct but Statement II is incorrect
(2) Both Statement I and Statement II are correct
(3) Both Statement I and Statement II are incorrect
(4) Statement I is incorrect but Statement II is correct
Ans. 3
O.S of oxygen are = –2, –1, 0
down the group stability of lower O.S. increases and Higher O.S. will decreases.

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74. Identify from the following species in which d2sp3 hybridization is shown by central atom:
(1) [Co(NH3)6]3+ (2) BrF5 (3) [Pt(Cl4)]2– (4) SF6
Ans. 1

[Co(NH3)6]3+  3d6 & SFL d2sp3

BrFs sp3 d2
[Pt Cl4]2– dsp2
SF6 sp3d2

75. Identify B formed in the reaction

Cl–(CH2)4–Cl 
excess NH3
 A 
NaOH
 B  H 2 O  NaCl

NH
(1) (2) H2N–(CH2)4–NH2

N
N
 
(3) Cl N H3 –  CH 2 4 – N H3Cl –
(4)

Ans. 2

Cl–(CH2)4–Cl excess NH3 H2N–(CH2)4–NH2+HCl

+ +
Cl––H3N –(CH2)4 –NH3Cl–
NaOH

H2N–(CH2)4–NH2

76. The quantity which changes with temperature is:

(1) Molarity (2) Mass percentage (3) Molality (4) Mole fraction
Sol. (1)
Molarity depends on temperature while other terms are mass dependent and temperature independent.

77. Which structure of protein remains intact after coagulation of egg white on boiling?
(1) Primary (2) Tertiary (3) Secondary (4) Quaternary
Ans. 1
The coagulation of egg white on boiling is a common example of denaturation. Due to denaturation, the
secondary and tertiary structure are destroyed but primary structure remain intact.

78. Which of the following cannot function as an oxidising agent?

(1) N3– (2) SO24 (3) BrO3 (4) MnO4
Ans. 1

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 SO4 2
BrO3 acts as oxidising agent
MnO4

N3– not acts as oxidising agent.

79. The incorrect statement regarding conformations of ethane is :

(1) Ethane has infinite number of conformations.
(2) The dihedralangle in staggered conformation is 60°.
(3) Eclipsed conformation is the most stable conformation.
(4) The conformations of ethane are inter-convertible to one-another.
Ans. 3
Staggered conformation is most stable not eclipsed.

80. Identity the incorrect pair from the following:

(1) Photography – AgBr (2) Polythene preparation – TiCl4, Al(CH3)3
(3) Haber process - Iron (4) Wacker process – Pt Cl2
Ans. 4
Wacker process PdCl2 acts as catalyst

unsaturated hydrocarbon 

PdCl2
 saturated hydrocarbon.
SECTION – B

81. Total number of ions from the following the noble gas configuration is ______.
Sr2+ (z = 38), Cs+ (z = 55), La2+ (z = 57), Pb2+ (z = 82), Yb2+ (z = 70) and Fe2+ (z = 26)
Ans. 2
Sr2+
Cs+
82. The number of non-polar molecules from the following is ______.
HF, H2O, SO2, H2, CO2, CH4, NH3, HCl, CHCl3, BF3
Ans. 4
H2
CO2
Nonpolar molecules
CH 4
BF3

83. Time required for completion of 99.9% of a First order reaction is ______ times of half life (t 1/2) of the
reaction.
Sol. 10
2.303  t1/2 100
t 99.9  log
0.693 0.1
t99.9 = 10 t1/2

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84. The Spin only magnetic moment value of square planar complex [Pt(NH3)2Cl(NH2CH3)]Cl is ____ B.M.
(Nearest integer)
(Given atomic number for Pt = 78)
Ans. 0
[Pt2+(NH3)2 Cl(NH2 CH3)]Cl
Pt = 5d6 6s1
Pt 2+ = 5d8 6s°
All big and behaus as S.F.L.

 = 0.0.

85. For a certain thermochemical reaction M  N at T = 400 K, H = 77.2 kJ mol–1, S = 122 JK–1, log
equilibrium constant (logK) is –_______ × 10–1.
Sol. 37
Go=Ho–TSo
= (77.2×103)–(400×122)
= 28400 J
Go=–2.303 RT log K
log K = 3.7 = 37×10–1
86. Volume of 3M NaOH (formula weight 40 g mol–1) which can be prepared from 84 g of NaOH is
____ × 10–1 dm3.
Sol. 7
84
Moles of NaOH   2.1mol
40
n
NaOH 2.1
Volume of solution  
m 3
= 0.7=7×10–1
87. 1 mole of PbS is oxidised by "X" moles of O3 to get "Y" moles of O2. X + Y = _______.
Sol. 8
Pbs+4O3  PbsO4+4O2
According to balanced equation
X=4 Y=4
X+Y=4+4=8
88. The hydrogen electrode is dipped in a solution of pH = 3 at 25°C. The potential of the electrode will be –
_______ × 10–2 V.
 2.303RT 
  0.059V 
 F 
Sol. 18
pH = 3
[H+] = 10–3
2H++2e–  H2(g)
0.059 PH 2
E=Eo – log
 H 
2
2
0.059
E=0 – 6
2
= –0.177= –17.7×10–2  18×10–2

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89. 9.3g of aniline is subjected to reaction with excess of acetic anhydride to prepare acetanilide. The mass of
acetanilide produced if the reaction is 100% completed is _____ × 10 –1 g.
(Given molar mass in g mol–1 N : 14, O : 16,
C : 12, H : 1)
Sol. 135
O
NH2 HN–C–CH3

+ CH3–C–O–C–CH3
O O
9.3 g
Excess + CH3–COOH
(Balanced)
9.3
moles = moles = 0.1
93
= 0.1 mole mas = 0.1×135
= 13.5 g

90. Total number of compounds with Chiral carbon atoms from following is _________.

O
O O

CH3 – CH2 – CH(NO2) – COOH

CH3 – CH2 – CHBr – CH2 – CH3
CH3 – CH(I) – CH2– NO2
CH3 – CH2 – CH(OH) – CH2OH
CH3 – CH – CH(I) – C2 H 5
|
I

Ans. 5
O


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Revised