SUBJECT

(ENVIRONMENTAL SCIENCE)
LECTURE COMPANION SEMESTER: I/II PREPARED BY:Darshika Shah

CHAPTER 3 ENVIRONMENTAL POLLUTION

3.2 AIR POLLUTION

3.2.1 DEFINATIONS
“Anything which degrades the quality of ambient air is known as Air Pollution”
OR
“Presence of unwanted and undesirable foreign particles an gases in the air which
may have adverse effects on living beings and important structure is known as Air
Pollution”

Air pollution is the presence of chemicals and particles in the atmosphere in

concentrations high enough to harm organisms, ecosystems, or human made materials, or to
alter climate.

3.2.2 COMPOSITION OF AIR

Atmosphere is a protective layer for the earth, which is made of three basic elements
i.e. gases, water, vapor and dust particles
The living being i.e. the bio sphere is developed due to the presence of atmosphere.
Human life, food, shelter (home) etc. are influenced by theatmosphere. The Gases
includes Nitrogen Oxygen, Argon, Carbon Dioxide and traces of Carbon monoxide,
oxide of sulphur, nitrogen and hydrocarbon etc., with changing concentration of
which decreases with increases in altitude.

The major gases in pollution free dry air are

(1) Nitorgen 78%
(2) Oxygen 21%
(3) Argon 0.9%
The minor gases in free dry air are
(1) Water vapor 0.1%
(2) Carbon Monoxide 0.032%
(3) Neon(Ne) 0.0018%
(4) Methane (CH4) 0.0002%

The Trace gases ( Gases which are less than 1% of total gas on earth)
Ozone (O3), CO, H2, NH3, NO, NO2 Gases having concentration less than
0.000006%.
3.2.3 STRUCTURE OF ATMOSPHERE:
Dependent on various parameter like temperature, pressure, density of atmosphere, it
is divided in five different layers.

(1) Troposphere
(2) Stratosphere
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(3) Mesosphere
(4) Thermosphere
(5) Exosphere

1. Troposphere :

About 75–80% of the earth’s air mass is

found in the troposphere, the atmospheric
layer closest to the
earth’s surface, where most living
organisms exists.

This layer extends only about 17 km above

sea level at the equator and 8 Km
kilometers over the poles

Temperature decreases with altitude, top

part of troposhere is known as Tropopause.
And temperature range of it 20 ℃ to - 56 ℃

2. Stratosphere
• A stable layer above Troposhere is called a Stratosphere ,which is exteds about
50-55 km above the surface of earth.
• It is known for presence of Ozone layer . which is found near about 20 – 25
Km above the surface of earth
• This layer is our protective layer which protect us from ultra violet radiations
• Because of absorption of ultraviolet radiation by ozone layer it raises the
temperature of this layer up to -56 ℃ to -2 ℃
• top part of this layer is called a Staratopause

3. Mesosphere
• It exists over stratosphere and in this layer, temperature decreases
with altitude because of low levels of ozone
• It absorbs ultraviolet radiation.
• layer between mesosphere and thermosphere is known as mesopause.
• It extended up to 50 km to 85 km and temperature range – 2 ℃ to – 92 ℃

4. Thermosphere
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• Thermosphere extends up to 500 km above earth’s surface.

• Temperature rises in this zone with altitude
• Ionization of elements like oxygen and nitric oxide take place in the
upper most portion of layer. Therefore, the upper layer of thermosphere
is also called ionosphere
• Temperature range of this layer is near about – 92℃ to 1200 ℃.
5. Exosphere
• The upper most layer of the atmosphere is called exosphere.
• individual atoms can escape from the Earth’s gravitational attraction therefore
this region is called exosphere
3.2.4 CLASSIFICATION OF AIR POLLUTANT:
Air pollutants can be classified as under
• Based on Origin
• Based on States of matter
a) Classification based on origin of pollutants
Depending upon the origin of pollutants, the air pollutants are classified as
1. Primary air pollutants
2. Secondary air pollutants

1. Primary Air Pollutants: Pollutants which are directly emitted from the sources to
the atmosphere primary air Pollutants.
e.g. Sulphur oxides (SOX), Nitrogen Oxides (NOX), Carbon Monoxide, Radio
active materials, Particulate matter etc…..

2. Secondary Air Pollutants : Pollutants which are formed by chemical reactions

among primary pollutants and atmospheric chemicals are known as Secondary Air
Pollutants.
e.g. Ozone, Sulphur Trioxide, Photo-chemical smog, etc. Petroxacyl nitrate (
PAN ) etc…

b) Classification based on States of matter

Based on states of matter air is classified in two categories
1. Gaseous air pollutants
2. Particulate air pollutants

1. Gaseous air pollutants: Pollutant which are found in the gaseous state at normal
temperature and pressure are called gaseous air pollutants
e.g. Carbon monoxide (CO), Carbon dioxide (CO2), Nitrogen oxides
(NOX), Sulphur oxides (SOX) etc…

2. Particulate air pollutants: Particulates are finely divided, air borne solid and liquid
particles which remain for very long period of time in air.
e.g. Aerosols, Dust, Smoke, mist, fog etc………

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NOTES:
• Aerosols : Air borne suspensions of solid or liquid particles smaller than 1 mm size
e.g. dust, smoke, mist etc.
• Dust: It consists of small solid particles having a size of 1 to 200 mm
• Smoke : it formed by incomplete combustion of organic matter (wood) having a size of 0.1
to 1 micro meter
• Mist : it consists of liquid droplets of size around 0.1 t 1 micro meter raised due to
condensation of vapours in the atmosphere

3.2.5 SOURCES OF AIR POLLUTANTS

1. Natural Sources
2. Man Made Sources

1. Natural sources:

The following are the different forms of natural sources:

(1) Atmospheric reactions:

In the atmosphere, different types of chemical reactions are always going on. In the lower
atmosphere, the gases or vapours are converted in solids and liquids by condensation or
oxidation.'
In the upper atmosphere, the photochemical reactions are going on by the absorption of ultra-
violet solar radiation. It breaks the complex molecules of organic matters.
The products of atmospheric reactions come down to earth Gases and ash released from
volcanic eruptions by rain, snowfall, etc.

(ii) Gases and ash released from volcanic eruptions.

(iii) Smoke and green house gases released by forest fires.
(iv) Harmful gases, particulates and chemicals from dust, storms,electric storms etc.
(v) Marsh gases due to decay of vegetable matter in marshy places.
(vi) Pollen: These may enter the atmosphere from the flowers of trees, grasses and weeds and
may be transported from place to place by wind.
(Vii) Salt spray from oceans.
(Viii) Microorganisms: These are in the form of algae, fungi, bacteria, yeast etc. These
organisms can be transported by wind to far distances and can affect plants, animals and
human beings,
(ix) Radioactive substances: The radioactive substances like uranium, radium, thorium, etc.
present in the earth crust are responsible for imparting the radioactivity of air.

2. Man-made sources: The following are the man made sources of air pollution
I. Combustion of fuel : In domestic areas, the burning of coal, wood, oil, LPG. etc.
forms harmful gases which pollutes the air..

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II. Automobile exhaust : Automobiles like truck, buses, cars, two wheelers,
autorickshows, etc. exhaust carbon monoxide (CO) which is dangerous to human
health.
III. Industries: The industries like iron and steel manufacturing oil refinery, chemical
factories, petro-chemical plants, pulp and paper, etc, cause serious air pollution
IV. Thermal and Nuclear power plants : The thermal power plants contribute
sulphur dioxide (S02) and nuclear power plants contribute radioactive fly ashes to
the atmospheric air.
V. Agricultural activities : Use of pesticides for growing crops may cause air
pollution
VI. Construction materials: The manufacture of bircks, cement, stone chips, etc.
pollutes the atmosphere by discharging smoke, gases and dusts.
VII. System of sanitation : The unscientific disposal of garbage produces foul gases,
bad odour and insanitary condition. In towns where the conservancy system is
followed, the system of disposal of night soil produces foul gases and fly
nuisance.
VIII. Mining
IX. Nuclear explosions
X. Air crafts
XI. Waste water treatment plants

The man-made sources of air pollution can be classified as:

A. Point or stationary sources: These are the sources which add pollutants to air from
one or more controllable points. e.g. Chimneys of different industries. Pollutants from
point sources affect only restricted areas.

B. Line or mobile sources : The line or mobile sources of air pollution are the sources
like automobiles, trains, ships aeroplanes, etc. which emit exhaust into air along a
narrow belt over long distance.

C. Area sources: Area sources are locations from which air pollutants are emitted from
a well defined area. e.g release of air pollutants from industrial area of town or city
which affects particular area.

3.2.6 MAJOR AIR POLLUTANTS- SOURCES AND EFFECTS

The major air pollutants are:

1) Carbon monoxide (CO)

2) Carbon dioxide (CO2)
3) Oxides of Nitrogen (NOx)
4) Oxides of Sulphur (SOx)
5) Hydrocarbons (HC)
6) Photochemical Oxidants
7) Particulate matter (PM)
8) Ground level ozone

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1) Carbon monoxide (CO): Carbon monoxide is a colourless, odourless, tasteless gas,

chemically inert under normal conditions of temperature and pressure. It is not soluble in
water.
At normal concentration (less than 0.1 ppm) it is not harmful, but if its concentration
exceed 0.1 ppm in atmosphere it seriously affect the human metabolism.
Sources:
1. Natural processes like volcanic eruptions, natural gas emissions, electric discharge during
storms, seed germination, manh gas production, etc. contribute a small amount of CO in the
atmosphere,
2 Transportation sources contribute about 65% of CO in air.
3. Solid waste disposal
4 Forest fires
5. Coal mines
6 Industrial processes such as electric furnaces and blast furnaces in iron and steel industry,
petroleum refining, paper industry, etc:

Effects:
1. CO has strong allinity with haemoglobin and it combines with blood haemoglobin to form
Carboxyhemoglobin (COHb) which reduces the oxygen carrying capacity of blood
2. It reduces vision, causes headache.
3. It affects the nervous system and imparts laziness.
4. It causes cardiovascular disorders.
3. It may cause coma, respiratory failure and even death.

Carbon dioxide (CO2): Carbon dioxide is ideally not considered as an air pollutant if its
presence does not exceed the concentration ideally present in atmosphere,
The content of CO2, in the air has increased by approximately 15% during the last century
inspite of the fact that photosynthesis process of green plants balance the CO2 - O2 ratio to a
large extent.

Sources:

1. Fossil fuel combusiton.

2. Jet planes use O2 and release CO2
3. Respiration process
4. Forest fires
5 Decay of organic matter, etc.

Effects :

1. It is the main green house gas responsible for rise in average temperature of
atmosphere.
2. CO2 is less dangerous than CO and causes nausea and headache.
3. It disturbs atmospheric stability and thus plays an important role in climate changes
in atmosphere.

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3) Oxides of Nitrogen (NOX): Among the six different oxides of nitrogen [NO, NO2,
N2O, N2O3, N2O4 N2O5 ] nitric oxide (NO) and nitrogen oxide (NO2) are very important
pollutants.
NO is colourless, odourless gas but NO2 is reddish brown and have suffocating odour.
NO and NO2 are formed as under
N2 + O2 = 2NO
2NO+O2 = 2NO2

Sources:

1. Foel combustion in automobiles and industries

2. Light thundering
3. Forest fires
4. Bacterial decomposition of organic matter
5. Natural ionizing radiations

Effects:

1. Like CO, nitric oxide (NO) can also combine with haemoglobin and reduces the oxygen
carrying capacity of blood.
2. NO2 is more toxic then NO and may affect lungs and cause bronchitis:
3. NO2 absorbs light and thus reduce the visibility.
4. NO2 reacts with atmospheric moisture to form nitric acid causes acid rain and affects
vegetables and metals.

4) Oxides of Sulphur (SOX): Sulphur oxides are called SOx. Among the six oxides of
sulphur [SO, SO2 ,SO3 ,S04, S2 03, S2O7] sulphur dioxide (SO2) and sulphur trioxide
(SO3) are very important pollutants.
SO2 is colourless, nonflammable and nonexplosive gas which may impart suffocation.
SO2 and SO3 form H2SO3 (sulfurous acid) and H2So4 (Sulfuric acid) in the air.

Sources:
Natural processes like volcanic eruptions contribute to 67% of SOx pollution, whereas
33%.come from anthropogenic sources as mentioned below:

1. Burning of fossil fuels

2. Emissions from vehicles
3. Emissions from industries - thermal power plants, oil
4. Solid waste disposal

Effects :

1. It causes cardiac diseases, asthma, bronchitis, eye irritation, throat troubles, ctc.
2. Long term exposures to high levels of SO, gas causes respiratory illness and heart disease
3. Oxides of sulphur attacks building materials especially marbles and lime stone. e.g. Taj
Mahal at Agra

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4 SO2 react with moisture in atmosphere to form sulphuric acid which causes acid rain and
affects vegetables and metals.
5. Oxides of sulphur may affect clothes, leather, paper and plants.

5) Hydrocarbons (HC) : The main hydrocarbons which may be gaseous and/or volatile air
pollutants are methane (CH). ethane, scetylene and ethylene

Sources:

1. Incomplete combustion of fossil fuels.

2. Refineries and industries
3. Agricultural burning
4. Emissions from vehicles.
5. Forest fires
6. Emissions from trees

Effects :

1. Unburned hydrocarbons with oxides of nitrogen in the presence of sunlight form

photochemical smog which can have adverse effects on humans and plants
2. Ethylene may inhibit the growth of plants
3. Some aromatic hydrocarbons may cause cancer.

6) Photochemical Oxidants : The major photochemical oxidant is ozone (O3). Ozone is

produced in the upper atmosphere by solar radiation. Small concentrations of this gas
diffuse downwards and become the major concern in air pollution

Formation: In the presence of sunlight, the oxides of nitrogen react with the unburned
hydrocarbons released by the exhausts of automobiles (fuel combustion) and following a
series of complex reactions produce secondary pollutants like peroxyacyfnitrate (PAN),
Ozone (O3), aldehydes and ketones etc,

Unburnt Hydrocarbon + NOx + Abundant Sunlight = Photochemical Smog

Sources:

(1) Automobile exhausts

Health Effects :

(1) Photochemical oxidants cause irritation of eye, nose and throat, headache etc, in man.
(2) Ozone damage chromozomes
(3) and PAN cause damage to plants by interfering with plant cell metabolism especially in
leafy vegetables.
(4) Premature fall and Yellowing of leaves are due to this pollutant.
(5) Photochemical oxidants also effect the materials like rubber plants, textile fibers etc.

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7) Particulate Matter (PM) : Particulate matter are finely divided air borne, solid and
liquid particles (droplets) which remain for very long time in air, in suspension.
The size of particulate ranges from 0.02 µ to 500 µ.
The examples of particulate matter are dust, fume, smokes, fog, mist, etc.
The more general classification of particulates is
a. TSPM - Total suspended particular matter
b. RPM - Respirable suspended particulate matter, popularly known as PM10
PM10 are particulates of equivalent spherical diameter of 10 µm or less. PM10 directly
affect health and not the whole range of sizes of particulates.

Sources
1. Valcanic eruptions
2. Spraying of salts by oceans.
3. Smoke from vehicles
4. Agricultural burning
5. Dust storms
6. Fly ash from combustion of fossil fuels
7. Mining

Effects
1. Fly ash and soot discharged by burning of coal causes respiratory diseases.
2. 2 Atmospheric dust causes allergic and respiratory diseases in man. If dust contains
silica it leads to silicosis.
3. Metal dust containing heavy metals and cotton dust may also cause respiratory
diseases
4. Air bome asbestos and toxic metals are carcinogenic.
5. Vehicular particulates containing lead affects haemoglobin formation
6. Aerosols released from aeroplanes may affect ozone layer.
7. Mist and fog reduce visibility
8. Flyash reduces pH balance and potability of water
9. Particulates cause damage to buildings, sculptures and plants

- Black Carbon: It is a particulate air pollutant produced from incomplete combustion of

fuels. It is a solid particle It is also called soot or aerosol.

Brown carbon is referred for green house gas.

Sources of black carbon :

diesel exhaust
cooking with solid fuels
biomass burning

Black carbon warms the earth by absorbing heat in the atmosphere

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It reduces albedo (the ability to reflect sunlight) when deposited on snow and ice. 25 to 35
% of black carbon in the global atmosphere comes from China and India
In India,’ Project Surya’ has been launched by the Government of India to reduce black
carbon in the atmosphere by introducing efficient stoves, solar cooker, solar lamps and biogas
plants.

8) Ground level Ozone: Ground level ozone is the ozone present in the earths lower
atmosphere. It is produced by a complex chemical reaction when nitrogen oxides (NOx).
Carbon monoxide (CO) and volatile organic compounds (VOCs) such as xylene, react in
the presence of sunlight. These chemicals are produced from cars, trucks, electric power
plants, paint fumes and industrial process. Ground level ozone is the primary constituent
of smog. Ground level ozone, though less concentrated than ozone in the stratosphere, is
more of a problem because of its health effects:

The major health effects are -

1. Irritation of the respiratory system causing coughing, throat irritation and an

uncomfortable sensation in the chest.
2. Aggravations of asthma. The reason is that ozone makes people more sensitive to
allergies, which in turn triggers asthma attacks.
3. Increases susceptibility to respiratory infections.
4. Inflammation and damage of the lining of lungs.

3.2.7 EFFECTS OF AIR POLLUTANTS

(a) Effects of Air pollution on Human health:

The general health effects of air pollution are:

1 . Carbon monoxide (CO) and nitric oxide (NO) combine with haemoglobin to form carboxy
haemoglobin (COHb) which reduces oxygen carrying capacity of blood.
2. Oxides of nitrogen (NO) and oxides of sulphur (S0,) cause irritation to eye, throat and
nose. They also cause diseases like asthma and bronchitis, etc.
3. Secondary pollutant (PAN) produced by hydrocarbons and NO results in the formation of
photochemical smog, which causes irritation of cyes, nose, throat and respiratory diseases.
4. Some aromatic hydrocarbons may cause cancer
5. Exposure to dust, smoke, smog and soot may induce several respiratory diseases like the
bronchitis and lung cancer.
6 Atmospheric dust containing slilica may cause silicosis.
7. Air borne asbestos and toxic metals are carcinogenic.
8. Heavy metals like lead may cause poisoning effects on nervous system, damage to kidney
and vision problems.
9. Pollens initiate asthamatic attacks.
10. Mercury from combustion of fossil fuels, plants result in nerve brain and kidney damage
11. Nickel particulates in tobacco smoke result in respiratory damage.
12. Radioactive substances cause lung diseases and affect kidney, liver, brain and sometimes
cause cancer.

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(b) Effects of Air pollution on plants and vegetations

1. Air pollutants affect plants by entering through stomata (leaf pores through which
gases diffuse), destroy chlorophyll and affect photosynthesis. During the day time the
stomata are wide open to facilitate photosynthesis. Air pollutants during day time
affect plants by entering the leaf through these stomata more than night.
2. Pollutants also erode waxy coating of the leaves called cuticle, Cuticle prevents
excessive water loss and damage from diseases, pests, drought and frost. Damage to
leaf structure causes dropping of leaves,
3. Particulate like dust, fog, soot deposit on plant leaves, block stomata and affect the
rate of transpiration.

(C) Effects of air pollution on Materials and Buildings:

1. Sulphur dioxide effects marble, limestone, roofing, paper, building, textile and
monuments.
2. NOx, fades away textile dyes like cotton, rayon etc. Higher level of NO, causes 10%
lop of fibre strength in cotton and rayon.
3. Leather also has afinity for SO2, which affects its strength and causes it to
disintegrate.
4. Low concentration of ozone induces chemical alteration in natural synthetic textiles,
paper, rubber and polymers
5. Particulates accelerate corrosion of metals. Dust, soot, mist, aerosols bring about
severe damage to soil, building, sulpture and monuments.
6. H2S and organic sulphides react with lead paints to form lead sulphide thereby
producin brown to black discoloration
7. Hydrocarbons (HC) pollutants damage long chains of carbon atoms loosing tensile
strength of polymers

(d) Effects of air pollution on climate :-

Due to man made activities like industrialization, automobiles, deforestations etc.,

concentration of Co, and other green house gases in atmosphere will increase. About 50% of
Green House Effect may be attributed to CO,, which resulted in the increase in temperature
of earth. This increase in temperature caused the melting of ice caps and glaciers. Thus the
increase in ambient air temperature will increase the mean sea level.

(e) Effect of air pollution on Aesthetic beauty

The most noticeable effect of air pollution on the properties of atmosphere is the reduction in
visibility, which may lead to safety hazards. Visibility is reduced by absorption and scattering
of light. The aesthetic beauty of nature is not visible due to scattering of light by air bome
particles (0.1 to 1 mm size). Industrial and automobiles emissions, sewage and garbage emit
foul odours causing loss of aestetic beauty.

(f) Effects of air pollution on Animals :

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Animals are indirectly affected by air pollution mainly by eating contaminated vegetation.
• Lead poisoning occurs in animals grazing near smelters and lead mines. It causes
paralys and difficulty in breathing. It also leads to loss of appetite and diarrhoea.
• Arsenic poisoning in animals causes severe salivation, thirst, vomiting irregular pulse
and respiration, abnormal body temperature and death,
• Farm animals like cattle and sheep are quite susceptible to fluorine toxicity. It affects
to la of apetite, periodic diarrhoea, muscular, weakness loss of weight and death.

3.2.8 CONTROL OF AIR POLLUTION :

The most effective means dealing with the problem of air pollution is to prevent the
formation the pollutants or minimise their emissions at the source itself.

Following measures can be taken to control air pollution :

1. Dilution
2 Zoning
3. Control at source
4. By using controlling equipments

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