Harshit Thermochemistry

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Bxanch o phusca chetishy ushihcloals Lith the

tanen ca act Slio achemícol sys terl BitssTOYdn,


hem a chonge a phaseox cheicA) Pxn tates da ca ithin

na chemícal ex
Reac tantPscdud
foy achenicol Rxn
A n <CA)produet -shu)Resutant

AHn s(Axo duct -&(AH) xeacamt

is ociahion enthaleg o oescat &poduc


qivem

Balamed humical an
3phyeical stak
Pasct chonge
Eg 2Kcleses
Slhemochemica Rx"
EmdothonnIC. ExotheumËc

Hy-Ho
Hp>He
Stalse ymoestasle
he amount hea evolvecl ox obsoYhed uhen na
mdes o Reacant acc do he baolamced chermica Rn had
conpltoly Uaded is called oot o Rxn.

d Las hennochom ísty


0) AH=XKTI emthalpy valuw sl be So
bat Sigaa chamge
(2)
MA

AH =3SoT

Hes laue Bz
SH

AH = NHt aH2t MH?

P
C 728 H100
Calcoloe AH 2 e
Soln

* Factxs Affechng Heat o Rng2


Rxn cond" & h chemicol xn arl caÍP) out at coytar

AH =2X(-x Kcal mo1

EX

Cagaplk ta 7 Co2
AHy 3g9-sKTmo

sp Hbd Asest bd
Dlamenel
kichoPfs eaM
T-T

ciç) At Const. vo)

Acum Ccim)e -slesa)


Noteg) Heat change o n coes not capend on dhe no. a) stp
Qi) Heat chamge a zxn does not upentd o iatamesiate pos"
t cepemd snly n 1nitia) &inal otate
(1) Heat chonge o a chemical gxn oloes mot sclopenc on dine

Lal) the partcipahing substouno axe in daeit stumdard stak


Stondand state Soeeerment
c qxaphite N’Nz(9)

mole a suhs anee iss foxned mitk


elornort ivn drein stada stale
DATE

lmole.

fosmakon enthalpy s element in tein dtamaard state


istaken ad Ze70.

AH=CAmpoduct-CAHnchuk

Jmoleoov

Cpasmond to co CAHcovk) CAH) X

mole) icaliseece mple cobX


Co
Jmole 2

product au eM
AMaM)Rsactat arpzcduel
vale

Conpleklybund
caloxilíc alus = ARcovb
LMolecashst
Unit =Kig Kal
HeatoCombus ion gxn ís aleyg enothenie
condn ane not qíve n then HComb Coaiderce cs AHCod
’ a hAs the highest caloxiíc waue lbut ít is not et
ecaical íseL

to change tae phe a a Subst. clon the fontcuko


valourisaten
Solíd Liquul
Cyatatigahon Condemsato
AHjon, AHvapoun ’ Sndothayche

Allo tsopic tcniHon'>


haley >CtH
Mo
phcue) gas Cinmo<ecul polyatomniç 1nQ boncl Mdloe
anouttal aw the is
Eatalg,e Bond mean Hverag
(AMleral) s0.d-uet bondp CAH AMy=
podet xeactautEg Erthalpyo disocahon ond
thup disociaton =Gano enthaley Bond Rrneral 2n
isovalent
cal qaseouy bonds
a Covalent
eamn enthle, aton fom Gond
íssociathon Bond Enthalege. Bone
Ex He)

Noe foy diaoe gase0 w) Molee, bHa= AHbovd


=DHSublmation
CNon-vie)

LH BorJ
Nq s

Heatco Tonísakon t is the antoutt o heatabsoted


shem
Heat o Neutolisationgk ísdho amaunt heot
lent a acid complelely neutsali_es ay Loe ym
Aadt Base $alt tt0
fo

Sfconart

last Oalcuate the Heotgi)ebsedabsot?

nea)NocH = NdGoy VWaot (n-facton)NgoH MaotXVNoa


Hc) t N a o a c t H 2 0

t t o.02-0.0)o.ol-oel oo) o)Remng Q-ele

Ay 3 KCa) Xo. o/

ondenge jonisatio n o, eckb


acidlaye
Latia enthalpg& Bord enthalpy kos iorie solk
lhe emthaley chage usthich occury nen ynde

LEg Nacls>
LE =tVe
Inpranad
LE > dssodatong_ Ioníc solída
Mg os)-MgTtozf AH Lotice
Lothie enthalyCalclaBed by Bon Haberds aycle
2 Ngcksz
AHabyAy

n one nolo a íonic cgd get


Aafg)t
a4

CG).t¡q

HychakS
Sa•t
OATE

it dis solves in a specilied ameunt hert


Nadcc) BRsolfCao) t ccã¡)

Stale OYa¯ing Stuctu.


Jes stabe R.E=-ye mott stobe
Shuchue StuctwD,
Cles nane)

MRE = AMcalcoated- AMhseree

puning Hydreynakon
2olc)honel

Let w Conaíder olloun get enlaalpy change


AH2asks t=2.QIKD
AR=-2-79K yn

Ato AHtton-2t
’ The entraly a ilshom o )n ishpendnt
amewt soluent addec

ncHz=ct lolys fcH,-cM


e h e n e o felyetter

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