12th Chemistry CH-14MCQs

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CHAPTER 7

FUNDAMENTAL PRICIPLES OF ORGANIC CHEMISTRY

1. The total coal resources of Pakistan estimated by geological survey are:


(a) 184 billion tonnes (b) 184 million tonnes
(c) 841 billion tonnes (d) 184 tonnes
2. How many isomers are possible for C6H14:
(a) 4 (b) 5 (c) 6 (d) 7
3. Which one of the following is an isomer of Dimetly ether:
(a) (CH3)2 CHOH (b) CH3CH2OH (c) CHO-CHO (d) None

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4. The hardest form of coal is:
(a) Bituminous (b) Sub-bituminous coal (c) Anthracite (d) Lignite
5. Which one of the following compounds is heterocyclic?
(a) Anthracene (b) Phenol (c) Pyridine (d) Aniline
6. Which molecule has a tetrahedral shape?
(a) CH3-CH3 (b) CH2=CH2 (c) CHΞCH (d) None

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7. The formula of aniline is:
(a) C6H5 (b) C6H5-NH-C6H5
(c) C6H5-NH2 (d) C6H5-NO2
8. The formula of cyclopropane is:
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(a) C3H8 (b) C3H4 (c) C3H5 (d) C3H6
9. The Octane number is 100 for:
(a) n-Octane (b) n-Heptane
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(c) Iso-Octane (d) n-Hexane
10. Homologues of alkanes differ from each other by:
(a) CH2 group (b) CH3 group
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(c) CH4 group (d) CH group


11. The major components of coal gas are:
(a) H2 and CH4 (b) Ethane and CO
(c) H2 and CO (d) H2, CH4 and CO
12. The compound in which two alkyl groups are attached to carbonyl group is called:
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(a) Ether (b) Alcohol


(c) Ketone (d) Aldehyde
13. Carbonyl group is present in:
(a) Aldehyde (b) Ketone
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(c) Alcohols (d) both a and b


14. The Chemical formula of urea is:
(a) (NH4)2CO (b) (NH2)4C
(c) (NH2)2CO (d) (NH4)2CO3
15. The fractional distillation of petroleum yields only:
(a) 20% Gasoline (b) 30% Gasoline
(c) 15% Gasoline (d) 10% Gasoline
16. Antiknocking agent is:
(a) (C2H5)2Pb (b) (C2H5)4Pb
(c) (C2H5)3Pb (d) (C2H5)4Pd
17. Father of Organic Chemistry is:
(a) Faraday (b) Hoffman
(c) F. Wohler (d) Democritus
18. The example of sp hybridization is:
(a) Methane (b) Benzene (c) Ethene (d) Ethyne
19. The number of chain isomers of Pentane are:
(a) Three (b) Two (c) One (d) Zero
20. Metamerism is only shown by:
(a) Ethers (b) Ketones
(c) Both a and b (d) every organic family
21. Octane number 100 is given to:
(a) n – octane (b) n – Heptane
(c) 2,2,4 – Trimethylpentane (Iso-octane) (d) 2,2,4 – Trimethyl octane
22. The type of hybridization of carbon atom in methane is:
(a) sp (b) sp2
(c) sp 3
(d) None of these
23. The boiling point range of petroleum ether is: (GRW 2007)
(a) 5 – 20oC (b) 10 – 30oC

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(c) 20 – 60oC (d) 30 – 90oC
24. Which one of the following is not a heterocyclic compound? (LHR 2008)
(a) Thiophene (b) Anthracene (c) Furan (d) Pyrrol
25. The state of hybridization of carbon atom in ethane is: (GRW 2008,12)
(a) sp3 (b) sp2 (c) sp (d) dsp2

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26. Geometric isomerism is present in: (GRW 2010)
(a) Methane (b) Ethane
(c) Propane (d) 2-Butene
27. Double bond consists of:
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(a) Two sigma bonds (b) One sigma one pi bond
(c) One sigma and two pi bonds (d) Two pi bonds
28. Which set of hybrid orbitals has planar triangular shape?
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(a) sp3 (b) sp (c) sp2 (d) dsp2
29. The type of hybridization of carbon atom in methane is: (LHR 2007,09)
(a) sp3 (b) sp (c) sp2 (d) dsp2
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30. The chemist who synthesized urea from ammonium cyanate was: (FSD 2014)
(a) G.N. Lewis (b) Fredrick Wohler
(c) Kolbe (d) Berzelius
31. The process used to improve the quality of gasoline is called: (LHR 2014)
(a) Thermal cracking (b) Reforming
(c) Steam cracking (d) Combustion
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32. An isomer of C2H5OH is: (SGD, GRW 2015)


(a) CH3OH (b) (C2H5)2O
(c) CH3OCH3 (d) CH3COCH3
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33. Linear shape is associated with which set of hybrid orbitals?


(MTN 08,13, SGD, FSD 09, GRW, BWP 09,15)
(a) sp3 (b) sp (c) sp2 (d) dsp2
34. Ethers show the phenomena of: (SGD 14, LHR 14,15, FSD 11)
(a) Metamerism (b) Functional group isomerism
(c) Position isomerism (d) cis-trans isomerism
35. Carbon atom in following is sp2 hybridized (LHR 2011)
(a) CH3CN (b) CHΞCH (c) HCOOH (d) CH2Cl2
36. The isomerism shown by alkanes is: (LHR 2011)
(a) Skeletal (b) Position
(c) Geometric (d) Metamerism
37. Hybridization of carbon in carbonyl group is: (FSD, SGD 15, RWP 10)
(a) sp3 (b) sp (c) sp2 (d) dsp2
38. How many isomers are there in pentane? (FSD 09, LHR 12, GRW 11)
(a) 6 (b) 5 (c) 3 (d) 2
39. Vital force theory was rejected by: (LHR 2012,14)
(a) G.N. Lewis (b) F.Wholer
(c) Greek Philosophers (d) Scientists of 20th century
40. Select one which shows cis-trans isomerism.
(FSD 2010)
(a) Cl2C=CCl2 (b) CH2=CH2
(c) ClCH=CHCl (d) Br2C=CBr2
41. Which of the following compound may exist as cis-trans isomer?
(a) 1-butene (b) 2-butene (c) Cyclopropane (d) Acetone
42. Urea belongs to which class of compounds? (RWP 2009)
(a) Imides (b) Amines
(c) Amides (d) carboxylic acid
43. In ethane, each carbon atom is: (GRW, FSD 12, LHR 10, DGK 09)

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(a) sp3 hybridized (b) sp2 hybridized
(c) sp hybridized (d) unhybridized
44. The hybridization of carbon atom in HCHO is: (MTN, RWP 2011)
(a) sp (b) sp2 (c) sp3 (d) dsp
45. Geometric isomerism in alkenes is due to: (MTN 2008)

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(a) Oscillation of H atoms between two polyvalent carbon atoms
(b) Optical rotation due to multiple bonds
(c) Free rotation about C=C bond
(d) Restricted rotation about C=C bond
46. Metamerism is shown by:
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(a) Amines (b) Ethers
(c) neither a nor b (d) Both a and b
47. Dimethyl ether and Ethyl alcohol are called: (MTN 2009)
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(a) Metamers (b) Functional group isomers
(c) Position isomers (d) cis-trans isomers
48. The self-linking property of elements is: (MTN 2009)
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(a) Aromatization (b) Polymerization (c) Association


(d) Catenation
49. The carbon atoms in propene are: (MTN 2010)
(a) sp (b) sp2
(c) sp3 and sp2 (d) sp2 and sp
50. Peat before conversion into coal is converted into: (BWP 2008)
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(a) Anthracite (b) Asphalt


(c) Lignite (d) all of these
51. Tetra methyl lead is added to petrol to: (BWP 2010)
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(a) Prevent its freezing point (b) Increase its boiling point
(c) Prevent knocking (d) Increase its viscosity
52. The crude petroleum is separated in fractions by: (DGK 2008)
(a) Filtration (b) Fractional distillation
(c) Steam distillation (d) Fractions sublimation
53. Carbon atom in Dimethyl ether is: (DGK 2009)
(a) sp3 hybridized (b) sp2 hybridized
(c) sp hybridized (d) unhybridized
54. Number of isomers of C4H10 is: (DGK 2010)
(a) 1 (b) 2 (c) 3 (d) 4
55. In t-butyl alcohol, the tertiary carbon is bonded to: (MTN, SGD 2015)
(a) Three hydrogen atoms (b) Two hydrogen atoms
(c) One hydrogen atom (d) No hydrogen atom
ANSWER KEY
1. 2. 3. 4. 5. 6. 7. 8. 9. 10
a a b c c a c d c a
11 12 13 14 15 16 17 18 19 20
d c d c a b c d a c
21 22 23 24 25 26 27 28 29 30
c c c b a d b c a b
31 32 33 34 35 36 37 38 39 40
b c b a c a b 3 b c
41 42 43 44 45 46 47 48 49 50

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b c a b d b b d c c
51 52 53 54 55
c b b b d

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