B 351 - B 351M - 01 - Qjm1ms9cmzuxts1sruq
B 351 - B 351M - 01 - Qjm1ms9cmzuxts1sruq
B 351 - B 351M - 01 - Qjm1ms9cmzuxts1sruq
1. Scope
1.1 This specification covers hot- and cold-finished zirconium and zirconium alloy bars, rod, and wire, other than those required
for reforging, including rounds, squares, and shapes.
1.2 One unalloyed grade and three alloy grades for use in nuclear applications are described.
1.3 The products covered include the following sections and sizes:
Bars:
Rounds, squares and hexagons ⁄ in. (9.5 mm) and over in diameter or size
38
reworking
Wire less than 3⁄8 in. (9.5 mm) in diameter or size
A
Thickness 1⁄8 in. (3.2 mm) to under 3⁄16 in. (4.8 m) can be cold-rolled strip as well as bar.
1.4 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units
are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must
be used independently of the other. SI values cannot be mixed with inch-pound values.
1.5 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not
purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to
establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents
2.1 ASTM Standards:
B 350/B 350M Specification for Zirconium and Zirconium Alloy Ingots for Nuclear Application2
1
This specification is under the jurisdiction of ASTM Committee B10 on Reactive and Refractory Metals and Alloys and is the direct responsibility of Subcommittee
B10.02 on Zirconium and Hafnium.
Current edition approved Nov. June 10, 20012. Published January August 2002. Originally published as B 351 – 60 T. Last previous edition B 351 – 9701.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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B 351/B 351M – 012
E 8 Test Methods of Tension Testing of Metallic Materials3
E 21 Test Methods for Elevated Temperature Tension Tests of Metallic Materials3
E 29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications4
E 114 Practice for Ultrasonic Pulse-Echo Straight—Beam Examination by the Contact Method5
E 214 Practice for Immersed Ultrasonic Examination by the Reflection Method Using Pulsed Longitudinal Waves5
G 2 Test Method for Corrosion Testing of Products of Zirconium, Hafnium, and Their Alloys in Water at 680°F or in Steam at
750°F6
3. Terminology
3.1 Definitions of Terms Specific to This Standard:
3.1.1 annealed—denotes material that exhibits a recrystallized grain structure.
3.2 Lot Definitions:
3.2.1 castings—a lot shall consist of all castings produced from the same pour.
3.2.2 ingot—no definition required.
3.2.3 rounds, flats, tubes, and wrought powder metallurgical products (single definition, common to nuclear and non-nuclear
standards)—a lot shall consist of a material of the same size, shape, condition, and finish produced from the same ingot or powder
blend by the same reduction schedule and the same heat treatment parameters. Unless otherwise agreed between manufacturer and
purchaser, a lot shall be limited to the product of an 8 h period for final continuous anneal, or to a single furnace load for final
batch anneal.
3.2.4 sponge—a lot shall consist of a single blend produced at one time.
3.2.5 weld fittings—definition is to be mutually agreed upon between manufacturer and the purchaser.
4. Ordering Information
4.1 Purchase orders for material under this specification should include the following information as required to adequately
describe the desired material:
4.1.1 Quantity (weight or number of pieces),
4.1.2 Name of material,
4.1.3 Condition (Section 6),
4.1.4 Finish (Section 14),
4.1.5 Cross section (round, square, etc.),
4.1.6 Form (bar, rod, wire),
4.1.7 Dimensions (size, thickness, width and length),
4.1.8 Grade (Table 1), and
4.1.9 ASTM designation and year of issue.
NOTE 1—A typical ordering description is as follows: 250 lb (100 kgs) zirconium alloy bar; hot rolled, annealed; mechanically descaled and pickled;
⁄ in. (19 mm) by 4 in. (100 mm) by 144 in. (3.6 m), ASTM Specification B 351, dated __, B 351 - 01, Grade R60802.
34
4.2 In addition to the data specified in 4.1, the following options and points of agreement between the manufacturer and the
purchaser should be specified on the purchase order as required:
4.2.1 Mechanical test temperature (see 8.1),
4.2.2 Tolerances (Section 10),
4.2.3 Workmanship standards (Section 13),
4.2.4 Special tests (Section 12),
4.2.5 Inspection (Section 16), and
4.2.6 Corrosion visual standards (Section 9).
4.2.7 Oxygen limits (see footnote A, Table 1).
5. Materials and Manufacture
5.1 Materials covered by this specification shall be produced by multiple vacuum melting in arc furnaces, electron beam
melting, or other melting processes conventionally used for reactive metals; all processes to be done in furnaces usually used for
reactive metals.
6. Condition
6.1 Grades R60001, R60802, and R60804 furnished under this specification shall be in the annealed condition unless otherwise
specified.
2
Annual Book of ASTM Standards, Vol 02.04.
3
Annual Book of ASTM Standards, Vol 03.01.
4
Annual Book of ASTM Standards, Vol 14.02.
5
Annual Book of ASTM Standards, Vol 03.03.
6
Annual Book of ASTM Standards, Vol 03.02.
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B 351/B 351M – 012
TABLE 1 Chemical Requirements
Composition, Weight %
Element
GradeUNS R60001 GradeUNS R60802 GradeUNS R60804 GradeUNS R60901
Tin . . . 1.20–1.70 1.20–1.70 ...
Iron . . . 0.07–0.20 0.18–0.24 ...
Chromium . . . 0.05–0.15 0.07–0.13 ...
Nickel . . . 0.03–0.08 ... ...
Niobium . . . ... ... 2.40–2.80
Niobium (columbium) . . . ... ... 2.40–2.80
A
Oxygen 0.09–0.16 0.09–0.16 0.09–0.13
A A A
Oxygen 0.09–0.15
Iron + chromium + nickel ... 0.18–0.38 ... ...
Iron + chromium ... ... 0.28–0.37 ...
Maximum Impurities, Weight %
Aluminum 0.0075 0.0075 0.0075 0.0075
Boron 0.00005 0.00005 0.00005 0.00005
Cadmium 0.00005 0.00005 0.00005 0.00005
Calcium ... 0.0030 0.0030 ...
Carbon 0.027 0.027 0.027 0.027
Chromium 0.020 ... ... 0.020
Cobalt 0.0020 0.0020 0.0020 0.0020
Copper 0.0050 0.0050 0.0050 0.0050
Hafnium 0.010 0.010 0.010 0.010
Hydrogen 0.0025 0.0025 0.0025 0.0025
Iron 0.150 ... ... 0.150
Magnesium 0.0020 0.0020 0.0020 0.0020
Manganese 0.0050 0.0050 0.0050 0.0050
Molybdenum 0.0050 0.0050 0.0050 0.0050
Nickel 0.0070 ... 0.0070 0.0070
Niobium ... 0.0100 0.0100 ...
Nitrogen 0.0080 0.0080 0.0080 0.0080
Phosphorus ... ... ... 0.0020
Silicon 0.0120 0.012 0.0120 0.0120
Silicon 0.0120 0.0120 0.0120 0.0120
Tin 0.0050 ... ... 0.0050
Tin 0.0050 ... ... 0.010
Titanium 0.0050 0.0050 0.0050 0.0050
Tungsten 0.010 0.010 0.010 0.010
Tungsten 0.010 0.010 0.010 0.010
Titanium 0.0050 0.0050 0.0050 0.0050
Uranium (total) 0.00035 0.00035 0.00035 0.00035
A
When so specified in the purchase order, oxygen shall be determined and reported. Maximum, minimum, or both, permissible values should be specified in the purchase
order.
6.2 Grade R60901 in sizes under 1 in. (25 mm) in minimum dimension furnished under this specification shall be in the
cold-worked condition unless otherwise specified. Sizes 1 in. (25 mm) and over in minimum dimension shall be furnished in the
annealed condition unless otherwise specified.
7. Chemical Composition
7.1 The material shall conform to the requirements for chemical composition as prescribed in Table 1.
7.2 The manufacturer’s ingot analysis made in accordance with Specification B 350/B 350M shall be considered the chemical
analysis for material produced to this specification except for hydrogen, oxygen, and nitrogen content, which shall be determined
on the finished product. Alternatively, the manufacturer may sample an intermediate or final size during processing with the same
frequency and in the same positions relative to the ingot, as specified in Specification B 350/B 350M, to determine the composition,
except for hydrogen, oxygen, and nitrogen, which shall be determined on the finished product.
7.3 Analysis shall be made using the manufacturer’s standard methods. In the event of disagreement as to the chemical
composition of the metal, methods of chemical analysis for reference purposes shall be determined by a mutually acceptable
laboratory.
7.4 Product Analysis—Product analysis is an analysis made by the purchaser or the manufacturer for the purpose of verifying
the composition of the lot. The product analysis tolerances reflect the variation between laboratories in the measurement of
chemical composition. The permissible variation in the product analysis from the specified range is as prescribed in Table 2.
7.5 Number of Tests—Two random samples for each 4000 lb (1800 kg) or fraction thereof shall be analyzed for hydrogen,
nitrogen, and oxygen.
8. Mechanical Properties
8.1 The material shall conform to the requirements prescribed in Table 3 for room temperature mechanical properties. Elevated
temperature properties shall be used to determine compliance only when specified in the purchase order.
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B 351/B 351M – 012
TABLE 2 Permissible Variations in Product Analysis
Permissible Variation from the
Alloying Elements
Specified Range (Table 1), %
Tin 0.050
Iron 0.020
Chromium 0.010
Nickel 0.010
Iron + chromium 0.020
Iron + chromium + nickel 0.020
Niobium 0.050
Oxygen 0.020
8.2 The yield strength shall be determined by the offset (0.2 % method) as prescribed in Test Methods E 8.
8.3 The tensile properties shall be determined using a strain rate of 0.003 to 0.007 in./in. (mm/mm)/min through the yield
strength. After the yield strength has been exceeded, the cross head speed may be increased to approximately 0.05 in./in.
(mm/mm)/min to failure.
8.4 Requirements for mechanical properties do not apply to wire.
8.5 The tensile properties enumerated in this specification shall be determined in accordance with Test Methods E 8 or E 21.
8.6 Number of Tests—Two random samples for each 4000 lb (1800 kg) or fraction thereof shall be tested for mechanical
properties in the longitudinal direction.
9. Corrosion Properties
9.1 Two samples chosen at random from each 4000 lb (181800 kg, a hard conversion) or fraction thereof shall be corrosion
tested in steam at 750°F (400°C), 1500 psi (10.3 MPa), for 72 h or 336 h at the option of the manufacturer in accordance with
Test Method G 2.
9.2 Acceptance Criterion:
9.2.1 Grades R60802 and R60804—All coupons thus tested shall exhibit a continuous, black, lustrous oxide film and be free
of white or brown corrosion product in excess of standards previously agreed upon between manufacturer and purchaser. Coupons
shall exhibit a weight gain of not more than 22 mg/dm2 in a 72-h test or 38 mg/dm2 in a 336-h test.
9.2.2 Grade R60901—All coupons shall exhibit a continuous, uniform, dark gray oxide film. Coupons shall exhibit a weight
gain of not more than 35 mg/dm2 in a 72-h test or 60 mg/dm2 in a 336-h test.
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B 351/B 351M – 012
TABLE 4 Permissible Variations in Sectional Dimensions for Hot-
Worked Bars in RoundsA and Squares
Maximum
Permissible
Permissible Variation in
Specified Size, in. (mm) Out-of-RoundB or
Size, in. (mm)
Out-of-SquareC
Section, in. (mm)
0.375–1.0 (9.5–25, incl –0 + 0.020 (–0 + 0.5) 0.013 (0.35)
Over 1.0–2.0 (25–50), excl –0 + 0.030 (–0 + 0.75) 0.021 (0.55)
Over 2.0–4.0 (50–101.0), incl –0 + 0.060 (–0 + 1.5) 0.050 (1.3)
Over 4.0–6.5 (101.0–165.0), excl –0 + 0.125 (–0 + 3.2) 0.070 (1.8)
A
Round sections ranging from 1⁄4 in. (6.4 mm) to approximately 5⁄8 in. (16 mm)
in diameter are commonly produced on rod mills in coils. Permissible variations on
the product made this way have not been established; for such variations the
producer should be consulted. Variations in size of coiled products made on rod
mills are greater than size tolerances for products made on bar mills.
B
Out-of-round is the difference between the maximum and minimum diameters
of the bar, measured at the same cross section.
C
Out-of-square section is the difference in the two dimensions at the same cross
section of a square bar, each dimension being the distance between opposite
corners.
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B 351/B 351M – 012
TABLE 8 Permissible Variations in Diameter for Round Wire
Permissible Variations, in. (mm)
Diameter, in. (mm)
Pickled Centerless Ground
Up–0.100 (2.5) 60.002 (60.05) ...
0.100–0.199 (2.5–5.0) 60.003 (60.10) 60.001 (60.03)
0.200–0.375 (5.1–9.6) 60.005 (60.13) 60.002 (60.05)
drilled perpendicular to the longitudinal product axis to a depth of 0.5 in. (13 mm).
12.1.3 Any defect reflections greater than the indication from the reference standard should be rejected.
12.2 Additional tests may be specified in the purchase order. The test method and standards shall be agreed upon in advance
between manufacturer and purchaser.
14. Finish
14.1 Bars or rod in the hot-finished condition shall be furnished with one of the following finishes as designated in the purchase
order:
14.1.1 Not descaled,
14.1.2 Mechanically descaled,
14.1.3 Mechanically descaled and pickled,
14.1.4 Rough machined 500 µin. (13 µm) or better,
14.1.5 Turned (round bars only) 500 µin. (13 µm) or better,
14.1.6 Ground (round bars 2 in. (50 mm) and under only) 125 µin. (3 µm) or better, or
14.1.7 Ground and polished 32 µin. (0.8 µm) or better.
14.2 Cold-reduced bars and wire shall be furnished with one of the following finishes as designated in the purchase order:
14.2.1 As cold reduced,
14.2.2 Pickled,
14.2.3 Ground 63 µin. (1.6 µm) or better, or
14.2.4 Polished 32 µin. (0.8 µm) or better.
15. Retests
15.1 If any sample or specimen exhibits obvious surface contamination or improper preparation disqualifying it as a truly
representative sample, it shall be discarded and replaced by a new sample or specimen.
15.2 If the results of the inspection of a lot are not in conformance with the requirements of this specification, the lot may be
reworked at the option of the manufacturer, providing the rework steps are within the previously approved specifications and
procedures used for the original fabrication. Deviations must be approved by the purchaser.
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B 351/B 351M – 012
15.3 If the result of any test does not meet the specification requirements, retests may be performed on twice as many samples
as originally tested for the characteristic, or using retest procedures mutually agreed upon between the manufacturer and the
purchaser.
15.3.1 All test results including the original test results shall be reported to the purchaser. Retest results shall be indicated with
the suffix “R”.
15.3.2 Only one set of retests is permitted and all retest results shall conform to the specification requirements for the retested
characteristic. Following a failed test, 100 % testing is not considered to be a retest.
16. Inspection
16.1 The manufacturer shall inspect the material covered by this specification prior to shipment. If so specified in the purchase
order, the purchaser or his representative may witness the testing and inspection of the material at the place of manufacture. In such
cases, the purchaser shall state in his purchase order which tests he desires to witness. The manufacturer shall give ample notice
to the purchaser as to the time and place of the designated tests. If the purchaser’s representative does not present himself at the
time agreed upon for the testing, the manufacturer shall consider the requirement for purchaser’s inspection at place of manufacture
to be waived.
16.2 The manufacturer shall afford the inspector representing the purchaser, without charge, all reasonable facilities to satisfy
him that the material is being furnished in accordance with this specification. This inspection shall be so conducted as not to
interfere unnecessarily with the operation of the works.
17. Rejection
17.1 Rejection for failure of the material to meet the requirements of this specification shall be reported to the manufacturer
within 60 calendar days from the receipt of the material by the purchaser. Unless otherwise specified, rejected material may be
returned to the manufacturer at the manufacturer’s expense, unless the purchaser receives, within three weeks of the notice of
rejection, other instructions for disposition.
18. Referee
18.1 In the event of disagreement between the manufacturer and the purchaser on the conformance of the material to the
requirements of this specification or any special test specified by the purchaser, a mutually acceptable referee shall perform the tests
in question. The results of the referee’s testing shall be used in determining conformance of the material to this specification.
19. Certification
19.1 A producer or supplier shall furnish the purchaser with a certificate that the material was manufactured, sampled, tested,
and inspected in accordance with this specification and has been found to meet the requirements. The certificate shall include a
report of the test results.
21. Keywords
21.1 bar; nuclear application; rod; wire; zirconium; zirconium alloy
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B 351/B 351M – 012
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