Chemical Analysis of Dental Alloys - 220417 - 142707

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Faculty of dentistry - tanta University

Name : omar galal mohamed megahed


Search about : Chemistry of dental ceramics

1- Introduction

Dental ceramics are materials that are part of systems


designed with the purpose of producing dental prostheses
that in turn are used to replace missing or damaged dental
structures. The literature on this topic defines ceramics
as inorganic, non-metallic materials made by man by the
heating of raw minerals at high temperatures.
Ceramics and glasses are brittle, which means that they
display a high compressive strength but low tensile strength
and may be fractured under very low strain (0.1%, 0.2%).
As restorative materials, dental ceramics have disadvantages
mostly due to their inability to withstand functional forces
that are present in the oral cavity. Hence, initially, they
found limited application in the premolar and molar areas,
although further development in these materials has enabled
their use as a posterior long-span fixed partial prosthetic
restorations and structures over dental implants. All dental
ceramics display low fracture toughness when compared
with other dental materials, such as metals.
Metal ceramic systems combine both the exceptional
esthetic properties of ceramics and the extraordinary
mechanical properties of metals. Some metals used as
restorative materials in dentistry may constitute a problem
for some patients. These problems may reveal themselves
as allergies,gum staining and release of metallic ions
into the gingival tissue and the gingival fluid.These drawbacks, as well as the
search for more esthetic materials
by patients and dentists, have stimulated research and
development of metal-free ceramic systems.
The main objective of this work is to review ceramic
dental materials, including their most relevant physical and
mechanical properties
2- HISTORICAL EVOLUTION OF DENTAL CERAMICS
Current dental ceramics are far from the early
ceramics that started being used over 200 years
ago. Early records of the first ceramics used as
dental materials date back to 1774, when French
apothecary Alexis Duchateau and Parisian
dentist Nicholas Dubois de Chemant
manufactured the first complete ceramic denture.
There are reports of complete dentures being
manufactured earlier by French dentist Pierre
Fauchard, although these dentures were
fabricated in a different class of ceramic, namely enamel [4].
The initial use of ceramic materials in dentistry
was in the obtention of complete dentures. Early
in the 19 th century, Italian dentist Giuseppangelo
Fonzi was capable of manufacturing individual
ceramic teeth attached to a metallic substructure
which, in turn, was attached to complete
dentures. The restoration of individual ceramic
teeth in the oral cavity was delayed until the late
1800s, when Logan constructed ceramic teeth
fused to metallic posts so that these posts could
function as an intraradicular retention for the
restoration [4, 5].
The method to manufacture dental prostheses
during the second half of the 20 th century was
through the fusion of ceramics and metallic
structures that could function as a core. Metal ceramic systems combine both
the exceptional
esthetic properties of ceramics and the extraordinary mechanical properties of
metals
[1]. Some metals used as restorative materials in
dentistry may constitute a problem for some
patients. These problems may reveal themselves
as allergies [6], gum staining [7, 8], and release
of metallic ions into the gingival tissue [9] and
the gingival fluid [10]. These drawbacks, as
well as the search for more esthetic materials by
patients and dentists, have stimulated research and development of metalfree
ceramic systems.
During the last 40 years, research has focused on
improving metalfree systems and developing
superior materials regarding esthetics and
clinical performance to offer patients several
alternatives to restore missing or damaged teeth.

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