MATERIAL BALANCE OF AMMONIA FRONT END AT

Components NG HP Header F-4201 O/L R-4202 O/L R-4203 O/L R-4204 O/L C-4302 O/L
N2 18.52 7.62 24.11 21.51 21.24 26.02
CH4 73.8 11.44 1 0.89 0.88 1.08
CO2 8 9.93 7.34 17.35 18.36 0.05
C2H6 0.2 0 0 0 0 0
CO 0 10.5 13.89 1.58 0.35 0.42
H2 0 60.51 53.43 58.46 58.97 72.18
Ar 0 0 0.23 0.21 0.2 0.25
C.NO 0.822 0.3187 0.2223 0.1982 0.1959 0.0155
M.Wt. 20.57 12.50 15.20 15.51 15.54 9.16
100.52 100 100 100 100 100

Carbon Balance at F-4201 inlet and outlet N2 Balance at F-4201 In & O

FRC-42007 FRC-42006 FRC-42012

Nmc/hr 39231 2499 80466.26
Kg/hr 36009.77 1025.11 64620
Total Mass Flow(Wet) at F-4201 Inlet Water %
Kg/hr 101654.88 63.57
Applying Carbon balance at F-4201 Applying N2 Balance at F-4201
Total dry gas flow at F-4201 O/L Total dry gas flow at F-4201 O/L
Nmc/hr 101309.58958268 104006.79
Kg/hr 56478.73 57982.38
Total Water content at F-4201 O/L Total Water content at F-4201 O/L
Kg/hr 45176.15 43672.50
Total Mass Flow(Wet) at F-4201 Outlet Water % Total Mass Flow(Wet) at F-4201 Outlet
Kg/hr 101654.88 44.44 101654.88

Carbon Balance at R-4202 inlet and outlet N2 Balance at R-4202 In & O

F-4201 O/L Dry FIC-42016 FRC-42022 F-4201 O/L Wet
Nmc/hr 101309.59 23902.91 39701.6 Not required
Kg/hr 56478.73 19195.70 51367.29 101654.88

Total Mass Flow (Wet) at R-4202 Inlet Water %

Kg/hr 172217.86 37.38
Applying Carbon balance at R-4202 Applying N2 Balance at R-4202
Total dry gas flow at R-4202 O/L Total dry gas flow at R-4202 O/L
Nmc/hr 145295.89 169121.83
Kg/hr 98536.91 114695.20
Total Water content at R-4202 O/L Total Water content at R-4202 O/L
Kg/hr 73680.96 57522.66
Total Mass Flow(Wet) at R-4202 Outlet Water % Total Mass Flow(Wet) at R-4202 Outlet
Kg/hr 172217.86 42.78 172217.86
 Carbon Balance at R-4203 inlet and outlet N2 Balance at R-4203 In & O
R-4202 O/L Dry R-4202 O/L Wet
Nmc/hr 145295.89 0.00
Kg/hr 98536.91 172217.86

Total Mass Flow (Wet) at R-4203 Inlet Dew Point at Inlet

Kg/hr 172217.86 14.6579601275605
3.82857155184025
DEW POINT AT MTSC INLET 196
Applying Carbon balance at R-4203 Applying N2 balance at R-4203
Total dry gas flow at R-4203 O/L Total dry gas flow at R-4203 O/L
Nmc/hr 162963.05 162858.39
Kg/hr 112740.46 112668.05
Total Water content at R-4203 O/L Total Water content at R-4203 O/L
kg/hr 59477.40 59549.81
Total Mass Flow(Wet) at R-4203 Outlet Water % Total Mass Flow(Wet) at R-4203 Outlet
Kg/hr 172217.86 34.54 172217.86

Carbon Balance at R-4204 inlet and outlet N2 Balance at R-4204 In & O

R-4203 O/L Dry R-4203 O/L Wet
Nmc/hr 162963.05 0.00
Kg/hr 112740.46 172217.86

Total Mass Flow (Wet) at R-4204 Inlet Dew Point at Inlet

Kg/hr 172217.86 11.7507395326695
3.42793517042978
DEW POINT AT LTSC INLET 185
Applying Carbon balance at R-4203 Applying N2 balance at R-4203
Total dry gas flow at R-4204 O/L Total dry gas flow at R-4204 O/L
Nmc/hr 164876.35 165034.62
Kg/hr 114278.23 114387.93
Total Water content at R-4204 O/L Total Water content at R-4204 O/L
kg/hr 57939.64 57829.94
Total Mass Flow(Wet) at R-4204 Outlet Water % Total Mass Flow(Wet) at R-4204 Outlet
Kg/hr 172217.86 33.64 172217.86

Condensate calculation from V-4304

V-4304 I/L Dry V-4304 I/L Wet
Nmc/hr 164876.35 234698.80
Kg/hr 114278.23 172217.86

Condensate drainage from V-4304 calculation

Kg/hr 57939.64 57.94 Tons to PCT

 Balance across C-4302
V-4304 O/L Dry
Nmc/hr 164876.35
Kg/hr 114278.23

Total CO2 flow in inlet feed to C-4302

Nmc/hr 30271.30
Kg/hr 59424.34

Other Gas flow absorbed Nmc/hr 2500 Nmc/hr

Treated Gas flow to R-4311
Nmc/hr 132105.05

Carbon Balance at R-4311 inlet and outlet N2 Balance at R-4311 In & O

C-4302 O/L Dry
Nmc/hr 132105.05
Kg/hr 53963.54

Applying Carbon balance at R-4311 Applying N2 balance at R-4311

Total dry gas flow at R-4311 O/L Total dry gas flow at R-4311 O/L
Nmc/hr 129596.73 130203.538855241
Kg/hr 53161.63

Condensate from V-4311 to PCT, TPH 801.91 0.80

Total Condensate flow to PCT, TPH 58.74

A FRONT END AT 117.6 %

R-4311 O/L
26.4 Note:
1.58 Only Put figures in green boxes only
0
0
0
71.77
0.25
0.0158
9.19
100

N2 Balance at F-4201 In & Out Difference B/w Both Balance

ying N2 Balance at F-4201

flow at F-4201 O/L
104006.79 -2697.20
57982.38 -1503.65
ntent at F-4201 O/L
43672.50
ow(Wet) at F-4201 Outlet Water %
101654.88 42.96

N2 Balance at R-4202 In & Out Difference B/w Both Balance

ying N2 Balance at R-4202

flow at R-4202 O/L
169121.83 -23825.94
114695.20 -16158.30
ntent at R-4202 O/L
57522.66
ow(Wet) at R-4202 Outlet Water %
172217.86 33.4011
N2 Balance at R-4203 In & Out Difference B/w Both Balance

ying N2 balance at R-4203

flow at R-4203 O/L
162858.39 104.66
112668.05 72.41
ntent at R-4203 O/L
59549.81
ow(Wet) at R-4203 Outlet Water %
172217.86 34.58

N2 Balance at R-4204 In & Out Difference B/w Both Balance

ying N2 balance at R-4203

flow at R-4204 O/L
165034.62 -158.27
114387.93 -109.70
ntent at R-4204 O/L
57829.94
ow(Wet) at R-4204 Outlet Water %
172217.86 33.58

rom V-4304

Analysis of Wet Process Gas to V-4304

N2 15.49
CH4 0.7
CO2 14.12
CO 0.14
H2 43.08
Ar 0.147
H20 26.2
 Total 99.877

4302
Process Gas to C-4302
N2 35019.74
CH4 1450.91
CO2 30271.30
CO 0.0035
H2 97227.58
Ar 329.75
H20 0
Total 164299.28

N2 Balance at R-4311 In & Out Difference B/w Both Balance

ying N2 balance at R-4311

flow at R-4311 O/L
130203.538855241 -606.81
 MATERIAL BALANCE OF AMMONIA FRONT END AT

Components NG HP Header F-4201 O/L R-4202 O/L R-4203 O/L R-4204 O/L C-4302 O/L
N2 17.85 7.23 23.66 21.31 20.98 26.24
CH4 70.86 11.68 1.09 1 0.99 1.2
CO2 11.05 13.91 9.46 18.26 19.24 0
C2H6 0.24 0 0 0 0 0
CO 0 7.58 12.46 0.88 0.19 0.24
H2 0 59.6 53.09 58.33 58.39 72.06
Ar 0 0 0.24 0.22 0.21 0.26
C.NO 0.8239 0.3317 0.2301 0.2014 0.2042 0.0144
M.Wt. 21.27 13.34 15.62 15.67 15.81 9.17

Carbon Balance at F-4201 inlet and outlet N2 Balance at F-4201 In &

FRC-42007 FRC-42006 FRC-42012

Nmc/hr 48400 600 103976.056
Kg/hr 45928.82 245.39 83500
Total Mass Flow(Wet) at F-4201 Inlet Water %
Kg/hr 129674.22 64.39
Applying Carbon balance at F-4201 Applying N2 Balance at F-4201
Total dry gas flow at F-4201 O/L Total dry gas flow at F-4201 O/L
Nmc/hr 120245.583358456 121680.50
Kg/hr 71565.38 72419.39
Total Water content at F-4201 O/L Total Water content at F-4201 O/L
Kg/hr 58108.83 57254.83
Total Mass Flow(Wet) at F-4201 Outlet Water % Total Mass Flow(Wet) at F-4201 Outlet
Kg/hr 129674.22 44.81 129674.22

Carbon Balance at R-4202 inlet and outlet N2 Balance at R-4202 In

F-4201 O/L Dry FIC-42016 FRC-42022 F-4201 O/L Wet
Nmc/hr 120245.58 5354.46 40400 Not required
Kg/hr 71565.38 4300.00 52270.90 129674.22

Total Mass Flow (Wet) at R-4202 Inlet Water %

Kg/hr 186245.12 33.51
Applying Carbon balance at R-4202 Applying N2 Balance at R-4202
Total dry gas flow at R-4202 O/L Total dry gas flow at R-4202 O/L
Nmc/hr 173392.35 175723.7
Kg/hr 120824.42 122448.9
Total Water content at R-4202 O/L Total Water content at R-4202 O/L
Kg/hr 65420.69 63796.12
Total Mass Flow(Wet) at R-4202 Outlet Water % Total Mass Flow(Wet) at R-4202 Outlet
Kg/hr 186245.12 35.13 186245.12
 Carbon Balance at R-4203 inlet and outlet N2 Balance at R-4203 In
R-4202 O/L Dry R-4202 O/L Wet
Nmc/hr 173392.35 0.00
Kg/hr 120824.42 186245.12

Total Mass Flow (Wet) at R-4203 Inlet Dew Point at Inlet

Kg/hr 186245.12 12.2152342270604
3.49502993221237
DEW POINT AT MTSC INLET 187
Applying Carbon balance at R-4203 Applying N2 balance at R-4203
Total dry gas flow at R-4203 O/L Total dry gas flow at R-4203 O/L
Nmc/hr 198101.19 192513.52
Kg/hr 138528.84 134621.47
Total Water content at R-4203 O/L Total Water content at R-4203 O/L
kg/hr 47716.28 51623.65
Total Mass Flow(Wet) at R-4203 Outlet Water % Total Mass Flow(Wet) at R-4203 Outlet
Kg/hr 186245.12 25.62 186245.12

Carbon Balance at R-4204 inlet and outlet N2 Balance at R-4204 In

R-4203 O/L Dry R-4203 O/L Wet
Nmc/hr 198101.19 0.00
Kg/hr 138528.84 186245.12

Total Mass Flow (Wet) at R-4204 Inlet Dew Point at Inlet

Kg/hr 186245.12 8.97786673604172
2.99630885191125
DEW POINT AT LTSC INLET 173
Applying Carbon balance at R-4203 Applying N2 balance at R-4203
Total dry gas flow at R-4204 O/L Total dry gas flow at R-4204 O/L
Nmc/hr 195384.82 201217.18
Kg/hr 137860.33 141975.55
Total Water content at R-4204 O/L Total Water content at R-4204 O/L
kg/hr 48384.78 44269.57
Total Mass Flow(Wet) at R-4204 Outlet Water % Total Mass Flow(Wet) at R-4204 Outlet
Kg/hr 186245.12 25.98 186245.12

Condensate calculation from V-4304

V-4304 I/L Dry V-4304 I/L Wet
Nmc/hr 195384.82 253815.17
Kg/hr 137860.33 186245.12

Condensate drainage from V-4304 calculation

Kg/hr 48384.78 48.38 Tons to PCT

 Balance across C-4302
V-4304 O/L Dry
Nmc/hr 195384.82
Kg/hr 137860.33

Total CO2 flow in inlet feed to C-4302

Nmc/hr 37592.04
Kg/hr 73795.38

Other Gas flow absorbed Nmc/hr 2500 Nmc/hr

Treated Gas flow to R-4311
Nmc/hr 155292.78

Carbon Balance at R-4311 inlet and outlet N2 Balance at R-4311 In

C-4302 O/L Dry
Nmc/hr 155292.78
Kg/hr 63504.56

Applying Carbon balance at R-4311 Applying N2 balance at R-4311

Total dry gas flow at R-4311 O/L Total dry gas flow at R-4311 O/L
Nmc/hr 154221.79 154644.498613355
Kg/hr 63074.69

Condensate from V-4311 to PCT, TPH 429.87 0.43

Total Condensate flow to PCT, TPH 48.81

NIA FRONT END AT 117.6 %

R-4311 O/L
26.35 Note:
1.45 Only Put figures in green boxes only
0
0
0
71.94
0.26
0.0145
9.17

N2 Balance at F-4201 In & Out Difference B/w Both Balance

pplying N2 Balance at F-4201

flow at F-4201 O/L
121680.50 -1434.91
72419.39 -854.00
ntent at F-4201 O/L
57254.83
ow(Wet) at F-4201 Outlet Water %
129674.22 44.15

N2 Balance at R-4202 In & Out Difference B/w Both Balance

plying N2 Balance at R-4202

flow at R-4202 O/L
175723.74 -2331.39
122448.99 -1624.57
ntent at R-4202 O/L
63796.12
ow(Wet) at R-4202 Outlet Water %
186245.12 34.25385
 N2 Balance at R-4203 In & Out Difference B/w Both Balance

plying N2 balance at R-4203

flow at R-4203 O/L
192513.52 5587.68
134621.47 3907.37
ntent at R-4203 O/L
51623.65
ow(Wet) at R-4203 Outlet Water %
186245.12 27.72

N2 Balance at R-4204 In & Out Difference B/w Both Balance

plying N2 balance at R-4203

flow at R-4204 O/L
201217.18 -5832.36
141975.55 -4115.22
ntent at R-4204 O/L
44269.57
ow(Wet) at R-4204 Outlet Water %
186245.12 23.77

n from V-4304

Analysis of Wet Process Gas to V-4304

N2 15.49
CH4 0.7
CO2 14.12
CO 0.14
H2 43.08
Ar 0.147
H20 26.2
 Total 99.877

C-4302
Process Gas to C-4302
N2 40991.73
CH4 1934.31
CO2 37592.04
CO 0.0019
H2 114085.20
Ar 410.31
H20 0
Total 195013.59

N2 Balance at R-4311 In & Out Difference B/w Both Balance

plying N2 balance at R-4311

flow at R-4311 O/L
154644.498613355 -422.70
 FRC-42007 Components NG HP Header
NMC/hr 48400 N2 17.85
kg/hr 45928.82 CH4 70.86
FRC-42006 CO2 11.05
NMC/hr 600 C2H6 0.24
FRC-42022 CO 0
NMC/hr 40400 H2 0
kg/hr 31225.02 Ar 0
FIC-42016 C.NO 0.8239
kg/hr 4300 M.Wt. 21.27
FRC-42012
kg/hr 83500
MTSC Dew point = [(Total water content @

Total dry gas flow at F-4201 O/L

Nmc/hr

Total mass flow at F-4201 outlet

total water content at F-4201 outlet

Total Mass flow rate at F-4201 inlet (wet)

Total dry gas flow at R-4202 O/L

Nmc/hr
Total mass flow at R-4202 outlet (dry)
kg/hr
Total mass flow at R-4202 inlet (wet)
kg/hr

total water content @ R-4202 outlet

kg/hr 53904.4005205895

10.8512519842
3.29412385683963
MTSC Inlet Dew Point 181.497213665655

LTSC Dew point = ((Total water content @

Total water content at R-4203 outlet = total mass flow rate at R

36686.6203478214

total mass flow rate at R-4203 inlet (wet)

Total dry gas flow rate at R-4203 outlet=

Total mass flow rate at R-4203 outlet (wet)=

LTSC Inlet Dew Point

 F-4201 O/L R-4202 O/L
7.23 23.66
11.68 1.09
13.91 9.46
0 0
7.58 12.46
59.6 53.09
0 0.24
0.3317 0.2301
13.34 15.62

nt = [(Total water content @ R-4202 outlet/total mass flow rate at R-4202 outlet (wet))*31.9] + 1.01

120245.583358456

Total dry gas flow at F-4201 O/L+ total water content at F-4201 outlet

total mass flow rate at F-4201 intlet - Total dry gas flow at F-4201 O/L
130028.823057018 kg/hr

173392.351151673 kg/hr

120824.422536428

174728.823057018

total mass flow @ R-2 inlet (wet) - total mass flow @ R-2 outlet (dry)
t = ((Total water content @ R-4203 outlet/total mass flow rate at R-4203 outlet (wet))*31.1 ) + 1.01

let = total mass flow rate at R-4203 inlet (wet) - total dry gas flow at R-4203 outlet

R-4202 O/L wet= R-4202 O/L dry + water content in R-2 outlet 174728.823057018

138042.202709197

Total dry gas flow at R-4203 O/L+ Total water content at R-4203 Outlet
174728.823057018
7.53985507974792
2.74587965500091
165.706959871965
 R-4311 O/L
26.35
1.45
0
0
0
71.94
0.26
0.0145
9.17

9] + 1.01

kg/hr 71565.3815630918
nt at F-4201 outlet

flow at F-4201 O/L 58463.4414939261

120824.422536428

t (dry)
) + 1.01 Components R-4203 O/L
N2 21.31
CH4 1
CO2 18.26
C2H6 0
CO 0.88
H2 58.33
Ar 0.22
C.NO 0.2014
M.Wt. 15.67
 FRC-42007 Components NG HP Header
NMC/hr 48400 N2 17.85
kg/hr 45928.823057 CH4 70.86
FRC-42006 CO2 11.05
NMC/hr 600 C2H6 0.24
kg/hr 245.39212992 CO 0
FRC-42022 H2 0
NMC/hr 40400 Ar 0
kg/hr 31225.02069 C.NO 0.8239
FIC-42016 M.Wt. 21.27
kg/hr 4300
FRC-42012
kg/hr 83500 MTSC Dew point = [(Total water cont

Total dry gas flow at F-4201 O/L

Nmc/hr 120245.583358456
kg/hr 71565.3815630918
Total mass flow at F-4201 outlet

Total water content at F-4201 outlet

kg/hr 58108.8336238449
Total Mass flow rate at F-4201 inlet (wet)
kg/hr 129674.215186937
Total dry gas flow at R-4202 O/L
Nmc/hr 173392.351151673
kg/hr 120824.422536428
Total mass flow at R-4202 outlet (dry)
kg/hr 120824.422536428
Total mass flow at R-4202 inlet (wet)
kg/hr 174374.215186937
Total water content @ R-4202 outlet
53549.7926505083

10.8063932552752
3.28730790393526
MTSC Inlet Dew Point 181.309346254826

LTSC Dew point = ((Total water conte

Total water content at R-4203 outlet

kg/hr 36332.0124777402

Total mass flow rate at R-4203 inlet (wet)

kg/hr 174374.215186937
 Total dry gas flow rate at R-4203 outlet=
kg/hr 138042.202709197

Total mass flow rate at R-4203 outlet (wet)

174374.215186937

7.48988916736565
2.73676618792429
LTSC Inlet Dew Point 165.431743868107
 F-4201 O/L R-4202 O/L
7.23 23.66
11.68 1.09
13.91 9.46
0 0
7.58 12.46
59.6 53.09
0 0.24
0.3317 0.2301
13.34 15.62

nt = [(Total water content @ R-4202 outlet/total mass flow rate at R-4202 outlet (wet))*31.9] + 1.01

Total dry gas flow at F-4201 O/L+ total water content at F-4201 outlet

Total mass flow rate at F-4201 intlet (wet) - Total dry gas flow at F-4201 O/L

Total mass flow @ R-2 inlet (wet) - total mass flow @ R-2 outlet (dry)

t = ((Total water content @ R-4203 outlet/total mass flow rate at R-4203 outlet (wet))*31.1 ) + 1.01

Total mass flow rate at R-4203 inlet (wet) - total dry gas flow at R-4203 outlet

R-4202 O/L wet= R-4202 O/L dry + water content in R-2 outlet
Total dry gas flow at R-4203 O/L + Total water content at R-4203 Outlet
 R-4311 O/L R-4203 O/L
26.35 21.31
1.45 1
0 18.26
0 0
0 0.88
71.94 58.33
0.26 0.22
0.0145 0.2014
9.17 15.67

9] + 1.01

58108.8336238449

) + 1.01