alexmo cosmetics GmbH

Handelshof 14a
D - 28816 Stuhr
[email protected]

MATERIAL SAFETY DATA SHEET

According to Regulation (EC) N° 1907/2006 and 453/2010
SECTION 1.PROUCT IDENTIFIER
1.1 Product identifier
Fragrance de Shea PÖ
UFI : U800-U0RP-S00R-17D5
1.2 Relevant identified uses of the substance or mixture and uses advised against
Fragrance compound only for industrial use.
1.3 Details of the supplier of the safety data sheet
alexmo cosmetics GmbH
Handelshof 14a
D-28816 Stuhr
Telefon: 0421-84003464
E-Mail: [email protected]
Web: www.alexmo-cosmetics.de
1.4 Emergency telephone number

+49 (0)551 192 40 (Giftinformationszentrum Nord)

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or the mixture
Regulation N° 1272/2008 (CLP)
Hazardous to the Aquatic Environment – Chronic Hazard 2 ( Aquatic Chronic 2;H411 )
Skin Corrosion / Irritation 2 ( Skin Irrit. 2;H315 )
Sensitisation - Skin 1B ( Skin. Sens. 1B;H317 )
2.2 Label elements
Regulation N° 1272/2008 (CLP)
Label elements complying with the regulation

Signal word : WARNING

Contains : 3-(p-methoxyphenyl)-2-methylpropionaldehyde, 2-isopropoxyethyl salicylate, 3,7-

dimethyl-3-octanol, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-
Additional Labelling naphthalenyl)ethan-1-one and isomers, 3-(2h-1,3-benzodioxol-5-yl)-2-
methylpropanal, 1,3-benzodioxole-5-ca

Hazard Statements
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H411 : Toxic to aquatic life with long lasting effects.

alexmo cosmetics GmbH - Handelshof 14a - 28816 Stuhr – Deutschland - Telefon: +49-421-84003464 - E-Mail: [email protected]
Page 1 / 7
MATERIAL SAFETY DATA SHEET
According to Regulation (EC) N° 1907/2006 and 453/2010
Fragrance de Shea PÖ
Precautionary
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
P261 : Avoid breathing dust/fume/gas/mist/vapours/ spray.
P264 : Wash...thoroughly after handling.
P321 : Traitement spécifique (voir ... sur cette étiquette)
P333+P313 : En cas d’irritation ou d'eruption cutanee: consulter un medecin.
P391 : Collect spillage.

2.3 Other hazards

The mixture does not contain substances included in the candidate list substances subject to authorization
- Article 59, paragraph 1 of Regulation (EC) 1907/2006.
The mixture does not contain PBT or vPvB substances as defined in Annex XIII of Regulation 253/2011/EC amending
Regulation 1097/2006/EC.

SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS :

3.1 Substances
Do not concern this product that is a mixture
3.2 Mixtures
Chemical name CAS # EINECS #
REACH Classification %
Registration No. Regulation (EC) No 1278/2008
1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2- 01-2119489989-
naphthalenyl)ethan-1-one and isomers 54464-57-2 259-174-3 04-0014 Aquatic Chronic 1 H410 Skin Irrit. 2 H315 Skin. Sens. 1B H317 [10-20]
01-0000016883-
(12E)-oxacyclohexadecen-2-one 111879-80-2 422-320-3 62 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 [0.1-5]
2-Ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-
buten-1-ol 28219-61-6 248-908-8 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Eye Dam. 2 H319 [0.1-5]
alpha, beta,2,2,3-Pentamethylcyclopent-3-ene-
1-butanol 65113-99-7 265-453-0 Aquatic Chronic 2 H411 [0.1-5]
(3R-(3a,3ab,6a,7b,8aa))-Octahydro-3,6,8,8-tetramethyl-
1H-3a,7-methanoazulen-5-yl A 77-54-3 201-036-1 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Skin. Sens. 1B H317 [0.1-5]
3-(2,3,3-Trimethyl-6-bicyclo(2,2,1)heptanyl) 01-2119979583-
cyclohexan-1-ol 3407-42-9 222-294-1 21 Aquatic Acute 1 H400 Aquatic Chronic 2 H411 Eye Dam. 2 H319 [0.1-5]
01-2119983608-
1,3-Benzodioxole-5-carbaldehyde 120-57-0 204-409-7 21 Skin. Sens. 1B H317 [0.1-5]
01-2119970582-
3-p-Cumenyl-2-methylpropionaldehyde 103-95-7 203-161-7 32 Aquatic Chronic 3 H412 Skin Irrit. 2 H315 Skin. Sens. 1B H317 [0.1-5]
01-2120765193-
2-isopropoxyethyl salicylate 79915-74-5 279-348-2 53 Acute Tox. 4 H302 Skin. Sens. 1B H317 [0.1-5]
01-2120740119-
3-(2H-1,3-benzodioxol-5-yl)-2-methylpropanal 1205-17-0 214-881-6 58 Aquatic Chronic 2 H411 Skin. Sens. 1B H317 [0.1-5]
01-2119454788-
3,7-dimethyl-3-octanol 78-69-3 201-133-9 21-0000 Eye Dam. 2 H319 Skin Irrit. 2 H315 Skin. Sens. 1B H317 [0.1-5]
01-2120769416-
3-(p-Methoxyphenyl)-2-methylpropionaldehyde 5462-06-6 226-749-5 45 Skin. Sens. 1B H317 [0.1-5]
(3R-(3a,3ab,7b,8aa))-2,3,4,7,8,8a-Hexahydro-3,6,8,8-
tetramethyl-1H-3a,7-methanoazulene 469-61-4 207-418-4 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Asp. Tox. 1 H304 [0.1-5]
[3R-(3a,3ab,7b,8aa)]-OCTAHYDRO-3,8,8-TRIMETHYL-
6-METHYLENE-1H-3a,7-METHANOAZULENE 546-28-1 208-898-8 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Asp. Tox. 1 H304 [0.1-5]

alexmo cosmetics GmbH - Handelshof 14a - 28816 Stuhr – Deutschland - Telefon: +49-421-84003464 - E-Mail: [email protected]
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MATERIAL SAFETY DATA SHEET
According to Regulation (EC) N° 1907/2006 and 453/2010
Fragrance de Shea PÖ
SECTION 4. FIRST-AID MEASURES
4.1 Description des premiers secours
General Note: It is highly recommended to have a medical follow-up in case of a potential poisoning.

Contact with skin: Remove contaminated clothing and only reuse it after decontamination. Wash immediately and
thoroughly with soap and water. Then rinse with clear water. In case of persistent skin irritation,
consult a doctor.

Contact with eyes: Abundant rinsing with water (15 minutes open eyelids) then washing with an ocular lotion standard
Dacryoserum. In case of vision disturbance, consult an ophthalmologist.

When swallowed: Rinse the mouth with water. Do not induce vomiting. See a doctor.

When inhaled: Remove the affected person(s) from the exposure area and move him/her(them) in fresh air room.
See a doctor if symptoms occurs.

4.2 Principaux symptômes et effets, aigus et différés

No further relevant data available for this product.

4.3 Soins médicaux et traitements particuliers

No further relevant data available.
SECTION 5. FIRE FIGHTING MEASURES
5.1 Extinguishing media
In case of fire, use appropriate fire extinguishers: pulverized water, water + additive or carbon dioxide according to the
regulation on the fire protections. The water jet stick is dissuaded.

Do not inhale smokes.

In case of insufficient ventilation, use a protection breath.

5.2 Special hazards arising from the substance or mixture

None.

5.3 Advice for firefighters

No special measure.

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes.
Wear appropriate protective equipment (see paragraph 8).
Provide proper ventilation.
Remove all sources of ignition.

6.2 Environmental precautions

Avoid contamination of soil and water, any discharge into drains, ditches, rivers.

6.3 Methods and material for containment and cleaning up

Absorb the material on a porous, inert material such as earth or sand and pumping water rinse after recovery of specific
waste in plastic containers and disposed of in accordance with local regulations.

6.4 Reference to other section

No data available

alexmo cosmetics GmbH - Handelshof 14a - 28816 Stuhr – Deutschland - Telefon: +49-421-84003464 - E-Mail: [email protected]
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 MATERIAL SAFETY DATA SHEET
According to Regulation (EC) N° 1907/2006 and 453/2010

Fragrance de Shea PÖ
SECTION 7. HANDLING & STORAGE
7.1 Precautions for safe handling
Wear adequate protective equipment (see section 8.2).
Do not handle near from high temperature source or any sources ignition. Maintain adequate local and general ventilation
where product is handled.
Good personal washing routines should be followed, do not eat, drink, smoke and wash hands before breaks and after work.

7.2 Conditions for safe storage, including any incompatibilities

It is recommended to store products in a cool airy place, protected against the light and against any source of ignition, in a
hermetically closed packaging. If needed, re-package them in a smaller compliant packaging.

Respect the main rules of incompatibility at the level of the storage. For example, the corrosive products or biocides must be
separated the one from the others, and flammable products must be stood apart in a zone tailored for that purpose and
locked.

7.3 Specific end use(s)

No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control Parameters
Professional Exposure Limit Values :
No specific data.

8.2 Exposure controls

It is recommended to use CE protective equipments.

Protection of eyes and face : use safety glasses, clean them and disinfect them regularly by following the
instructions of the manufacturer.

Protection of hands : use gloves resisting chemicals and replace them in the first sign of deterioration.

Protection of the skin other than hands : wear only professionnal protective clothings as well as anti-skid safety footwear.

Protection of respiratory tracts : a protection of respiratory tracts is not normally necessary when the room is
correctly aerated (unless the danger class requires it). In stuffy, weakly ventilated places, a respiratory protection can be
required

SECTION 9. PHYSICAL & CHEMICAL PROPERTIES

9.1 Informatrions on basic physical and clinical properties
a) Flash point (°C) 125.5
b) Refractive index @ 20°C 1.45490 / 1.46490
c) Densité relative (d20/20) @ 20°C 0.96900 / 1.02900
d) Odour Greedy floral
e) Color Colourless
f) Apearance Liquid
9.2 Other informations
No data available

alexmo cosmetics GmbH - Handelshof 14a - 28816 Stuhr – Deutschland - Telefon: +49-421-84003464 - E-Mail: [email protected]
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MATERIAL SAFETY DATA SHEET
According to Regulation (EC) N° 1907/2006 and 453/2010

Fragrance de Shea PÖ
SECTION 10. STABILITY & REACTIVITY
10.1 Reactivity
No reaction none.
10.2 Chemical stability
Good stability during approximatively 360 days.
10.3 Possibility of hazardous reactions
No hazardous reaction if storage and handling conditions are respected.
10.4 Conditions to avoid
Avoid contact with oxidizing agents.
Do not warm closed containers.
10.5 Incompatible materials
Unknown.
10.6 Hazardous decomposition products
The thermal decomposition may release/form carbon monoxide (CO) and /or carbon dioxide (CO2).
SECTION 11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
No toxological tests have been made on this mixture.
No data dealing with it is thus available.
11.1.1 Substances
Acute toxicity
3-(2H-1,3-benzodioxol-5-yl)-2-methylpropanal - 1205-17-0 - - DL50 (oral) 3561 mg/kg - DL 50 (cutaneous) 2000 mg/kg
3-p-Cumenyl-2-methylpropionaldehyde - 103-95-7 - - DL50 (oral) 2000 mg/kg - DL 50 (cutaneous) 5000 mg/kg
3-(p-Methoxyphenyl)-2-methylpropionaldehyde - 5462-06-6 - - DL50 (oral) 4000 mg/kg - DL 50 (cutaneous) 5000 mg/kg
1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethan-1-one and isomers - 54464-57-2 - - DL50 (oral) 5000 mg/kg - DL 50 (cutaneous) 5000
mg/kg
(12E)-oxacyclohexadecen-2-one - 111879-80-2 - - DL50 (oral) 2000 mg/kg - DL 50 (cutaneous) 2000 mg/kg

11.1.2 Mixtures
Acute toxicity
The value of the estimated acute toxicity of the mixture is:
oral No specific data.
dermal No specific data.
Inhalation No specific data.
SECTION 12. ECOLOGICAL INFORMATION
This mixture was not subjected to toxicological.
No experimental data dealing with it are thus available.
12.1 Toxicity
Not available.
12.2 Persistence and degradability
Not available.
12.3 Bioaccumulative potential
Not available.
12.4 Mobility in soil
Not available.
12.5 Results of PBT and vPvB assessment
Not applicable.
12.6 Other adverse effects
Not applicable.

alexmo cosmetics GmbH - Handelshof 14a - 28816 Stuhr – Deutschland - Telefon: +49-421-84003464 - E-Mail: [email protected]
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MATERIAL SAFETY DATA SHEET
According to Regulation (EC) N° 1907/2006 and 453/2010
Fragrance de Shea PÖ
SECTION 13. DISPOSAL CONSIDERATIONS
Waste must be eliminated according to the current local regulations.
The polluted packagings must be treated as waste and given to an approved dealer.
SECTION 14. TRANSPORT REGULATIONS
Land transport ADR/RID Sea transport IMDG Air transport ICAO-TI and IATA-DGR

14.1 UN Number
3082 3082 3082
14.2 UN proper shipping name

ENVIRONMENTALLY HAZARDOUS ENVIRONMENTALLY HAZARDOUS ENVIRONMENTALLY HAZARDOUS

SUBSTANCE, LIQUID, N.O.S SUBSTANCE, LIQUID, N.O.S SUBSTANCE, LIQUID, N.O.S

(1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8- (P.E : 125.5 °C - 1-(1,2,3,4,5,6,7,8- (1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-

tetramethyl-2-naphthalenyl)ethan-1-one Octahydro-2,3,8,8-tetramethyl-2- tetramethyl-2-naphthalenyl)ethan-1-
and isomers) naphthalenyl)ethan-1-one and isomers) one and isomers)
14.3 Transport hazard class(es)
9 9 9

14.4 Packing group

III III III
14.5 Environmental hazards

Environmentally hazardous yes Marine pollutant yes

Environmentally hazardous yes
1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,

14.6 Special precautions for user

ADR
Tunnel restriction code (-)
Classification code M6
IATA
Packing Instruction (PAX) 964
Packing Instruction (CAO) 964
IMG
EMS F-A,S-F
Customs nomenclature: 33029090

SECTION 15. REGULATORY INFORMATION

15.1 Safety, health and environment regulations/legislations specific for the substance or mixture
Regulation (EC) n° 1907/2006 (REACH) and its successives amendments
Regulation (EC) n° 453/2010
Regulation (EC) n° 878/2020
Regulation (EC) n° 1272/2008 (CLP) and its successives amendments
Directive 2000/39/EC (Occupational exposure limits)
Directive 98/24/EC (Safety of workers)

Refer to the following standards when applicable:

Regulation (EC) n° 648/2004 (Detergents)
Directive 1999/13/EC (COV) and its successives amendments

15.2 Chemical safety assessment

No chemical safety assessment has been carried out on the mixture itself.

alexmo cosmetics GmbH - Handelshof 14a - 28816 Stuhr – Deutschland - Telefon: +49-421-84003464 - E-Mail: [email protected]
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 MATERIAL SAFETY DATA SHEET
According to Regulation (EC) N° 1907/2006 and 453/2010
Fragrance de Shea PÖ
SECTION 16. OTHER INFORMATION
16.1 Indication of changes
The revisions are indicated by a black line in the margin.

16.2 Abbreviations and acronyms

ECHA : European Chemicals Agency

REACH : Registration, Evaluation and Authorisation of Chemicals Regulation (EC) No 1907/2006

CLP : Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS : Chemical Abstracts Service number
IUPAC : International Union for Pure Applied Chemistry
CMR : Carcinogens, mutagens or substances toxic to reproduction
SVHC : Substances of Very High Concern
PBT : Persistent Bioaccumulative Toxic
vPvB: Very Persistent, Very Bioaccumulative
LD50 : Lethal Dose to 50% of a test population (Median Lethal Dose)
LC50 : Lethal Concentration to 50 % of a test population
OEL : Occupational Exposure Limit Value
ADR : European Agreement concerning the International Carriage of Dangerous Goods by Road
IMDG : International Maritime Dangerous Goods
IATA : International Air Transport Association
ICAO-TI : Technical Instructions for the Safe Transport of Dangerous Goods by Air
16.3 Key literature references and sources for data
Suppliers data
CLP
ECHA
Guidance on the compilation of safety data sheets of ECHA
REACH
This material safety data sheet was realised in accordance with Annex II of the Regulation REACH.
16.4 Classification and procedure used to derive the classification for mixtures according to Regulation (EC)
1272/2008 [CLP]
Classes of hazards to human health and the environment were determined by calculation method.
Classes of physical hazards were determined on basis of test data.
16.5 Relevant R-phrases and/or H-statements (number and full text)
Phrase H
H302 : Harmful if swallowed.
H304 : May be fatal if swallowed and enters airways.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H319 : Causes serious eye irritation.
H400 : Very toxic to aquatic life.
H410 : Very toxic to aquatic life with long lasting effects.
H411 : Toxic to aquatic life with long lasting effects.
H412 : Harmful to aquatic life with long lasting effects.
The pieces of information and the recommendations on this safety data sheet are based on the state of our knowledge
relative to the products composing this mixture at the indicated date.
It is up to the user to evaluate these pieces of information in a careful way and to use them considering the usage this
product has been developed for.

The above data corresponds to our present knowledge and is a correct copy of the existing original certificate from our supplier. Any recommendations or
suggestions are made without warranty or guarantee, as the conditions of use are beyond our control. Applicable laws and regulations as well as patent or
other third party rights must be taken into account by the recipient.

alexmo cosmetics GmbH - Handelshof 14a - 28816 Stuhr - Deutschland

Telefon: +49-421-84003464 - Telefax: +49-421-84003462
E-Mail: [email protected]
USt-IdNr.: DE318501788 - eingetragen im Handelsregister des Amtsgerichtes Walsrode
Handelsregisternummer HRB 207256
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