MTR Aghs en
MTR Aghs en
MTR Aghs en
1. IDENTIFICATION
Product identifier
Product Name TitraVerÒ (EDTA) Standard Solution 0.010M (0.020N)
Manufacturer Address
Hach Company, P.O.Box 389, Loveland, CO 80539, USA, +1(970) 669-3050
2. HAZARDS IDENTIFICATION
Classification
Regulatory Status
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Label elements
Signal word
None
Hazard statements
The product contains no substances which at their given concentration, are considered to be hazardous to health
3. COMPOSITION/INFORMATION ON INGREDIENTS
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
Version 4 Page 2 / 16
Substance
Not applicable
Mixture
General advice No hazards which require special first aid measures. Use first aid treatment according to the
nature of the injury.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a physician.
Ingestion Clean mouth with water and drink afterwards plenty of water.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient.
Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.
fire-fighters Use personal protection equipment.
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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U.S. Notice Only persons properly qualified to respond to an emergency involving hazardous
substances may respond to a spill according to federal regulations (OSHA 29 CFR
1910.120(a)(v)) and per your company's emergency response plan and
guidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside
of the US, only persons properly qualified according to state or local regulations should
respond to a spill involving chemicals.
Environmental precautions
Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder,
sawdust). Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Reference to other sections See section 8 for more information. See section 13 for more information.
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice.
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Control parameters
Exposure Guidelines
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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Hand Protection Wear suitable gloves. Barrier creams may help to protect the exposed areas of skin.
Gloves must be inspected prior to use. The selected protective gloves have to satisfy the
specifications of EU Directive 2016/425 and the standard EN 374 derived from it. Chemical
resistant gloves made of butyl rubber or nitrile rubber category III according to EN
374-1:2016.
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin and body protection No special protective equipment required. Avoid contact with eyes, skin and clothing.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained. Do not allow
into any sewer, on the ground or into any body of water.
pH 5.0 @ 20 °C
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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Coefficient
Autoignition temperature No data available
Solubility(ies)
Water solubility
Other information
Metal Corrosivity
Chemical name CAS No Volatile organic compounds CAA (Clean Air Act)
(VOC) content
Formaldehyde 50-00-0 No data available X
Methanol 67-56-1 100% X
Explosive properties
Flammable properties
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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Reactivity
Not applicable.
Chemical stability
Stable under normal conditions.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Hazardous polymerization
None under normal processing.
Conditions to avoid
None known based on information supplied.
Incompatible materials
Strong oxidizing agents, strong acids, and strong bases.
Product Information
Acute toxicity
Based on available data, the classification criteria are not met
Mixture
No data available.
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Rat 100 mg/kg None reported None reported GESTIS
(<0.1%) LD50
CAS#: 50-00-0
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Rabbit 270 mg/kg None reported None reported GESTIS
(<0.1%) LD50
CAS#: 50-00-0
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Rat 0.578 mg/L 4 hours None reported LOLI
(<0.1%) LC50
CAS#: 50-00-0
Skin corrosion/irritation
Based on available data, the classification criteria are not met.
Mixture
No data available.
Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Formaldehyde Standard Draize Human 0.150 mg 72 hours Corrosive to skin RTECS
(<0.1%) Test
CAS#: 50-00-0
Methanol OECD Test 439: In Rabbit None reported 20 hours Not corrosive or ECHA
(<0.1%) Vitro Skin Irritation: irritating to skin
CAS#: 67-56-1 Reconstructed
Human Epidermis
(Rhe) Test Method
Mixture
No data available.
Chemical name Test method Species Reported Exposure Results Key literature
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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Mixture
No data available.
Chemical name Test method Species Results Key literature references and
sources for data
Formaldehyde Patch test Human Confirmed to be a skin sensitizer ERMA
(<0.1%)
CAS#: 50-00-0
Methanol OECD Test No. Guinea pig Not confirmed to be a skin sensitizer ECHA
(<0.1%) 406: Skin
CAS#: 67-56-1 Sensitization
Chemical name Test method Species Results Key literature references and
sources for data
Formaldehyde IgE Specific Guinea pig Confirmed to be a respiratory CICAD
(<0.1%) Immune Response sensitizer
CAS#: 50-00-0 Test
Mixture
No data available.
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Human 70 mg/kg None reported Gastrointestinal RTECS
(<0.1%) LDLo Kidney, Ureter, or Bladder
CAS#: 50-00-0 Liver
Other changes
Ulcerated stomach
Other changes
Methanol Human 143 mg/kg None reported Lungs, Thorax, or RTECS
(<0.1%) LDLo Respiration
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Methanol Human 300 mg/L None reported Lungs, Thorax, or RTECS
(<0.1%) TCLo Respiration
CAS#: 67-56-1 Other changes
Mixture
No data available.
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Methanol Monkey 2340 mg/kg 3 days None reported ECHA
(<0.1%)
CAS#: 67-56-1
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Human 0.017 mg/L 0.5 days Eye RTECS
(<0.1%) TCLo Lungs, Thorax, or
CAS#: 50-00-0 Respiration
Lacrimation
Other changes
Carcinogenicity
Based on available data, the classification criteria are not met.
Mixture
No data available.
Legend
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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Chemical name Test Cell Strain Reported Exposure Results Key literature
dose time references and
sources for data
Methanol DNA inhibition Human lymphocyte 300 mmol/L None reported Positive test result for RTECS
(<0.1%) mutagenicity
CAS#: 67-56-1
Reproductive toxicity
Based on available data, the classification criteria are not met.
Mixture
No data available.
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Methanol Rat 4118 mg/kg 10 days Effects on Embryo or Fetus RTECS
(<0.1%) TDLo Specific Developmental
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Methanol Rat 0.0026 mg/L 22 days Effects on Embryo or Fetus RTECS
(<0.1%) TCLo Fetotoxicity (except death e.g.
CAS#: 67-56-1 stunted fetus)
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Rat 40 mg/L 14 days Effects on Embryo or Fetus RTECS
(<0.1%) TCLo Fetotoxicity (except death e.g.
CAS#: 50-00-0 stunted fetus)
Aspiration hazard
Based on available data, the classification criteria are not met.
Ecotoxicity Based on available data, the classification criteria are not met.
Unknown aquatic toxicity 0% of the mixture consists of components(s) of unknown hazards to the aquatic
environment.
Mixture
Substance
Fish
Chemical name Exposure Species Endpoint Reported dose Key literature references and
time type sources for data
Formaldehyde 96 hours Morone saxatilis LC50 6.7 mg/L PEEN
(<0.1%)
CAS#: 50-00-0
Crustacea
Chemical name Exposure Species Endpoint Reported dose Key literature references and
time type sources for data
Formaldehyde 48 Hours Daphnia pulex EC50 5.8 mg/L PEEN
(<0.1%)
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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CAS#: 50-00-0
Mixture
No data available.
Mixture
No data available.
Mobility
Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.
Chemical name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
Formaldehyde U122 Included in waste - U122
50-00-0 streams: K009, K010,
K038, K040, K156, K157
Methanol - Included in waste stream: - U154
67-56-1 F039
Special instructions for disposal Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate.
Open cold water tap completely, slowly pour the reacted material to the drain. Allow cold
water to run for 5 minutes to completely flush the system.
Additional information
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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There is a possibility that this product could be contained in a reagent set or kit composed of various compatible dangerous goods.
If the item is not in a reagent set or kit, the classification given above applies.
If the item is part of a reagent set or kit the classification would change to the following:
UN3316 Chemical Kit, Hazard Class 9, Packing Group II or III.
If the item is not regulated, the Chemical Kit classification does not apply.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
International Inventories
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL - Existing substances Complies
PICCS Complies
TCSI Complies
AICS Complies
NZIoC Complies
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical name CWA - Reportable CWA - Toxic Pollutants CWA - Priority CWA - Hazardous
Quantities Pollutants Substances
Formaldehyde 100 lb - - X
50-00-0
CERCLA
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
WARNING: This product can expose you to chemicals including Formaldehyde, Methanol, which are known to the State of
California to cause cancer or birth defects or reproductive harm.
For more information, go to http://www.P65Warnings.ca.gov
Additional information
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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Key or legend to abbreviations and acronyms used in the safety data sheet
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Product Code(s) 20553 Product Name TitraVerÒ (EDTA) Standard Solution 0.010M
(0.020N)
Issue Date 04-Dec-2018 Revision Date 08-Feb-2023
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TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
Disclaimer
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.
Ó2022
HACH COMPANYÓ
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