WT16

(Batches: e-SANKALP-2325 S1, T1 & P1)
IIT – JEE, 2325 Paper Code

100992
(CLASS XI)
Time: 2 Hours Maximum Marks: 126
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.
B. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section–1 (01 – 06) contains (06) Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases
5 Section–2 (07 – 09) contains (03) Multiple Choice Questions which have one or more than one
correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
6. Section–3 (10 – 12) contains (03) Non-Negative Numerical Value Questions, the answer to each
question is a Non-Negative Numerical Value. For each question, enter the correct numerical value
corresponding to the answer and each question carries +4 marks for correct answer. There is no
negative marking.
Enrolment No. :
Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
e-Sankalp2325 S1, T1 & P1-XI-PCM-(100992)-2
PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. A cylinder has a radius r. To what height h should it be filled with water so that the thrust on its
walls is equal to that on its bottom
(A) h = 2r (B) h = r
(C) h = (r/2) (D) h = (r/4)
2. A tube filled with water (density w) and closed at both ends O
 P1 P2
uniformly rotates in a horizontal plane about OO-axis. The
manometers fixed in the tube wall at distance r1 and r2 from
the rotational axis indicate pressure P1 and P2 respectively
as shown in the figure. Angular velocity ‘’ of rotation of the
r1
tube is
r2
O
2(P1  P2 ) (P1  P2 )
(A) 2 (B)
w (r12  r22 ) w (r12  r22 )
(P1  P2 ) 2(P1  P2 )
(C) (D)
2w (r12  r22 ) w (r12  r22 )
3. The cylindrical tube of a spray pump has a radius R, one end of which has n fine holes, each of
radius r. If the speed of flow of the liquid in the tube is V, the speed of ejection of the liquid
through the holes is
2
R r 
(A) V  (B) V     n
r R
2
V R  V R
(C)   (D) 
n r n r
Space for Rough work
4. Shampoo is being poured into a vessel of frustum shaped with constant volume flow
3
rate 16.5 cm /s. At what rate is its level in the bottle rising at a point where diameter of the bottle
is 6.30 cm. (keeping significant figures in view)
(A) 0.063 cm/s (B) 0.63/cm/s
(C) 0.529 cm/s (D) 0.729 cm/s
5. Consider a wooden block immersed in a beaker containing water. If the

beaker now starts accelerating upwards then:
(A) Tension in the string will increase
M
(B) Tension the string will decrease
(C) Tension in the string will remain unchanged
(D) data insufficient
6. A hemispherical portion of radius R is removed from the bottom of a

cylinder of radius R. The volume of the remaining cylinder is V and its
h
mass is M. It is suspended by a string in a liquid of density  where it
stays vertical. The upper surface of the cylinder is at a depth h below the 
liquid surface. The force on the bottom of the cylinder by the liquid is
2R
(A) Mg (B) Mg – V g
(C) Mg + R2hg (D) g(V +R2h)
SECTION – 2 : (One or More Than One Options Correct Type)
This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
7. A cubical block is floating in a liquid with one third of it’s volume immersed in the liquid. When the
whole system accelerates upwards with acceleration of g/2.
(A) The fraction of volume immersed in the liquid will change.
(B) The buoyancy force on the block will change.
(C) The buoyancy force will increase by 50 percent.
(D) The pressure in the liquid will increased.
8. A cylindrical tube, with its base as shown in the figure, is filled d

with water. It is moving down with a constant acceleration a
along a fixed inclined plane with angle  = 45. P1 and P2 are
pressures at points 1 and 2, respectively located at the base g
of the tube. Let  = (P1 P2) / (gd), where  is density of
water, d is the inner diameter of the tube and g is the
acceleration due to gravity. Which of the following 2
statement(s) is(are) correct? a
1
 = 45
(A)  = 0 when a = g / 2 (B)  > 0 when a = g / 2
2 -1 1
(C) β = when a = g / 2 (D) β = when a = g / 2
2 2
9. A spherical body of radius R consists of a fluid of constant density and is in equilibrium under its
own gravity. If P(r) is the pressure at r(r < R), then the correct option(s) is(are)
P(r  3R / 4) 63
(A) P(r = 0) = 0 (B) 
P(r  2R / 3) 80
P(r  3R / 5) 16 P(r  R / 2) 20
(C)  (D) 
P(r  2R / 5) 21 P(r  R / 3) 27
SECTION – 3: (Numerical Answer Type)
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
10. A rectangular tank of height 6 m filled with water, is

placed near the bottom of an incline of angle 300. At
height x from bottom a small hole is made (as shown
in figure) such that the stream coming out from hole, 6m x
x 0
strikes the inclined plane normally. Find in metre. 30
2
11. In a large cylindrical water tank there are two small holes Q and P on
the wall at a depth of h1 from upper level of water and at a height of h2 Q h1
from the lower end of the tank respectively as shown in the figure.
Water coming out from both the holes strike the ground at the same P h2
point. Find the ratio of h1 and h2.
12. A hot air balloon is carrying some passengers, and a few sandbags of mass 1 kg each so that its
total mass is 480 kg. Its effective volume giving the balloon its buoyancy is V. The balloon is
floating at an equilibrium height of 100 m. When N number of sandbags are thrown out, the
balloon rises to a new equilibrium height close to 150 m with its volume V remaining unchanged.
h

h0
If the variation of the density of air with height h from the ground is   h   0 e , where 0 = 1.25
N
kg m−3 and h0 = 6000 m, the value of is _________.
10
PART II : CHEMISTRY
SECTION – 1: (Only One Options Correct Type)
and (D) out of which ONE is correct.
1. Which of the given statement is/are correct for the given reaction knowing the fact that higher the
number of hyperconjugative structures higher the stability of carbocation


 CD3 3 C   CH3 3 CH 
  CH3 3 C   CD3 3 CH

(A) The equilibrium constant should be higher than one for the above reaction
(B) The equilibrium constant should be lower than one for the above reaction
+ +
(C) (CD3)3C will be more stable than (CH3)3C due to higher electron releasing nature of
deuterium than hydrogen
(D) (CD3)3C+ will be more stable than (CH3)3C+ due to presence of stronger C – D bond than
C – H bond
2. In the following carbocation H/CH3 that is most likely to migrate to the positively charged carbon
is
H H
1 2 4 5
H3C C C C CH3
3
OH H CH3
(A) CH3 at C-4 (B) H at C-4
(C) CH3 at C-2 (D) H at C-2
3. The correct stability order for the following species is
O O
(I) (II) (III) (IV)
(A) (II) > (IV) > (I) > (III) (B) (I) > (II) > (III) > (IV)
(C) (II) > (I) > (IV) > (III) (D) (I) > (III) > (II) > (IV)
Space for rough work
4. Which of the following is correct order of stability of carbanion?
CH2 CH2 CH2 CH2
CH3 NO 2 NH2
(I) (II) (III) (IV)
(A) I > II > III > IV (B) IV > II > I > III
(C) III > I > II > IV (D) III > IV > I > II
5. Arrange the following cations in the increasing order of stability:

 C6H5 3 C ,  CF3 3 C ,  CCl3 3 C ,  CH3 3 C 
I II III IV 
(A) I < II < III < IV (B) II < III < IV < I
(C) III < II < IV < I (D) III < II < I < IV
6. Arrange the following in increasing order of their stability:
CH2 CH2 CH2 CH2
OH CH3 NO 2
(I) (II) (III) (IV)
(A) IV > I > III > II (B) IV < I < III < II
(C) IV < I < II < III (D) I < IV < III < II
SECTION – 2: (Multi Correct Choice Type)
out of which ONE OR MORE may be correct.
7. Which of the following is correct order for stability of carbanion:
NC CN
NC CN
(I) (II) (III) (IV)
(A) III > I (B) III > I
(C) IV > II (D) IV > I
8. Which of the following is correct order of stability of carbocation:
(C6H5)3C C H2C CH CH2 H3C CH2 CH2

3
(I) (II) (III) (IV)
(A) II > III (B) II > I
(C) IV > III (D) I > IV
9. Which of the following stability order are correct?
(I) (II) (III) (IV)

(A) I > II (B) II > III
(C) III > IV (D) IV > I
10. Among the following, the number of aromatic compound(s) is
11. The total number of contributing structure showing hyperconjugation (involving CH bonds) for
the following carbocation is
H3C CH2 CH3
12. Total number of hyperconjugating hydrogen in the following structures is/are:
CH2 CH3 CH3 CH3
, , ,
PART III : MATHEMATICS

SECTION – 1: (Only One Options Correct Type)
and (D) out of which ONE is correct.
x2 y 2
1. A variable chord of the hyperbola   1 , subtends a right angle at the centre of the
4 8
hyperbola. If this chord touches a fixed circle concentric with the hyperbola, then the equation of
the circle is
(A) x2 + y2 = 4 (B) x2 + y2 = 8
2 2
(C) x + y = 16 (D) x2 + y2 = 64
 1  2 2
2. Tangent drawn from P   h, 0  to hyperbola x – y = 1 touches it at A. If A is joined to
 2 
QS
S  2, 0  and foot of perpendicular from P on AS is Q lim is equal to
h0 h
1
(A) 2 (B)
2
(C) 2 (D) none of these
x2 y 2
3. If from a given point P on a hyperbola   1 chords are drawn at right angles to meet the
2 1
hyperbola at R and T such that all the chords RT are concurrent at the point Q. If the eccentric

angle of point P is , then is the coordinates of point Q is given by
4
(A) (6, 3) (B) (6, 3)
(C) (4, 2) (D) (8, 6)
x2 y2
4. A straight line intersects the same branch of the hyperbola   1 in P1 and P2 and meets
a2 b2
its asymptotes in Q1 and Q2. Then P1Q2  P2Q1 is equal to
(A) (a  b) (B) a2  b2  ab
(C) 0 (D) a2  b2
x 2 y2  x  4 2 y 2
5. Let E1 :   1 and E 2 :   1 . If E2 rolls on E1, without slipping, then which of the
4 3 4 3
following is/are false?
(A) Locus of centre of E2 is a polynomial of fourth degree
(B) Locus of one of the focus of E2 is polynomial of third degree
(C) Locus of centre of E2 is a closed curve
(D) Locus of one of the focus of E2 is a closed curve
x2 y 2 x2 y 2
6. In the coordinate plane, ellipse C1 :   1 (a 1 0, b1 > 0 and hyperbola C 2 :  1
a12 b12 a22 b22
(a2, b2 > 0) has the same focus points F1, F2. Point P is one of the intersection points of C1 and C2
and PF1 is perpendicular to PF2. If e1 is the eccentricity of C1 and e2 is the eccentricity of C2. Then
minimum value of 9e12  e22 is
(A) 2 (B) 4
(C) 6 (D) 8
SECTION – 2: (Multi Correct Choice Type)
out of which ONE OR MORE may be correct.
7. Let ABC be a triangle with fixed base BC = 1 and vertex ‘A’ is variable. If one base angle is
double of the other base angle then locus of A is a hyperbola
(A) Whose eccentricity is 4 (B) Whose L.R is 4
(C) Whose eccentricity is 2 (D) Whose L.R. is 2.
8. The variable line mx – y + 2 = 0  m  R either touches or intersects the curves y = x 2 and

2 y2
x =1+ in total three distinct points then the possible values of m can be
4
(A) 2 2 (B) 2 2
(C) 2 (D) –2
2
9. Normals are drawn from the external point (h, k) to the rectangular hyperbola xy = c . If circles are
drawn through the feet of these normals taken three at a time then centre of circle lies on another
hyperbola whose centre and eccentricity is
h k
(A)  ,  (B) (h, k)
 2 2
(C) 2 (D) 2 1
10. Consider ABC with vertices A[sin( – ), – cos( – )], B[–sin( + ), cos( + )],
C[–sin, – cos], where  is a real constant and  is a variable angle, –  <  < . An circle
1
(circumscribing ABC) is drawn which acts as auxiliary circle to an ellipse with eccentricity
2
(horizontal ellipse). If a rectangular hyperbola is drawn such that its focus is same as ellipse then
1
one of its directrix is x = (k > 0) where k is ____________
k
x2 y 2
11. A circle having centre C(a, b) lying on the ellipse   1 cuts the rectangular hyperbola
4 9
xy = 2 in four points (xi, yi); i = 1, 2, 3, 4. If the locus of the centroid of triangle formed by any three
 2a  2b  2 2
points of intersection is  x   y  3   k , then the value of 2 is
 3   k
x2 y 2
12. If the tangent at the point (h, 2) on the hyperbola 2
 2  1 cuts the circle x2 + y2 = a2 at the
a b
1 1
points Q(x1y1) and R(x2y2), then the value of  is _____
y1 y 2

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(Batches: e-SANKALP-2325 S1, T1 & P1)

IIT – JEE, 2325 Paper Code

B. Question Paper Format

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

Space for Rough work

5. Consider a wooden block immersed in a beaker containing water. If the

6. A hemispherical portion of radius R is removed from the bottom of a

Space for Rough work

SECTION – 2 : (One or More Than One Options Correct Type)

8. A cylindrical tube, with its base as shown in the figure, is filled d

Space for Rough work

SECTION – 3: (Numerical Answer Type)

10. A rectangular tank of height 6 m filled with water, is

Space for Rough work

3. The correct stability order for the following species is

Space for rough work

4. Which of the following is correct order of stability of carbanion?

CH2 CH2 CH2 CH2

5. Arrange the following cations in the increasing order of stability:

6. Arrange the following in increasing order of their stability:

CH2 CH2 CH2 CH2

Space for rough work

SECTION – 2: (Multi Correct Choice Type)

7. Which of the following is correct order for stability of carbanion:

8. Which of the following is correct order of stability of carbocation:

(C6H5)3C C H2C CH CH2 H3C CH2 CH2

9. Which of the following stability order are correct?

(I) (II) (III) (IV)

Space for rough work

SECTION – 3: (Numerical Answer Type)

10. Among the following, the number of aromatic compound(s) is

12. Total number of hyperconjugating hydrogen in the following structures is/are:

CH2 CH3 CH3 CH3

Space for rough work

PART III : MATHEMATICS

Space for rough work

SECTION – 2: (Multi Correct Choice Type)

Space for rough work

8. The variable line mx – y + 2 = 0  m  R either touches or intersects the curves y = x 2 and

SECTION – 3: (Numerical Answer Type)

Space for rough work

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