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(Batches: e-SANKALP-2325 S1, T1 & P1)

I I T – JEE, 2 3 2 5 Paper Code


000000
(CLASS XI)
Time: 2 Hours Maximum Marks: 126
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.

B. Question Paper Format


The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section–1 (01 – 06) contains (06) Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases
5 Section–2 (07 – 09) contains (03) Multiple Choice Questions which have one or more than one
correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
6. Section–3 (10 – 12) contains (03) Non-Negative Numerical Value Questions, the answer to each
question is a Non-Negative Numerical Value. For each question, enter the correct numerical value
corresponding to the answer and each question carries +4 marks for correct answer. There is no
negative marking.

Enrolment No. :

Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax
26513942
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-2

PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.

1. A uniform thin rod AB is equipped at both ends with the hooks B


shown and is supported by a frictionless horizontal table. Initially
C
the rod is hooked at A to a fixed pin C about which it rotates with B
a constant angular velocity 1. Suddenly end B of the rod hits pin A 1 D
D and gets hooked to pin D, causing end A to be released. 2
A
Determine the magnitude of the angular velocity 2 of the rod in
its subsequent rotation about D. (Assume length and mass of the
hook is negligible. Pin C & D are lying on a same horizontal line)
(A) 31 (B) 1/2
(C) 1 (D) none of these

2. The figure shows two rods BC and OA hinged from B and O respectively. B
C
Rod BC has a groove in which point A of rod OA can slide smoothly. At a A

given instant, the rod BC has an angular velocity 0. The speed of end A 0

of the rod OA at this instant will be 
(A) 0 (B) 20 O
(C) 30 (D) None of these.

3. A square plate of mass 10 kg and side 20 m is moving along D


the groove with the help of two ideal rollers (massless),
connected at the corners A and B of the square. At a certain
moment of time as shown in the figure, during motion, the
corner A is moving with velocity 16 m/s downward. Find the
speed of corner D. A C
(A) 32 m/s (B) 16 m/s
(C) 8 m/s (D) none
20m

450

Space for Rough work

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4. The wheel of radius R rolls without slipping on horizontal


rough surface, and its centre O has an horizontal
acceleration a0 in forward direction. A point P on the wheel R
is a distance r from O and angular position  from O  a0 v0
horizontal. For a given values of a0, R and r, determine the r
angle  for which point P has no acceleration in this P
position.
r r
(A) cos1 (B) tan1
R R
1 r 1 r
(C) sin (D) cos
R 2R

5. A heavy disc with radius R is rolling down hanging on


two non-stretched string wound around the disc very
tightly. The free ends of the string are attached to a fixed 
horizontal support. The strings are always tensed during
the motion. At some instant, the angular velocity of the 
disc is , and the angle between the strings is . Find
the velocity of centre of mass of the disc at this moment.

R R
(A) (B)
 
sin   cos  
2 2
2R 2R
(C) (D)
 
sin   cos  
2 2

6. A flat surface of a thin uniform disk A of radius R is glued to a


horizontal table. Another thin uniform disk B of mass M and with the
same radius R rolls without slipping on the circumference of A , as
shown in the figure. A flat surface of B also lies on the plane of the
table. The center of mass of B has fixed angular speed ω about the
vertical axis passing through the center of A . The angular momentum B
of B is nMωR2 with respect to the center of A . Which of the following A
is the value of n ?
(A) 2 (B) 5
(C) 7/2 (D) 9/2

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-4

SECTION – 2 : (One or More Than One Options Correct Type)

This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.

7. A uniform rod AB of length '' is thrown upwards such that initially


AB is horizontal, velocity of centre is 'u' upwards and angular
velocity '' is such that velocity of 'B' at this moment is zero. The
values of '' and 'u' are also such that the rod becomes vertical first
time at the moment when the centre of rod reaches the highest
point of its motion.
2u
(A) The value of '' in terms of 'u' and '' is equal to .

u
(B) The value of '' in terms of 'u' and '' is equal to .

g
(C) The value of ‘u’ is equal to
4
g
(D) The value of ‘u’ is equal to
2

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-5

z
8. The figure shows a system consisting of (i) a ring of outer
radius 3R rolling clockwise without slipping on a horizontal 
surface with angular speed  and (ii) an inner disc of radius
2R rotating anti-clockwise with angular speed /2. The ring /2
and disc are separated by frictionless ball bearings. The 3R

point P on the inner disc is at a distance R from the origin, O


x
2R
where OP makes an angle of 300 with the horizontal. Then
with respect to the horizontal surface,
(A) the point O has linear velocity 3R î
11 ˆ 3
(B) the point P has linear velocity R i  Rkˆ .
4 4
13 3
(C) the point P has linear velocity R ˆi  Rkˆ
4 4
 3 1
(D) the point P has linear velocity  3 
  R ˆi  Rkˆ
 4  4

9. Two thin circular discs of mass 2 kg and radius 10 cm each are


joined by a rigid massless rod of length 20 cm. The axis of the  
rod is along the perpendicular to the plane of the disc through O
their centres (see fig.). This object is kept on a truck in such a 20 cm
way that the axis of the object is horizontal and perpendicular to
the direction of the motion of the truck.
Its friction with the floor of the truck is large enough so that the object can roll on the truck without
slipping. Take x axis as the direction of motion of the truck and z-axis as vertically upwards
direction. If the truck has an acceleration of 9 m/s 2. Choose correct option(s).

(A) The force of friction on each disc is f   3N ˆi .

(B) The force of friction on each disc is f   6N ˆi .
(C) The frictional torque acting about the centre of mass O of the object is 1.2ˆj
(D) The frictional torque acting about the centre of mass O of the object is 1.2ˆj  1.2kˆ

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-6

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).

10. A long horizontal rod has a bead which can slide along its length and initially placed at a distance
L( = 3 m) from one end A of the rod. The rod is set in angular motion about A with constant
angular acceleration  (= 1 rad/sec2). If the coefficient of friction between the rod and the bead is
(=1) and gravity is neglected, then find the time (in sec) after which bead starts slipping.

11. A cylinder of height h, diameter h/2 and mass M and with a h/2
homogeneous mass distribution is placed on a horizontal
table. One end of a string running over a pulley is fastened h M
to the top of the cylinder, a body of mass m is hung from
the other end and the system is released. Friction is
negligible everywhere. At what minimum ratio m/M will the m
cylinder tilt?

12. A small body A is fixed to the inside of a thin rigid hoop of


radius R and mass equal to that of the body A. The hoop rolls
without slipping over a horizontal plane; at the moments when
the body A gets into the lower position, the centre of the hoop
v0
moves with velocity v0. If hoop moves without bouncing for
minimum v0 = 80kgR . Find the value of k. R

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax
26513942
website: www.fiitjee.com.
eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-7

PART II : CHEMISTRY
SECTION – 1 : (Only One Option Correct Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.

1. The electrolytic oxidation of N2O4 was carried out in a solution buffered by NaHCO3 and Na2CO3.
The reaction involved was:
N2O4  2H2 O   2NO3  4H  2e
100 ml of 1M solution of N2O4 buffered initially at pOH = 3, was oxidized, with reaction above
going to completion. The total ionic concentration initially, i.e. [NaHCO 3 + Na2CO3] was 0.4 M.
The pH of the solution after oxidation will be: (For H2CO3. K a1  106 and K a2  10 11 ) :
(A) 5.7 (B) 6.0
(C) 6.3 (D) 11.0

2. The self ionization constant for pure formic acid K  HCOOH2  HCOO   has been estimated as
10-6 at room temperature. The density of formic acid is 1.15 g/cm3. What percentage of formic
acid molecules convert to formate anion:
(A) 0.001% (B) 0.002%
(C) 0.003% (D) 0.004%

3. A 1.025 gm sample containing a weak acid HX (mol. wt = 82) is dissolved in 60 ml H2O and
titrated with 0.25 M NaOH solution. When half of the acid is neutralized the pH was found to be
5.0 and the pH at equivalence point is 9.0. Calculate the percentage of HX in the original sample.
(Assume law of conservation of volume is obeyed)
(A) 40% (B) 80%
(C) 65% (D) 78%
Space for Rough work

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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-8

4. The ionization constant of benzoic acid is 6.46  10 5 and Ksp for C6H5 COOAg is 2.5  10 13 .
How many times is silver benzoate more soluble in buffer of pH 3.19 as compared to pure water.
(A) 1.658 (B) 2.5
(C) 3.316 (D) 1.55

5. The acid ionization constant for


Zn2   H2 O    Zn  OH  H is 1.0  10 9 . Calculate the pH of 0.0010 M solution of ZnCl2.

(A) 5 (B) 6
(C) 8 (D) 9

6. Calculate the pH of 0.05 M KHC8H4O4


H2 C8H4 O 4  H2O    H3 O   HC8H4 O 4 ; pK a1  2.94
HC8H4 O 4  H2O    H3 O  C8H4 O24  ; pK a2  5.44
(A) 4.19 (B) 2.94
(C) 5.44 (D) 5.64
Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax
26513942
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-9

SECTION – 2 : (One or More Than One Options Correct Type)

This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.

7. Solubility product of the hydroxide M(OH)2 is 4 × 10-12 select the correct statement(s) among the
following
(A) the pH of its saturated solution will be 10.3
(B) its solubility will decrease in a buffer medium of pH = 11
(C) its solubility will increases in a buffer medium of pH = 1
(D) its solubility is unaffected by pH of the medium

8. 
H3PO 4  H  H2PO 4 ;
 K a1

H2PO 4  H  HPO 42  ;
 K a2

HPO  H  PO ;
2

4
 3
4 K a3
Mark out the correct statement:
pK a1  pK a2
(A) K a1  K a2  K a3 
(B) pH H2PO4   2
(C) HPO 24  is less acidic than H2PO 4 (D) only HPO 24  is amphiprotic in the solution

9. Silver ions are added to a solution with Br    Cl   CO32     AsO 43   0.1 M . Which
compound will not precipitate at the lowest  Ag  ?
(A) AgBr K sp  5  10 13  (B) AgCl K sp  1.8  10 10 
(C) Ag2CO3 K sp  8.1 10 12  (D) Ag3 AsO 4 K sp  1 10 22 

Space for Rough work

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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-10

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).

Given: Ag NH3 2    Ag  2NH3 , K C  6.2  10 8 and K sp of AgCl  1.8  1010 at 298 K. If the

10.
concentration of the complex in 1.0 M aqueous ammonia is x then calculate 100x.

11. Determine the mole of AgI which may be dissolved in 1.0 litre of 1.0 M CN solution. Ksp of AgI

and KC for  Ag  CN2  are 1.2  10 17 M2 and 7.1 1019 M2 respectively.

12. A buffer solution of 0.080 M Na2HPO4 and 0.020 M Na3PO4 is prepared. The electrolytic oxidation
of 1.0 m mole RNHOH is carried out in 100 mL buffer to give.
RNHOH  H2O   RNO 2  4H  4e
Calculate approximate pH of the solution after oxidation is complete.
pK a1 , pK a2 and pK a3 of H3PO 4 are 2.12, 7.20 and 12.0 respectively.

Space for Rough work

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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-11

PART III : MATHEMATICS


SECTION – 1 : (Only One Option Correct Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.

1. Number of solutions of the equation where x  (0, /2) cot() + cot( – /3) + cot( – /3) +
3cot(3) = 0
(A) Infinite (B) 0
(C) 1 (D) none of these

2. If the equation p sin 2x + cos x = p has a solution, then the range of p is


(A) (–, ) (B) [–1, 1]
(C) ]–, 0] (D) [0, [

3. The number of solutions of the equations 2 sin2 x + sin2 2x = 2, sin 2x + cos 2x = tan x in [0, 4]
satisfying the condition 2 cos2 x + sin x  2 is
(A) 4 (B) 6
(C) 8 (D) 2

4. If x, y, z are angles of a triangle and tan x = 2 cot y and tan x + tan y + tan z = 6 then value of z is

(A) n  ; n  I (B) n  tan1 2 ; n  I
4
(C) n  tan1 3 ; n  I (D) n; n  I

5. The equation 2x = (2n + 1) (1 – cosx), where n is a positive integer


(A) has infinitely many real roots (B) has exactly one real root
(C) has exactly 2n + 2 real roots (D) has exactly 2n + 3 real roots

 
The number of solutions of the equation sin x  cos x  ln x   1 is
3
6.
2 2
(A) 4 (B) 6
(C) 8 (D) none of these

Space for rough work

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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-12

SECTION – 2: (Multi Correct Choice Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.

7. The roots of the equation sin3 = 4sin sin(x + ) sin(x  ), 0  x   where sin  0 and  is
acute angle, is/are

(A)  (B)   
2
 2
(C) (D)
3 3

sin2 2x  4 sin 4 x  4 sin2 x cos2 x


1
8. If 2 2

then,
4  sin 2x  4 sin x 9
(A) number of possible value of x is 4 in the interval (0, 2)
(B) number of possible value of x is 2 in the interval (0, 2)
(C) sum of the roots of the equation in the interval (0, 2) is 4
(D) sum of the roots of the equation in the interval (0, 2) is 5

 7 
9. If sin   a has exactly 3 solutions in   0,  then the value of ‘a’ is
 3
10  2 5 5 1
(A) (B)
4 4
5 1 3 1
(C) (D)
4 2 2

Space for rough work

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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-13

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).


10. If cos is a root of the equation 8x3 + 4x2 – 4x – 1 = 0. Then n = ______ (n  N).
n 1

 x  2x 
11. Number of solution of the equation sin    cos    2 _____
 4   4 

    
12. If   1   2  3  , then number of values of     ,  satisfying
2 2  2 2
(tan  – tan 1) (tan  – tan 2) (tan  – tan 3) –    tan   tan    is __________.
i

Space for rough work

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