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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-2
PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
2. The figure shows two rods BC and OA hinged from B and O respectively. B
C
Rod BC has a groove in which point A of rod OA can slide smoothly. At a A
given instant, the rod BC has an angular velocity 0. The speed of end A 0
of the rod OA at this instant will be
(A) 0 (B) 20 O
(C) 30 (D) None of these.
450
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-3
R R
(A) (B)
sin cos
2 2
2R 2R
(C) (D)
sin cos
2 2
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-4
This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-5
z
8. The figure shows a system consisting of (i) a ring of outer
radius 3R rolling clockwise without slipping on a horizontal
surface with angular speed and (ii) an inner disc of radius
2R rotating anti-clockwise with angular speed /2. The ring /2
and disc are separated by frictionless ball bearings. The 3R
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-6
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
10. A long horizontal rod has a bead which can slide along its length and initially placed at a distance
L( = 3 m) from one end A of the rod. The rod is set in angular motion about A with constant
angular acceleration (= 1 rad/sec2). If the coefficient of friction between the rod and the bead is
(=1) and gravity is neglected, then find the time (in sec) after which bead starts slipping.
11. A cylinder of height h, diameter h/2 and mass M and with a h/2
homogeneous mass distribution is placed on a horizontal
table. One end of a string running over a pulley is fastened h M
to the top of the cylinder, a body of mass m is hung from
the other end and the system is released. Friction is
negligible everywhere. At what minimum ratio m/M will the m
cylinder tilt?
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-7
PART II : CHEMISTRY
SECTION – 1 : (Only One Option Correct Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. The electrolytic oxidation of N2O4 was carried out in a solution buffered by NaHCO3 and Na2CO3.
The reaction involved was:
N2O4 2H2 O 2NO3 4H 2e
100 ml of 1M solution of N2O4 buffered initially at pOH = 3, was oxidized, with reaction above
going to completion. The total ionic concentration initially, i.e. [NaHCO 3 + Na2CO3] was 0.4 M.
The pH of the solution after oxidation will be: (For H2CO3. K a1 106 and K a2 10 11 ) :
(A) 5.7 (B) 6.0
(C) 6.3 (D) 11.0
2. The self ionization constant for pure formic acid K HCOOH2 HCOO has been estimated as
10-6 at room temperature. The density of formic acid is 1.15 g/cm3. What percentage of formic
acid molecules convert to formate anion:
(A) 0.001% (B) 0.002%
(C) 0.003% (D) 0.004%
3. A 1.025 gm sample containing a weak acid HX (mol. wt = 82) is dissolved in 60 ml H2O and
titrated with 0.25 M NaOH solution. When half of the acid is neutralized the pH was found to be
5.0 and the pH at equivalence point is 9.0. Calculate the percentage of HX in the original sample.
(Assume law of conservation of volume is obeyed)
(A) 40% (B) 80%
(C) 65% (D) 78%
Space for Rough work
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-8
4. The ionization constant of benzoic acid is 6.46 10 5 and Ksp for C6H5 COOAg is 2.5 10 13 .
How many times is silver benzoate more soluble in buffer of pH 3.19 as compared to pure water.
(A) 1.658 (B) 2.5
(C) 3.316 (D) 1.55
(A) 5 (B) 6
(C) 8 (D) 9
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-9
This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
7. Solubility product of the hydroxide M(OH)2 is 4 × 10-12 select the correct statement(s) among the
following
(A) the pH of its saturated solution will be 10.3
(B) its solubility will decrease in a buffer medium of pH = 11
(C) its solubility will increases in a buffer medium of pH = 1
(D) its solubility is unaffected by pH of the medium
8.
H3PO 4 H H2PO 4 ;
K a1
H2PO 4 H HPO 42 ;
K a2
HPO H PO ;
2
4
3
4 K a3
Mark out the correct statement:
pK a1 pK a2
(A) K a1 K a2 K a3
(B) pH H2PO4 2
(C) HPO 24 is less acidic than H2PO 4 (D) only HPO 24 is amphiprotic in the solution
9. Silver ions are added to a solution with Br Cl CO32 AsO 43 0.1 M . Which
compound will not precipitate at the lowest Ag ?
(A) AgBr K sp 5 10 13 (B) AgCl K sp 1.8 10 10
(C) Ag2CO3 K sp 8.1 10 12 (D) Ag3 AsO 4 K sp 1 10 22
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-10
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
Given: Ag NH3 2 Ag 2NH3 , K C 6.2 10 8 and K sp of AgCl 1.8 1010 at 298 K. If the
10.
concentration of the complex in 1.0 M aqueous ammonia is x then calculate 100x.
11. Determine the mole of AgI which may be dissolved in 1.0 litre of 1.0 M CN solution. Ksp of AgI
and KC for Ag CN2 are 1.2 10 17 M2 and 7.1 1019 M2 respectively.
12. A buffer solution of 0.080 M Na2HPO4 and 0.020 M Na3PO4 is prepared. The electrolytic oxidation
of 1.0 m mole RNHOH is carried out in 100 mL buffer to give.
RNHOH H2O RNO 2 4H 4e
Calculate approximate pH of the solution after oxidation is complete.
pK a1 , pK a2 and pK a3 of H3PO 4 are 2.12, 7.20 and 12.0 respectively.
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-11
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. Number of solutions of the equation where x (0, /2) cot() + cot( – /3) + cot( – /3) +
3cot(3) = 0
(A) Infinite (B) 0
(C) 1 (D) none of these
3. The number of solutions of the equations 2 sin2 x + sin2 2x = 2, sin 2x + cos 2x = tan x in [0, 4]
satisfying the condition 2 cos2 x + sin x 2 is
(A) 4 (B) 6
(C) 8 (D) 2
4. If x, y, z are angles of a triangle and tan x = 2 cot y and tan x + tan y + tan z = 6 then value of z is
(A) n ; n I (B) n tan1 2 ; n I
4
(C) n tan1 3 ; n I (D) n; n I
The number of solutions of the equation sin x cos x ln x 1 is
3
6.
2 2
(A) 4 (B) 6
(C) 8 (D) none of these
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-12
This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.
7. The roots of the equation sin3 = 4sin sin(x + ) sin(x ), 0 x where sin 0 and is
acute angle, is/are
(A) (B)
2
2
(C) (D)
3 3
7
9. If sin a has exactly 3 solutions in 0, then the value of ‘a’ is
3
10 2 5 5 1
(A) (B)
4 4
5 1 3 1
(C) (D)
4 2 2
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eSANKALP2325S1, T1 & P1-PCM-Paper-(000000)-13
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
10. If cos is a root of the equation 8x3 + 4x2 – 4x – 1 = 0. Then n = ______ (n N).
n 1
x 2x
11. Number of solution of the equation sin cos 2 _____
4 4
12. If 1 2 3 , then number of values of , satisfying
2 2 2 2
(tan – tan 1) (tan – tan 2) (tan – tan 3) – tan tan is __________.
i
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