WT18

(Batches: e-SANKALP-2325 S1, T1 & P1)
IIT – JEE, 2325 Paper Code

101006
(CLASS XI)
Time: 2 Hours Maximum Marks: 126
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.
B. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section–1 (01 – 06) contains (06) Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases
5 Section–2 (07 – 09) contains (03) Multiple Choice Questions which have one or more than one
correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
6. Section–3 (10 – 12) contains (03) Non-Negative Numerical Value Questions, the answer to each
question is a Non-Negative Numerical Value. For each question, enter the correct numerical value
corresponding to the answer and each question carries +4 marks for correct answer. There is no
negative marking.
Enrolment No. :
Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax
26513942
website: www.fiitjee.com.
e-Sankalp2325 S1, T1 & P1-XI-PCM-()-2
PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. A soap film of surface tension T is created on a

non-conducting ring of radius R having a R
Ring of h
positive charge q at its centre. The ring and radius R  
q q
charge at its centre are held at rest as shown.
That is another positive charge shown so that Soap film
the film finally takes approximately a conical
shape of height h and at that instant charge
becomes rest and also in equilibrium.
(Assuming h << R, and also assume gravity free
space and soap film to be non-conducting).
Then find the value of h3.
q2 q2
(A) (B)
40 T 80 T
q2 q2
(C) (D)
162 0 T 8 2  0 T
2. A thin and light thread of sufficient length L is

attached to a wire frame. The frame (along L
with the thread) is dipped into soap solution.
When the frame is taken out of the solution,
the thread takes the form of a semicircle with
a soap film extending between the frame and
the thread as show in the figure (a). Now the F
thread is deformed into two semicircles by fig. (a) fig. (b)
applying a force of F at the middle of the thread, as a result the film gets stretched as shown in
the figure (b). Calculate the surface tension of the soap solution.
F F
(A) (B)
2L L
2F 1 F
(C) (D)
L 4 L
Space for Rough work
26513942
3. A vessel, having a hole of diameter d in its bottom, is hanging from a lift moving upward with
acceleration a. The vessel contains mercury of surface tension T and height h, but it does not
pour out from the hole. The maximum acceleration a so that mercury will not pour out, is (density
of Hg is , assume d<<h).
2T 2T
(A) g (B)
dh dh
2T 4T
(C) g (D) g
dh dh
4. A tube of radius r and sufficient height is dipped in a liquid of surface tension S and density .
Heat developed upto steady state will be
S2 cos2  S2 cos2 
(A) (B)
g 2g
2S cos 
2 2
4S2 cos2 
(C) (D)
g g
5. A cylinder has a radius r. To what height h should it be filled with water so that the thrust on its
walls is equal to that on its bottom
(A) h = 2r (B) h = r
(C) h = (r/2) (D) h = (r/4)
6. An inverted vertical U tube whose two limbs have Area  106 m2 and 2 106 m2 submerged in
water so that water level in one of the limb is at same level as that in container and in another its
level is higher. Height in the another limb will be (given surface tension T  7  102 N / m , contact
angle = 00)
(A) 4.1 mm (B) 8.4 cm
(C) 6.2 mm (D) 5.4 cm
26513942
SECTION – 2 : (One or More Than One Options Correct Type)
This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
7. Ideal fluid flows along a tube of uniform cross section, located in a

horizontal plane and bent as shown in figure. The flow is steady, 1
and 2 are two points in the tube. If P1 and P2 are pressure at the
two points and v 1 and v2 are the respective velocities, then 2
(A) P1 < P2 (B) P1 > P2
1
(C) v1  v 2 (D) v1  v 2
8. A vertical U-tube of glass contains water of r1

density ‘’. Now it moves with a constant r2 a
horizontal acceleration ‘a’ Let h1 & h2 are the
heights of liquid column in left and right limbs
and r1 and r2 are the radius of curvature of h1 h2
meniscus are respectively as shown in the A
figure.
Assume ‘P0’ is the atmosphere pressure and ‘S’ is the surface tension of liquid. The pressure at
point ‘A’ is / are
2S 2S
(A) gh1 + P0 - (B) gh2 + P0 -  a
r1 r2
2S 2S
(C) gh1 + P0 + (D) gh2 + P0 +  a
r1 r2
9. A small ball of mass m and radii r is released from rest in a viscous liquid of coefficient of
viscosity  and density half that of the ball. Choose incorrect option(s).
(A) the velocity of ball will remain constant.
mln2
(B) after time t = the velocity of the ball will be ¼ of the terminal velocity.
6r
(C) the ball will never attain constant velocity

(D) the instantaneous velocity of ball at a time t is given by V = VT 1  e

6 r
m
t

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SECTION – 3: (Numerical Answer Type)
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
10. Four point charges, each of +q, are rigidly fixed at the four corners of a square planar soap film of
side ‘a’. The surface tension of the soap film is . The system of charges and planar film are in
1/N
 q2 
equilibrium, and a  k   , where ‘k’ is a constant. Then N is
  
11. A thin square plate of side  = 10cm is

dragged with constant velocity v = 3cm/s in
d/2
an oil. The width ‘d’ of the oil column is
2mm. Square plate is placed symmetrically
d v
as shown in the figure. Assumed velocity of
layer of oil at the end is negligible. The
d/2
coefficient of viscosity is 150 poise. Find
the horizontal force (in Newton) required to
move the square plate with constant
velocity.
12. A cylinder of diameter d, attached with a piston P has a small orifice

at its bottom (see figure). The cylinder is filled with a liquid of density P
 and the piston is pushed with a constant force F. Find the speed (in F d
m/s) with which water comes out the hole when the distance of the
piston from the hole is x (x > 0). Assume the gravity to be absent and
piston to be massless. x
Given: d = 1m, g = 10 m/s2,  = 100 kg/m3 and F = 200 N
26513942
PART II : CHEMISTRY
SECTION – 1: (Only One Options Correct Type)
and (D) out of which ONE is correct.
1. How many trichloro derivatives are possible for cyclo pentane excluding stereoisomers:
(A) 2 (B) 3
(C) 4 (D) 5
2. How many dibromo derivatives are possible for the following structures excluding stereoisomers
(A) 5 (B) 6
(C) 7 (D) 8
3. How many cyclic structures are possible for the formulae C4H6 excluding stereoisomers:
(A) 2 (B) 3
(C) 4 (D) 5
4. How many different enols are possible for
(A) 2 (B) 3
(C) 4 (D) 5
5. The increasing order of the acidity of the hydrogen marked in bold italics among the following is :
H H H H H H
I II III
(A) III < II < I (B) II < I < III
(C) I < II < III (D) II < III < I
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6. The order of basicity among the following compound is

NH NH 2
HN N
N NH NH 2 NH
H3 C NH 2
III
I II IV
(A) II > I > IV > III (B) IV > II > III > I
(C) IV > I > II > III (D) I > IV > III > II
SECTION – 2: (Multi Correct Choice Type)
out of which ONE OR MORE may be correct.
7. How many of the following statements are correct?
O O
(A) enol form is more stable than keto form for the compound
Ph Ph
(B) enol form is more stable than keto form for H C C CH3
3
O
O
(C) can form aromatic enol
(D) enol form of this compound is highly unstable
26513942
8. Which of the following statements are not correct?

O
O
(A) and are metamers
(B) CH3CH2COOH and HCOCH2CH2OH are functional isomers

(C) enol form is less stable than keto form of H C C CH C CH3
3 2
O O
(D) Molecular formula C4H6 will have 4 different non-cyclic structures excluding stereoisomers.
9. With respect to the compounds I – V, choose the correct statement(s).
(A) The acidity of compound I is due to delocalization in the conjugate base

(B) The conjugate base of compound IV is aromatic
(C) Compound II becomes more acidic, when it has a NO2 substituent
(D) The acidity of compounds follows the order I > IV > V > II > III
Space for rough work
26513942
10. How many of the following can tautomerize?

O
Ph C Ph Ph C CH3 CH 3CHO
O O
O NH O O O
O
H3C C CH 2 C CH3
O O
NH O O
11. How many of the following can form aromatic enol?
NH O
O
O
O O HN NH
(iii) O (iv)
(i) (ii)
O O O
NH
NH
N OH O
(v) (vi) (vii)
26513942
12. How many of the following compounds will liberate CO2 gas from NaHCO3 solution?
OH COOH SO3H OH
O 2N NO 2
CH 3 CH 2 OH
NO 2
COOH
HO O
HO O
NO 2
26513942
PART III : MATHEMATICS

SECTION – 1: (Only One Options Correct Type)
and (D) out of which ONE is correct.
1. The number of ways in which we can select three numbers from the set {10, 11, …, 100} such
that they form a G.P. with common ratio greater than 1, is
(A) 18 (B) 19
(C) 20 (D) none of these
2. Triplet (x, y, z) is chosen from the set {1, 2, 3, …., n}, such that x  y < z. The number of such
triplets is
(A) n3 (B) nC3
(C) nC2 (D) none of these
3. The sum of the factors of 7!, which are odd and are of the form 3t + 1 where t is a whole
number, is
(A) 10 (B) 8
(C) 9 (D) 15
4. The number of solutions in positive integers of 2x + 3y = 763 is

(A) 125 (B) 126
(C) 127 (D) 128
5. A seven digit number without repetition and divisible by 9 is to be formed by using 7 digits out of
1, 2, 3, 4, 5, 6, 7, 8, 9. The number of ways in which this can be done is;
(A) 9! (B) 2 (7!)
(C) 4 (7!) (D) none of these
6. The total number of 10 digit numbers that can be formed by using the numbers 0, 1, 2, 3, 4, 5, 6,
7, 8, 9, only once that are divisible by 11111.
(A) 3456 (B) 6543
(C) 3564 (D) 3546
26513942
SECTION – 2: (Multi Correct Choice Type)
out of which ONE OR MORE may be correct.
7. If D1, D2, D3, ..... D1000 are 1000 doors and P1, P2, P3, ..... P1000 are 1000 persons. Initially all doors
are closed. Changing the status of doors means closing the door if it is open or opening it if it is
closed. P1 changes the status of all doors. Then P2 changes the status of D2, D4, D6, ..... D1000
(doors having numbers which are multiples of 2). Then P3 changes the status of D3, D6, D9, .....
D999 (doors having number which are multiples of 3) and this process is continued till P 1000
changes the status of D1000, then the doors which are finally open is/are
(A) D961 (B) D269
(C) D413 (D) D729
8. Three alternate numbers a, b, c are removed from n numbers listed 1, 3, 5, 7, 9, ..... If the
105
arithmetic mean of the remaining numbers is , then which of the following option(s) is/are
2
correct?
(A) sum of the removed numbers is 81
(B) sum of the removed numbers is 61
(C) number of integral solutions of the equation xyz = n are 36
(D) number of positive integral solutions of the equation x + y + z = n :
(where x, y, z are odd) is 325
9. Given an alphabet with three letters a, b, c, then the number of words of n letter which contain
even number of a’s?
 n
1  1 
n  n
1  1 
n
(A) 2n   1     1    (B) 2n1   1     1   
 2  2   2  2 
1 n  1 n 
(C) 3 1 (D) 3 1
4 2
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10. Four letters, two ‘a’s and two ‘b’s, are filled into 16 cells of a matrix
as shown in figure. It is required that each cell contains at most one
letter, and each row or column cannot contain the same letters.
Then there are _____ different ways that the matrix can be filled
11. A person starts from the origin O(0, 0) in the x-y plane. He takes steps of one unit along the
positive x-axis or the positive y-axis. Travelling in this manner, the total number of ways he can
reach A(9, 6) avoiding both the points P(3, 3) and Q(6, 4)
12. Ten points are given in a plane such that no three points are collinear and no four of them form a
trapezium. From every point, all the possible lines are drawn which are parallel to lines formed by
taking any two points out of remaining points. Find the total number of points of intersection of
these lines. (excluding the given ten points)
26513942

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(Batches: e-SANKALP-2325 S1, T1 & P1)

IIT – JEE, 2325 Paper Code

B. Question Paper Format

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

1. A soap film of surface tension T is created on a

2. A thin and light thread of sufficient length L is

Space for Rough work

Space for Rough work

SECTION – 2 : (One or More Than One Options Correct Type)

7. Ideal fluid flows along a tube of uniform cross section, located in a

8. A vertical U-tube of glass contains water of r1

SECTION – 3: (Numerical Answer Type)

11. A thin square plate of side  = 10cm is

12. A cylinder of diameter d, attached with a piston P has a small orifice

Space for Rough work

4. How many different enols are possible for

Space for Rough work

6. The order of basicity among the following compound is

SECTION – 2: (Multi Correct Choice Type)

(C) can form aromatic enol

(D) enol form of this compound is highly unstable

Space for Rough work

8. Which of the following statements are not correct?

(B) CH3CH2COOH and HCOCH2CH2OH are functional isomers

9. With respect to the compounds I – V, choose the correct statement(s).

(A) The acidity of compound I is due to delocalization in the conjugate base

Space for rough work

SECTION – 3: (Numerical Answer Type)

10. How many of the following can tautomerize?

(v) (vi) (vii)

Space for Rough work

Space for rough work

PART III : MATHEMATICS

4. The number of solutions in positive integers of 2x + 3y = 763 is

Space for rough work

SECTION – 2: (Multi Correct Choice Type)

Space for rough work

SECTION – 3: (Numerical Answer Type)

Space for rough work

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