Aits Jee Mains Part Test 2 Question Paper

FIITJEE
ALL INDIA TEST SERIES

PART TEST – II
JEE (Main)-2018-19
TEST DATE: 11-11-2018
Time Allotted: 3 Hours Maximum Marks: 360
General Instructions:
 The test consists of total 90 questions.
 Each subject (PCM) has 30 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each part has only one section: Section-A.
Section-A (01 – 30, 31 – 60, 61 – 90) contains 90 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
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AITS-PT-II-PCM-JEE(Main)/19 2
Physics PART – I
SECTION – A
(One Options Correct Type)
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. An array of point charges and a set of closed Gaussian S2

surfaces S1, S2, and S3 are illustrated in the figure.
Choose the correct statement:
S3 2C
+4C
+3C
3C
S1
1C
(A) Flux passing through S1 is
0
2C
(B) Flux passing through S2 is
0
4C
(C) Flux passing through S3 is
0
2C
(D) Flux passing through S1 is
0
Ans. B
Sol. Gauss’ Law

q
flux = enclosed
0
2. Two electrons enter a region at same point between charged capacitor +Q –Q

plates with equal speed v. Electron A is moving horizontally to the left while
electron B’s velocity is directed at 30° below the horizontal. Each electron v A
reaches left plate. Which one of the following choice best compares the
speeds of electron upon arrival at the left plate? Ignore mutual interaction
30°
B
between electrons, gravity, any fringing effect of the fields and relativistic v
effects. Assume electric field between plates does not change due to
electrons. (vA : speed of electron A when it reaches left plate. v B : speed of
electron B when it reaches left plate.) d
(A) v A  vB
(B) v A  vB
3 AITS-PT-II-PCM-JEE(Main)/19
(C) v A  vB
(D) The answer depends on magnitude of the charge, Q on each plate.
Ans. B
Sol. Using conservation of mechanical energy for the particle field system as the particle cross the
region between the plates, we write KE + PE = 0 where PE = qV. Since the potential
difference between the plates will be the same for each charge, the change in PE of the charge
field system is the same in each case, meaning the change in KE is the same for each charge.
Hence, each charge reaches the other side with the same speed.
3. Five identical light bulbs are connected in a circuit as shown. V

All wires are ideal with no resistance, and the ideal battery has
emf V. When the switch S in the circuit is closed, aside from B2
B1
bulb B5, which of the other bulbs glow brighter than before.
B4 B5
B3
S
(A) Only Bulb B4
(B) Only Bulb B1 and B3
(C) Only Bulb B3 and B4
(D) Only Bulb B2, B3, and B4
Ans. B
Sol. The equivalent circuit before and after the switch is closed for the resistors is shown in the figure.
In words, by closing the switch the resistance of the entire circuit goes down since the resistance
of the bottom branch drops from 2R to (3/2)R. Since there is less resistance in the circuit, there is
more current, meaning that there is more current through bulb B3 from Kirchhoff’s loop rule with
the battery and bulb B1. Bulb B2 is dimmer. Finally, since the resistance of the bottom branch
decreased, it now gets a higher amount of current.
V V
B1 B1
B2
B2
B5
B3
B4 B3 B4
4. An infinite long cylindrical C

shell of radius 5 cm has a
charge of 30 nC/m per unit
axial length on its surface 100 cm
B
(uniformly distributed), as
shown in the figure. Choose 10 cm
the INCORRECT statement. A
3 cm
50 cm
(A) The electric field at point A at distance of 3 cm from axis of cylinder is 0 N/C
(B) The electric field at point B at distance of 10 cm from axis of cylinder is 5400 N/C
(C) The electric field at point C at distance of 100 cm from axis of cylinder is 540 N/C
(D) The electric field at point D at distance of 50 cm from axis of cylinder is 1800 N/C
Ans. D
 9  109  2  30  10 9 540
Sol. E   N/C
20r r r
5. Eight identical charged particles are located on a circle as shown in the figure-(1). Which vector
shown in figure-(2), best represents the direction of net force acting on the charged particle-4 due
to other charged particles.
y y
1
2 A
8
45 45
45 45
3
7 O x D O x
45 45
6 4 B
5 C
Figure 1 Figure 2
(A) A
(B) B
(C) C
(D) D
Ans. B
Sol. Since all of the charges around the circle are equal, the forces between them are repulsive.
Particle 3 and 5 are at same distance away from particle-4

and repel the particle-4 with the same
force in magnitude and resulting force will be along OB . Likewise for particles 2 and 6 and

particle 1 and 7. The force of particle-8 on particle-4 will be along OB . Hence net force on

particle-4 will be along OB .
6. In the circuit shown, the switch S has been left open 3 k 1 k

for a very long time. All circuit elements are
considered to be ideal. Which one of the following
statements best describes the behaviour of the
current through the switch S once it is closed? S
9V
(A) The current initially is 12 mA and decreases to a steady 3 mA
(B) The current initially is 3 mA and increases to a steady 12 mA
(C) The current initially is 9 mA and decreases to a steady 3 mA
(D) The current initially is 6 mA and decreases to a steady 3 mA
Ans. A
Sol. Using Kirchoff loop Rule around the outside of the circuit reveals that the potential difference
across the capacitor is 9V since there is no current after a long time. Once the switch is closed,
there is a loop that encloses the battery and 3 k resistor resulting in a total of 9 = 3000 I  I = 3
mA through the resistor. For the other branch on the right, there is a capacitor initially charged
and a 1 k resistor.
7. An LCR series circuit is connected to a sinusoidal AC voltage of variable angular frequency and
the graph between peak current and angular frequency is plotted as shown in the figure. If
capacitance of capacitor used is 6 F, then choose the correct alternative.
6F
L R
i0
i0 / 2
~
80 100 120 (rad/s)
(A) L = 16.67 H, R = 1.3 k
(B) L = 3.34 H, R = 12 k
(C) L = 16.67 H, R = 0.67 k
(D) can’t be calculated
Ans. C
 100 5
Sol. Q  
2 40 2
L 5 1
Q 0  0 C 
R 2 R
2 1 2
R  6
 R  10 4
5 100  6  10 30
2
  103  0.67 k
3
1 1 106
0  L   16.67H
LC 2C 10 4  6
8. All rods have identical length and cross-sectional area. Find 100°C k C
the temperature at junction A. The thermal conductivity of D 75°C
E
k
rod-AF, rod-GH rod-BL & rod-AD are and the thermal
2 k
conductivity of rod-EF, rod-CD, rod-AB & rod-AG are k. k/2
F B
k/2 A k
k k/2
k/2
H L
25°C G 50°C
125C
(A)
4
125C
(B)
2
(C) Zero
(D) 125°C
Ans. B
x  100 x  75 x  25 x  50
Sol.    0
3R 3R 3R 3R
4x  250  0
250C
x
4
9. An L–R circuit is made so that the AC - input (angular L

frequency : ) is applied across the combination of L and R.
The output is taken across R. The circuit works as a filter
circuit. If the time constant of the DC (L – R) circuit is , then Vin R Vout
Vout
the ratio: equals
Vin
(where Vout and Vin are peak values of output and input
voltage respectively.)
1
(A)
2
1   
(B) 
2
(C) 1   
1
(D)

Ans. A
Sol. The phasor diagram of the circuit, in operation, is

shown in the adjacent figure
Z  R2  x12 , Vin = iZ iXL
where XL  L
Vout
The ratio 
Vin
R 1
  iR = Vout
2 2 2
R X L  L 
1  
 R 
10. A solenoid of cross sectional area , N turns and length

 carries a constant current I. An iron rod of constant
permeability  and cross sectional area  is partially x  x
inserted in the solenoid along its axis. Calculate the force
acting on the iron rod. (Neglect the end effects and
assume that when the iron rod is moved slightly through a
distance x from its position, the field structure remains
the same.)
   0  N2I2 
(A)
2
   0  N2I2 
(B)
2 2
   0  N2I2 
(C)
4 2
2     0  N2I2 
(D)
2
Ans. B
Sol. The only difference is that a length x of the rod is effectively transferred from the extreme right
hand end of the rod (outside the field region) to the uniform field region within the solenoid. The
difference in the magnetic energy of the two configurations is
1
U  U  x  x   U  x      0   H2 dV, (i)
2 v
Where V  x and H = NI/  = the magnetic field intensity inside the solenoid. Since H is
constant, we obtain from (i)
1 N2I2
U     0  2 x.
2 
U 1 N2I2 
The force on the rod is Fx      0  2
x I 2 
11. A conducting rod of length  rotates about its one end with 
angular velocity . Find the potential difference between A
and B (e : charge on electron, m : mass of electron). O
A B
1 2
(A)

m 2  2  21 
e
(B)

m 2  2  22 
e
(C)

m 2  2  21 
2e
(D)

m 2  2  22 
2e
Ans. C
WAB 
Sol. VAB  dx
q
2
dV = m xdx/e
mw 2 xdx
dV  x
e
 
m 2
 dV  e  xdx
0 1
m2 2
V
2e

   21 
 VAB 

m 2  2  21 
2e
12. In the circuit shown, find the value of C and L if net current 5 mF 20 

from the source is to lead net voltage by a time
40 C L
seconds.
20  2H
10V, 5/ Hz
(A) 2.5 mF, 2H
(B) 5 mF, 2H
(C) 5 mF, 1 H
(D) 2.5 mF, 1 H
Ans. A
Sol. Phasor diagram : I1

  
To lead by s  ,
40  4  I2
I3
V I3
I3 
R2  XL2
V
I2 
(XC  XL )2 /4
V V
I1 
/4
R  X2C
2
I2  I12  I32
I1
13. A metallic charged ball, having charge q0 is immersed into the liquid of dielectric constant K and
low resistivity . Find the time constant of disappearance of charge on the ball
1
(A) 0 K
2
(B) 0  K
(C) 2 0  K
3
(D) 0 K
2
Ans. B
Sol. As we know that

E q
J 
 40 Kr 2
q q
I  s  J  4r 2  
40 Kr 2  0 K
q0
 I0 
 0 K
q0
   0 K
I0
14. An external force is applied to move a square loop of dimension 

5 cm × 5 cm and resistance 10 at a constant speed across a × × × ×× × × ×

region of uniform magnetic field B = 0.20 Tesla. The side of the × × × ×B× × × × v
square loop makes an angle  = 45° with the boundary of the ××××××××
field region, as shown in figure. At t = 0, the loop is completely ×××××××× l
inside the field region, with its right vertex at the boundary. ××××××××
Total charge flown through loop when loop is completely
outside the magnetic region.
(A) 0.05 milli coulomb
(B) 0.10 milli coulomb
(C) 0.4 milli coulomb
(D) 1 milli coulomb
Ans. A
 Ba2
Sol. Q  
R R
15. Two bar magnets having same geometry with magnetic moments 1.5 M and 2.5 M are placed in
such a way that their similar poles are on the same side, and its time period of oscillations is T1.
Now if the polarity of one of the magnets is reversed, keeping other quantities same, then the
time period of oscillation is T2. Choose the correct option.
T1 1
(A) 
T2 2
T1 2
(B) 
T2 1
T1 1
(C) 
T2 4
T1 4
(D) 
T2 1
Ans. A
1 T1 M2 2.5M  1.5M 1
Sol. T    
M T2 M1 2.5M  1.5M 2
16. A uniform charged (thin) non-conducting rod is located on the central axis a z
distance b from the center of an uniformly charged non-conducting disk. The
length of the rod is L and has a linear charge density . The disk has radius z=b+L
a and a surface charge density . The electrostatic force on the rod due to
disc is
z=b
  
 a2  kˆ
2 2 2
(A) F L  a  b  b  L 
20  
 a2L
(B) F kˆ
4  0b 2
 a2L
(C) F kˆ
80b2
   L 
(D) F 1   kˆ
20  L  a2
2

Ans. A
Sol. The electric field created at any point along the central axis is given by
   z 
E z   1   kˆ
20  2
a z 2
Breaking up the rod into an infinite number of infinitesimally small point charges dq, we have that
 
the net force on each tiny charge is dF  dqE  z  . Summing up all these contributions, and using
the fact that dq =  dz gives
   z  
b L
 z 
F   dq  1   kˆ  k̂  dz  1 
 
20  2 2
a z  20 b  a  z2
2

  2 2 
 L  a   b  L   a  b  kˆ
2 2

20  
17. A cycle followed by an engine (using one mole of an P

ideal gas in a cylinder with a piston) is shown in B C
PB=PC
figure. Heat exchanged by the engine, with the
surroundings for each section of the cycle is (Cv =
(3/2) R).
AB : constant volume
BC : constant pressure PA=PD D
CD : adiabatic A
DA : constant pressure
VA=VB VC VD V
5
(A) Q AB  VA  PB  PA  , QBC   3 / 2  PB  VC  VA  , QCD  0 , QDA   5 / 2  PA  VA  VD 
2
3
(B) Q AB  VA  PB  PA  , QBC   5 / 2  PB  VC  VA  , QCD  0 , QDA   5 / 2  PA  VA  VD 
2
3
(C) Q AB  VA  PB  PA  , QBC   5 / 2  PB  VC  VA  , QCD  0 , QDA   3 / 2  PA  VA  VD 
2
5
(D) Q AB  VA  PB  PA  , QBC   5 / 2  PB  VC  VA  , QCD  0 , QDA   5 / 2  PA  VA  VD 
2
Ans. B
3 3
Sol. Q AB  UAB  R  TB  TA   VA PB  PA 
2 2
QBC  UBC  WBC
  3 / 2  PB  VC  VB   PB  VC  VB 
  5 / 2  PB  VC  VA 
QCA  0
QDA   5 / 2  PA  VA  VD 
18. The figure shows the variation of average Pav

power versus angular frequency of source
voltage of two series. LCR-Circuits
connected to same voltage source (the
circuit-1 has resistance R1, capacitance C1,
inductance L1 and quality factor Q1 while
circuit-2 has resistance R2, capacitance C2,
inductance L2 and quality factor Q2 2 Circuit-2
respectively. 1  Circuit-1
Choose the correct option: O
(A) Q1  Q2 and R1  R2 , L1L2  C1C2
(B) Q1  Q2 and R1  R2 , L1C2  L2 C1
(C) Q1  Q2 and R1  R2 , L1C1  L 2 C2
(D) Q1  Q2 and R1  R2 , L1 / L 2  C1 / C2
Ans. C

Sol. Quality Factor = Q 
2
0L
Q Q1  Q2
R
V
Pav max  0  R1  R2
R
10  20  L1C1  L 2 C2
19. The figure shows a non-conducting (thin) disk with a hole. The radius of a
the disk is b and the radius of the hole is a. A total charge Q is uniformly
b
distributed on its surface. Assuming that the electric potential at infinity is
zero, what is the electric potential at the center of the disk?
Q
(A)
20  b  a 
Q
(B)
20  b  a 
Q
(C)

20 b2  a2 
(D) 0
Ans. A
Sol. The potential produced by a charged disk of radius R, at a distance z from it, along its central axis
was

20
z2  R2  z  …(1)
By superposition, we can think of the potential created by disk with the hole as the sum of two
disks, with the same but opposite surface densities:
  
V z 
20

z 2  b2  z 
20
 
z 2  a2  z 
20

z 2  b2  z 2  a2  
Since we are only interested at the center, we have

V 0  b  a 
20
The total area of the disk with the hole is A   b2  a2 , thus  
Q


 b2  a2 
Finally
1 Q 2kQ  b  a  2kQ
V 0  b  a  2 2  
20 
 b a  b  a  b  a  ba
20. Choose the INCORRECT Statement
(A) The paramagnetic material displays greater magnetization when cooled, for the same
magnetizing field.
(B) The diamagnetic property of material is almost independent temperature.
(C) If a toroid uses bismuth for its core, the magnetic field in the core will be slightly greater
than when core is empty.
(D) The permeability of a ferromagnetic material depends on the magnetic field.
Ans. C
Sol. (A) On cooling, the tendency of thermal agitations to disrupt the alignment of magnetic dipoles
decreases in case of paramagnetic materials. These they display greater amount of
magnetism.
(B) on placing a sample of diamagnetic material in magnetic field, the magnetization (Induced
dipole moment) is opposite direction of magnetizing field. Thus it does not affected by
temperature.
(C) The field in core will be slightly less than when core is empty as Bismuth is a diamagnetic
material (B = 0r nI).
B H
(D)   , so permeability of ferromagnetic
H
a
material is dependent on the applied magnetic b
field. As shown in graph for B & H, B is larger
for smaller value of H, thus permeability is
greater for lower fields.
B
c O f
d e
21. If 100 gm water at 20C is mixed with 100 gm ice at 20C. Let in final state system consists of
m1 gm ice and m2 gm water. Choose the correct option.
Specific heat capacity of ice is 0.5 cal/g/°C.
Specific heat capacity of water is 1 cal/g/°C.
Latent heat of fusion of water is a 80 cal/g.
Latent heat of vaporisation of water is a 540 cal/g.
(A) m1 = 200 gm, m2 = 0 gm,  = –5C
(B) m1 = 87.5 gm, m 2 = 112.5 gm,  = 0C
(C) m1 = 112.5 gm, m 2 = 87.5 gm,  = 0C
(D) m1 = 200 gm, m2 = 0 gm,  = –3C
Ans. B
Sol. All ice will not melt. It means in final state, Water Ice
the system will contain both ice and water 100 gm 200
20C 20C
at 0C. Let x gm of ice melts due excess
heat.  1 = 100  20  1/2
= 1000 cal
1000 Q1 = 100  1  20 Ice at
x  12.5gm = 2000 cal 0C
80  2 = 100  80
Water in final state = 112.5 gm = 8000 cal
Water Water
ice in final state = 87.5 gm at 0C at 0C
Second method : Let whole system is at 0C in the state of water so.
Heat constant = Q1  H1  H2 = 7000 cal
It means the heat available will force the water to freeze to compensate the 7000 cal (negative
heat). Let x gm of water to fulfil the condition so
7000
x = 87.5 gm
80
Water = 112.5 gm
22. A conducting rod of mass = 1 kg, length = 1m

 Non-conducting
suspended in uniform magnetic field B   2T  kˆ .
30° string
The rod is attached with two different string as 30°
shown in the figure. Tension in each string is 20 
N. Find the value of current in the wire. (g = 10 B  B0 kˆ  2kˆ
m/s2).
(A) 10 Amp
(B) 5 Amp
(C) 2.5 Amp
(D) 0.5 Amp
Ans. B
Sol. 2T sin30  B0i  mg T T

Non-conducting
 T  B0i  mg
30° string 30° 30°
 20  B0 i  10 30°
 B0 i  10 
B  B0kˆ  2kˆ
10 10
 i 
B0   B0 B0 i  mg
= 5A.
23. An ideal mutual inductor is made from a primary coil of inductance 5mH and a secondary coil of
inductance 10 mH. Find the value of the Mutual inductance ( Approximately).
Assume no flux leakage.
(A) 28 mH
(B) 21 mH
(C) 14 mH
(D) 7 mH
Ans. D
Sol. M Lp L s  5  103  10  103  50  103 H = 7 mH
24. A non-conducting sphere has mass m = 88 g and radius r = 20.0 cm. A flat compact coil of wire
with 5 turns is wrapped tightly around it, with each turn concentric with the sphere, as shown.
The sphere is placed on a rough inclined
plane that slopes downward to the left,
making an angle θ with the horizontal, so B
that the coil is parallel to the inclined plane.
A uniform magnetic field of 0.350 T
vertically upward exists in the region of the
sphere.
22
Take   ; g  10m / s 2 .
7

(A) The current in the coil, that will enable the sphere to rest in equilibrium on the inclined
plane is 2.5 A.
(B) The current in the coil, that will enable the sphere to rest in equilibrium on the inclined
plane is 1.25 A.
(C) The current in the coil, that will enable the sphere to rest in equilibrium on the inclined
plane is 0.8 A.
(D) The current in the coil, that will enable the sphere to rest in equilibrium on the inclined
plane is 0.6 A.
Ans. C
Sol. The diagram shows a free-body diagram for the sphere on the incline.
We will use the following notation: f is the force of  B
static friction; B is the external magnetic filed given
as B = 0.350 T; I is the unknown current in the 
coil; µ is the magnetic moment of the current in the

I
coil; m= 0.088 kg is the mass of the sphere; g = 10 fs
m/s2 is the free fall acceleration; r = 0.200 m is the
radius of the sphere; and N = 5 is the number of
turns in the coil. We will use everywhere three
significant digits as given in the problem
statement. mg

The sphere is in translational equilibrium, thus

f s  mg sin   0 ……………….. (1)
The sphere is in rotational equilibrium. If torques are taken about the center of the sphere, the
magnetic field produces a clockwise torque of magnitude
µB sinθ, and the frictional force a counter-clockwise torque of magnitude f s R. Thus:
fs R – µBsinθ = 0 …………………. (2)
From (1): fs= Mg sinθ. Substituting this in (2) and cancelling out sinθ , one obtains
µB = MgR  I 
mgr

mg


88 10 3  10 
 0.8 A
N  r 2 B N  rB 5   22 / 7   0.2  .35
The current must be counter-clockwise as seen from above.
The result does not depend upon the angle of inclination θ.
25. Two circular loops A and B have their planes parallel to each other, as A
shown in figure. Loop A has a current flowing in the counterclockwise
direction, viewed from above.
I
B A
(A) If the current in loop A decreases with time, the two loops attract each other.
(B) If the current in loop A increases with time, the two loops attract each other
(C) If current in loop A decreases current in B is clockwise.
(D) If current in loop A increases, current in B will be anticlockwise.
Ans. A
Sol. Apply Lenz’s law
26. If magnetic dip in India is found to be 18°. One of the option, that is closer to the magnetic dip in
Britain, is
(A) 18°
(B) 70°
(C) –18°
(D) 16°
Ans. B
Sol. Britain is closer to magnetic north.
27. In the system of three charged particles, each charge particle is in equilibrium under their
electrostatic forces only. Choose the INCORRECT option
(A) The particle must be collinear.
(B) All the charges cannot have the same magnitude.
(C) All the charges cannot have the same sign.
(D) The equilibrium is stable.
Ans. D
Sol. Basic concept
28. In a moving coil galvanometer the number of turns N = 30, area of the coil A = 4  103 m2 and
the magnetic field strength B = 0.3T. (The resistance per unit length of the wire of coil is ).
Choose the INCORRECT option
(A) To increase its voltage sensitivity by 50% we increase number of turns to 60
(B) To increase its voltage sensitivity by 50% we increase area to 9  103 m2
(C) To increase its voltage sensitivity by 50% we increase magnetic field to 0.45 T
(D) To increase its voltage sensitivity by 50% we change the material of wire such that its
specific resistance would be 2/3rd of the specific resistance of the present wire.
Ans. A
Sol. BINA = C
C
I
BNA
CR
V  IR  …(1)
BNA

R    C1 A N where C1 is a constant.
a
C1C d B A
V  SV   .
B A dV  CC1
29. A non conducting solid cylinder of infinite length having uniform charge
density  and radius of cylinder is 5R. Find the flux passing through the
surface ABCD as shown in figure.
‘’
B
8R
A R
C
D
12R3
(A)
0
6R3
(B)
0
R 3
(C)
0
3R3
(D)
0
Ans. A
1 
  8R  3R  R 3
q 2   12R
Sol.   in   5R
0 0 0
3R
8R
30. A conducting rod of length 25 cm is free to slide on two parallel × × × ×× × × × ××

conducting bars as shown in the figure. In addition, two R1 × ×B× ×v× × × × ×× R2
resistors 5 and 10 are connected across the ends of the ×××××××× ××
bars. There is a uniform magnetic field 0.02 tesla pointing ×××××××× ××
inside the plane of paper. Suppose an external agent pulls the Sliding rod
–1
bar towards the left at a constant speed 5 ms .
(A) Current through 5 resistor is 5 mA
(B) Current through 10  resistor is 10 mA
(C) Force applied by agent to maintain constant 5 ms–1 velocity is 20 N
(D) Power delivered by external agent is 50 watt.
Ans. A
Sol. Bv  iR
1
0.02   5  i  5
4
Chemistry PART – II
SECTION – A
Straight Objective Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
31. Hydrolysis of mustard gas give HCl and a diol. Which of the following intermediate will form
during the hydrolysis
(A)
Cl S
(B)
HO
S
(C) Cl +
S
(D)
HO S Cl
Ans. C
Sol.
Cl Cl Fast
Cl +
S 
-Cl
 S
Mustard gas H2O
H
+ Cl OH
S OH S
H2O
H HO OH
S
32.
OH H2SO4
 A 
Major product formed in the above reaction (A) is:
(A)
(B)
(C)
(D)
Ans. C
Sol.
OH H2SO4

 H2 O
1 Ring closure


2 H

 
33. Number of monochloro structural isomers form when A undergoes monchlorination
Cl /h
2
Monochlorination
 Products
(A) 1
(B) 2
(C) 3
(D) 7
Ans. C
34. Which of the following is correct?
(A) An achiral molecule which is superimposable on its mirror image cannot exist as two
enantiomers.
(B) Changing the configuration of a molecule always means that bonds are broken.
(C) Both (A) and (B)
(D) None of these
Ans. C
35. Which of the following correct for E2 elimination in chloro cyclohexanes:

H
Cl
H
(A) (B)
Cl
(A) Rate of E2 elimination in (A) is faster than (B).
(B) Rate of E2 elimination in (B) is faster than (A).
(C) (B) can undergo E2 elimination only if (B) undergoes ring inversion.
(D) Both (A) and (B) are correct.
Ans. B
36. Which of the following molecule showing the correct direction of dipole moment:
(A)
N
H
(B) CN
CN
(C) CN
Cl
(D)
N
H
Ans. A
37. Predict the major product formed when the following reaction occurs in dilute base:
O O OH/

(A)
O
(B) O
(C)
(D)
Ans. B
Sol. O
O O O
OH

 

O

  OH
38. Propanol is more volatile as compared to glycerol because of
(A) Less extent of hydrogen bonding
(B) High molar mass of propanol
(C) Hybridization
(D) All of the above
Ans. A
39. The IUPAC name of the following compound is:

O
(A) Cyclopentanedioic anhydride
(B) Pentanedicarboxylic anhydride
(C) Pentanedioic anhydride
(D) Dicyclopentane anhydride
Ans. C
40. Predict the product of the following reaction:

RCOOAg  I2   A   CO 2  AgI
1:1
(A) Alkyl iodide
(B) Carboxylic acid
(C) Ester
(D) Alcohol
Ans. A
41. Which of the following compound will form when acetic anhydride reacts with o-Fluoroanisole in
presence of dry AlCl3.
(A) O
C CH3
F
OCH3
(B) O
C
CH3
F
OCH3
(C) O
C
CH3
(D) O
C
CH3
Ans. A
42. Which of the following species is most stable?
(A)
O
N
(B) O
O
N
(C) O O
(D)
O O
N
Ans. D
43. The hybridization of C-1 and C-2 carbon atoms marked in the following structure of benzyne
intermediate?
1
(A) sp2 and sp2
(B) sp and sp
2
(C) sp and sp
(D) None of these
Ans. A
44. Predict the major product formed in the following reaction:

Ni
 H2 
200o C

(A)
(B)
(C) C2H6
(D) No reaction
Ans. B
 i I /Red P
45. Alcohol 2
ii AgNO
 A 
2
Compound A does not react with HNO2 and gives a colourless solution with NaOH.
Degree of the alcohol taken initially
(A) 1
(B) 2
(C) 3
(D) None of these
Ans. C
46. Predict the product of the following reaction:

HO OH

 
O
(A) Lactone
(B) Anhydride
(C) Alcohol
(D) Alkene
Ans. A
47. The correct order of basic strength of the following compound is:
O
1  2 3  4
N N N N
H H H
(A) 1>2>3>4
(B) 1>3>2>4
(C) 4>3>2>1
(D) 1>2>4>3
Ans. D
48. Predict the product of the following reaction?

i Ph3P
CH3I ii BuLi

 iii  O
(A) CH3CHO
(B) OH
(C)
(D)
Ans. C
49. Which mechanism the following reaction will follows:

SOCl
C2H5OH 
Pyridine  C 2H5 Cl  SO2
2
(A) SN1
(B) SN2
(C) SNi
(D) None of the above
Ans. B
50. In the following reaction

Ag O PCl3 H /H O
CH2  CH2 
2
 A  
2
  B    C
The compound (C) is:
(A) CH3 – CH3
(B) CH3 – CH2 – Cl
(C) CH2  CH2

| |
Cl Cl
(D) CH3 – Cl
Ans. C
51. Which of the following product will form in the following reaction:
H 

OH 
 HO
O
(A)
OH
(B)
O O
(C) CHO
CHO
(D)
O O
Ans. B
52. The possible product of the following reaction:

i CH3MgBr
H3C  CH2  COOH  ii H3O

(A) CH3 – CH3
(B) CH3CH2OH
O
||
(C) CH3  CH2  C CH3
(D) CH4
Ans. D
 2
NH Cl i H O, HCl,
53. CH3CHO    A  
KCN 
4
  B 
 ii OH
Compound B formed in the above reaction is:
(A) Glycine
(B) Alanine
(C) Threonine
(D) Serine
Ans. B
54. The only two pKa values of an amino acid are 2.32 and 9.62. The isoelectric point of the amino
acid is:
(A) 7.3
(B) 11.94
(C) 5.97
(D) 9.62
Ans. C
55. Which of the following products will form when cellulose undergoes complete hydrolysis:
(A) D-fructose
(B) D-ribose
(C) L-glucose
(D) D-glucose
Ans. D
56. Neoprene is prepared by polymerization of:
(A) 2-Chloro-1,3-butadiene
(B) Butadiene
(C) Acrylonitrile
(D) Styrene
Ans. A
57. An organic compound ‘X’ gives CO2 gas on reaction with NaHCO3. The compound ‘X’ is:
(A) Picric acid
COOH
(B)
OH
SO 3 H
(C)
(D) All of these
Ans. D
58. The degree of unsaturation in the following compound is:
(A) 8
(B) 10
(C) 2
(D) 6
Ans. B
59. Predict the compound ‘X’ in the following reaction:

O
C
NH2

Br2  NaOH   X  Na 2CO3  2NaBr  2H2O
(A)
(B) NH2
(C) H
N
(D) CH3NH2
Ans. B
60. Compound ‘A’ on reductive ozonolysis will give:

i O
3

ii Zn/H O

2
(A) OH
HO
(B) O
O
(C) O
O
(D) O
Ans. B
Mathematics PART – III
SECTION – A
Straight Objective Type
This section contains 30 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D),
out of which only ONE is correct
61. Normals having slope m1, m2, m3; (m1 < 0) are drawn at points P(a, b), Q, R respectively on the
curve y2 – 6y – 16x + 73 = 0 so as to intersect at point S(19, 6), then a + b is equal to
(A) 24
(B) 28
(C) 32
(D) 36
Ans. B
3
Sol. Roots of the equation 4m3 – 7m + 3 = 0 are m 1, m2, m3 solving m1  
2
 9  3
 a  4 1   , b  3  8   
 4  2
a = 13, b = 15
62. The locus of the centroid of triangle PSQ, where PQ is any chord of the parabola y2 = 8(x + 2)
subtending right angle at the vertex and S be its focus is also a parabola whose latus rectum is
equal to
1
(A)
3
4
(B)
3
8
(C)
3
(D) 2
Ans. C
Sol. t1t2 = –4 P(t1)

If (h, k) is the centroid of PSQ,
3h  4 3k
Then  t12  t 22 ,  t1  t 2
2 4 S
8
 k 2  h  4 
3
8 Q(t2)
 Latus rectum =
3
63. A hyperbola having foci A(4, –1) and B(4, 5) has x + y – 7 = 0 as one of its tangent, then the point
of contact of this tangent is
9 5
(A)  , 
 2 2
(B) (1, 6)
(C) (0, 7)
(D) (2, 5)
Ans. C
Sol. Image of A(4, –1) about the tangent x + y – 7 = 0 is P(8, 3)

 Equation of line passing through P(8, 3) and B(4, 5) is 2y + x – 14 = 0
Solving this with tangent, we get point of contact
64. The equation of circle touching the parabola y = 1 – x2 at the point (2, –3) and having its centre on
the line y + x = 0 is
(A) (x – 3)2 + (y + 3)2 = 1
2 2
 14   14  17
(B) x    y   
 5   5  25
2 2
 14   14  17
(C) x   y   
 25   25  25
(D) (x – 4)2 + (y + 4)2 = 5
Ans. B
Sol. Normal to the parabola y = 1 – x2 at (2, –3) is 4y – x + 14 = 0

Let centre of circle is (, –) which lies on the normal
14
 
5
17
 Radius is
5
x2 y2 x2 y 2 1
65. If the ellipse  2  1 , b > 0 and the hyperbola   intersect orthogonally, then the
16 b 81 63 16
2
value of b is
(A) 5
(B) 7
(C) 9
81
(D)
7
Ans. B
Sol. Foci of the two curves are coincident
x2 y2
66. If the line joining the foci of the hyperbola S1    1  0 does not subtend a right angle at
a2 b2
x2 y2 2
any point on the hyperbola S 2  2
 2
 1 , then number of integral values of 4e is/are (e is
4a b
eccentricity of S2 = 0)
(A) 1
(B) 2
(C) 3
(D) 4
Ans. B
Sol. Circle having foci of the hyperbola S1 as the extremities of diameter should not intersect the
hyperbola S2 at real points
 a2 + b2 < 4a2
2 2
 b < 3a
2
 e < 7/4
2
 4 < 4e < 7
67. One of the sides of a triangle is divided into segments of 4 and 6 units by the point of tangency of
the inscribed circle which has radius 2 2 units, then the largest side of triangle is
(A) 10
21
(B)
2
43
(C)
4
(D) 11
Ans. D
A 1 C 2 A
Sol. tan  , tan  4
2 2 2 3 4
 A  C 5
 tan  6
2 2 2 x
B x 5
 cot  
2 2 2 2 2 B C
x 6
x=5
Alternate: Use  = rs
68. Let Sn = 13 + 23 + 33 + ..... + n3; n  N, then 64Sn is always less than
(A) (2n – 1)4
(B) (n + 2)4
(C) (2n + 1)4
(D) 2(n + 1)4
Ans. C
2
2  1
Sol. 64 n3  16  n  n  1   16  n2  n  
 4
x2 y2
69. A line is drawn from A(–4, 0) to intersect the curve   1 at P and Q above x-axis. If
8 4
1 1 3
  , then the maximum value of the slope of line is
AP AQ 2
(A) 2 3
1
(B)
3
4
(C)
5
(D) 3
Ans. B
Sol. AP and AQ are the roots of the equation (r cos  – 4)2 + 2(r sin )2 = 8
 r2(cos2  + 2 sin2 ) – 8 cos  r + 8 = 0
1 1 8cos  3
   
AP AQ 8 2
3 1
 cos    tan  
2 3
 1 
70. If two distinct chords drawn from the point  2 2 sin ,  to the circle
 2
1
x2 + y2 = 2 2 sin  x + y , ( is a parameter) are bisected by x-axis, then the exhaustive set in
2
which  lies is
  3 
(A)  n  , n  ; n  I
 4 4 
  5 
(B)  n  , n  ; n  I
 6 6 
  3 
(C)  2n  , 2n  ; n  I
 4 4 
(D) (2n, (2n + 1)); n  I
Ans. A
1 1
1 2 2 sin ,
2 2 1 2 sin , 2
Sol.   1 2 2
2 sin   h 
2 2 2 sin   h 
1 (h, 0)
 h2  3 2 sin   h  4 sin2   0
4
For distinct real roots
1   3 
D > 0  sin2  >     n  , n  ; n  I
2  4 4 
71. Let A be (100, 50), a point B on the line y = x and point C on x-axis such that AB + BC + CA is
minimum, then the coordinates of C is
(A) (50, 0)
 200 
(B)  , 0
 3 
 250 
(C)  , 0
 3 
 400 
(D)  , 0
 3 
Ans. C
Sol. Image of A(100, 50) about x-axis is P(100, –50) and about y = x is Q(50, 100)
Equation of line PQ is y + 3x – 250 = 0
250
Putting y = 0, x 
3
x y
72. A line L1    1 intersects the coordinate axes at points A and B. Another line L2
10 8
perpendicular to L1 intersects the coordinate axes at C and D. The locus of circumcentre of ABD
is
(A) 5x – 4y = 9
(B) 5x – 4y = 18
(C) 4x – 5y = 9
(D) 4x – 5y = 18
Ans. A
Sol. Circumcentre will lie on the perpendicular bisector of AB
   
73. The value of cot 4  4cot 3  6cot 2  4 cot  2 is
16 16 16 16
(A) 0
(B) –1
(C) 2
(D) 1
Ans. D
Sol. cot 4A 
1  tan2 2A
 1

1  tan2 A  4 tan2 A 
; A

2 tan 2A 2
4 tan A 1  tan A  16 
   
 tan4  4 tan3  6 tan2  4 tan  1  0
16 16 16 16
74. The equation of two sides of a triangle are 3x + 4y – 12 = 0, 2x + y – 8 = 0. If the circumcentre is

(0, 3), then the centroid of the triangle is
 7
(A)  0, 
 3
 14 
(B)  0, 
 3 
 16 
(C)  0, 
 3 
(D) (0, 6)
Ans. B
Sol. Foot of perpendicular from (0, 3) on the line P(0, 8)

2x + y – 8 = 0 is (2, 4)
Hence, P is (0, 8) which is orthocentre
 14  2x + y – 8 = 0
 Centroid is  0, 
 3 
(0, 3)
Q(–4, 6) R(4, 0)
3x + 4y – 12 = 0
 cot A  
75.  
The value of sec 1  cosec A   tan1 cot 3 A  cot 1  2 ,0<A<
 cot A  1  6
is
(A) 0
(B) 3 tan–1 1
1
(C) 3 tan1
3
(D) tan–1 1
Ans. C
 cot A 
Sol.  cot 1  2
 cot A  1 
1 1
  tan  cot A   tan cot A 3

  cot A   cot A 
=     cot 1  2      tan
1
2

  1  cot A   1  cot A 2
76. If the incircle of a triangle ABC passes through the circumcentre, then value of
(cos A + cos B + cos C)2 is
(A) 1
(B) 2
(C) 2
9
(D)
4
Ans. C
Sol. Distance between circumcentre and incentre = R2  2Rr

 R 2  2Rr  r
r
  2 1
R
77. The minimum value of the expression (t2 + 1 – )2 + (2t –  – 4)2, (t,   R) is
(A) 2
(B) 3
(C) 8
(D) 10
Ans. C
1
Sol. Slope of tangent 1  t = 1 Q
t
224
 P(2, 2)  PQ  2 2 P (1 + t2, 2t)
2
y=x+4

78. In ABC, A = , then the maximum value of sin2 B + sin2 C is
6
(A) 3 1
3
(B) 1
2
3
(C)
2
3
(D) 2
2
Ans. B
 5  3 sin2B  3cos 2B
Sol. sin2 B  sin2   B  = 1
 6  4
4x 2  4x  7
79. If 8 cos y  2
; x  R, then the range of sin2 y + cos y + 1 is
x  x 1
 9
(A) 1, 4 
 
 13 
(B) 1, 4 
 
 9
(C) 2, 4 
 
 13 
(D) 3, 4 
 
Ans. C
3 1
Sol. 8 cos y  4  2
  cos y  1
x  x 1 2
x2 y2
80. Two tangents to the hyperbola   1 having slopes m 1 and m2 cuts the coordinate axes at
100 81
2
four concyclic points. If m 1 and m2 satisfy the equation 2 – 5 + k = 0, then the value of k is
(A) 1
(B) 2
3
(C)
2
5
(D)
4
Ans. B
Sol. m1m2 = 1
81. A parabola is drawn through two given points A(2, 0) and B(–2, 0) such that its directrix always
touch the circle x 2  y 2  16 , then locus of focus of the parabola is
(A) 3x2 + 4y2 = 48
(B) 4x2 + 3y2 = 48
(C) 3x2 + 4y2 = 60
(D) 4x2 + 3y2 = 60
Ans. A
Sol. Let focus be S(h, k), then

(h – 2)2 + k2 = 4(cos  – 2)2 ..... (1)
(h + 2)2 + k2 = 4(cos  + 2)2 ..... (2)
h
 cos  
4
2
2 h  h2 k 2
 h  2  k2  4   2    1
4  16 12
82. The locus of foot of perpendicular from (1, 2) on each member of the family of lines
(1 + 2t)x + (1 – t)y + t – 1 = 0; t  R is
2 2
(A) x + y + x – 3y + 2 = 0
(B) x2 + y2 – x – 3y + 2 = 0
(C) x2 + y2 – x – 3y – 4 = 0
(D) none of these
Ans. B
Sol. Given family passes through the point (0, 1)

k  2 k 1 (h, k)
   1
h 1 h (0, 1)
x(x – 1) + (y – 1)(y – 2) = 0
2 2
x + y – x – 3y + 2 = 0
(1, 2)
x2
83. Consider point P with ordinate t lying on the curve  y 2  1 ; t  N. If Sn represents the
4
minimum distance from point P to the line 2y – x = 0, then lim  t Sn  is
t 
1
(A)
2
3
(B)
4
1
(C)
5
2
(D)
5
Ans. C
Sol. 
P 2 1  t2 , t 
 Sn 
2  1  t  t  = lim t  S
2
= lim
2t  1 t  t =
2
1
(By rationalizing)
n
5 t  t  5 5
84. In ABC, if medians from B and C are mutually perpendicular, then the possible value of
cot B + cot C is
1
(A)
3
2
(B)
5
1
(C)
2
3
(D)
4
Ans. D
y y C
Sol. tan    tan  
x 2x
y y 2y
1  2 2
cotB  x 2x  2x  y E
y y 3xy
 x
x 2x
y
2y 2  x 2  2x
Similarly cot C  
3xy B A
D
x 2  y2 2
 cotB  cot C  
3xy 3
89
1 cot 90k 2
85. If  sin  n  1 k  sinnk  sink
 , then k is given by
3
n 1

(A) n  ; n  I
3

(B) 2n  ; n  I
3

(C) n  ; n  I
6

(D) 2n  ; n  I
6
Ans. B
89
1 1 89 sin   n  1 k  nk 
Sol.  sin n  1 k sinnk = 
sink k 1 sin  n  1 k sinnk
n 1
1 89 cot k cot 90k

=  cot  nk   cot n  1 k  sink  sink
sink n1
cosk 2 
 2
  k  2n  ; n  I
sin k 3 3
86. Let two tangents 3x – 4y + 20 = 0 and x – y – 3 = 0 of a parabola intersect the tangent at vertex at
points P(0, 5) and Q(3, 0) respectively, then the length of latus rectum is
12
(A)
34
18
(B)
34
24
(C)
34
(D) 34
Ans. C
Sol. Focus is (6, –3) and equation of tangent at vertex is 5x + 3y – 15 = 0

30  9  15 24
 LR = 4 
34 34
x2 y2
87. From point P(8, t); t being the parameter, tangents are drawn to the ellipse   1 so as to
16 12
touch the curve at A and B. The locus of the image of P about AB is
(A) x = –4
(B) x+y=2
(C) x = –8
(D) x+y=4
Ans. A
h8 kt
Sol.  2,  0  h = –4
2 2
88. Let the equation of incircle of ABC be 4(x2 + y2) = 25 which touches the sides BC, CA, and AB at
D, E and F respectively. If BD, CE and AF are in AP with common difference 2.5, then the
circumradius of ABC is
(A) 5
(B) 6.25
(C) 7.5
(D) 10
Ans. B
Sol. s = 3x B
r


3x x  d 2
 2
 2.5
2
 x–d x–d
s 3x D F
x=5
 Sides are 7.5, 10, 12.5 x x+d
7.5  10  12.5
 R  6.25
4  37.5 C A
x E x+d

89. The number of solutions of the equation sin1  cos3x   cos 1  sin3x   ; x  [–, ] is/are
2
(A) 2
(B) 3
(C) 5
(D) 6
Ans. D
 
Sol. sin–1(cos 3x) = sin–1(sin 3x)  cos 3x – sin 3x = 0  cos  3x    0
 4
n 
 x  ;nI
3 12
1
90. The lower one-fifth portion of a vertical tower subtends an angle   tan1 at a point A in the
5
horizontal plane through its foot and at a distance 100 m from the foot. If the angle subtended by
the upper four fifth portion of tower at point A is , then  –  is
5
(A) tan1
17
17
(B) tan1
7
7
(C) tan1
17
11
(D) tan1
17
Ans. C
h 1 C
Sol.  tan   
500 5 4
h
 h = 100 m 5
Hence tan( + ) = 1
1 h
tan  
5 2  5
  1  tan   
tan  3 A B
1 100
5
2 1

Also, tan      3 5  7
2 17
1
15

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FIITJEE

ALL INDIA TEST SERIES

 The test consists of total 90 questions.

 Each subject (PCM) has 30 questions.

 This question paper contains Three Parts.

 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

 Each part has only one section: Section-A.

1. An array of point charges and a set of closed Gaussian S2

Sol. Gauss’ Law

2. Two electrons enter a region at same point between charged capacitor +Q –Q

(D) The answer depends on magnitude of the charge, Q on each plate.

3. Five identical light bulbs are connected in a circuit as shown. V

(A) Only Bulb B4

(B) Only Bulb B1 and B3

(C) Only Bulb B3 and B4

(D) Only Bulb B2, B3, and B4

4. An infinite long cylindrical C

6. In the circuit shown, the switch S has been left open 3 k 1 k

(A) The current initially is 12 mA and decreases to a steady 3 mA

(B) The current initially is 3 mA and increases to a steady 12 mA

(C) The current initially is 9 mA and decreases to a steady 3 mA

(D) The current initially is 6 mA and decreases to a steady 3 mA

(A) L = 16.67 H, R = 1.3 k

(C) L = 16.67 H, R = 0.67 k

(D) can’t be calculated

9. An L–R circuit is made so that the AC - input (angular L

Sol. The phasor diagram of the circuit, in operation, is

10. A solenoid of cross sectional area , N turns and length

(A) 2.5 mF, 2H

(D) 2.5 mF, 1 H

Sol. Phasor diagram : I1

Sol. As we know that

14. An external force is applied to move a square loop of dimension 

(A) 0.05 milli coulomb

(B) 0.10 milli coulomb

(C) 0.4 milli coulomb

(D) 1 milli coulomb

17. A cycle followed by an engine (using one mole of an P

18. The figure shows the variation of average Pav

(A) Q1  Q2 and R1  R2 , L1L2  C1C2

(B) Q1  Q2 and R1  R2 , L1C2  L2 C1

(C) Q1  Q2 and R1  R2 , L1C1  L 2 C2

20. Choose the INCORRECT Statement

(B) The diamagnetic property of material is almost independent temperature.

(D) The permeability of a ferromagnetic material depends on the magnetic field.

(A) m1 = 200 gm, m2 = 0 gm,  = –5C

(B) m1 = 87.5 gm, m 2 = 112.5 gm,  = 0C

(C) m1 = 112.5 gm, m 2 = 87.5 gm,  = 0C

(D) m1 = 200 gm, m2 = 0 gm,  = –3C

22. A conducting rod of mass = 1 kg, length = 1m

(C) 2.5 Amp

(D) 0.5 Amp

Sol. 2T sin30  B0i  mg T T

Sol. M Lp L s  5  103  10  103  50  103 H = 7 mH

coil; µ is the magnetic moment of the current in the

The sphere is in translational equilibrium, thus

(C) If current in loop A decreases current in B is clockwise.

(D) If current in loop A increases, current in B will be anticlockwise.

Sol. Apply Lenz’s law