Pre Progression Exam March 2023

64

191774/5 D
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4 Which p-block element contains atoms with one unpaired electron?

A AZ
B Si

C p

D S

Your answer D [1]

5 The equation for a redox reaction is shown below.

2HCZO3 + 2HCZ ---- -► 2CZO2 + Cl 2 + 2H2 O

Which statement is correct?

A CZ is both oxidised and reduced.

B CZ is oxidised and O is reduced.

C O is both oxidised and reduced.

D O is oxidised and Cl is reduced.

Your answer D [1]

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6 Potassium ferrate(VI) contains two potassium ions for every ferrate(VI) ion.

What is the formula of the ferrate(VI) ion?

A Feo/-

B Feo/-

C Feo/-

D Feo/-

Your answer D [1]

7 The unbalanced equation for the reaction of copper with concentrated nitric acid is shown below.

What is the number of moles of HN03 that react with 1 mole of Cu?

A 2

B 3

C 4

D 6

Your answer D [1]

8 2.0dm3 of Cl 2 gas reacts with 2.0dm3 of CZF3 gas to form 6.0dm3 of a gaseous compound.
The reaction has 100% atom economy and all volumes are measured at the same temperature
and pressure.

What is the molecular formula of the compound formed?

A CZF

B CZ2 F3

C CZ3 F2

□
D CZ3 F3

Your answer [1]

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9 Which sample contains the greatest number of molecules?

A 1 g of methanol, CH30H

B 2g of nitrogen dioxide, N02

C 3g of phosphorus, P 4

D 4g of iodine, ! 2

Your answer D [1]

10 Hydrogen and oxygen react as shown below.

Bond enthalpies are shown in the table.

Bond H-H O=O

Bond enthalpy
+436 +498
/kJ moI-1

What is the bond enthalpy, in kJ moI-1, for the 0-H bond?

A +221

B +355

C +464

D +928

Your answer D [1]

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11 Hydrogen gas can be produced as shown below.

11H = +206 kJ moI-1

Which conditions produce the greatest equilibrium yield of hydrogen?

A Low temperature and high pressure

B Low temperature and low pressure

C High temperature and high pressure

D High temperature and low pressure

Your answer D [1 ]

12 The reversible reaction below is in equilibrium.

The equilibrium concentrations are shown in the table.

Substance SO2 (g) Oig) SO3(g)

Equilibrium concentration
4.00 2.40 1.44
/mol dm-3

What is the numerical value of Kc?

A 0.0375

B 0.0540

C 0.150

D 18.5

Your answer D [1]

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13 Which statement is correct for the two structures below?

A They have the same empirical formula.

B They have different relative molecular masses.

C They are structural isomers.

D They have different functional groups.

Your answer D [1]

14 Which property explains the low reactivity of alkanes?

A Electron pair repulsion between a-bonds

B Free rotation about a-bonds

C High C-C bond enthalpy

D High polarity of the C-H bonds

Your answer D [1]

15 Which term correctly describes cyclohexane?

A Arene

B Alkene

C Aliphatic

D Unsaturated

Your answer D [1]

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16 Which substance cannot be made in a single step from C2H4?

A C2H5OH

B C2H5Br

C C2H6

D C2H5NH2

Your answer D [1]

17 A student reacts 24.24 g of 2-bromobutane in the reaction below.

CH3CH2 CHBrCH3 + NaOH � CH3CH2CHOHCH 3 + NaBr

Mr= 136.9 Mr= 74.0

The reaction produces 4.81 g of CH 3CH2CHOHCH 3.

What is the percentage yield of CH3CH2 CHOHCH3?

A 10.7%

B 19.8%

C 36.7%

□
D 54.1%

Your answer [1]

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18 Which substance will not give 3-methylpentane when reduced with hydrogen?

A 2-ethylbut-1-ene
B 3-methylpent-2-ene

C 2-methylpent-1-ene

D 3-methylpent-1-ene

Your answer D [1]

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SECTION B

Answer all the questions.

19 This question is about atoms, isotopes and mass spectrometry.

(a) Complete the table to show the number of electrons that can fill the first four shells.

Shell 1st shell 2nd shell 3rd shell 4th shell

Number of electrons
[1]

(b) Most elements contain atoms of different isotopes.

State any differences and similarities between the atomic structures of isotopes of the same
element.

Differences ................................................................................................................................

Similarities ................................................................................................................................

[2]

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20 This question is about compounds of bromine.

(a) Bromine reacts with phosphorus, P4, to form phosphorus tribromide, PBr 3.

(i) Complete the electron configuration of a bromine atom.

1 s2 ................................................................................................................................ [1]

(ii) Write the equation for the reaction of phosphorus with bromine.

...................................................................................................................................... [1]

(b) A compound of bromine is a solid at room temperature. The electrical conductivity of the
compound at different physical states is shown in the table.

Physical state Electrical conductivity

solid poor
liquid good

Name the type of lattice in the compound at room temperature and explain the different
electrical conductivities.

Name of lattice ..........................................................................................................................

Explanation for different conductivities .....................................................................................

[ 2]

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21 This question is about barium hydroxide.

(a) Barium hydroxide is an alkali which releases hydroxide ions, OH-, in aqueous solution.

A barium hydroxide solution contains 3.89 g of Ba(OH) 2 in 100 cm 3 at 20 cc.

Calculate the concentration of hydroxide ions, OH-, in mol dm-3 , of this solution at 20 cc.

Give your answer to 3 significant figures.

concentration of OH- ions = .......................................... mol dm-3 [3]

(b) A student carries out a titration to determine the concentration of an aqueous solution of
Ba(OH) 2.

The student adds 25.0 cm3 of the Ba(OH) 2 (aq) solution to a conical flask.
The student titrates this solution by adding 0.160 mol dm-3 HNOiaq) from the burette.

The equation is shown below.

The student repeats the titration until concordant titres are obtained.

The mean titre of 0.160 mol dm-3 HNO 3(aq) is 26.75 cm3 .

(i) What is meant by concordant titres?

...................................................................................................................................... [1]

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(ii) Calculate the concentration, in mol dm-3, of the Ba(OHMaq) solution.

concentration of Ba(OH)iaq) = .......................................... mol dm-3 [3]

22 This question is about making ammonia, NH3.

(a) Ammonia is manufactured by reacting nitrogen with hydrogen:

Standard enthalpy changes of combustion, !),. cH 0 , are given in the table.

Substance AcH 0 / kJ mo1- 1

N2(g) +180
H 2(g) -286
NHig) -293

Calculate the standard enthalpy change of formation, !),.fH 0 , for NHig).

!),.fH 0 for NH3(g) = ........................................... kJ mo1-1 [3]

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(b) The industrial manufacture of NH3 from N2 and H 2 is carried out at an increased temperature
and in the presence of a catalyst.

Explain, using Boltzmann distributions, why increasing the temperature and using a catalyst
both increase the reaction rate.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . [5]

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23 This question is about unsaturated hydrocarbons.

(a) Two reactions of propene are shown below.

In the boxes, show the structures of the organic products of the reactions.

H CH3
\C====CI polymerisation

H
I \H
one repeat unit

[3]

(b) Propene also reacts with bromine.

Outline the mechanism for the reaction of propene with bromine, Br2.
The structure of propene has been provided.

Show curly arrows, relevant dipoles and product(s).

H CH3
\C====CI
H
I \H

[4]

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(c) The 'alkynes' is a homologous series of hydrocarbons.

The table shows three alkynes.

Alkyne Structural formula Molecular formula

ethyne H C=C H C2 H 2
propyne C H 3C=C H C3 H 4
but-1-yne C H 3C H 2C=C H C4 H 5

(i) Explain what is meant by the term: homologous series .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . [2]

(ii) Suggest the general formula of the alkynes.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . [1]

(iii) Propyne reacts with bromine to form a saturated compound.

Write an equation for the reaction, showing the structure of the organic product.

[2]
(iv) But-1-yne is a structural isomer of C4 H 6.

Draw the structures of 2 other structural isomers of C4 H 6.

[2]
(v) Draw the structure of 2,5-dimethylhept-3-yne.

[1]

END OF QUESTION PAPER

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