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    DPT 31 Xii Centre Rasi Che Iit Key 07-12-23

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    Deena chemist
    The document discusses various organic chemistry reactions and concepts including: 1. SN1 and SN2 reaction mechanisms and factors that influence their rates such as carbocation stability and nucleophilicity. 2. The reactivity of compounds in SN2 reactions decreases with increased steric hindrance around the leaving group carbon. 3. Aryl halides undergo SN1, not SN2, reactions due to resonance stabilization of the carbon-halogen bond. 4. For a bimolecular nucleophilic substitution reaction, the rate is proportional to the concentration of the reactant and nucleophile.

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    DPT 31 Xii Centre Rasi Che Iit Key 07-12-23

    Uploaded by

    Deena chemist
    23 views4 pages
    The document discusses various organic chemistry reactions and concepts including: 1. SN1 and SN2 reaction mechanisms and factors that influence their rates such as carbocation stability and nucleophilicity. 2. The reactivity of compounds in SN2 reactions decreases with increased steric hindrance around the leaving group carbon. 3. Aryl halides undergo SN1, not SN2, reactions due to resonance stabilization of the carbon-halogen bond. 4. For a bimolecular nucleophilic substitution reaction, the rate is proportional to the concentration of the reactant and nucleophile.

    Original Title

    DPT 31 XII CENTRE RASI CHE IIT KEY 07-12-23

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    The document discusses various organic chemistry reactions and concepts including: 1. SN1 and SN2 reaction mechanisms and factors that influence their rates such as carbocation stability and nucleophilicity. 2. The reactivity of compounds in SN2 reactions decreases with increased steric hindrance around the leaving group carbon. 3. Aryl halides undergo SN1, not SN2, reactions due to resonance stabilization of the carbon-halogen bond. 4. For a bimolecular nucleophilic substitution reaction, the rate is proportional to the concentration of the reactant and nucleophile.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    23 views4 pages

    DPT 31 Xii Centre Rasi Che Iit Key 07-12-23

    Uploaded by

    Deena chemist
    The document discusses various organic chemistry reactions and concepts including: 1. SN1 and SN2 reaction mechanisms and factors that influence their rates such as carbocation stability and nucleophilicity. 2. The reactivity of compounds in SN2 reactions decreases with increased steric hindrance around the leaving group carbon. 3. Aryl halides undergo SN1, not SN2, reactions due to resonance stabilization of the carbon-halogen bond. 4. For a bimolecular nucleophilic substitution reaction, the rate is proportional to the concentration of the reactant and nucleophile.

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    © All Rights Reserved
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    of 4

    PINNAACLE CLASSES

    1. (a)
    SN1 reaction stability of carbocation

    2. (a)

    (i) NaOH, Δ
    (ii ) HNO 3
      
    (iii ) AgNO3
    No ppt.

    (i) NaOH, Δ
    (ii ) HNO
      
    3
    
    (iii ) AgNO3

    3. (b)
    Nucleophilicity order

    4. (b)
    The reactivity of a compound towards SN2 reaction decreases as the crowding at
    the C-atom containing leaving group increases

    5. (a)
    Rate of SN1 reaction stability of carbocation

    6. (c)
    On the basis of carbocation stability.

    7. (c)

    8. (a)

    Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371
    PINNAACLE CLASSES

    In aryl halides the C–X bond has partial double bond character due to resonance so
    it will not give SN reaction.

    9. (c)
    Rate of S N 2∝ [ R−X ] [ Nu ]
    −

    r2
    =
    [
    [ 3 RX ] 1 OH −
    2 ]
    r 1 [ RX ] [ OH − ]
    r 2 =1 .5 r 1

    10. (b)

    PCl
     
    5

    Product is R - 2- Chlorobutane

    11. (b)

      No E2 reaction


     No E2 reaction because b-hydrogen and leaving
    group must not present in anti.

    12. (b)
    CH 3
    —

    CH 3 — CH 2 — N— C H 2— CH 2— CH 3
    —


    OH / 
    CH 3  
     CH
    2= CH2

    13. (d)
    In 4th negative charge is not taking part in conjugation

    Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371
    PINNAACLE CLASSES

    14. (a)

    15. (d)
    is not a strong base so it do not gives E2 reaction.

    16. (b)

    17. (b) Greater the molecular mass, stronger the van der Waal’s forces of attraction
    and hence, higher is the melting point or boiling point.

    18. (b)

    19. (c) Breathing about 900 parts of chloroform per million parts of air (900 parts per
    million ) for a short time can cause dizziness, fatigue and headache.

    20. (b) The reaction of C6H5CH CHCH3 with HBr produces .

    21. 6.00
    Electrophile attack where the electron density high.which shows +M or +1 effects
    are ortho/para directing because they increase electron density at ortho and para

    +M , ,

    The following groups are meta directing , , -OMe, SO3H They

    decreases electron density at ortho/para so, electrophile attack at meta position.

    22. 5
    From (6) product will be Ph-CH3. Others (1 5) will give benzene.

    23. l

    Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371
    PINNAACLE CLASSES

    The electrophile

    is singlet carbene so it has on lone pair.

    24. 3
    The presence of electron-withdrawing groups (like -CN, -COOH, -NO2 ) at o- and
    p-positions with respect to halogen atom activates the aryl halide towards
    nucleophilic substitution reactions.

    25. 4
    There are two stereo centrers.
    So, number of stereoisomers
    =2n
    = 22
    =4

    Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371

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